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N P K
Nutrition
Principles
Dr. Rai Mukaram
Site Specific Management:
Accounting for spatial variability
Nutrition Principles
Nitrogen
Cycle
Factors
Affecting
Availability
Sources
Forms
Taken up
Role in
Plants
Nitrogen
Key Presentation Points
Role in Plants
• Protein
• Nucleic acid
• Chlorophyll
• Carbohydrate
utilization
Four nitrogenous bases –
adenine (A), thymine (T), guanine
(G), and cytosine (C) are
components in the DNA double
helix.
Forms Plants Uptake
Ammonia
• Plants uptake both forms.
• Uptake NO3
-
the most.
• NO3
-
is mobile, NH4 is not.
• NO3- prefers acidic pH.
• NH4
+
prefers neutral pH.
• Combination is better.
Which form is vulnerable to leaching losses?
Nitrate
Nitrogen Cycle
• N in soil enters, exits, and changes
forms in many ways.
• Can you name some of the processes
and pools in N cycles?
mineralization, immobilization,
nitrification, denitrification, nitrogen
fixation, nitrogen leaching…
NITROGEN CYCLE
Denitrification
N2
Biologicaland
Chemical
FixationAtmospheric
Nitrogen, 78%
NH3 + H+
= NH4
Clay Fixation
and Release
NO3
Leaching
N2
N2O
Immobilization
(use by the plant)
N states
NO3 Nitrate ion
NO2 Nitrite ion
NO Nitric oxide oxide
N20 Nitrous oxide oxide
N2 Dinitrogen gas
Various states of N
NITROGEN
Denitrification
N2
Biologicaland
Chemical
Fixation
Atmospheric
Nitrogen, 78%
NH3 + H+
= NH4
Clay Fixation
and Release
NO3
Leaching
N2
N2O
Immobilization
(use by the plant)
N from air is fixed by
microbes and
lightning.
N Fixation
NITROGEN Nitrogen Fixation
Denitrification
N2
Biologicaland
Chemical
FixationAtmospheric
Nitrogen, 78%
NH3 + H+
= NH4
Clay Fixation
and Release
NO3
Leaching
N2
N2O
Immobilization
(use by the plant)N from
Organic
Matter
N is released from
organic matter
decomposition.
Mineralization
Mineralization
Denitrification
N2
Biologicaland
Chemical
FixationAtmospheric
Nitrogen, 78%
NH3 + H+
= NH4
Clay Fixation
and Release
NO3
Leaching
N2
N2O
Immobilization
(use by the plant)
N from
NH4
When the process
reverses with plant
and microbial uses
Immobilization
M
ineralization
Fertilizer Nitrogen
• Nitrogen fertilizer should be
added to the soil when the crop
will use it, adding excess N will
cause losses that may harm the
environment.
• Nitrogen is expensive and using
only what the crop needs for
adequate growth is important -
• THUS it becomes important to
give N - CREDITS for previous
management (legumes, manure or
other organic additions with low
C:N ratios).
Wheat with N response
Nitrogen soil testing
• Mobile nutrient
• In drier areas use a
fall or spring nitrate-
N soil test.
• In humid areas, use
spring nitrate-N test
or table value based on
previous crop and
organic matter.
Nitrogen soil testing
• After arriving at N
recommendation then
credits need to be taken
for:
– Previous crop
– Previous manure
applications or sludge
– 2nd
year after alfalfa
More on
The story behind residual
nutrient credits to growers
NH2
Upon decomposition plant
animal residues, N-containing
molecules are released from
Chlorophyll
DNA and RNA
Protein
}
NH2
Chlorophyll
DNA and RNA
Protein
}
NH2
N molecules from
this amino group
NH2
NH2
NH2
When organic matter
decomposes, N-containing
molecules are released from
H
H
combine with H to
produce NH3 and NH4
NH3 + H = NH4
-
Ammonium
Chlorophyll
DNA and RNA
Protein
}
NH2
First they make
this gas, then
NH2
NH2
NH2 NH3
H
H+
H
+ NH4
AmmoniumAmmonia
(gas)
=
The simple steps in the mineralization process are now complete.
The process is also called ammonification.
When organic matter
decomposes, N-containing
molecules are released from
Denitrification
N2
Biologicaland
Chemical
Fixation
NH3 + H+
= NH4
Clay Fixation
and Release
NO3
N2
N2O
Immobilization
(use by the plant)
NITROGEN
Oxidation of NH4 to NO3 is
nitrification.
Nitrobactor
Nitrosomonas
Nitrification
NO2
Two kinds of bacteria are
involved in two steps.
Denitrification
N2
Biologicaland
Chemical
Fixation
NH3 + H+
= NH4
Clay Fixation
and Release
NO3
N2
N2O
Immobilization
(use by the plant) NITROGEN
In water-logged soil, NO3
transforms to gaseous N, and
this loss to air is denitrification.
Nitrobactor
Nitrosomonas
Nitrification
NO2
Steps: NO2--NO--N2O and N2
Denitrification
N2
Biologicaland
Chemical
FixationAtmospheric
Nitrogen, 78%
NH3 + H+
= NH4
Clay Fixation
and Release
NO3
Leaching
N2
N2O
Immobilization
(use by the plant)
NITROGEN
Clay Fixation and
Release of NH4
Denitrification
N2
Biologicaland
Chemical
FixationAtmospheric
Nitrogen, 78%
NH3 + H+
= NH4
Clay Fixation
and Release
NO3
Leaching
N2
N2O
Immobilization
(use by the plant)
NITROGEN
Nitrate Leaching
Sources of N in Wheat
• Organic – residue breakdown (slow)
• Organic manures (N content varies)
• Commercial
– Urea
– Ammonia
– Monoammonium phosphate (MAP)/diammonium
phosphate (DAP)
– Potassium nitrate
– URAN (urea + ammonium nitrate) solutions
– Ammonium nitrate
More discussion in Sections 4 and 5
P Nutrition Principles
How the materials will be presented
P-cycle
Key
Factors
Sources
Forms
uptake
Role in
plant
P
P Essentiality
• Second most important
nutrient
• Its concentration in soil
solution is low
• Low solubility
• Low availability
• Low mobility
Nutrient Amount in
Solution (mg/L)
NO3
-
60
NH4
+
--
H2
PO4
-
, HPO4
2-
0.8
K+
14
Ca2+
60
Mg2+
40
SO4
2-
26
are key characteristics for
better management
Role in Plants
• ATP
• DNA/RNA
• Enhance crop maturity
• Root growth
Can you
justify how
P is
important
in these
Role in Plants
• ATP
• DNA/RNA
• Enhance crop maturity
• Root growth P is a critical component of
cell’s energy currency, ATP
Role in Plants
• ATP
• DNA/RNA
• Enhance crop maturity
• Root growth
P containing sugar
phosphate is the
backbone of DNA
Orthophosphate ions: H2PO4
-
& HPO4
2-
Plant Available Forms
7.2 pH
Availability is pH dependent
Both species are even at this pH
Phosphorus Cycle
• Not involved in atmospheric exchanges
• Cycles among various pools
– Soil solution
– Organic matter
– Inorganic minerals
• Interaction among pools is complex.
• Knowledge of each pool is necessary.
Phosphorus Cycle
Secondary
Minerals
Fe & Al PO4
CaPO4
Nonlabile P
Primary
Minerals
(Nonlabile P)
Solution P
H2PO4
-
HPO4
2-
Microbial-
P
bacteriaFungi
nematode
Plant residue
Labile P
Adsorbed
P
Dissolution
Dissolution
Precipitation
Adsorption
Desorption
Immobilization
Mineralization
Fertilizer-P
Soil Organic
Matter
Microbial P
(Nonalabile P)
(Labile P)
1. Soil Solution: plant uptake poolAdsorption and DesorptionPrecipitation and DissolutionMineralization and Immobilization
SOIL SOLUTION POOL
INTERACTIONS
Phosphorus Cycle
Secondary
Minerals
Fe & Al PO4
CaPO4
Nonlabile P
Primary
Minerals
(Nonlabile P)
Solution P
H2PO4
-
HPO4
2-
Microbial-
P
bacteriaFungi
nematode
Plant residue
Labile P
Adsorbed
P
Dissolution
Dissolution
Precipitation
Adsorption
Desorption
Immobilization
Mineralization
Fertilizer-P
Soil Organic
Matter
Microbial P
(Nonalabile P)
(Labile P)
Crop residue
and organic
matter release
P by
mineralization
Various factor
affects rate of
mineralization
including C/P
ratio
Net
immobilization
(available for
plant uptake) at
C/P >300
ORGANIC POOL
INTERACTIONS
What is good – high or low C/P?
Why?
Organic-P, quick facts
• P of organic matter range
between 1% and 3%
• Organic P is ~50% of total
P in soil
• Organic P decreases with
soil depth
• Organic-P increases with
increased organic-C (the
C/P, likewise N and C/N)
Phosphorus Cycle
Secondary
Minerals
Fe & Al PO4
CaPO4
Nonlabile P
Primary
Minerals
(Nonlabile P)
Solution P
H2PO4
-
HPO4
2-
Microbial-
P
bacteriaFungi
nematode
Plant residue
Labile P
Adsorbed
P
Dissolution
Dissolution
Precipitation
Adsorption
Desorption
Immobilization
Mineralization
Fertilizer-P
Soil Organic
Matter
Microbial P
(Nonalabile P)
(Labile P)
INORGANIC POOL
INTERACTIONS
Inorganic P fixed or released by
primary and secondary minerals
P
• Soil test for P (Bray pH<7.4 of soil)
• 0-5 ppm = very low
• 6-10 ppm = LOW
• 11-15 ppm = med
• 16-20 ppm = high
• > =21 ppm = very high
• No reason to have soil
test > 21
• environmental problems
when P >16
• ppm x 2 = lbs/acre
P deficient tomato
Soil P
• Crops need more P than is
dissolved in the soil solution at any
one time, therefore, this P in the
solution phase must be replenished
many times during the growing
season.
• The ability of a soil to maintain
adequate levels of phosphorus in
the solution phase is the key to
the plant available P status of the
soil. The solid phase P is both
organic and inorganic
Solid P Phase Solution Phase Root Hair
P deficiency reduces root growth
Inorganic-P, quick facts
• Low concentration & solubility of P due to slow
release and fixation
• Minerals mainly with Ca, in alkaline soils
• Minerals with Fe, Al, and Mg in acidic soils
•
Solubility of P-containing compounds
Compound Formula Compound type
Monocalcium phosphate
Dicalcium phosphate
Octacalcium phosphate
Tricalcium phosphate
Oxy apatite
Hydroxy apatite
Carbonate apatite
Fluorapatite
Ca(H2
PO4
)2
.H2
O
CaHPO4
.2H2
O
Ca8
H2
(PO4
)6
.5H2
O
Ca3
(PO4
)2
[3Ca3
(PO4
)2
].CaO
[3Ca3
(PO4
)2
].Ca(OH)2
[3Ca3
(PO4
)2
].CaCO3
3Ca3
(PO4
)2
].CaF2
Calcium
Strengite FePO4
-2H2
O Iron
Variscite AlPO4
-2H2
O Aluminum
• Ca-phosphate - major contributor in alkaline
soils
• pH determines its availability
• Solubility decreases in order of: mono >
di > tri calcium phosphates
Commercial P Fertilizers
K Nutrition Principles
K-Cycle
Key
Factors Sources
Forms
Taken up
Role in
Plants
K
P Essentiality Principles
• Plant absorbs larger amount of K next
only to N
• Plant tissue K: ~2.5% to 4.5% leaf dry
wt.
• Soil K: 0.5% to 2.5%
• Most soil K’s are tied up, availability is
often limited
Role in Plants
• Enzyme activation
• Water relations
(stomatal control)
• Energy relations
• Translocation (sugar
transport)
• Crop quality
Justify
how K is
important
in these
Role in Plants
• Enzyme activation
• K activates at least 60 enzymes in cell
• K level determines reactions catalyzed by enzymes
Potassium Fertility (Potash)
• Potassium (K+) is a problem
on acid soils, soils with low
CEC and with irrigation or
high rainfall where leaching
can readily occur.
• Potassium can be stored in
the soil from one year to
the next
• K is not a pollutant - even if
leached from soil, K does
not cause environmental
problems.
K deficient corn
Role in Plants
• Water relations
– K regulates stomatal
opening
K is critical to stomatal opening and closure in
regulating gas exchanges (CO2 in and H2O out)
Role in Plants
• Energy relations
– K is required for production of ATP
• Crop quality
– Increases root growth
– Enhances translocation of sugar
– Increase protein content in plant
– Reduces lodging
Forms uptake
K+
Soil K Pools and Concentrations
Mineral…………..… 5000 – 25000 ppm
Non-exchangeable…...….50 – 750 ppm
Exchangeable…………..400 – 600 ppm
Solution……………...………1 – 10 ppm
K-Cycle will show
interaction among pools
K forms - characteristics
1. Mineral – K : Minerals like
Mica, Feldspar, K is mainly
unavailable
2. Non-exchangeable – K : K in
secondary minerals like vermiculite
or colloidal-size mica, K is slowly
available
……more
In the non-exchangeable fraction of K
Most K
trapped
K slowly available K is widely
exchangeable
K forms - characteristics
3. Exchangeable-K: K on the cation
exchange sites of soil colloids is
readily available
K forms - characteristics
4. Soil solution-K: K is readily
available. Range in most cropland
soils ~ 1-10ppm.
~80% K plant uptake by diffusion,
availability depends of many
factors
Exchangeable K+
K+
K+
K+
K+
K+
K+
K+
Nonexchangeable K+
Plant &
animal
residues
2:1 Clay minerals
Soil solution
K+
Plant uptake
Desorption
Adsorption
Weathering
90-98%
0.1-0.2%
1-2%1-10%
ErosionLeaching
Feldspar
Mica
Primary
minerals
K
Mineral-K, mostly
unavailable, accounts
for majority of soil K
K
Non-exchangeable-K,
in secondary minerals, slowly
available, 2:1 clay
K
Exchangeable-K,
readily available, K
in cation exchange
site…
Exchangeable K+
K+
K+
K+
K+
K+
K+
K+
Nonexchangeable K+
2:1 Clay minerals
Soil solution
K+
Plant uptake
Desorption
Adsorption
Plant/
animal
residues
Weathering
90-98%
0.1-0.2%
1-2%1-10%
ErosionLeaching
Feldspar
Mica
Primary
minerals
K
K K
Residue K recovery is
minor, usually leach out
K leaching loss is often substantial
K Cycle Quick Fact
• K transfer from minerals is slow but
continuous
• Exchangeable and soluble K equilibrate
rapidly
• Fixed K equilibrate very slowly
• Transfer from mineral to other form is
very slow, usually unavailable (in one
crop year)
K Fixation – who is involved?
• Reentrapment of K ions between the layers of
2:1 clay (illite) is a major reason
• The 1:1 clay (kaolinite) do not fix potassium
• Major factor affecting K availability
– Clay minerals, CEC, nature of cations
– Soil moisture
– Soil temperature
– Amount of exchangeable K, capacity to fix K
Potassium Fertilizers
• Organic sources – K content varies with sources,
range in manure is 4-40 pounds
• Commercial sources – potassium oxide (K2O) is
guaranteed standard for fertilizer K
• Potash and Potassium names are used
interchangeably
• The world’s largest high-grade potash deposit is in
Canada
END OF SECTION 02 INSTRUCTION
Tools for detecting nutrient deficiency
• 1) Tissue testing -involves a complete
and detailed laboratory analysis of
nutrient elements in the plant leaves.
This is a very accurate way of assessing
how much nutrient the plant has
actually taken up from the soil.
• Recommendations are made on the
basis of these test results:
– Backed by research
– Dependent on plant growth stage and plant
part.
Soil testing
• Collecting a soil
sample to determine
the current nutrient
status of the soil.
Calibration
• Process of ascertaining the degree of
limitation to crop growth or the probability
of getting a growth response to applied
nutrient at any soil test level.
• Soil test interpretation develops fertilizer
recommendations.
Correlation - process
• Exploratory
fertilization trial
– Greenhouse – a
controlled environment
with soil homogeneity.
• Trials in field with
selected soils.
N P K  Nutrition Principles

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N P K Nutrition Principles

  • 2. Site Specific Management: Accounting for spatial variability
  • 4. Role in Plants • Protein • Nucleic acid • Chlorophyll • Carbohydrate utilization Four nitrogenous bases – adenine (A), thymine (T), guanine (G), and cytosine (C) are components in the DNA double helix.
  • 5. Forms Plants Uptake Ammonia • Plants uptake both forms. • Uptake NO3 - the most. • NO3 - is mobile, NH4 is not. • NO3- prefers acidic pH. • NH4 + prefers neutral pH. • Combination is better. Which form is vulnerable to leaching losses? Nitrate
  • 6. Nitrogen Cycle • N in soil enters, exits, and changes forms in many ways. • Can you name some of the processes and pools in N cycles? mineralization, immobilization, nitrification, denitrification, nitrogen fixation, nitrogen leaching…
  • 7. NITROGEN CYCLE Denitrification N2 Biologicaland Chemical FixationAtmospheric Nitrogen, 78% NH3 + H+ = NH4 Clay Fixation and Release NO3 Leaching N2 N2O Immobilization (use by the plant) N states NO3 Nitrate ion NO2 Nitrite ion NO Nitric oxide oxide N20 Nitrous oxide oxide N2 Dinitrogen gas Various states of N
  • 8. NITROGEN Denitrification N2 Biologicaland Chemical Fixation Atmospheric Nitrogen, 78% NH3 + H+ = NH4 Clay Fixation and Release NO3 Leaching N2 N2O Immobilization (use by the plant) N from air is fixed by microbes and lightning. N Fixation NITROGEN Nitrogen Fixation
  • 9. Denitrification N2 Biologicaland Chemical FixationAtmospheric Nitrogen, 78% NH3 + H+ = NH4 Clay Fixation and Release NO3 Leaching N2 N2O Immobilization (use by the plant)N from Organic Matter N is released from organic matter decomposition. Mineralization Mineralization
  • 10. Denitrification N2 Biologicaland Chemical FixationAtmospheric Nitrogen, 78% NH3 + H+ = NH4 Clay Fixation and Release NO3 Leaching N2 N2O Immobilization (use by the plant) N from NH4 When the process reverses with plant and microbial uses Immobilization M ineralization
  • 11.
  • 12.
  • 13. Fertilizer Nitrogen • Nitrogen fertilizer should be added to the soil when the crop will use it, adding excess N will cause losses that may harm the environment. • Nitrogen is expensive and using only what the crop needs for adequate growth is important - • THUS it becomes important to give N - CREDITS for previous management (legumes, manure or other organic additions with low C:N ratios). Wheat with N response
  • 14. Nitrogen soil testing • Mobile nutrient • In drier areas use a fall or spring nitrate- N soil test. • In humid areas, use spring nitrate-N test or table value based on previous crop and organic matter.
  • 15. Nitrogen soil testing • After arriving at N recommendation then credits need to be taken for: – Previous crop – Previous manure applications or sludge – 2nd year after alfalfa
  • 16. More on The story behind residual nutrient credits to growers
  • 17. NH2 Upon decomposition plant animal residues, N-containing molecules are released from Chlorophyll DNA and RNA Protein } NH2
  • 18. Chlorophyll DNA and RNA Protein } NH2 N molecules from this amino group NH2 NH2 NH2 When organic matter decomposes, N-containing molecules are released from H H combine with H to produce NH3 and NH4 NH3 + H = NH4 - Ammonium
  • 19. Chlorophyll DNA and RNA Protein } NH2 First they make this gas, then NH2 NH2 NH2 NH3 H H+ H + NH4 AmmoniumAmmonia (gas) = The simple steps in the mineralization process are now complete. The process is also called ammonification. When organic matter decomposes, N-containing molecules are released from
  • 20. Denitrification N2 Biologicaland Chemical Fixation NH3 + H+ = NH4 Clay Fixation and Release NO3 N2 N2O Immobilization (use by the plant) NITROGEN Oxidation of NH4 to NO3 is nitrification. Nitrobactor Nitrosomonas Nitrification NO2 Two kinds of bacteria are involved in two steps.
  • 21. Denitrification N2 Biologicaland Chemical Fixation NH3 + H+ = NH4 Clay Fixation and Release NO3 N2 N2O Immobilization (use by the plant) NITROGEN In water-logged soil, NO3 transforms to gaseous N, and this loss to air is denitrification. Nitrobactor Nitrosomonas Nitrification NO2 Steps: NO2--NO--N2O and N2
  • 22. Denitrification N2 Biologicaland Chemical FixationAtmospheric Nitrogen, 78% NH3 + H+ = NH4 Clay Fixation and Release NO3 Leaching N2 N2O Immobilization (use by the plant) NITROGEN Clay Fixation and Release of NH4
  • 23. Denitrification N2 Biologicaland Chemical FixationAtmospheric Nitrogen, 78% NH3 + H+ = NH4 Clay Fixation and Release NO3 Leaching N2 N2O Immobilization (use by the plant) NITROGEN Nitrate Leaching
  • 24. Sources of N in Wheat • Organic – residue breakdown (slow) • Organic manures (N content varies) • Commercial – Urea – Ammonia – Monoammonium phosphate (MAP)/diammonium phosphate (DAP) – Potassium nitrate – URAN (urea + ammonium nitrate) solutions – Ammonium nitrate More discussion in Sections 4 and 5
  • 25.
  • 26. P Nutrition Principles How the materials will be presented P-cycle Key Factors Sources Forms uptake Role in plant P
  • 27. P Essentiality • Second most important nutrient • Its concentration in soil solution is low • Low solubility • Low availability • Low mobility Nutrient Amount in Solution (mg/L) NO3 - 60 NH4 + -- H2 PO4 - , HPO4 2- 0.8 K+ 14 Ca2+ 60 Mg2+ 40 SO4 2- 26 are key characteristics for better management
  • 28. Role in Plants • ATP • DNA/RNA • Enhance crop maturity • Root growth Can you justify how P is important in these
  • 29. Role in Plants • ATP • DNA/RNA • Enhance crop maturity • Root growth P is a critical component of cell’s energy currency, ATP
  • 30. Role in Plants • ATP • DNA/RNA • Enhance crop maturity • Root growth P containing sugar phosphate is the backbone of DNA
  • 31. Orthophosphate ions: H2PO4 - & HPO4 2- Plant Available Forms 7.2 pH Availability is pH dependent Both species are even at this pH
  • 32. Phosphorus Cycle • Not involved in atmospheric exchanges • Cycles among various pools – Soil solution – Organic matter – Inorganic minerals • Interaction among pools is complex. • Knowledge of each pool is necessary.
  • 33. Phosphorus Cycle Secondary Minerals Fe & Al PO4 CaPO4 Nonlabile P Primary Minerals (Nonlabile P) Solution P H2PO4 - HPO4 2- Microbial- P bacteriaFungi nematode Plant residue Labile P Adsorbed P Dissolution Dissolution Precipitation Adsorption Desorption Immobilization Mineralization Fertilizer-P Soil Organic Matter Microbial P (Nonalabile P) (Labile P) 1. Soil Solution: plant uptake poolAdsorption and DesorptionPrecipitation and DissolutionMineralization and Immobilization SOIL SOLUTION POOL INTERACTIONS
  • 34. Phosphorus Cycle Secondary Minerals Fe & Al PO4 CaPO4 Nonlabile P Primary Minerals (Nonlabile P) Solution P H2PO4 - HPO4 2- Microbial- P bacteriaFungi nematode Plant residue Labile P Adsorbed P Dissolution Dissolution Precipitation Adsorption Desorption Immobilization Mineralization Fertilizer-P Soil Organic Matter Microbial P (Nonalabile P) (Labile P) Crop residue and organic matter release P by mineralization Various factor affects rate of mineralization including C/P ratio Net immobilization (available for plant uptake) at C/P >300 ORGANIC POOL INTERACTIONS What is good – high or low C/P? Why?
  • 35. Organic-P, quick facts • P of organic matter range between 1% and 3% • Organic P is ~50% of total P in soil • Organic P decreases with soil depth • Organic-P increases with increased organic-C (the C/P, likewise N and C/N)
  • 36. Phosphorus Cycle Secondary Minerals Fe & Al PO4 CaPO4 Nonlabile P Primary Minerals (Nonlabile P) Solution P H2PO4 - HPO4 2- Microbial- P bacteriaFungi nematode Plant residue Labile P Adsorbed P Dissolution Dissolution Precipitation Adsorption Desorption Immobilization Mineralization Fertilizer-P Soil Organic Matter Microbial P (Nonalabile P) (Labile P) INORGANIC POOL INTERACTIONS Inorganic P fixed or released by primary and secondary minerals
  • 37. P • Soil test for P (Bray pH<7.4 of soil) • 0-5 ppm = very low • 6-10 ppm = LOW • 11-15 ppm = med • 16-20 ppm = high • > =21 ppm = very high • No reason to have soil test > 21 • environmental problems when P >16 • ppm x 2 = lbs/acre P deficient tomato
  • 38. Soil P • Crops need more P than is dissolved in the soil solution at any one time, therefore, this P in the solution phase must be replenished many times during the growing season. • The ability of a soil to maintain adequate levels of phosphorus in the solution phase is the key to the plant available P status of the soil. The solid phase P is both organic and inorganic Solid P Phase Solution Phase Root Hair P deficiency reduces root growth
  • 39. Inorganic-P, quick facts • Low concentration & solubility of P due to slow release and fixation • Minerals mainly with Ca, in alkaline soils • Minerals with Fe, Al, and Mg in acidic soils •
  • 40. Solubility of P-containing compounds Compound Formula Compound type Monocalcium phosphate Dicalcium phosphate Octacalcium phosphate Tricalcium phosphate Oxy apatite Hydroxy apatite Carbonate apatite Fluorapatite Ca(H2 PO4 )2 .H2 O CaHPO4 .2H2 O Ca8 H2 (PO4 )6 .5H2 O Ca3 (PO4 )2 [3Ca3 (PO4 )2 ].CaO [3Ca3 (PO4 )2 ].Ca(OH)2 [3Ca3 (PO4 )2 ].CaCO3 3Ca3 (PO4 )2 ].CaF2 Calcium Strengite FePO4 -2H2 O Iron Variscite AlPO4 -2H2 O Aluminum • Ca-phosphate - major contributor in alkaline soils • pH determines its availability • Solubility decreases in order of: mono > di > tri calcium phosphates
  • 42.
  • 43. K Nutrition Principles K-Cycle Key Factors Sources Forms Taken up Role in Plants K
  • 44. P Essentiality Principles • Plant absorbs larger amount of K next only to N • Plant tissue K: ~2.5% to 4.5% leaf dry wt. • Soil K: 0.5% to 2.5% • Most soil K’s are tied up, availability is often limited
  • 45. Role in Plants • Enzyme activation • Water relations (stomatal control) • Energy relations • Translocation (sugar transport) • Crop quality Justify how K is important in these
  • 46. Role in Plants • Enzyme activation • K activates at least 60 enzymes in cell • K level determines reactions catalyzed by enzymes
  • 47. Potassium Fertility (Potash) • Potassium (K+) is a problem on acid soils, soils with low CEC and with irrigation or high rainfall where leaching can readily occur. • Potassium can be stored in the soil from one year to the next • K is not a pollutant - even if leached from soil, K does not cause environmental problems. K deficient corn
  • 48. Role in Plants • Water relations – K regulates stomatal opening K is critical to stomatal opening and closure in regulating gas exchanges (CO2 in and H2O out)
  • 49. Role in Plants • Energy relations – K is required for production of ATP • Crop quality – Increases root growth – Enhances translocation of sugar – Increase protein content in plant – Reduces lodging
  • 50. Forms uptake K+ Soil K Pools and Concentrations Mineral…………..… 5000 – 25000 ppm Non-exchangeable…...….50 – 750 ppm Exchangeable…………..400 – 600 ppm Solution……………...………1 – 10 ppm K-Cycle will show interaction among pools
  • 51. K forms - characteristics 1. Mineral – K : Minerals like Mica, Feldspar, K is mainly unavailable 2. Non-exchangeable – K : K in secondary minerals like vermiculite or colloidal-size mica, K is slowly available ……more
  • 52. In the non-exchangeable fraction of K Most K trapped K slowly available K is widely exchangeable
  • 53. K forms - characteristics 3. Exchangeable-K: K on the cation exchange sites of soil colloids is readily available
  • 54. K forms - characteristics 4. Soil solution-K: K is readily available. Range in most cropland soils ~ 1-10ppm. ~80% K plant uptake by diffusion, availability depends of many factors
  • 55. Exchangeable K+ K+ K+ K+ K+ K+ K+ K+ Nonexchangeable K+ Plant & animal residues 2:1 Clay minerals Soil solution K+ Plant uptake Desorption Adsorption Weathering 90-98% 0.1-0.2% 1-2%1-10% ErosionLeaching Feldspar Mica Primary minerals K Mineral-K, mostly unavailable, accounts for majority of soil K K Non-exchangeable-K, in secondary minerals, slowly available, 2:1 clay K Exchangeable-K, readily available, K in cation exchange site…
  • 56. Exchangeable K+ K+ K+ K+ K+ K+ K+ K+ Nonexchangeable K+ 2:1 Clay minerals Soil solution K+ Plant uptake Desorption Adsorption Plant/ animal residues Weathering 90-98% 0.1-0.2% 1-2%1-10% ErosionLeaching Feldspar Mica Primary minerals K K K Residue K recovery is minor, usually leach out K leaching loss is often substantial
  • 57. K Cycle Quick Fact • K transfer from minerals is slow but continuous • Exchangeable and soluble K equilibrate rapidly • Fixed K equilibrate very slowly • Transfer from mineral to other form is very slow, usually unavailable (in one crop year)
  • 58. K Fixation – who is involved? • Reentrapment of K ions between the layers of 2:1 clay (illite) is a major reason • The 1:1 clay (kaolinite) do not fix potassium • Major factor affecting K availability – Clay minerals, CEC, nature of cations – Soil moisture – Soil temperature – Amount of exchangeable K, capacity to fix K
  • 59. Potassium Fertilizers • Organic sources – K content varies with sources, range in manure is 4-40 pounds • Commercial sources – potassium oxide (K2O) is guaranteed standard for fertilizer K • Potash and Potassium names are used interchangeably • The world’s largest high-grade potash deposit is in Canada END OF SECTION 02 INSTRUCTION
  • 60. Tools for detecting nutrient deficiency • 1) Tissue testing -involves a complete and detailed laboratory analysis of nutrient elements in the plant leaves. This is a very accurate way of assessing how much nutrient the plant has actually taken up from the soil. • Recommendations are made on the basis of these test results: – Backed by research – Dependent on plant growth stage and plant part.
  • 61. Soil testing • Collecting a soil sample to determine the current nutrient status of the soil.
  • 62. Calibration • Process of ascertaining the degree of limitation to crop growth or the probability of getting a growth response to applied nutrient at any soil test level. • Soil test interpretation develops fertilizer recommendations.
  • 63. Correlation - process • Exploratory fertilization trial – Greenhouse – a controlled environment with soil homogeneity. • Trials in field with selected soils.