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Thinking Green
 While Teaching Chemistry at Skyline High School
How we got started
• Skyline High
  School - Ann Arbor,
  Michigan

• LEED certified
  building

• Geo-thermal

• Recycled materials

• Wind Turbine
What does Green Chemistry

                   mean at Skyline?

•   Preventing Pollution

•   Using less energy

•   Using fewer or safer
    chemicals

•   Sustaining the Earth/
    Civilization
How does Green Chemistry works towards
     SUSTAINABILITY at Skyline?
   •   Using chemicals that do not harm either our health or the
       environment.

   •   Using industrial processes that reduce or eliminate hazardous
       chemicals.

   •   Designing more efficient labs that minimize the production of waste
       materials and decreases the amount of non-renewable energy used.

   •   Incorporating Green technology and educating our student to address
       the three E’s when conducting investigations.

       •   Social Equity

       •   Economics

       •   Environment
Our Science Department’s
         Mission
• Developed a Sustainable/Green
  Chemistry course
 • Goals
   • Raise student’s awareness of Green
     Chemistry and its 12 Principles
   • As a department adhere to these
     principles when designing
     experiments.
S/G Chem I
Taken by all tenth graders
Students will be prepared to take AP Chemistry or S/G
Chem 2
I trimester course; covers some Chemistry HSCEs
Instructors practice green chemistry methods
Students learn about 12 principles of green chemistry
and investigate and conduct Presidential Green
Chemistry Award processes.
Opinion Activity

• First day of class
• Great activity to do outside with
  students.
• Have students trade answer sheets and
  try to explain why that person gave the
  answer.
Second Day of class
• Defining Sustainability

  • Students are asked to brainstorm what they
    would like to see last beyond their lifetime.

  • Break it down into the Three E’s

    • Environment

    • Social Equity

    • Economics
12 Principles of   Green Chemistry
    • Pollution Prevention
    • Atom Economy
    • Less Hazardous Synthesis
    • Design Safer Chemicals
    • Safer Solvents
    • Energy Efficiency
12 Principles of   Green Chemistry
    • Renewable Feedstocks
    • Reduce Derivatives
    • Catalysis
    • Design for Degradation
    • Real-Time Analysis
    • Accident Prevention
You expect me to explain this to a teenager!!
  •   Synonyms Simplify

      •   Activity that starts with
          common sayings and
          turning them into
          scientific terminology

      •   Example: Homo sapiens
          who reside in vitreous
          domiciles should not
          launch geological pieces.

      •   Students in groups are
          assigned one of the 12
          principles and they
          simplify it.
Recipe Rescue

• Making Lemonade
 • Using lots of unnecessary ingredients
   as a batch of lemonade is made.
 • Students write in their journals what
   things were not necessary and what
   could be changed.
Atom Economy


• We use M & M’s where the green ones
  are the molecules that we want and
  every other color is waste.
How Green is my Orange
 • Supercritical CO2
  • Students extract the essential oil d-limonene
    from the rind of orange peels.

  • Use both steam distillation and supercritical
    CO2

  • Compare the use of hazardous chemicals in
    both extractions and energy costs.
Three E’s Triangle
S/G Chem 2
Two trimester course
Covers state HSCEs for
Chemistry for 1.0 credit
Includes units in
toxicology, organic, and
polymer chemistry
Trick out my Wheels
• Manufacture a car
  paint that adheres
  to the principles of
  green chemistry as
  closely as possible
  in all areas of the
  manufacturing
  process.
Toxicology Unit
• The Dose Makes      • Environmental
  the Poison            Hazards.

• Dose Response       • Research paper on
  Relationship          organic molecules
                        and its toxicity.
• What is the Risk?

• Organic structure
  and toxicity
Polymers
• And the Award goes to ... Petretec
 • Students build dimers of
   polyethylene terephthalate (PET) as
   used in water bottles.
 • Dimers are put together to make the
   polymer and find it cannot be broken
   apart back to dimers.
Purpose of Petretec Activity
   • Look at PET plastic and consider its end use.

   • Understand various types of plastics
     formation.

   • Consider whether plastics are sustainable.

   • Consider lifecycle of a plastic

   • Difference between closed-loop and open-
     looped recycling.

   • Look at green chemistry award winning
     technology
The Footprint       of a Chemistry Teacher

  • Science teachers are acutely aware of
    the environment.
  • We also have a footprint in our
    chemistry classrooms that can have a
    profound effect on the earth.
  • We tend to conduct labs with very little
    thought as to the impact of our
    classroom on the environment.
Two most important properties of matter that we want to
         emphasize in our chemistry courses.




•Toxicity
•Impact on the environment
Chemistry in the 21st Century
•   Before we begin an experiment: How have our starting materials been made?

•   Can we trace them back to renewable resources?

•   How much waste is generated from the process?

•   What happens to our waste?

•   From where do we get the energy needed for the reaction and how is it generated?

•   Finally we will end up with a complete picture of not only what happens in our
    experiment but how our reaction interacts with the environment.

•   In most cases it will be difficult to determine all parameters in exact measures, but even
    rough estimates allow the identification of problems and opportunities for
    improvement.

•   Asking these questions in our laboratory courses will change the way students look at
    a chemical reaction and prepare them much better for the professional tasks.
Why change the way we teach
  chemistry in high school?
 • C & E News Letters to the Editor
   August 7, 2006
  • “But we should not lead our society to think
    chemists should be able to develop nontoxic
    materials. Let us provide training with a
    proper basis so that “armies of students will
    rise to the challenge and work to invent a
    safer future.”
How can we change our labs?
       ACS, Beyond Benign & Univ. of Oregon
            http://www.beyondbenign.org/
  Beyond Benign has Green Chemistry Info, lesson plans,
                      resources.

      http://greenchem.uoregon.edu/gems.html
Greener Education Materials for Chemists from the Univeristy
                       of Oregon

                        www.acs.org
  American Chemical Society has Green Chemistry Institute;
             Info, lesson plans and resources.
Chemistry Textbook
 A Natural Approach to Chemistry
Feel free to contact me :)
   Kathe Blue Hetter
 hetter@aaps.k12.mi.us

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Kathe Skyline Green Chemistry

  • 1. Thinking Green While Teaching Chemistry at Skyline High School
  • 2. How we got started • Skyline High School - Ann Arbor, Michigan • LEED certified building • Geo-thermal • Recycled materials • Wind Turbine
  • 3. What does Green Chemistry mean at Skyline? • Preventing Pollution • Using less energy • Using fewer or safer chemicals • Sustaining the Earth/ Civilization
  • 4. How does Green Chemistry works towards SUSTAINABILITY at Skyline? • Using chemicals that do not harm either our health or the environment. • Using industrial processes that reduce or eliminate hazardous chemicals. • Designing more efficient labs that minimize the production of waste materials and decreases the amount of non-renewable energy used. • Incorporating Green technology and educating our student to address the three E’s when conducting investigations. • Social Equity • Economics • Environment
  • 5. Our Science Department’s Mission • Developed a Sustainable/Green Chemistry course • Goals • Raise student’s awareness of Green Chemistry and its 12 Principles • As a department adhere to these principles when designing experiments.
  • 6. S/G Chem I Taken by all tenth graders Students will be prepared to take AP Chemistry or S/G Chem 2 I trimester course; covers some Chemistry HSCEs Instructors practice green chemistry methods Students learn about 12 principles of green chemistry and investigate and conduct Presidential Green Chemistry Award processes.
  • 7. Opinion Activity • First day of class • Great activity to do outside with students. • Have students trade answer sheets and try to explain why that person gave the answer.
  • 8. Second Day of class • Defining Sustainability • Students are asked to brainstorm what they would like to see last beyond their lifetime. • Break it down into the Three E’s • Environment • Social Equity • Economics
  • 9. 12 Principles of Green Chemistry • Pollution Prevention • Atom Economy • Less Hazardous Synthesis • Design Safer Chemicals • Safer Solvents • Energy Efficiency
  • 10. 12 Principles of Green Chemistry • Renewable Feedstocks • Reduce Derivatives • Catalysis • Design for Degradation • Real-Time Analysis • Accident Prevention
  • 11. You expect me to explain this to a teenager!! • Synonyms Simplify • Activity that starts with common sayings and turning them into scientific terminology • Example: Homo sapiens who reside in vitreous domiciles should not launch geological pieces. • Students in groups are assigned one of the 12 principles and they simplify it.
  • 12. Recipe Rescue • Making Lemonade • Using lots of unnecessary ingredients as a batch of lemonade is made. • Students write in their journals what things were not necessary and what could be changed.
  • 13. Atom Economy • We use M & M’s where the green ones are the molecules that we want and every other color is waste.
  • 14. How Green is my Orange • Supercritical CO2 • Students extract the essential oil d-limonene from the rind of orange peels. • Use both steam distillation and supercritical CO2 • Compare the use of hazardous chemicals in both extractions and energy costs.
  • 16.
  • 17. S/G Chem 2 Two trimester course Covers state HSCEs for Chemistry for 1.0 credit Includes units in toxicology, organic, and polymer chemistry
  • 18. Trick out my Wheels • Manufacture a car paint that adheres to the principles of green chemistry as closely as possible in all areas of the manufacturing process.
  • 19. Toxicology Unit • The Dose Makes • Environmental the Poison Hazards. • Dose Response • Research paper on Relationship organic molecules and its toxicity. • What is the Risk? • Organic structure and toxicity
  • 20. Polymers • And the Award goes to ... Petretec • Students build dimers of polyethylene terephthalate (PET) as used in water bottles. • Dimers are put together to make the polymer and find it cannot be broken apart back to dimers.
  • 21. Purpose of Petretec Activity • Look at PET plastic and consider its end use. • Understand various types of plastics formation. • Consider whether plastics are sustainable. • Consider lifecycle of a plastic • Difference between closed-loop and open- looped recycling. • Look at green chemistry award winning technology
  • 22. The Footprint of a Chemistry Teacher • Science teachers are acutely aware of the environment. • We also have a footprint in our chemistry classrooms that can have a profound effect on the earth. • We tend to conduct labs with very little thought as to the impact of our classroom on the environment.
  • 23. Two most important properties of matter that we want to emphasize in our chemistry courses. •Toxicity •Impact on the environment
  • 24. Chemistry in the 21st Century • Before we begin an experiment: How have our starting materials been made? • Can we trace them back to renewable resources? • How much waste is generated from the process? • What happens to our waste? • From where do we get the energy needed for the reaction and how is it generated? • Finally we will end up with a complete picture of not only what happens in our experiment but how our reaction interacts with the environment. • In most cases it will be difficult to determine all parameters in exact measures, but even rough estimates allow the identification of problems and opportunities for improvement. • Asking these questions in our laboratory courses will change the way students look at a chemical reaction and prepare them much better for the professional tasks.
  • 25. Why change the way we teach chemistry in high school? • C & E News Letters to the Editor August 7, 2006 • “But we should not lead our society to think chemists should be able to develop nontoxic materials. Let us provide training with a proper basis so that “armies of students will rise to the challenge and work to invent a safer future.”
  • 26. How can we change our labs? ACS, Beyond Benign & Univ. of Oregon http://www.beyondbenign.org/ Beyond Benign has Green Chemistry Info, lesson plans, resources. http://greenchem.uoregon.edu/gems.html Greener Education Materials for Chemists from the Univeristy of Oregon www.acs.org American Chemical Society has Green Chemistry Institute; Info, lesson plans and resources.
  • 27. Chemistry Textbook A Natural Approach to Chemistry
  • 28. Feel free to contact me :) Kathe Blue Hetter hetter@aaps.k12.mi.us

Editor's Notes