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H. Arabshahi and Z. Momeni / International Journal of Engineering Research and Applications
(IJERA) ISSN: 2248-9622 www.ijera.com
Vol. 3, Issue 4, Jul-Aug 2013, pp.1625-1626
1625 | P a g e
The Theoretical Study of Affecting Factor on the Performance of
Silica Solar Cells with P-N Junction
1
Hadi Arabshahi, 2
Zahra Momeni and 2
Parisa Ashori
1
Department of Physics, Payame Noor University, Tehran, Iran
2
Department of Physics, Payame Noor University, Mashhad, Iran
ABSTRACT
In this study one–dimensional PC1D
software is used to simulate the solar cell and the
effect of different factors, such as anti –reflective
coating; textured surface of cell and impurity of
density on the performance and efficiency of solar
cells has been studied. The result show that by
increasing impurities, the open circuit voltage
(Voc) increase and the short circuit current (I sc)
decrease. The optimum amount of impurities,
which is achieved the highest efficiency is about
1×1017cm-3
.
Keywords – Optimize of efficiency, anti-reflection
coating, and solar cell.
I. INTRODUCTION
Solar cells are optoelectronic devices, which
convert sunlight directly to electricity. Due to decrease
of the fossil fuel reserves, the basic requirement for
achieving these tools can be fully felt. Currently, due
to the high costs of making these cells and the very
low efficiency, use of these devices to produce energy
is not economical. Solar cells are usually forms from a
P-N bond. To make P-N bond, first, extract silicon
from the soil, which is the most abundant element, and
pure it about 99.9%. Ten it has been in single–crystal
called crystalline and with the injunction of both
impurities in it, and finally to bond P-N, phosphorus
impurities are distributed over the surface of P [1].
T study the performance of these cells and the
effect of various parameters on their performance and
finally the designing of cells with better efficiency,
some software is designed to examine the relationship
of optoelectronic devices. After design and simulation
of cells, according to scientific limits governing this
device, the results are analyzed. One of the software
that is designed to simulate the solar cell is PC1D, and
one-dimensional software [2]. In this software,
transport equations of charge carriers in the
semiconductor and Poisson's equation are solved using
Newton repetition and then the effect of parameters
such as anti-reflective coating, the amount of
impurities (base), the BFS factor, cell thickness,
distribution of impurity phosphorus on emitter, carrier
diffusion length and temperature on the cell
performance of that with proper choice of parameters,
the cell [3].
Comparing the efficiency of the cells with the
specified characteristics which are simulated by
software and cells mode in the laboratory with the
Same characteristics, it can be seen that the obtained
efficiency for laboratory cell is usually less than
calculated efficiency.
One of the reasons which can be seen from
this is that the small amount of sunlight that shines on
the cell surface is absorbed by the anti- reflective
coating, and this is not considered in the calculations.
In practice is attempted to choose the appropriate thick
ness of material to use in coating, so it can absorb as
much as possible.
II. METHOD OF CALCULATIONS AND
DISCUSSION
We consider four silica cells with a thickness
of 300 cm and a specific base resistance of 0.8 Ω-cm
which are on the average solar radiation intensity of
0.1 w/cm2
. We consider sample A as a cell which its
emitter is impure the density of 1×1020 cm-3 and the
depth of 0.5 cm and its upper surface has a constant
reflection of 30 percent . We consider sample B as cell
A with the difference that its surface is covered by a
three –layer anti- reflective coating of MgF2/ZnS/Sio2
which is bring the reflections in the range of 600-1000
nanometers ware length to the amount of less than four
percent [4].
Coating upper surface of cell by these layers
considering the reflective index and the thickness of
these layers increases the optical absorption coefficient
and thus increase the number of generated electron –
hole pairs and eventually leads to a significant increase
in I se [5].
Also, because of Sio2 that acts as an
insulating layer in a three–layer coating, speeds of
recombination in the front surface of cell will decrease
[6]. As a result, the reduction increases Voc about
7mV. Consider sample cell C with the characteristics
of cell B. with the difference that we add BFS factor
with the impurity density of 5×1019
m-3
and thickness
of 5µm(BSF of a P-N bond cell means that a layer
with high impurity (P+) is linked to the P district at a
low surface of cell).Increasing of BSF in cell decrease
the re combination in lower surface of cell and also the
potential barrier height between the metal and the
semiconductor can be increased by this factor [1]. So
the reverse saturation current 10 is reduced and Voc is
increased. Also considering junction at the bottom of
H. Arabshahi and Z. Momeni / International Journal of Engineering Research and Applications
(IJERA) ISSN: 2248-9622 www.ijera.com
Vol. 3, Issue 4, Jul-Aug 2013, pp.1625-1626
1626 | P a g e
the cell, we have contact with small ohmic resistance
which is reduce power dissipation and improve
efficiency of cell.
Fig 1. Change of Voc according to base impurity.
ISC_NA
28
29
30
31
32
33
34
1.00E+15 1.00E+16 1.00E+17 1.00E+18 1.00E+19
NA(cm
-3
)
ISC(mA)
with BSF
without BSF
Fig 2. Changes in short circuit current according to
changes in amount of impurity.
13.5
14
14.5
15
15.5
16
16.5
17
17.5
1.00E
+15
1.00E
+16
1.00E
+17
1.00E
+18
1.00E
+19
NA(cm-3
)
Eff(%)
with BSF
without BSF
Fig 3. Changes in cell efficiency according to
changing the amount of impurity.
REFRENCES
[1] M.A.Green; "Solar Cell Operating Principles
Technology and System Applications ",
(1982).
[2] D. A. Clugston, and P.A Basore, " PC1D
Version 5:32- bit solar cell simulation on
Personal computers ", Proc .26 TH IEEE
Photovoltaic Specialists Conf. Anaheim CA
(IEEE NewYork 1997) P.207.
H. J. Hovel;" Solar Cells, Semiconductor and
Semimetals Series" (New York, Academic
press), (1975).
[3] A. Meijerink, R. E. L. Schropp, " Modeling
Improvement of Spectral Response of Solar
Cells by Deployment of Spectral Converts
Containing Semiconductor Nano-crystalline
"; 8 (2004).
[4] E. S. Heavens, "Optical Properties of Thin
Solid Films ", (London, Butterwarths) (1955),
See also http:// www.thinfilmcenter.com/.
[5] H.B.Serreze," Optimization Solar Cell by
Simultaneous Consideration of Grid
Pattern Design and Interconnect
Configuration”, pp. 609-614. (2002). [7]
P. A. Bsore, "Extended Spectral Analysis of
Internal Quantum Efficiency", 23rd IEEE
PVSC, (1993), pp. 147-152.
[6] J. Streentman, "Solid State and
Semiconductor Devices" (1978).
VOC_NA
605
610
615
620
625
630
635
1.00E+15 1.00E+16 1.00E+17 1.00E+18 1.00E+19
NA(cm
-3
)
VOC(mV)
with BSF
without BSF

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  • 1. H. Arabshahi and Z. Momeni / International Journal of Engineering Research and Applications (IJERA) ISSN: 2248-9622 www.ijera.com Vol. 3, Issue 4, Jul-Aug 2013, pp.1625-1626 1625 | P a g e The Theoretical Study of Affecting Factor on the Performance of Silica Solar Cells with P-N Junction 1 Hadi Arabshahi, 2 Zahra Momeni and 2 Parisa Ashori 1 Department of Physics, Payame Noor University, Tehran, Iran 2 Department of Physics, Payame Noor University, Mashhad, Iran ABSTRACT In this study one–dimensional PC1D software is used to simulate the solar cell and the effect of different factors, such as anti –reflective coating; textured surface of cell and impurity of density on the performance and efficiency of solar cells has been studied. The result show that by increasing impurities, the open circuit voltage (Voc) increase and the short circuit current (I sc) decrease. The optimum amount of impurities, which is achieved the highest efficiency is about 1×1017cm-3 . Keywords – Optimize of efficiency, anti-reflection coating, and solar cell. I. INTRODUCTION Solar cells are optoelectronic devices, which convert sunlight directly to electricity. Due to decrease of the fossil fuel reserves, the basic requirement for achieving these tools can be fully felt. Currently, due to the high costs of making these cells and the very low efficiency, use of these devices to produce energy is not economical. Solar cells are usually forms from a P-N bond. To make P-N bond, first, extract silicon from the soil, which is the most abundant element, and pure it about 99.9%. Ten it has been in single–crystal called crystalline and with the injunction of both impurities in it, and finally to bond P-N, phosphorus impurities are distributed over the surface of P [1]. T study the performance of these cells and the effect of various parameters on their performance and finally the designing of cells with better efficiency, some software is designed to examine the relationship of optoelectronic devices. After design and simulation of cells, according to scientific limits governing this device, the results are analyzed. One of the software that is designed to simulate the solar cell is PC1D, and one-dimensional software [2]. In this software, transport equations of charge carriers in the semiconductor and Poisson's equation are solved using Newton repetition and then the effect of parameters such as anti-reflective coating, the amount of impurities (base), the BFS factor, cell thickness, distribution of impurity phosphorus on emitter, carrier diffusion length and temperature on the cell performance of that with proper choice of parameters, the cell [3]. Comparing the efficiency of the cells with the specified characteristics which are simulated by software and cells mode in the laboratory with the Same characteristics, it can be seen that the obtained efficiency for laboratory cell is usually less than calculated efficiency. One of the reasons which can be seen from this is that the small amount of sunlight that shines on the cell surface is absorbed by the anti- reflective coating, and this is not considered in the calculations. In practice is attempted to choose the appropriate thick ness of material to use in coating, so it can absorb as much as possible. II. METHOD OF CALCULATIONS AND DISCUSSION We consider four silica cells with a thickness of 300 cm and a specific base resistance of 0.8 Ω-cm which are on the average solar radiation intensity of 0.1 w/cm2 . We consider sample A as a cell which its emitter is impure the density of 1×1020 cm-3 and the depth of 0.5 cm and its upper surface has a constant reflection of 30 percent . We consider sample B as cell A with the difference that its surface is covered by a three –layer anti- reflective coating of MgF2/ZnS/Sio2 which is bring the reflections in the range of 600-1000 nanometers ware length to the amount of less than four percent [4]. Coating upper surface of cell by these layers considering the reflective index and the thickness of these layers increases the optical absorption coefficient and thus increase the number of generated electron – hole pairs and eventually leads to a significant increase in I se [5]. Also, because of Sio2 that acts as an insulating layer in a three–layer coating, speeds of recombination in the front surface of cell will decrease [6]. As a result, the reduction increases Voc about 7mV. Consider sample cell C with the characteristics of cell B. with the difference that we add BFS factor with the impurity density of 5×1019 m-3 and thickness of 5µm(BSF of a P-N bond cell means that a layer with high impurity (P+) is linked to the P district at a low surface of cell).Increasing of BSF in cell decrease the re combination in lower surface of cell and also the potential barrier height between the metal and the semiconductor can be increased by this factor [1]. So the reverse saturation current 10 is reduced and Voc is increased. Also considering junction at the bottom of
  • 2. H. Arabshahi and Z. Momeni / International Journal of Engineering Research and Applications (IJERA) ISSN: 2248-9622 www.ijera.com Vol. 3, Issue 4, Jul-Aug 2013, pp.1625-1626 1626 | P a g e the cell, we have contact with small ohmic resistance which is reduce power dissipation and improve efficiency of cell. Fig 1. Change of Voc according to base impurity. ISC_NA 28 29 30 31 32 33 34 1.00E+15 1.00E+16 1.00E+17 1.00E+18 1.00E+19 NA(cm -3 ) ISC(mA) with BSF without BSF Fig 2. Changes in short circuit current according to changes in amount of impurity. 13.5 14 14.5 15 15.5 16 16.5 17 17.5 1.00E +15 1.00E +16 1.00E +17 1.00E +18 1.00E +19 NA(cm-3 ) Eff(%) with BSF without BSF Fig 3. Changes in cell efficiency according to changing the amount of impurity. REFRENCES [1] M.A.Green; "Solar Cell Operating Principles Technology and System Applications ", (1982). [2] D. A. Clugston, and P.A Basore, " PC1D Version 5:32- bit solar cell simulation on Personal computers ", Proc .26 TH IEEE Photovoltaic Specialists Conf. Anaheim CA (IEEE NewYork 1997) P.207. H. J. Hovel;" Solar Cells, Semiconductor and Semimetals Series" (New York, Academic press), (1975). [3] A. Meijerink, R. E. L. Schropp, " Modeling Improvement of Spectral Response of Solar Cells by Deployment of Spectral Converts Containing Semiconductor Nano-crystalline "; 8 (2004). [4] E. S. Heavens, "Optical Properties of Thin Solid Films ", (London, Butterwarths) (1955), See also http:// www.thinfilmcenter.com/. [5] H.B.Serreze," Optimization Solar Cell by Simultaneous Consideration of Grid Pattern Design and Interconnect Configuration”, pp. 609-614. (2002). [7] P. A. Bsore, "Extended Spectral Analysis of Internal Quantum Efficiency", 23rd IEEE PVSC, (1993), pp. 147-152. [6] J. Streentman, "Solid State and Semiconductor Devices" (1978). VOC_NA 605 610 615 620 625 630 635 1.00E+15 1.00E+16 1.00E+17 1.00E+18 1.00E+19 NA(cm -3 ) VOC(mV) with BSF without BSF