The ALTER command in MySQL is used to modify the structure of existing tables. It allows you to add, drop, or modify columns, change the data type of columns, rename tables, and change the table type. Some key things the ALTER command allows you to do include:
1. Add or drop columns from a table.
2. Modify column definitions by changing the data type, default value, nullability, or length of a column.
3. Change the name of a table or rename columns.
4. Change the table type, such as converting between InnoDB and MyISAM.