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Carus Corporation
Manganese Based Products, Properties and Uses
Jordi Aragones
1
Carus Corporation
Celebrating 100 years (1915-2015)
2
Founded in LaSalle, Illinois, USA in 1915, Carus is a family-owned
environmental company that produces and supplies technologies and services
for water treatment, soil remediation, and air purification. Carus is a member of
the American Chemistry Council and actively participates in the industry’s
award-winning Responsible Care® initiative, sharing a common commitment to
improve environmental, health, safety, and security performance.
Peru, IL
• Corporate Headquarters
• Administration
• Sales and Marketing
La Salle, IL
• Manufacturing / Laboratory / Corporate R&D
1
HQ
Regional
Office/Warehouse
Manufacturing &
Warehousing
Carus Corporation
3
1
Carus Manganese Based Products
• Solid – Potassium Permanganate
• Liquid - Sodium Permanganate
• Permanganate Applications
• Water and Wastewater Treatment
• Site Remediation
• Industrial Applications
• CARULITE ® Catalysts
• Carbon Monoxide Destruction
• Ozone Destruction
• Ethylene Oxide destruction
4
1
CARULITE ® Breathing Air Applications
5
1
CARULITE ® Industrial / Commercial Applications
6
1
Potassium Permanganate’s chemical formula is: KMnO4
Sodium Permanganate’s chemical formula is: NaMnO4
Permanganate is a stable chemical oxidizing agent, produced
and delivered as a dry crystalline powder or as a concentrated
liquid.
Because it is stable, it can be packaged, stored and delivered
to the user.
What is Permanganate?
7
18
MANGANATE
CENTRIFUGE
0XIDIZER
LEACHER FILTER
CAUSTIC POTASH OXYGENMANGANESE DIOXIDE
MANGANATE
MIX TANK
CARUS CHEMICAL COMPANY
CAIROX®
POTASSIUM PERMANGANATE PROCESS
PERMANGANATE
CENTRIFUGE
DRYER
FREE-FLOW
ADDITIVE
CRYSTALLIZER
LANDFILL
POTASSIUM
RECOVERY
EVAPORATOR
CONCENTRATOR
CAIROX®
POTASSIUM
PERMANGANATE
ELECTROLYTIC
CELLS
Potassium Permanganate Manufacturing Process
1
Synthesis
9
1
Commercial Permanganate Synthesis Reactions
Starting Material Intermediate Chemistry End Product
Diacetone sorbose 2-ketogulonic acid R-CH2OH ► R-COOH Ascorbic acid
o-toluene sulfamide o-benzoic acid
sulfimide
Ar-CH3 ► Ar-COOH Saccharine
Pinacolone (t-butyl
methyl ketone)
Trimethyl pyruvic acid (CH3) 3CCOOH ►
(CH3)3COCOOH
Sencor (herbicide)
Sclareol Lactone Tobacco flavourant
Mesitylene Trimesic acid Rocket Fuel
component
Beta picoline Pyradine beta
carboxylic acid
Nicotinic acid (Niacin)
2,3 lutidine Quinolinic acid Arsenal (herbicide)
p-nitro ethyl benzene P-nitro acetophenone Chloroamphenicol
(Chloromycetin)
10
1
Purification
11
1
Bleaching with Permanganate
12
1
Therapeutics
13
1
Aquaculture
14
1
Drinking Water Purification
15
1
Treatment of Micropollutants in Drinking Water
PPCPs/EDCs
Class
Compound Chemical
Structure
Use
PCP
Antibacterial/
Antiseptic
Triclocarban Antibacterial agent commonly used in personal care
products, such as soaps and lotions
PHC
Analgesic
Paracetamol
(Acetaminophen)
Used to treat pain and fever
EDC
Bisphenol
Bisphenol A (BPA) Used in the production of certain plastics, epoxy
resins, flame retardants, and rubber chemicals
PHC
Antiepileptic
Carbamazepine
(Tegretol)
Treatment of epilepsy and neuropathic pain
PHC
Antidepressant
Fluoxetine
(Prozac)
Treatment of major depressive disorder, OCD, panic
disorder, and bulimia nervosa
PHC
Lipid-Regulator
Gemfibrozil Gemfibrozil is the generic name used mainly to lower
plasma lipid levels
PHC
Anti-
Inflammatory
Naproxen (Aleve) Relief of pain, fever, swelling, and stiffness
PHC
Antibiotic
Sulfamethoxazole Antibiotic for bacterial infections such as bronchitis,
and prostatitis
16
1
Wastewater Treatment / Odor Control
17
1
Metal Surface Treatment
18
1
Printed Circuit Board Manufacturing
19
1
Equipment Surface Treatment
20
1
Refinery Pyrophoric Iron Sulfide
21
1
Environmental
22
1
In-Situ Chemical Oxidation
23
1
Mining / Hydrometallurgical
24
1
Technologies for Passive Treatment
of Mining Influenced Water
• Permanganate Tablets (Solid KMnO4)
• Passive treatment for Mn/Fe removal
• Viable in winter with a dispensing system that
compensates for variable flows
• Safe/easy transport for remote locations
• Slow-release form of permanganate
• Alkaline Permanganate (Liquid NaMnO4)
• A single stable permanganate/pH adjusting blend for Mn/Fe removal
and pH adjustment
25
1
World Wide Manganese Chemistry R&D
• Secondary Batteries
• Manganese oxides as the cathode material
• Supercapacitors
• Manganese oxides as the cathode material
• Water Oxidation Reaction
• Manganese is the active element in natures photosynthesis energy
conversion process
• Solar Cells
• Manganese as a component in photovoltaic cells
• Synthesis Catalysts
• CO2 conversion, light hydrocarbon conversion
26
1
Municipal Water Treatment
Waste Water Treatment
Industrial Cleanup
Chemical Manufacturing
Metal Cleaning
Site Remediation
Refineries
Electronics
Agricultural
Environmental
Mining
Air Purification
Pharmaceutical
There are Many Uses for Manganese!
27

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Manganese Based Products, Properties, and Uses

  • 1. 1 Carus Corporation Manganese Based Products, Properties and Uses Jordi Aragones
  • 2. 1 Carus Corporation Celebrating 100 years (1915-2015) 2 Founded in LaSalle, Illinois, USA in 1915, Carus is a family-owned environmental company that produces and supplies technologies and services for water treatment, soil remediation, and air purification. Carus is a member of the American Chemistry Council and actively participates in the industry’s award-winning Responsible Care® initiative, sharing a common commitment to improve environmental, health, safety, and security performance. Peru, IL • Corporate Headquarters • Administration • Sales and Marketing La Salle, IL • Manufacturing / Laboratory / Corporate R&D
  • 4. 1 Carus Manganese Based Products • Solid – Potassium Permanganate • Liquid - Sodium Permanganate • Permanganate Applications • Water and Wastewater Treatment • Site Remediation • Industrial Applications • CARULITE ® Catalysts • Carbon Monoxide Destruction • Ozone Destruction • Ethylene Oxide destruction 4
  • 5. 1 CARULITE ® Breathing Air Applications 5
  • 6. 1 CARULITE ® Industrial / Commercial Applications 6
  • 7. 1 Potassium Permanganate’s chemical formula is: KMnO4 Sodium Permanganate’s chemical formula is: NaMnO4 Permanganate is a stable chemical oxidizing agent, produced and delivered as a dry crystalline powder or as a concentrated liquid. Because it is stable, it can be packaged, stored and delivered to the user. What is Permanganate? 7
  • 8. 18 MANGANATE CENTRIFUGE 0XIDIZER LEACHER FILTER CAUSTIC POTASH OXYGENMANGANESE DIOXIDE MANGANATE MIX TANK CARUS CHEMICAL COMPANY CAIROX® POTASSIUM PERMANGANATE PROCESS PERMANGANATE CENTRIFUGE DRYER FREE-FLOW ADDITIVE CRYSTALLIZER LANDFILL POTASSIUM RECOVERY EVAPORATOR CONCENTRATOR CAIROX® POTASSIUM PERMANGANATE ELECTROLYTIC CELLS Potassium Permanganate Manufacturing Process
  • 10. 1 Commercial Permanganate Synthesis Reactions Starting Material Intermediate Chemistry End Product Diacetone sorbose 2-ketogulonic acid R-CH2OH ► R-COOH Ascorbic acid o-toluene sulfamide o-benzoic acid sulfimide Ar-CH3 ► Ar-COOH Saccharine Pinacolone (t-butyl methyl ketone) Trimethyl pyruvic acid (CH3) 3CCOOH ► (CH3)3COCOOH Sencor (herbicide) Sclareol Lactone Tobacco flavourant Mesitylene Trimesic acid Rocket Fuel component Beta picoline Pyradine beta carboxylic acid Nicotinic acid (Niacin) 2,3 lutidine Quinolinic acid Arsenal (herbicide) p-nitro ethyl benzene P-nitro acetophenone Chloroamphenicol (Chloromycetin) 10
  • 16. 1 Treatment of Micropollutants in Drinking Water PPCPs/EDCs Class Compound Chemical Structure Use PCP Antibacterial/ Antiseptic Triclocarban Antibacterial agent commonly used in personal care products, such as soaps and lotions PHC Analgesic Paracetamol (Acetaminophen) Used to treat pain and fever EDC Bisphenol Bisphenol A (BPA) Used in the production of certain plastics, epoxy resins, flame retardants, and rubber chemicals PHC Antiepileptic Carbamazepine (Tegretol) Treatment of epilepsy and neuropathic pain PHC Antidepressant Fluoxetine (Prozac) Treatment of major depressive disorder, OCD, panic disorder, and bulimia nervosa PHC Lipid-Regulator Gemfibrozil Gemfibrozil is the generic name used mainly to lower plasma lipid levels PHC Anti- Inflammatory Naproxen (Aleve) Relief of pain, fever, swelling, and stiffness PHC Antibiotic Sulfamethoxazole Antibiotic for bacterial infections such as bronchitis, and prostatitis 16
  • 17. 1 Wastewater Treatment / Odor Control 17
  • 19. 1 Printed Circuit Board Manufacturing 19
  • 25. 1 Technologies for Passive Treatment of Mining Influenced Water • Permanganate Tablets (Solid KMnO4) • Passive treatment for Mn/Fe removal • Viable in winter with a dispensing system that compensates for variable flows • Safe/easy transport for remote locations • Slow-release form of permanganate • Alkaline Permanganate (Liquid NaMnO4) • A single stable permanganate/pH adjusting blend for Mn/Fe removal and pH adjustment 25
  • 26. 1 World Wide Manganese Chemistry R&D • Secondary Batteries • Manganese oxides as the cathode material • Supercapacitors • Manganese oxides as the cathode material • Water Oxidation Reaction • Manganese is the active element in natures photosynthesis energy conversion process • Solar Cells • Manganese as a component in photovoltaic cells • Synthesis Catalysts • CO2 conversion, light hydrocarbon conversion 26
  • 27. 1 Municipal Water Treatment Waste Water Treatment Industrial Cleanup Chemical Manufacturing Metal Cleaning Site Remediation Refineries Electronics Agricultural Environmental Mining Air Purification Pharmaceutical There are Many Uses for Manganese! 27