MPI (Message Passing Interface) is a standard for writing message passing programs between parallel processes. It was developed in the late 1980s and early 1990s due to increasing computational needs. An MPI program typically initializes and finalizes the MPI environment, declares variables, includes MPI header files, contains parallel code using MPI calls, and terminates the environment before ending. Key MPI calls initialize and finalize the environment, determine the process rank and number of processes, and get the processor name.