The study assesses the hydrochemistry and environmental status of the Vaigai River in Tamil Nadu, India, revealing that water quality parameters such as total dissolved solids (TDS), total suspended solids (TSS), electrical conductivity (EC), dissolved oxygen (DO), and magnesium (Mg) are within permissible limits for drinking. Seasonal variations were observed, with TDS values generally higher in summer. The findings underscore the necessity of proper water treatment and management to ensure the health of aquatic ecosystems and human populations reliant on the river.