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Isosteric Heat of Adsorption
Isosteric heat of adsorption is one of the basic quantities in the adsorption studies, which is define as the ratio of the
infinitesimal change in the adsorbate enthalpy to the infinitesimal change in the amount adsorbed. The information
regarding the heat released is important in the kinetic studies because when heat is released due to adsorption the released
energy is partly absorbed by the solid adsorbent and partly released to surrounding. The portion absorbed by the solid
increases the particle temperature and it is this rise in temperature that slow down the adsorption kinetics because the mass
uptake controlled by the rate of cooling of the particle in the later course of adsorption
The isosteric heat may or may not vary with loading. It is calculated from the following thermodynamic equation
This equation is applied with the assumption that the volume of the adsorbed phase is negligible which is not true at high
pressure so the equation is further modified by Chakrabarty et al., which is given in equation
Hear the first term of the right hand side is derived from Clausius-Clayperon equation and the second term comes due to
non ideality of the gas.
Gold APP Instruments Corporation China is a professional researcher and manufacturer for laboratory and analytical
instruments, such as BET surface area analyzer, surface area and pore size analyzer, gas pycnometer true density analyzer,
high pressure and high temperature gas adsorption analyzer, sample preparation degasser and so on for particle, porous,
powder and fiber materials by measuring methods BET surface area method, Langmuir surface area, t-plot, BJH pore size,
pore volume, pore size distribution, MP micropore, SF, HK, DR, DA micropore and mesopore analyzing. Welcome to find
more from our web www.jinaipu.com or email to sales@jinaipu.com.

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Isosteric heat of adsorption

  • 1. GOLD APP INSTRUMENTS CHINA 1 Address: Floor 6th , Tianli Building, No.56th , Zhichun Rd., Haidian Dist., Beijing 100098, CHINA Tel:(8610)-82132122, Mobile:(86)-18210009838, Fax:(8610)-82118197, Skype:Gold-APP-Instruments http://www.jinaipu.com Email: sales@jinaipu.com Lead You to Particles World Better Isosteric Heat of Adsorption Isosteric heat of adsorption is one of the basic quantities in the adsorption studies, which is define as the ratio of the infinitesimal change in the adsorbate enthalpy to the infinitesimal change in the amount adsorbed. The information regarding the heat released is important in the kinetic studies because when heat is released due to adsorption the released energy is partly absorbed by the solid adsorbent and partly released to surrounding. The portion absorbed by the solid increases the particle temperature and it is this rise in temperature that slow down the adsorption kinetics because the mass uptake controlled by the rate of cooling of the particle in the later course of adsorption The isosteric heat may or may not vary with loading. It is calculated from the following thermodynamic equation This equation is applied with the assumption that the volume of the adsorbed phase is negligible which is not true at high pressure so the equation is further modified by Chakrabarty et al., which is given in equation Hear the first term of the right hand side is derived from Clausius-Clayperon equation and the second term comes due to non ideality of the gas. Gold APP Instruments Corporation China is a professional researcher and manufacturer for laboratory and analytical instruments, such as BET surface area analyzer, surface area and pore size analyzer, gas pycnometer true density analyzer, high pressure and high temperature gas adsorption analyzer, sample preparation degasser and so on for particle, porous, powder and fiber materials by measuring methods BET surface area method, Langmuir surface area, t-plot, BJH pore size, pore volume, pore size distribution, MP micropore, SF, HK, DR, DA micropore and mesopore analyzing. Welcome to find more from our web www.jinaipu.com or email to sales@jinaipu.com.