This document discusses nitrogen, phosphorus, and potassium nutrition principles for plants. It covers the nitrogen, phosphorus, and potassium cycles, factors affecting their availability, forms taken up by plants, and their roles in plants. For each nutrient, it discusses mineralization, immobilization, fixation, leaching, uptake forms and plant functions. It also addresses soil testing and fertilizer sources for each nutrient.
CONTROLS OF TOXIC ELEMENTS IN ABIOTIC REDUCTIVE DISSOLUTION OF URANIUM MILL R...Mario Alberto Gomez
U mill tailings in northern Saskatchewan, Canada are alkaline (pH 8 to 10) and often contain elevated concentrations of the elements of concern (EOC) As, Se, Mo and Ni. These EOCs are immobilized within the tailings solids by secondary ferrihydrite (FH). Recent analysis of tailings solids (i.e., neutralized mill raffinates and tailings) also showed the presence of a significant reservoir of a secondary Mg-Al hydrotalcite (HTLC) nano-phase which also has been shown to immobilize EOCs. The bonding via EXAFS of Arsenic on HTLC at the final pH 10 stage of the process in the Key Lake mill samples is also not the same as that found for As-FH at lower pH 4-8 found in the Rabbit Lake mill case.
Although the tailings are oxic and have remained so for more than 20 years, concern exists as to impact of the development of anaerobic conditions in the tailings and thus the long-term stability of the EOCs. Research suggests ferrihydrite is unstable under moderately reducing conditions (Eh ~ +100 mV) and may undergo phase transformation resuling in redox active species (e.g., Fe, As, and Se) being released into solution. A series of batch abiotic tests were conducted (7 day and 6 months) to investigate the impact of abiotic (via Fe(II)(aq)) reduction
on the sequestered EOCs in neutralized U-mill raffinates and tailings (pH 8 and 10).
Ssac 353 lecture no. 13 and 14 n fertilizers classification, fate of n fert...DrAnandJadhav
This document discusses nitrogen fertilizers, including their classification, manufacturing processes, properties, and reactions in soil. It covers important nitrogen fertilizers like urea, ammonium sulfate, ammonium nitrate, and calcium ammonium nitrate. For each fertilizer, it describes the manufacturing process, chemical properties, and how they react after application to soil. The document aims to provide an overview of different nitrogen fertilizers for agricultural use.
Ssac 353 lecture no. 18 19 p fertilizers_ classification_manufacturing_fate i...DrAnandJadhav
The document discusses different types of phosphatic fertilizers including their manufacturing processes and properties. It describes how phosphoric acid is produced through wet and furnace processes and used to manufacture superphosphates like single super phosphate (SSP) and triple super phosphate (TSP) by treating rock phosphate with sulfuric acid. Complex fertilizers like monoammonium phosphate (MAP) and diammonium phosphate (DAP) are also produced by reacting phosphoric acid and ammonia. The document provides details on the specifications and production of various phosphatic fertilizers used in India.
First lab managers’ meeting of the South-East Asia Laboratory NETwork (SEALNET 2.0) - Quality improvement in Asian soil laboratories: towards standardization and harmonization of soil analyses and their interpretation, Bogor, Indonesia, 20 - 24 November 2017.
This document provides an overview of nitrogen (N), phosphorus (P), and potassium (K) nutrition principles for plants. It discusses the essential roles of N, P, and K in plants including protein synthesis, energy production, photosynthesis, and growth. The key cycles and processes involving N, P, and K in soils are summarized, including mineralization, nitrification, fixation, leaching, precipitation, and adsorption. Soil testing methods and interpreting results for N, P, and K are covered. Commercial fertilizer sources of N, P, and K are also mentioned.
nutrition principles introduction and principlesjntuhcej
This document provides an overview of nitrogen (N), phosphorus (P), and potassium (K) nutrition principles for plants. It discusses the essential roles of N, P, and K in plants including protein synthesis, nucleic acids, chlorophyll (N), ATP, DNA/RNA (P), and enzyme activation, water relations (K). The key cycles and processes are described such as nitrogen fixation, mineralization, nitrification, denitrification (N cycle) and interactions between soil solution and organic/inorganic pools (P cycle). Optimal soil testing levels and deficiency symptoms are covered. Commercial fertilizer sources and forms taken up by plants are also summarized.
Here are the steps to determine the actual elemental composition by weight of a fertilizer labeled 48-72-31:
- 48% is the actual nitrogen (N) content since N is expressed as a percentage.
- 72% is the P2O5 content. To determine the actual P content:
- P2O5 is 43.6% P
- So P = 0.436 x 72% = 31.5%
- 31% is the K2O content. To determine the actual K content:
- K2O is 83% K
- So K = 0.83 x 31% = 25.7%
Therefore, the actual elemental composition by weight of a fertilizer labeled
Effect of chemical composition of crop residues on nitrogen mineralizationHarsha Maluvelu
This document summarizes research on the effect of chemical composition of crop residues on nitrogen mineralization. It discusses three research papers. The first paper examines the chemical composition and nitrogen mineralization rates of 20 plant residues. It finds higher nitrogen and lower lignin/polyphenol residues like Gliricidia sepium release nitrogen rapidly, while lower quality residues like sugarcane immobilize nitrogen. The second paper studies nitrogen mineralization from soil amended with high and low quality residues. The third paper determines decomposition and nitrogen mineralization of individual and mixed maize and soybean residues.
CONTROLS OF TOXIC ELEMENTS IN ABIOTIC REDUCTIVE DISSOLUTION OF URANIUM MILL R...Mario Alberto Gomez
U mill tailings in northern Saskatchewan, Canada are alkaline (pH 8 to 10) and often contain elevated concentrations of the elements of concern (EOC) As, Se, Mo and Ni. These EOCs are immobilized within the tailings solids by secondary ferrihydrite (FH). Recent analysis of tailings solids (i.e., neutralized mill raffinates and tailings) also showed the presence of a significant reservoir of a secondary Mg-Al hydrotalcite (HTLC) nano-phase which also has been shown to immobilize EOCs. The bonding via EXAFS of Arsenic on HTLC at the final pH 10 stage of the process in the Key Lake mill samples is also not the same as that found for As-FH at lower pH 4-8 found in the Rabbit Lake mill case.
Although the tailings are oxic and have remained so for more than 20 years, concern exists as to impact of the development of anaerobic conditions in the tailings and thus the long-term stability of the EOCs. Research suggests ferrihydrite is unstable under moderately reducing conditions (Eh ~ +100 mV) and may undergo phase transformation resuling in redox active species (e.g., Fe, As, and Se) being released into solution. A series of batch abiotic tests were conducted (7 day and 6 months) to investigate the impact of abiotic (via Fe(II)(aq)) reduction
on the sequestered EOCs in neutralized U-mill raffinates and tailings (pH 8 and 10).
Ssac 353 lecture no. 13 and 14 n fertilizers classification, fate of n fert...DrAnandJadhav
This document discusses nitrogen fertilizers, including their classification, manufacturing processes, properties, and reactions in soil. It covers important nitrogen fertilizers like urea, ammonium sulfate, ammonium nitrate, and calcium ammonium nitrate. For each fertilizer, it describes the manufacturing process, chemical properties, and how they react after application to soil. The document aims to provide an overview of different nitrogen fertilizers for agricultural use.
Ssac 353 lecture no. 18 19 p fertilizers_ classification_manufacturing_fate i...DrAnandJadhav
The document discusses different types of phosphatic fertilizers including their manufacturing processes and properties. It describes how phosphoric acid is produced through wet and furnace processes and used to manufacture superphosphates like single super phosphate (SSP) and triple super phosphate (TSP) by treating rock phosphate with sulfuric acid. Complex fertilizers like monoammonium phosphate (MAP) and diammonium phosphate (DAP) are also produced by reacting phosphoric acid and ammonia. The document provides details on the specifications and production of various phosphatic fertilizers used in India.
First lab managers’ meeting of the South-East Asia Laboratory NETwork (SEALNET 2.0) - Quality improvement in Asian soil laboratories: towards standardization and harmonization of soil analyses and their interpretation, Bogor, Indonesia, 20 - 24 November 2017.
This document provides an overview of nitrogen (N), phosphorus (P), and potassium (K) nutrition principles for plants. It discusses the essential roles of N, P, and K in plants including protein synthesis, energy production, photosynthesis, and growth. The key cycles and processes involving N, P, and K in soils are summarized, including mineralization, nitrification, fixation, leaching, precipitation, and adsorption. Soil testing methods and interpreting results for N, P, and K are covered. Commercial fertilizer sources of N, P, and K are also mentioned.
nutrition principles introduction and principlesjntuhcej
This document provides an overview of nitrogen (N), phosphorus (P), and potassium (K) nutrition principles for plants. It discusses the essential roles of N, P, and K in plants including protein synthesis, nucleic acids, chlorophyll (N), ATP, DNA/RNA (P), and enzyme activation, water relations (K). The key cycles and processes are described such as nitrogen fixation, mineralization, nitrification, denitrification (N cycle) and interactions between soil solution and organic/inorganic pools (P cycle). Optimal soil testing levels and deficiency symptoms are covered. Commercial fertilizer sources and forms taken up by plants are also summarized.
Here are the steps to determine the actual elemental composition by weight of a fertilizer labeled 48-72-31:
- 48% is the actual nitrogen (N) content since N is expressed as a percentage.
- 72% is the P2O5 content. To determine the actual P content:
- P2O5 is 43.6% P
- So P = 0.436 x 72% = 31.5%
- 31% is the K2O content. To determine the actual K content:
- K2O is 83% K
- So K = 0.83 x 31% = 25.7%
Therefore, the actual elemental composition by weight of a fertilizer labeled
Effect of chemical composition of crop residues on nitrogen mineralizationHarsha Maluvelu
This document summarizes research on the effect of chemical composition of crop residues on nitrogen mineralization. It discusses three research papers. The first paper examines the chemical composition and nitrogen mineralization rates of 20 plant residues. It finds higher nitrogen and lower lignin/polyphenol residues like Gliricidia sepium release nitrogen rapidly, while lower quality residues like sugarcane immobilize nitrogen. The second paper studies nitrogen mineralization from soil amended with high and low quality residues. The third paper determines decomposition and nitrogen mineralization of individual and mixed maize and soybean residues.
The document discusses plant nutrition and nutrient uptake. It outlines that plants require essential macronutrients like carbon, hydrogen, oxygen, nitrogen, phosphorus, and sulfur, and micronutrients like chlorine, iron, manganese, boron, zinc, copper, nickel and molybdenum. Nutrient deficiencies can impact plant growth and development. The mechanisms of nutrient absorption from the soil are described, including nitrogen fixation by bacteria and mycorrhizal associations between fungi and plant roots that enhance nutrient and water uptake. Adaptations like nitrogen-fixing root nodules, mycorrhizal relationships, epiphytic growth, parasitism, and carnivory are discussed as ways some
An introduction to professional plant nutrition | Haifa GroupHaifa Group
Explore an in-depth agronomic introduction to plant nutrition. Learn about the essential nutrients crops consume, and the specific role of every mineral on the overall plant growth. Haifa Group’s experts are sharing knowledge. Haifa Group’s experts are sharing knowledge.
This document discusses the transformation of nitrogen, phosphorus, potassium, and sulfur in soils. It describes the key processes involved in each transformation, including mineralization, nitrification, denitrification, immobilization, solubilization, and oxidation/reduction. It notes that microorganisms play a critical role in transforming organic forms of nutrients into plant-available inorganic forms through the secretion of enzymes and organic acids. Specific microbes involved in each transformation are also outlined, such as nitrifying bacteria, phosphate solubilizing bacteria and fungi, potassium solubilizing bacteria, and sulfur oxidizing bacteria.
Phosphate-based fertilizers are produced through various chemical reactions between phosphate rock, acids like phosphoric and sulfuric acid, and bases like ammonia. Common phosphate fertilizers include single super phosphate (SSP), triple super phosphate (TSP), monoammonium phosphate (MAP), and diammonium phosphate (DAP). NPK compound fertilizers contain multiple nutrients and are produced by granulation processes that mix raw materials like ammonium phosphates, urea, and potassium salts.
This document discusses the uses of phosphorus in industry and society. It notes that phosphorus is essential for life and is mainly used in fertilizers worldwide. It describes the production of phosphoric acid from phosphate rock and how this is used to make various fertilizers and feed phosphates. It also outlines some of the major derivatives of elemental phosphorus such as phosphorus pentachloride and how these are used in flame retardants, detergents, pesticides, and other applications. In closing, it discusses the need to design phosphorus uses to make recovery and reuse possible to better manage this essential element across technical and biological cycles.
PHOSPHATIC FERTILIZERS - BEHAVIOR IN SOILS AND MANAGEMENT.pptxAVINASH K
Phosphorus (P) was first discovered by Brandt in 1669. The word is derived from Greek, ‘phos’
meaning light and ‘phorus’ meaning bringing. Phosphorus is a major nutrient next to N and
plays an important role in plant physiology and biochemistry. It is involved in the building blocks,
a component of genetic material (nucleic acids) and an energy currency (ATP) of plants. However,
unlike N and K, P is taken up in smaller quantities by the plants. Further, P contrasts from N with
respect to its transformation in soil after fertilizer P is applied. While N is easily lost from the soil
system, P does not. It is mined from the finite natural resources and the supply is expected to
dwindle in the next 100–150 years. Thus, efficient use of the P fertilizers will play a key role in
sustaining crop production. understanding different forms of soil P and its transformation
in soils and the various factors influencing P availability is crucial. Followed by the role of P in plants,
its absorption and crop P requirements. Understanding Fertilizer P materials and the various
strategies that are needed for efficient use of P are important for field applications.
This document provides information about soil amendments and fertilizers for saucer magnolia plants. It discusses adding compost to improve soil structure and provide nutrients. It also describes various nitrogen, phosphorus, and potassium amendment options and how they can affect soil pH levels. Organic amendments like compost, cottonseed meal, and manure are recommended to feed the plants and enrich the soil over time.
Phosphorus Removal Essentials in wastewater | YSI WebinarXylem Inc.
Are you facing challenges with lower effluent phosphorus limits at your WRRF? YSI experts review phosphorus removal strategies in municipal wastewater applications.
Phosphorus, primarily existing as phosphate, is a nutrient of concern for many wastewater operators. Effluent phosphorus limits continue to be lowered to protect our lakes and rivers from eutrophication. To meet these limits, operators need to improve treatment processes to remove phosphorus as efficiently as possible.
This document discusses phenols, including their:
- Classification into simple phenols, monohydric phenols, dihydric phenols, and trihydric phenols
- Nomenclature and physico-chemical properties such as acidity, hydrogen bonding, and effect of substituents on acidity
- Preparation methods like hydrolysis of diazonium salts, alkali fusion of sulfonates
- Reactions including acidity/salt formation, ester formation, ring substitution, and reactions with formaldehyde
- Qualitative tests for phenols using ferric chloride and Libermann reaction
- Uses of phenol, o-cresol, resorcinol, and
http://www.extension.org/67702 Land application of manure in regions with intense confined livestock and poultry production is an environmental concern when land is limiting because it promotes soil phosphorus (P) surplus and potential pollution of water resources. A net accumulation of soil P results from the disproportion between lower nitrogen (N) and P ratio (N:P) in animal manure and the higher N:P ratio in harvested crops. Although manure can be moved off the farm, its transportation becomes less economical with increasing distances from the source. Thus, management alternatives to land application are needed to resolve agronomic P imbalances for more effective recycling of manure P.
The nitrogen cycle describes the transformation of nitrogen between inorganic and organic forms. Key processes include nitrogen fixation by bacteria and archaea, which converts atmospheric nitrogen to ammonium; ammonification and nitrification, which convert organic and ammonium nitrogen to nitrates; and denitrification, where nitrates are converted back to nitrogen gas and released to the atmosphere. Nitrogen is essential for amino acids, proteins and nucleic acids and cycles through different reservoirs in the biosphere, hydrosphere, lithosphere and atmosphere.
This document discusses several micronutrients that are essential for plant growth including iron, manganese, zinc, copper, boron, molybdenum, chlorine, and nickel. Micronutrients are required by plants in small quantities and include trace elements, minor elements, and oligo elements. Chelates are organic compounds that bond with micronutrients like iron, zinc, copper, and manganese, increasing their solubility and availability to plant roots. The document discusses sources of each micronutrient in soil, factors affecting their availability, functions in plants, and deficiency symptoms.
The document describes the nitrogen cycle, including its various sources, forms, reservoirs, and transformations. Key processes in the nitrogen cycle include nitrogen fixation by bacteria and cyanobacteria; ammonification and mineralization of organic nitrogen into ammonium; nitrification of ammonium to nitrite then nitrate by microbes; and denitrification of nitrates back to nitrogen gas by other microbes under anaerobic conditions. The nitrogen cycle is essential for providing nitrogen, a limiting nutrient, to living organisms and maintaining a balanced global nitrogen reservoir.
The nitrogen cycle describes the transformation of nitrogen between inorganic and organic forms. Key processes include nitrogen fixation by bacteria and archaea, which converts atmospheric nitrogen to ammonium; ammonification and nitrification, which convert organic and ammonium nitrogen to nitrates; and denitrification, where nitrates are converted back to nitrogen gas and released to the atmosphere. Nitrogen is essential for amino acids, proteins and nucleic acids and cycles through different reservoirs in the biosphere, hydrosphere, lithosphere and atmosphere.
Increasing efficiency of ROCK PHOSPHATE on problematic soilssamanyita94
PHOSPHATE ROCK-
Phosphate rock denotes the product obtained from the mining and subsequent metallurgical processing of P-bearing ores.
PRs can be used-
as raw materials in the industrial manufacture of WSP fertilizers,or as P sources for direct application in agriculture
Phosphate rocks as raw materials for P-fertilizer manufacturing:
1.Sulphuric acid and PR are the raw materials used in the production of single superphosphate (SSP) and phosphoric acid.
2.Phosphoric acid is an important intermediate by-product that is used to make triple superphosphate (TSP) and ammonium phosphate.
3.It is used for industrial purposes and for the production of animal feed supplements and food products.
4.used in the manufacture of elemental P and its derivatives, in particular sodium tri-polyphosphate(a major component of heavy-duty laundry detergents).
Rock phosphate for direct application:
As mentioned above, PRs mainly of sedimentary origin are suitable for direct application because they consist of fairly open, loosely consolidated aggregates of micro crystals with a relatively large specific surface area.
They show a considerable proportion of isomorphic substitution in the crystal lattice and contain a variable proportion and amounts of accessory minerals and impurities.
Advantages – less expensive , slow and steady supply of P and More P restoration capacity.
Factors affecting the effectiveness of rock phosphate:
Reactivity of RP: Reactivity is a measure of its rate of dissolution.
Particle size: Finer the particle size, more is the dissolution.
Usually less than 0.15mm.
Soil properties:Low pH (less than 5.5 ), high organic-matter content and low solution concentration of Ca ions.
Soil acidity, Cation exchange capacity, and exchangeable calcium and magnesium, Soil organic matter, Crop species and Soil solution ‘P’ concentration and retension capacity
B. Management practices: PR placement, Rate of PR application, Timing of PR application, Lime application
ways for improving efficiency of rock phosphates:
Depends on various factors:-
the physical and chemical properties of PRs;
soil and climate factors;
plant species and the cropping system; and
farming management practices.
biological,chemical and physical means of increasing efficiency
5 R's of reduce India's dependency on phosphate rock derived P
EWOCS-I: The catalog of X-ray sources in Westerlund 1 from the Extended Weste...Sérgio Sacani
Context. With a mass exceeding several 104 M⊙ and a rich and dense population of massive stars, supermassive young star clusters
represent the most massive star-forming environment that is dominated by the feedback from massive stars and gravitational interactions
among stars.
Aims. In this paper we present the Extended Westerlund 1 and 2 Open Clusters Survey (EWOCS) project, which aims to investigate
the influence of the starburst environment on the formation of stars and planets, and on the evolution of both low and high mass stars.
The primary targets of this project are Westerlund 1 and 2, the closest supermassive star clusters to the Sun.
Methods. The project is based primarily on recent observations conducted with the Chandra and JWST observatories. Specifically,
the Chandra survey of Westerlund 1 consists of 36 new ACIS-I observations, nearly co-pointed, for a total exposure time of 1 Msec.
Additionally, we included 8 archival Chandra/ACIS-S observations. This paper presents the resulting catalog of X-ray sources within
and around Westerlund 1. Sources were detected by combining various existing methods, and photon extraction and source validation
were carried out using the ACIS-Extract software.
Results. The EWOCS X-ray catalog comprises 5963 validated sources out of the 9420 initially provided to ACIS-Extract, reaching a
photon flux threshold of approximately 2 × 10−8 photons cm−2
s
−1
. The X-ray sources exhibit a highly concentrated spatial distribution,
with 1075 sources located within the central 1 arcmin. We have successfully detected X-ray emissions from 126 out of the 166 known
massive stars of the cluster, and we have collected over 71 000 photons from the magnetar CXO J164710.20-455217.
The document discusses plant nutrition and nutrient uptake. It outlines that plants require essential macronutrients like carbon, hydrogen, oxygen, nitrogen, phosphorus, and sulfur, and micronutrients like chlorine, iron, manganese, boron, zinc, copper, nickel and molybdenum. Nutrient deficiencies can impact plant growth and development. The mechanisms of nutrient absorption from the soil are described, including nitrogen fixation by bacteria and mycorrhizal associations between fungi and plant roots that enhance nutrient and water uptake. Adaptations like nitrogen-fixing root nodules, mycorrhizal relationships, epiphytic growth, parasitism, and carnivory are discussed as ways some
An introduction to professional plant nutrition | Haifa GroupHaifa Group
Explore an in-depth agronomic introduction to plant nutrition. Learn about the essential nutrients crops consume, and the specific role of every mineral on the overall plant growth. Haifa Group’s experts are sharing knowledge. Haifa Group’s experts are sharing knowledge.
This document discusses the transformation of nitrogen, phosphorus, potassium, and sulfur in soils. It describes the key processes involved in each transformation, including mineralization, nitrification, denitrification, immobilization, solubilization, and oxidation/reduction. It notes that microorganisms play a critical role in transforming organic forms of nutrients into plant-available inorganic forms through the secretion of enzymes and organic acids. Specific microbes involved in each transformation are also outlined, such as nitrifying bacteria, phosphate solubilizing bacteria and fungi, potassium solubilizing bacteria, and sulfur oxidizing bacteria.
Phosphate-based fertilizers are produced through various chemical reactions between phosphate rock, acids like phosphoric and sulfuric acid, and bases like ammonia. Common phosphate fertilizers include single super phosphate (SSP), triple super phosphate (TSP), monoammonium phosphate (MAP), and diammonium phosphate (DAP). NPK compound fertilizers contain multiple nutrients and are produced by granulation processes that mix raw materials like ammonium phosphates, urea, and potassium salts.
This document discusses the uses of phosphorus in industry and society. It notes that phosphorus is essential for life and is mainly used in fertilizers worldwide. It describes the production of phosphoric acid from phosphate rock and how this is used to make various fertilizers and feed phosphates. It also outlines some of the major derivatives of elemental phosphorus such as phosphorus pentachloride and how these are used in flame retardants, detergents, pesticides, and other applications. In closing, it discusses the need to design phosphorus uses to make recovery and reuse possible to better manage this essential element across technical and biological cycles.
PHOSPHATIC FERTILIZERS - BEHAVIOR IN SOILS AND MANAGEMENT.pptxAVINASH K
Phosphorus (P) was first discovered by Brandt in 1669. The word is derived from Greek, ‘phos’
meaning light and ‘phorus’ meaning bringing. Phosphorus is a major nutrient next to N and
plays an important role in plant physiology and biochemistry. It is involved in the building blocks,
a component of genetic material (nucleic acids) and an energy currency (ATP) of plants. However,
unlike N and K, P is taken up in smaller quantities by the plants. Further, P contrasts from N with
respect to its transformation in soil after fertilizer P is applied. While N is easily lost from the soil
system, P does not. It is mined from the finite natural resources and the supply is expected to
dwindle in the next 100–150 years. Thus, efficient use of the P fertilizers will play a key role in
sustaining crop production. understanding different forms of soil P and its transformation
in soils and the various factors influencing P availability is crucial. Followed by the role of P in plants,
its absorption and crop P requirements. Understanding Fertilizer P materials and the various
strategies that are needed for efficient use of P are important for field applications.
This document provides information about soil amendments and fertilizers for saucer magnolia plants. It discusses adding compost to improve soil structure and provide nutrients. It also describes various nitrogen, phosphorus, and potassium amendment options and how they can affect soil pH levels. Organic amendments like compost, cottonseed meal, and manure are recommended to feed the plants and enrich the soil over time.
Phosphorus Removal Essentials in wastewater | YSI WebinarXylem Inc.
Are you facing challenges with lower effluent phosphorus limits at your WRRF? YSI experts review phosphorus removal strategies in municipal wastewater applications.
Phosphorus, primarily existing as phosphate, is a nutrient of concern for many wastewater operators. Effluent phosphorus limits continue to be lowered to protect our lakes and rivers from eutrophication. To meet these limits, operators need to improve treatment processes to remove phosphorus as efficiently as possible.
This document discusses phenols, including their:
- Classification into simple phenols, monohydric phenols, dihydric phenols, and trihydric phenols
- Nomenclature and physico-chemical properties such as acidity, hydrogen bonding, and effect of substituents on acidity
- Preparation methods like hydrolysis of diazonium salts, alkali fusion of sulfonates
- Reactions including acidity/salt formation, ester formation, ring substitution, and reactions with formaldehyde
- Qualitative tests for phenols using ferric chloride and Libermann reaction
- Uses of phenol, o-cresol, resorcinol, and
http://www.extension.org/67702 Land application of manure in regions with intense confined livestock and poultry production is an environmental concern when land is limiting because it promotes soil phosphorus (P) surplus and potential pollution of water resources. A net accumulation of soil P results from the disproportion between lower nitrogen (N) and P ratio (N:P) in animal manure and the higher N:P ratio in harvested crops. Although manure can be moved off the farm, its transportation becomes less economical with increasing distances from the source. Thus, management alternatives to land application are needed to resolve agronomic P imbalances for more effective recycling of manure P.
The nitrogen cycle describes the transformation of nitrogen between inorganic and organic forms. Key processes include nitrogen fixation by bacteria and archaea, which converts atmospheric nitrogen to ammonium; ammonification and nitrification, which convert organic and ammonium nitrogen to nitrates; and denitrification, where nitrates are converted back to nitrogen gas and released to the atmosphere. Nitrogen is essential for amino acids, proteins and nucleic acids and cycles through different reservoirs in the biosphere, hydrosphere, lithosphere and atmosphere.
This document discusses several micronutrients that are essential for plant growth including iron, manganese, zinc, copper, boron, molybdenum, chlorine, and nickel. Micronutrients are required by plants in small quantities and include trace elements, minor elements, and oligo elements. Chelates are organic compounds that bond with micronutrients like iron, zinc, copper, and manganese, increasing their solubility and availability to plant roots. The document discusses sources of each micronutrient in soil, factors affecting their availability, functions in plants, and deficiency symptoms.
The document describes the nitrogen cycle, including its various sources, forms, reservoirs, and transformations. Key processes in the nitrogen cycle include nitrogen fixation by bacteria and cyanobacteria; ammonification and mineralization of organic nitrogen into ammonium; nitrification of ammonium to nitrite then nitrate by microbes; and denitrification of nitrates back to nitrogen gas by other microbes under anaerobic conditions. The nitrogen cycle is essential for providing nitrogen, a limiting nutrient, to living organisms and maintaining a balanced global nitrogen reservoir.
The nitrogen cycle describes the transformation of nitrogen between inorganic and organic forms. Key processes include nitrogen fixation by bacteria and archaea, which converts atmospheric nitrogen to ammonium; ammonification and nitrification, which convert organic and ammonium nitrogen to nitrates; and denitrification, where nitrates are converted back to nitrogen gas and released to the atmosphere. Nitrogen is essential for amino acids, proteins and nucleic acids and cycles through different reservoirs in the biosphere, hydrosphere, lithosphere and atmosphere.
Increasing efficiency of ROCK PHOSPHATE on problematic soilssamanyita94
PHOSPHATE ROCK-
Phosphate rock denotes the product obtained from the mining and subsequent metallurgical processing of P-bearing ores.
PRs can be used-
as raw materials in the industrial manufacture of WSP fertilizers,or as P sources for direct application in agriculture
Phosphate rocks as raw materials for P-fertilizer manufacturing:
1.Sulphuric acid and PR are the raw materials used in the production of single superphosphate (SSP) and phosphoric acid.
2.Phosphoric acid is an important intermediate by-product that is used to make triple superphosphate (TSP) and ammonium phosphate.
3.It is used for industrial purposes and for the production of animal feed supplements and food products.
4.used in the manufacture of elemental P and its derivatives, in particular sodium tri-polyphosphate(a major component of heavy-duty laundry detergents).
Rock phosphate for direct application:
As mentioned above, PRs mainly of sedimentary origin are suitable for direct application because they consist of fairly open, loosely consolidated aggregates of micro crystals with a relatively large specific surface area.
They show a considerable proportion of isomorphic substitution in the crystal lattice and contain a variable proportion and amounts of accessory minerals and impurities.
Advantages – less expensive , slow and steady supply of P and More P restoration capacity.
Factors affecting the effectiveness of rock phosphate:
Reactivity of RP: Reactivity is a measure of its rate of dissolution.
Particle size: Finer the particle size, more is the dissolution.
Usually less than 0.15mm.
Soil properties:Low pH (less than 5.5 ), high organic-matter content and low solution concentration of Ca ions.
Soil acidity, Cation exchange capacity, and exchangeable calcium and magnesium, Soil organic matter, Crop species and Soil solution ‘P’ concentration and retension capacity
B. Management practices: PR placement, Rate of PR application, Timing of PR application, Lime application
ways for improving efficiency of rock phosphates:
Depends on various factors:-
the physical and chemical properties of PRs;
soil and climate factors;
plant species and the cropping system; and
farming management practices.
biological,chemical and physical means of increasing efficiency
5 R's of reduce India's dependency on phosphate rock derived P
EWOCS-I: The catalog of X-ray sources in Westerlund 1 from the Extended Weste...Sérgio Sacani
Context. With a mass exceeding several 104 M⊙ and a rich and dense population of massive stars, supermassive young star clusters
represent the most massive star-forming environment that is dominated by the feedback from massive stars and gravitational interactions
among stars.
Aims. In this paper we present the Extended Westerlund 1 and 2 Open Clusters Survey (EWOCS) project, which aims to investigate
the influence of the starburst environment on the formation of stars and planets, and on the evolution of both low and high mass stars.
The primary targets of this project are Westerlund 1 and 2, the closest supermassive star clusters to the Sun.
Methods. The project is based primarily on recent observations conducted with the Chandra and JWST observatories. Specifically,
the Chandra survey of Westerlund 1 consists of 36 new ACIS-I observations, nearly co-pointed, for a total exposure time of 1 Msec.
Additionally, we included 8 archival Chandra/ACIS-S observations. This paper presents the resulting catalog of X-ray sources within
and around Westerlund 1. Sources were detected by combining various existing methods, and photon extraction and source validation
were carried out using the ACIS-Extract software.
Results. The EWOCS X-ray catalog comprises 5963 validated sources out of the 9420 initially provided to ACIS-Extract, reaching a
photon flux threshold of approximately 2 × 10−8 photons cm−2
s
−1
. The X-ray sources exhibit a highly concentrated spatial distribution,
with 1075 sources located within the central 1 arcmin. We have successfully detected X-ray emissions from 126 out of the 166 known
massive stars of the cluster, and we have collected over 71 000 photons from the magnetar CXO J164710.20-455217.
The debris of the ‘last major merger’ is dynamically youngSérgio Sacani
The Milky Way’s (MW) inner stellar halo contains an [Fe/H]-rich component with highly eccentric orbits, often referred to as the
‘last major merger.’ Hypotheses for the origin of this component include Gaia-Sausage/Enceladus (GSE), where the progenitor
collided with the MW proto-disc 8–11 Gyr ago, and the Virgo Radial Merger (VRM), where the progenitor collided with the
MW disc within the last 3 Gyr. These two scenarios make different predictions about observable structure in local phase space,
because the morphology of debris depends on how long it has had to phase mix. The recently identified phase-space folds in Gaia
DR3 have positive caustic velocities, making them fundamentally different than the phase-mixed chevrons found in simulations
at late times. Roughly 20 per cent of the stars in the prograde local stellar halo are associated with the observed caustics. Based
on a simple phase-mixing model, the observed number of caustics are consistent with a merger that occurred 1–2 Gyr ago.
We also compare the observed phase-space distribution to FIRE-2 Latte simulations of GSE-like mergers, using a quantitative
measurement of phase mixing (2D causticality). The observed local phase-space distribution best matches the simulated data
1–2 Gyr after collision, and certainly not later than 3 Gyr. This is further evidence that the progenitor of the ‘last major merger’
did not collide with the MW proto-disc at early times, as is thought for the GSE, but instead collided with the MW disc within
the last few Gyr, consistent with the body of work surrounding the VRM.
Travis Hills of MN is Making Clean Water Accessible to All Through High Flux ...Travis Hills MN
By harnessing the power of High Flux Vacuum Membrane Distillation, Travis Hills from MN envisions a future where clean and safe drinking water is accessible to all, regardless of geographical location or economic status.
The binding of cosmological structures by massless topological defectsSérgio Sacani
Assuming spherical symmetry and weak field, it is shown that if one solves the Poisson equation or the Einstein field
equations sourced by a topological defect, i.e. a singularity of a very specific form, the result is a localized gravitational
field capable of driving flat rotation (i.e. Keplerian circular orbits at a constant speed for all radii) of test masses on a thin
spherical shell without any underlying mass. Moreover, a large-scale structure which exploits this solution by assembling
concentrically a number of such topological defects can establish a flat stellar or galactic rotation curve, and can also deflect
light in the same manner as an equipotential (isothermal) sphere. Thus, the need for dark matter or modified gravity theory is
mitigated, at least in part.
The cost of acquiring information by natural selectionCarl Bergstrom
This is a short talk that I gave at the Banff International Research Station workshop on Modeling and Theory in Population Biology. The idea is to try to understand how the burden of natural selection relates to the amount of information that selection puts into the genome.
It's based on the first part of this research paper:
The cost of information acquisition by natural selection
Ryan Seamus McGee, Olivia Kosterlitz, Artem Kaznatcheev, Benjamin Kerr, Carl T. Bergstrom
bioRxiv 2022.07.02.498577; doi: https://doi.org/10.1101/2022.07.02.498577
Mending Clothing to Support Sustainable Fashion_CIMaR 2024.pdfSelcen Ozturkcan
Ozturkcan, S., Berndt, A., & Angelakis, A. (2024). Mending clothing to support sustainable fashion. Presented at the 31st Annual Conference by the Consortium for International Marketing Research (CIMaR), 10-13 Jun 2024, University of Gävle, Sweden.
Discovery of An Apparent Red, High-Velocity Type Ia Supernova at 𝐳 = 2.9 wi...Sérgio Sacani
We present the JWST discovery of SN 2023adsy, a transient object located in a host galaxy JADES-GS
+
53.13485
−
27.82088
with a host spectroscopic redshift of
2.903
±
0.007
. The transient was identified in deep James Webb Space Telescope (JWST)/NIRCam imaging from the JWST Advanced Deep Extragalactic Survey (JADES) program. Photometric and spectroscopic followup with NIRCam and NIRSpec, respectively, confirm the redshift and yield UV-NIR light-curve, NIR color, and spectroscopic information all consistent with a Type Ia classification. Despite its classification as a likely SN Ia, SN 2023adsy is both fairly red (
�
(
�
−
�
)
∼
0.9
) despite a host galaxy with low-extinction and has a high Ca II velocity (
19
,
000
±
2
,
000
km/s) compared to the general population of SNe Ia. While these characteristics are consistent with some Ca-rich SNe Ia, particularly SN 2016hnk, SN 2023adsy is intrinsically brighter than the low-
�
Ca-rich population. Although such an object is too red for any low-
�
cosmological sample, we apply a fiducial standardization approach to SN 2023adsy and find that the SN 2023adsy luminosity distance measurement is in excellent agreement (
≲
1
�
) with
Λ
CDM. Therefore unlike low-
�
Ca-rich SNe Ia, SN 2023adsy is standardizable and gives no indication that SN Ia standardized luminosities change significantly with redshift. A larger sample of distant SNe Ia is required to determine if SN Ia population characteristics at high-
�
truly diverge from their low-
�
counterparts, and to confirm that standardized luminosities nevertheless remain constant with redshift.
Evidence of Jet Activity from the Secondary Black Hole in the OJ 287 Binary S...Sérgio Sacani
Wereport the study of a huge optical intraday flare on 2021 November 12 at 2 a.m. UT in the blazar OJ287. In the binary black hole model, it is associated with an impact of the secondary black hole on the accretion disk of the primary. Our multifrequency observing campaign was set up to search for such a signature of the impact based on a prediction made 8 yr earlier. The first I-band results of the flare have already been reported by Kishore et al. (2024). Here we combine these data with our monitoring in the R-band. There is a big change in the R–I spectral index by 1.0 ±0.1 between the normal background and the flare, suggesting a new component of radiation. The polarization variation during the rise of the flare suggests the same. The limits on the source size place it most reasonably in the jet of the secondary BH. We then ask why we have not seen this phenomenon before. We show that OJ287 was never before observed with sufficient sensitivity on the night when the flare should have happened according to the binary model. We also study the probability that this flare is just an oversized example of intraday variability using the Krakow data set of intense monitoring between 2015 and 2023. We find that the occurrence of a flare of this size and rapidity is unlikely. In machine-readable Tables 1 and 2, we give the full orbit-linked historical light curve of OJ287 as well as the dense monitoring sample of Krakow.
JAMES WEBB STUDY THE MASSIVE BLACK HOLE SEEDSSérgio Sacani
The pathway(s) to seeding the massive black holes (MBHs) that exist at the heart of galaxies in the present and distant Universe remains an unsolved problem. Here we categorise, describe and quantitatively discuss the formation pathways of both light and heavy seeds. We emphasise that the most recent computational models suggest that rather than a bimodal-like mass spectrum between light and heavy seeds with light at one end and heavy at the other that instead a continuum exists. Light seeds being more ubiquitous and the heavier seeds becoming less and less abundant due the rarer environmental conditions required for their formation. We therefore examine the different mechanisms that give rise to different seed mass spectrums. We show how and why the mechanisms that produce the heaviest seeds are also among the rarest events in the Universe and are hence extremely unlikely to be the seeds for the vast majority of the MBH population. We quantify, within the limits of the current large uncertainties in the seeding processes, the expected number densities of the seed mass spectrum. We argue that light seeds must be at least 103 to 105 times more numerous than heavy seeds to explain the MBH population as a whole. Based on our current understanding of the seed population this makes heavy seeds (Mseed > 103 M⊙) a significantly more likely pathway given that heavy seeds have an abundance pattern than is close to and likely in excess of 10−4 compared to light seeds. Finally, we examine the current state-of-the-art in numerical calculations and recent observations and plot a path forward for near-future advances in both domains.
4. Role in Plants
• Protein
• Nucleic acid
• Chlorophyll
• Carbohydrate
utilization
Four nitrogenous bases –
adenine (A), thymine (T), guanine
(G), and cytosine (C) are
components in the DNA double
helix.
5. Forms Plants Uptake
Ammonia
• Plants uptake both forms.
• Uptake NO3
-
the most.
• NO3
-
is mobile, NH4 is not.
• NO3- prefers acidic pH.
• NH4
+
prefers neutral pH.
• Combination is better.
Which form is vulnerable to leaching losses?
Nitrate
6. Nitrogen Cycle
• N in soil enters, exits, and changes
forms in many ways.
• Can you name some of the processes
and pools in N cycles?
mineralization, immobilization,
nitrification, denitrification, nitrogen
fixation, nitrogen leaching…
13. Fertilizer Nitrogen
• Nitrogen fertilizer should be
added to the soil when the crop
will use it, adding excess N will
cause losses that may harm the
environment.
• Nitrogen is expensive and using
only what the crop needs for
adequate growth is important -
• THUS it becomes important to
give N - CREDITS for previous
management (legumes, manure or
other organic additions with low
C:N ratios).
Wheat with N response
14. Nitrogen soil testing
• Mobile nutrient
• In drier areas use a
fall or spring nitrate-
N soil test.
• In humid areas, use
spring nitrate-N test
or table value based on
previous crop and
organic matter.
15. Nitrogen soil testing
• After arriving at N
recommendation then
credits need to be taken
for:
– Previous crop
– Previous manure
applications or sludge
– 2nd
year after alfalfa
18. Chlorophyll
DNA and RNA
Protein
}
NH2
N molecules from
this amino group
NH2
NH2
NH2
When organic matter
decomposes, N-containing
molecules are released from
H
H
combine with H to
produce NH3 and NH4
NH3 + H = NH4
-
Ammonium
19. Chlorophyll
DNA and RNA
Protein
}
NH2
First they make
this gas, then
NH2
NH2
NH2 NH3
H
H+
H
+ NH4
AmmoniumAmmonia
(gas)
=
The simple steps in the mineralization process are now complete.
The process is also called ammonification.
When organic matter
decomposes, N-containing
molecules are released from
20. Denitrification
N2
Biologicaland
Chemical
Fixation
NH3 + H+
= NH4
Clay Fixation
and Release
NO3
N2
N2O
Immobilization
(use by the plant)
NITROGEN
Oxidation of NH4 to NO3 is
nitrification.
Nitrobactor
Nitrosomonas
Nitrification
NO2
Two kinds of bacteria are
involved in two steps.
21. Denitrification
N2
Biologicaland
Chemical
Fixation
NH3 + H+
= NH4
Clay Fixation
and Release
NO3
N2
N2O
Immobilization
(use by the plant) NITROGEN
In water-logged soil, NO3
transforms to gaseous N, and
this loss to air is denitrification.
Nitrobactor
Nitrosomonas
Nitrification
NO2
Steps: NO2--NO--N2O and N2
24. Sources of N in Wheat
• Organic – residue breakdown (slow)
• Organic manures (N content varies)
• Commercial
– Urea
– Ammonia
– Monoammonium phosphate (MAP)/diammonium
phosphate (DAP)
– Potassium nitrate
– URAN (urea + ammonium nitrate) solutions
– Ammonium nitrate
More discussion in Sections 4 and 5
25.
26. P Nutrition Principles
How the materials will be presented
P-cycle
Key
Factors
Sources
Forms
uptake
Role in
plant
P
27. P Essentiality
• Second most important
nutrient
• Its concentration in soil
solution is low
• Low solubility
• Low availability
• Low mobility
Nutrient Amount in
Solution (mg/L)
NO3
-
60
NH4
+
--
H2
PO4
-
, HPO4
2-
0.8
K+
14
Ca2+
60
Mg2+
40
SO4
2-
26
are key characteristics for
better management
28. Role in Plants
• ATP
• DNA/RNA
• Enhance crop maturity
• Root growth
Can you
justify how
P is
important
in these
29. Role in Plants
• ATP
• DNA/RNA
• Enhance crop maturity
• Root growth P is a critical component of
cell’s energy currency, ATP
30. Role in Plants
• ATP
• DNA/RNA
• Enhance crop maturity
• Root growth
P containing sugar
phosphate is the
backbone of DNA
31. Orthophosphate ions: H2PO4
-
& HPO4
2-
Plant Available Forms
7.2 pH
Availability is pH dependent
Both species are even at this pH
32. Phosphorus Cycle
• Not involved in atmospheric exchanges
• Cycles among various pools
– Soil solution
– Organic matter
– Inorganic minerals
• Interaction among pools is complex.
• Knowledge of each pool is necessary.
33. Phosphorus Cycle
Secondary
Minerals
Fe & Al PO4
CaPO4
Nonlabile P
Primary
Minerals
(Nonlabile P)
Solution P
H2PO4
-
HPO4
2-
Microbial-
P
bacteriaFungi
nematode
Plant residue
Labile P
Adsorbed
P
Dissolution
Dissolution
Precipitation
Adsorption
Desorption
Immobilization
Mineralization
Fertilizer-P
Soil Organic
Matter
Microbial P
(Nonalabile P)
(Labile P)
1. Soil Solution: plant uptake poolAdsorption and DesorptionPrecipitation and DissolutionMineralization and Immobilization
SOIL SOLUTION POOL
INTERACTIONS
34. Phosphorus Cycle
Secondary
Minerals
Fe & Al PO4
CaPO4
Nonlabile P
Primary
Minerals
(Nonlabile P)
Solution P
H2PO4
-
HPO4
2-
Microbial-
P
bacteriaFungi
nematode
Plant residue
Labile P
Adsorbed
P
Dissolution
Dissolution
Precipitation
Adsorption
Desorption
Immobilization
Mineralization
Fertilizer-P
Soil Organic
Matter
Microbial P
(Nonalabile P)
(Labile P)
Crop residue
and organic
matter release
P by
mineralization
Various factor
affects rate of
mineralization
including C/P
ratio
Net
immobilization
(available for
plant uptake) at
C/P >300
ORGANIC POOL
INTERACTIONS
What is good – high or low C/P?
Why?
35. Organic-P, quick facts
• P of organic matter range
between 1% and 3%
• Organic P is ~50% of total
P in soil
• Organic P decreases with
soil depth
• Organic-P increases with
increased organic-C (the
C/P, likewise N and C/N)
36. Phosphorus Cycle
Secondary
Minerals
Fe & Al PO4
CaPO4
Nonlabile P
Primary
Minerals
(Nonlabile P)
Solution P
H2PO4
-
HPO4
2-
Microbial-
P
bacteriaFungi
nematode
Plant residue
Labile P
Adsorbed
P
Dissolution
Dissolution
Precipitation
Adsorption
Desorption
Immobilization
Mineralization
Fertilizer-P
Soil Organic
Matter
Microbial P
(Nonalabile P)
(Labile P)
INORGANIC POOL
INTERACTIONS
Inorganic P fixed or released by
primary and secondary minerals
37. P
• Soil test for P (Bray pH<7.4 of soil)
• 0-5 ppm = very low
• 6-10 ppm = LOW
• 11-15 ppm = med
• 16-20 ppm = high
• > =21 ppm = very high
• No reason to have soil
test > 21
• environmental problems
when P >16
• ppm x 2 = lbs/acre
P deficient tomato
38. Soil P
• Crops need more P than is
dissolved in the soil solution at any
one time, therefore, this P in the
solution phase must be replenished
many times during the growing
season.
• The ability of a soil to maintain
adequate levels of phosphorus in
the solution phase is the key to
the plant available P status of the
soil. The solid phase P is both
organic and inorganic
Solid P Phase Solution Phase Root Hair
P deficiency reduces root growth
39. Inorganic-P, quick facts
• Low concentration & solubility of P due to slow
release and fixation
• Minerals mainly with Ca, in alkaline soils
• Minerals with Fe, Al, and Mg in acidic soils
•
40. Solubility of P-containing compounds
Compound Formula Compound type
Monocalcium phosphate
Dicalcium phosphate
Octacalcium phosphate
Tricalcium phosphate
Oxy apatite
Hydroxy apatite
Carbonate apatite
Fluorapatite
Ca(H2
PO4
)2
.H2
O
CaHPO4
.2H2
O
Ca8
H2
(PO4
)6
.5H2
O
Ca3
(PO4
)2
[3Ca3
(PO4
)2
].CaO
[3Ca3
(PO4
)2
].Ca(OH)2
[3Ca3
(PO4
)2
].CaCO3
3Ca3
(PO4
)2
].CaF2
Calcium
Strengite FePO4
-2H2
O Iron
Variscite AlPO4
-2H2
O Aluminum
• Ca-phosphate - major contributor in alkaline
soils
• pH determines its availability
• Solubility decreases in order of: mono >
di > tri calcium phosphates
44. P Essentiality Principles
• Plant absorbs larger amount of K next
only to N
• Plant tissue K: ~2.5% to 4.5% leaf dry
wt.
• Soil K: 0.5% to 2.5%
• Most soil K’s are tied up, availability is
often limited
45. Role in Plants
• Enzyme activation
• Water relations
(stomatal control)
• Energy relations
• Translocation (sugar
transport)
• Crop quality
Justify
how K is
important
in these
46. Role in Plants
• Enzyme activation
• K activates at least 60 enzymes in cell
• K level determines reactions catalyzed by enzymes
47. Potassium Fertility (Potash)
• Potassium (K+) is a problem
on acid soils, soils with low
CEC and with irrigation or
high rainfall where leaching
can readily occur.
• Potassium can be stored in
the soil from one year to
the next
• K is not a pollutant - even if
leached from soil, K does
not cause environmental
problems.
K deficient corn
48. Role in Plants
• Water relations
– K regulates stomatal
opening
K is critical to stomatal opening and closure in
regulating gas exchanges (CO2 in and H2O out)
49. Role in Plants
• Energy relations
– K is required for production of ATP
• Crop quality
– Increases root growth
– Enhances translocation of sugar
– Increase protein content in plant
– Reduces lodging
50. Forms uptake
K+
Soil K Pools and Concentrations
Mineral…………..… 5000 – 25000 ppm
Non-exchangeable…...….50 – 750 ppm
Exchangeable…………..400 – 600 ppm
Solution……………...………1 – 10 ppm
K-Cycle will show
interaction among pools
51. K forms - characteristics
1. Mineral – K : Minerals like
Mica, Feldspar, K is mainly
unavailable
2. Non-exchangeable – K : K in
secondary minerals like vermiculite
or colloidal-size mica, K is slowly
available
……more
52. In the non-exchangeable fraction of K
Most K
trapped
K slowly available K is widely
exchangeable
53. K forms - characteristics
3. Exchangeable-K: K on the cation
exchange sites of soil colloids is
readily available
54. K forms - characteristics
4. Soil solution-K: K is readily
available. Range in most cropland
soils ~ 1-10ppm.
~80% K plant uptake by diffusion,
availability depends of many
factors
55. Exchangeable K+
K+
K+
K+
K+
K+
K+
K+
Nonexchangeable K+
Plant &
animal
residues
2:1 Clay minerals
Soil solution
K+
Plant uptake
Desorption
Adsorption
Weathering
90-98%
0.1-0.2%
1-2%1-10%
ErosionLeaching
Feldspar
Mica
Primary
minerals
K
Mineral-K, mostly
unavailable, accounts
for majority of soil K
K
Non-exchangeable-K,
in secondary minerals, slowly
available, 2:1 clay
K
Exchangeable-K,
readily available, K
in cation exchange
site…
56. Exchangeable K+
K+
K+
K+
K+
K+
K+
K+
Nonexchangeable K+
2:1 Clay minerals
Soil solution
K+
Plant uptake
Desorption
Adsorption
Plant/
animal
residues
Weathering
90-98%
0.1-0.2%
1-2%1-10%
ErosionLeaching
Feldspar
Mica
Primary
minerals
K
K K
Residue K recovery is
minor, usually leach out
K leaching loss is often substantial
57. K Cycle Quick Fact
• K transfer from minerals is slow but
continuous
• Exchangeable and soluble K equilibrate
rapidly
• Fixed K equilibrate very slowly
• Transfer from mineral to other form is
very slow, usually unavailable (in one
crop year)
58. K Fixation – who is involved?
• Reentrapment of K ions between the layers of
2:1 clay (illite) is a major reason
• The 1:1 clay (kaolinite) do not fix potassium
• Major factor affecting K availability
– Clay minerals, CEC, nature of cations
– Soil moisture
– Soil temperature
– Amount of exchangeable K, capacity to fix K
59. Potassium Fertilizers
• Organic sources – K content varies with sources,
range in manure is 4-40 pounds
• Commercial sources – potassium oxide (K2O) is
guaranteed standard for fertilizer K
• Potash and Potassium names are used
interchangeably
• The world’s largest high-grade potash deposit is in
Canada
END OF SECTION 02 INSTRUCTION
60. Tools for detecting nutrient deficiency
• 1) Tissue testing -involves a complete
and detailed laboratory analysis of
nutrient elements in the plant leaves.
This is a very accurate way of assessing
how much nutrient the plant has
actually taken up from the soil.
• Recommendations are made on the
basis of these test results:
– Backed by research
– Dependent on plant growth stage and plant
part.
62. Calibration
• Process of ascertaining the degree of
limitation to crop growth or the probability
of getting a growth response to applied
nutrient at any soil test level.
• Soil test interpretation develops fertilizer
recommendations.
63. Correlation - process
• Exploratory
fertilization trial
– Greenhouse – a
controlled environment
with soil homogeneity.
• Trials in field with
selected soils.