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NITRILE RUBBER
• Nitrile rubbers are copolymers having
acrylonitrile and butadiene monomers ratios
in the range of 18/82 to 45/55.
H H CN
H2C – C = C - CH2 x [ - H2C – CH2 -]
butadiene Acrylonitrile
•Curative: Sulfur and Peroxide
•Standard Recipe:
Nitrile Rubber :100, Sulfur - 0.40, SRF
black-60, Zinc Oxide – 4, TDQ 1.0, 4020-
1.0, DOP – 7, MBTS – 20, TMTD – 2.0,
Stearic Acid – 0.5.
GRADATION OF NITRILE
RUBBERS
• Acrylonitrile (ACN) content
• Mooney Viscosity
• Hot or Cold Polymerization
• Staining or Non-staining
Increasing Acrylonitirle content results in:
- Better oil resistance
- Better heat resistance
- Higher Tg (poorer low temp. flexibility)
- Lower resilience
- Higher compression set
- Lower air/gas permeability
- Higher elec. Conductivity (lower resistivity)
• Increasing Mooney Viscosity results in:
- better physical properties
- better filler & oil loading capability
- processing more difficult
Modifications of Nitrile
rubbers
1. NBR/PVC blends:
Combines the ozone/weathering properties of PVC with elastomeric
properties of NBR. (Rollers, Hoses, Cable Jackets, Gas Tubing etc.)
2. Crosslinked NBR:
Pre-crosslinked during manufacture for better processing
(LOW EXTRUSION DIE-SWELL, LOW CALENDER SHRINKAGE,
SMOOTH SURFACE)
3. Oil-extended NBR.
Grades extended with DOP plasticizer (usually 50 phr)
4. Carboxylated NBR:
Polymerized with an acidic organic monomer. Gives hard and tough,
abrasion resistant vulcanizates, with lower flexibility and resilience.
(USED IN TEXTILE COTS & APRONS, CONVEYOR BELTS,
INDUSTRIAL SOLES, etc.)
5. Powdered NBR:
Used mainly in plastics modification.
HYDROGENATED NITRILE
RUBBER (HNBR)
Produced by the catalytic hydrogenation of NBR
Manufacturers : Bayer AG - Trade Name: Therban
: Zeon Chemical - Trade Name: Zetpol
Gradation : ACN Content
Mooney Viscosity
Unsaturation – Fully saturated (<1% unsaturation)
Partially unsaturated (2-6% Saturation)
Properties : Very good physical properties – high T.S., abrasion resistance.
: Very good resistance to heat, oxygen, ozone and weathering
compared to NBR.
: Very good resistance to oils containing aggressive additives, crude
oils with H2S and amines.
Applications : Automotive timer belts & poly V-belts
: Oil – seals.
: Oil Industry – blowout preventers- packer seals, drill pipe
protectors, etc.
Butyl Rubber
Butyl rubber is the copolymer of isobutylene with a small amount of
isoprene.
H CH3 H CH3 H CH3 H CH3 H CH3 CH3 H
-C – C = C – C – C – C – C - -C – C – C – C – C = C – C -
H H H CH3 H CH3 H CH3 H CH3 H H
Isoprene Isobutylene
Mol. Wt. 5000
Commercial Butyl Rubber
Grades
Mooney Range Supplier and Grades
ML 1+4
100°C
125°C Mole %
Unsaturation
Exxon
Chemical
company
Polysar Ltd., Canada.
41-49 ---- 0.7-1.0 Exxon Butyl
065
Polysar butyl 100
--- 46-56 0.7-1.0 Exxon Butyl
007
101-3
46-56 1.5-1.8 Exxon Butyl
268
Polysar butyl 301
43-51 ---- 2.0-2.2 Exxon Butyl
365
Polysar Butyl 402
The basic formulation of Butyl Rubber inner tube
Butyl Elastomer 100
Zno 5
St. acid 2
GPF 70
Parafine Oil 25
Sulfur 2.0
TMTD 1.0
MBT 0.5
Cure range – 5’ at 350°F.
This can be cured by resin also & tentative formulation for Tire-
curing bladder compounds are as under:
1 2
Exxon Butyl 268 10
0
10
0
Neoprene GN 5 ---
HAF Carbon black 50 50
Process oil 5 5
Reactive phenol formal dehyde Resin a
10 -
Brominated phenol b
Formaldehyde Resin --- 10
a Amberol St. 137
b : Sp –1055 Schenectady chemical co.
Properties of Butyl:
a) Good Ozone and weather resistance
b) Good vibration Damping characteristic
c) Good air permeability
Modified Butyl Rubber
Halogenated butyl is the elastomeric isobutylene - isoprene
copolymer containing reactive halogen.
- Chlorobutyl
- Bromobutyl
Halogen atoms are in isoprene units shown as under
CH2
CH2 – C - CH - CH2
Br
Curing agent : Zinc Oxide and Stearic acid
Used as – blend with unsaturated rubber.
Application: - 1) Moulded & extruded product
2) Tyre inner liner.

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Nitrile Rubber and rubber system of materials

  • 1. NITRILE RUBBER • Nitrile rubbers are copolymers having acrylonitrile and butadiene monomers ratios in the range of 18/82 to 45/55. H H CN H2C – C = C - CH2 x [ - H2C – CH2 -] butadiene Acrylonitrile
  • 2. •Curative: Sulfur and Peroxide •Standard Recipe: Nitrile Rubber :100, Sulfur - 0.40, SRF black-60, Zinc Oxide – 4, TDQ 1.0, 4020- 1.0, DOP – 7, MBTS – 20, TMTD – 2.0, Stearic Acid – 0.5.
  • 3. GRADATION OF NITRILE RUBBERS • Acrylonitrile (ACN) content • Mooney Viscosity • Hot or Cold Polymerization • Staining or Non-staining Increasing Acrylonitirle content results in: - Better oil resistance - Better heat resistance - Higher Tg (poorer low temp. flexibility) - Lower resilience - Higher compression set - Lower air/gas permeability - Higher elec. Conductivity (lower resistivity)
  • 4. • Increasing Mooney Viscosity results in: - better physical properties - better filler & oil loading capability - processing more difficult
  • 5. Modifications of Nitrile rubbers 1. NBR/PVC blends: Combines the ozone/weathering properties of PVC with elastomeric properties of NBR. (Rollers, Hoses, Cable Jackets, Gas Tubing etc.) 2. Crosslinked NBR: Pre-crosslinked during manufacture for better processing (LOW EXTRUSION DIE-SWELL, LOW CALENDER SHRINKAGE, SMOOTH SURFACE) 3. Oil-extended NBR. Grades extended with DOP plasticizer (usually 50 phr)
  • 6. 4. Carboxylated NBR: Polymerized with an acidic organic monomer. Gives hard and tough, abrasion resistant vulcanizates, with lower flexibility and resilience. (USED IN TEXTILE COTS & APRONS, CONVEYOR BELTS, INDUSTRIAL SOLES, etc.) 5. Powdered NBR: Used mainly in plastics modification.
  • 7. HYDROGENATED NITRILE RUBBER (HNBR) Produced by the catalytic hydrogenation of NBR Manufacturers : Bayer AG - Trade Name: Therban : Zeon Chemical - Trade Name: Zetpol Gradation : ACN Content Mooney Viscosity Unsaturation – Fully saturated (<1% unsaturation) Partially unsaturated (2-6% Saturation)
  • 8. Properties : Very good physical properties – high T.S., abrasion resistance. : Very good resistance to heat, oxygen, ozone and weathering compared to NBR. : Very good resistance to oils containing aggressive additives, crude oils with H2S and amines. Applications : Automotive timer belts & poly V-belts : Oil – seals. : Oil Industry – blowout preventers- packer seals, drill pipe protectors, etc.
  • 9. Butyl Rubber Butyl rubber is the copolymer of isobutylene with a small amount of isoprene. H CH3 H CH3 H CH3 H CH3 H CH3 CH3 H -C – C = C – C – C – C – C - -C – C – C – C – C = C – C - H H H CH3 H CH3 H CH3 H CH3 H H Isoprene Isobutylene Mol. Wt. 5000
  • 10. Commercial Butyl Rubber Grades Mooney Range Supplier and Grades ML 1+4 100°C 125°C Mole % Unsaturation Exxon Chemical company Polysar Ltd., Canada. 41-49 ---- 0.7-1.0 Exxon Butyl 065 Polysar butyl 100 --- 46-56 0.7-1.0 Exxon Butyl 007 101-3 46-56 1.5-1.8 Exxon Butyl 268 Polysar butyl 301 43-51 ---- 2.0-2.2 Exxon Butyl 365 Polysar Butyl 402
  • 11. The basic formulation of Butyl Rubber inner tube Butyl Elastomer 100 Zno 5 St. acid 2 GPF 70 Parafine Oil 25 Sulfur 2.0 TMTD 1.0 MBT 0.5 Cure range – 5’ at 350°F.
  • 12. This can be cured by resin also & tentative formulation for Tire- curing bladder compounds are as under: 1 2 Exxon Butyl 268 10 0 10 0 Neoprene GN 5 --- HAF Carbon black 50 50 Process oil 5 5 Reactive phenol formal dehyde Resin a 10 - Brominated phenol b Formaldehyde Resin --- 10 a Amberol St. 137 b : Sp –1055 Schenectady chemical co. Properties of Butyl: a) Good Ozone and weather resistance b) Good vibration Damping characteristic c) Good air permeability
  • 13. Modified Butyl Rubber Halogenated butyl is the elastomeric isobutylene - isoprene copolymer containing reactive halogen. - Chlorobutyl - Bromobutyl Halogen atoms are in isoprene units shown as under CH2 CH2 – C - CH - CH2 Br Curing agent : Zinc Oxide and Stearic acid Used as – blend with unsaturated rubber. Application: - 1) Moulded & extruded product 2) Tyre inner liner.