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Greenhouse Water

Recycling and Reusing Water
    Steven E. Newman, Ph.D., A.A.F.
    Greenhouse Crops Extension Specialist and
    Professor of Floriculture
    Colorado State University Extension
Water Quality

Water is the one factor that will more than
 likely ultimately control the population
 growth of Colorado
Water is also one of the major factors of a
 greenhouse that influence crop
 productivity
Water quality is just as important as water
 quantity
Water Quality

 Greenhouses get
  their water from three
  sources:
  – Agricultural wells
Water Quality

 Greenhouses get
  their water from three
  sources:
  – Agricultural wells
  – Surface irrigation
    canals or reservoirs
Water Quality

 Greenhouses get
  their water from three
  sources:
  – Agricultural wells
  – Surface irrigation
    canals or reservoirs
  – Municipal providers
     • well or surface
How do we measure water quality?


 Alkalinity
 Salinity
 pH
 Sodium Absorption
  Ratio
 Specific Ions
 Suspended Solids
Alkalinity

 The ability to neutralize acid
  (meq·L-1) or ppm (upper limits)
   – 2 meq·L-1 = 100 ppm alkalinity
     as total carbonates
   – 122 ppm bicarbonates (HCO3 )
     1 meq·L-1 = 122 ppm
   – Hardness (Ca + Mg) 150 ppm
     as CaCO3
 Restrictions to use:
   – <2       None
   – 2-8.5    Slight to
     moderate
   – > 8.5    Severe
Salinity

 Total dissolved solids
 Measured by electrical
  conductivity
   – determined by passing a
     current through the solution
     and determining its
     electrical conductance
   – units are millimhos/cm, or
   – decisiemens/meter (dS/m)
Irrigation Water Sanitation

                  Pythium          Plant pathogens
                                   have been found in
                                   irrigation water

  Fusarium                       Nematodes


Phytophthora                Tobacco mosaic virus




                  Erwinia
Irrigation Water and Fungicides




Fungicides are often considered to be the grower’s
first line of defense.

• Intended to be applied to the substrate
• May be applied through the irrigation system
• Blending with irrigation is a violation of the label
Irrigation Water Disinfection

UV-C Sterilization
Heat Treatment
Chlorination
Ozone Treatment
Hydrogen Peroxide
Ultraviolet (UV) Radiation




UV-radiation is electro-
                                   Visible light 200
magnetic energy between
                                   and 400 nm
200 and 400 nm
UV Radiation


                                                           UV Radiation


                                                     UV-A                         UV-B
                                                  315-400 nm                   290-315 nm
                                                  Smog, fades                 Effects plants
                                                    fabrics                    and animals



                                                                   UV-C
                                                                  220-290
Movie courtesy of the NASA/Goddard Space Flight                 Absorbed by
Center Scientific Visualization Studio                          ozone layer
UV-C Sterilization
                                                                      UV-C dose assuming
   Plant Diseases                                                               25% clarity
                                                                      Priva@ Vialux system

  Bacteria, nematodes
Pythium, Phytophthora           80
         and Fusarium

  Pepino mosaic virus                         150

        Other viruses                                           250


                        0      50       100     150       200     250
                                                      2
                                    UV-C dose (mJ/cm )


                            H 310 Greenhouse Management
UV-C for Greenhouse Irrigation




         H 310 Greenhouse
         Management
Vialux Disinfection System




    H 310 Greenhouse
    Management
Vialux Disinfection System




Multimedia     Acid injection
filter
             H 310 Greenhouse
             Management
Vialux Disinfection System




UV-C Lamp
chamber




                H 310 Greenhouse
                Management
Issues With UV-C Disinfection




                           Issues:
                           • Turbidity
                           • Scale
                           • No residual
                             disinfection


        H 310 Greenhouse
        Management
Heat Pasteurization of Water




                  Heat Pasteurization
                  203 F for 30 seconds




      H 310 Greenhouse
      Management
Heat Pasteurization of Water

Hot water pasteurization for greenhouse irrigation water




               H 310 Greenhouse
               Management
Cost of Heat Pasteurization



      Natural Gas Consumption

        270-530 ft3 fuel / 100 gallons water
          or 3-5 therms / 100 gallons water




     H 310 Greenhouse
     Management
Oxidation Reduction



Oxidation is defined as an
increase in the positive
oxidation number with a
corresponding loss of electrons


Reduction is a decrease in
the positive number of
ions with a corresponding
gain in electrons

                             H 310 Greenhouse
                             Management
Industrial Oxidizing Compounds

Common industrial oxidizers and their potential relative to chlorine
                              Oxidation potential   Oxidation relative
Oxidant                              (mV)              to chlorine
Fluorine                             3,050                 2.25
Ozone                                2,070                 1.52
Hydrogen peroxide                    1,780                 1.31
Potassium permanganate               1,680                 1.25
Chlorine dioxide                     1,570                 1.15
Chlorine                             1,360                 1.00
Bromine                              1,070                 0.70

                     H 310 Greenhouse
                     Management
Hypochlorous Acid and pH

Water solutions of sodium hypochlorite and its impact on
oxidation reduction potential and pH
                       Oxidation potential
     NaOCl (%)                (mV)                 pH
       Water                  210                  6.8
        0.3                   715                  8.9
        0.5                   690                  9.6
        1.0                   655                  10.1
        1.5                   630                  10.6
        2.0                   599                  11.2
        3.0                   570                  11.7

                 H 310 Greenhouse
                 Management
Oxidation Reduction and pH


                         OCl-




                         pH



                         HOCl
      H 310 Greenhouse
      Management
Oxidation Reduction and pH


                                    Acid injection
Regal geranium
stock plants
   ------------------
Hypochlorous
acid injected into
irrigation water




                        H 310 Greenhouse
                        Management
Oxidation Reduction and Cl


                            Colorado
                          Greenhouse
                            Example
                        ---------------------
                        With acid injection
                          ORP=825 mV
                           Free Cl=1.4
                          Total Cl=2.25




     H 310 Greenhouse
     Management
ORP and Pathogen Survival

Pathogen survival from laboratory simulations and
   hydrocooler studies according to Suslow (2003)
                                     Survival at ORP (mV)
Pathogen                     < 485       550<X<620          >665
E. coli O157:H7             > 300 s         < 60 s      < 10 s
Salmonella spp.             > 300 s        > 300 s      < 20 s
L. monocytogenes            > 300 s        > 300 s      < 20 s
Thermotolerant coliform     > 48 hr        > 48 hr      < 30 s

                   H 310 Greenhouse
                   Management
ORP Measurement and
                             Chlorine

Panel Mount with Installed      Handheld
      ORP Electrode             ORP Meter




                                            $135-$150




                                 Free
                                Chlorine

                      H 310 Greenhouse
                      Management
Chlorine Sources


Sources                   Chlorine reaction in water

Chlorine gas              Cl2 + H2O 4 HCl + HOCl

Sodium hypochlorite       NaOCl + H2O 4 NaOH + HOCl

Calcium hypochlorite      Ca(OCl)2 + 2 H2O 4 Ca(OH)2 + 2 HOCl

Chlorine dioxide          HOCl+HCl+2NaClO2 4 2ClO2+2NaCl+H2O

                       H 310 Greenhouse
                       Management
Chlorine Gas


     Chlorine Gas
 --------------------------
  Cheapest source
Inject at 25-200 ppm
Most active pH 6-7.5

Dangerous to handle




          H 310 Greenhouse
          Management
Sodium Hypochlorite

                   Chemical
                   Injectors




H 310 Greenhouse
Management
Hypochlorous Acid (OxcideTM)




Metering
Pumps




           H 310 Greenhouse
           Management
Calcium Hypochlorite

                           High volume system




Tablet
reservoir
      HOCl
      concentrate
                    H 310 Greenhouse
                    Management
Calcium Hypochlorite

             Medium volume
             system        Water
                           Storage




Tablet
feeder

         H 310 Greenhouse
         Management
Chlorine Dioxide

                                  Gas pure
                                  membrane


Sodium
chlorite
from storage
                                                      25x more active
                              +                       than chlorate
                                                      No
                           Cell              Water
                                                      trihalomethanes
               Water
       Pump                                   Weak caustic
                 Control          -           soda
                 system

                 H 310 Greenhouse
                 Management
Ozonation of Irrigation Water


Ozone occurs naturally
-------------------------------
Lightening
Automobile exhaust
Arc welders
Copy machines                                        Single bond of
                                                     ozone is unstable
                                                     and will oxidize
                                                     organic materials




                                  H 310 Greenhouse
                                  Management
Ozone Generator

            Electrode chambers

Air inlet



O3 outlet



             Air pump

             H 310 Greenhouse
             Management
Ozone Generator




H 310 Greenhouse
Management
Hydrogen Peroxide

Common industrial oxidizers and their potential relative to chlorine
                              Oxidation potential   Oxidation relative
Oxidant                              (mV)              to chlorine
Fluorine                             3,050                 2.25
Ozone                                2,070                 1.52
Hydrogen peroxide                    1,780                 1.31
Potassium permanganate               1,680                 1.25
Chlorine dioxide                     1,570                 1.15
Chlorine                             1,360                 1.00
Bromine                              1,070                 0.70

                     H 310 Greenhouse
                     Management
Hydrogen Peroxide


                   3% as a disinfectant




                       10% for hair treatment



                          35% for greenhouse
                          and industrial
H 310 Greenhouse
Management
Hydrogen Peroxide



 ZeroTol (hydrogen dioxide)
   – Contaminated water
      • 1:500 dilution
      • 540 ppm H2O2
   – Clean water
      • 1:10,000 dilution
      • 27 ppm H2O2



                         H 310 Greenhouse
                         Management
Water in the West


With water, the law of the
West is simple:

      The first one to use it
      gets it.

This doctrine, known as "prior
appropriation," originated
during the California Gold
Rush days, with miners who
needed water for their placer
operations on public lands.

To this day, prior appropriation
governs water in nine Western      Frederick Remington’s 1903 painting “Fight for the Water Hole”
states.
Western Water Rights



"Farms and friendships
have been lost over water
rights, and the tension it
creates is more real than
in any Hollywood
Western."

             Elizabeth Arnold
        National Public Radio
                 28 Aug 2003




                                 Discussing Water Rights, A Western Pastime
                                      Duckboy Cards – Paul Stanton
Developing Water in the West

In 1878, explorer and scientist John
Wesley Powell published a report, which
laid out a concrete strategy for settling the
West without fighting over scarce water.
He wanted to stall the waves of
homesteaders moving across the plains
and mountains. He proposed planned
settlements based in part on the
cooperative model practiced in Utah by
Mormon settlers.

“If Congress had listened to Powell 125
years ago, the American West today might
be an entirely different place.”

                                Howard Berkes
                          National Public Radio
                                   26 Aug 2003

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Irrigation water recycling in the greenhouse

  • 1. Greenhouse Water Recycling and Reusing Water Steven E. Newman, Ph.D., A.A.F. Greenhouse Crops Extension Specialist and Professor of Floriculture Colorado State University Extension
  • 2. Water Quality Water is the one factor that will more than likely ultimately control the population growth of Colorado Water is also one of the major factors of a greenhouse that influence crop productivity Water quality is just as important as water quantity
  • 3. Water Quality  Greenhouses get their water from three sources: – Agricultural wells
  • 4. Water Quality  Greenhouses get their water from three sources: – Agricultural wells – Surface irrigation canals or reservoirs
  • 5. Water Quality  Greenhouses get their water from three sources: – Agricultural wells – Surface irrigation canals or reservoirs – Municipal providers • well or surface
  • 6. How do we measure water quality?  Alkalinity  Salinity  pH  Sodium Absorption Ratio  Specific Ions  Suspended Solids
  • 7. Alkalinity  The ability to neutralize acid (meq·L-1) or ppm (upper limits) – 2 meq·L-1 = 100 ppm alkalinity as total carbonates – 122 ppm bicarbonates (HCO3 ) 1 meq·L-1 = 122 ppm – Hardness (Ca + Mg) 150 ppm as CaCO3  Restrictions to use: – <2 None – 2-8.5 Slight to moderate – > 8.5 Severe
  • 8. Salinity  Total dissolved solids  Measured by electrical conductivity – determined by passing a current through the solution and determining its electrical conductance – units are millimhos/cm, or – decisiemens/meter (dS/m)
  • 9. Irrigation Water Sanitation Pythium Plant pathogens have been found in irrigation water Fusarium Nematodes Phytophthora Tobacco mosaic virus Erwinia
  • 10. Irrigation Water and Fungicides Fungicides are often considered to be the grower’s first line of defense. • Intended to be applied to the substrate • May be applied through the irrigation system • Blending with irrigation is a violation of the label
  • 11. Irrigation Water Disinfection UV-C Sterilization Heat Treatment Chlorination Ozone Treatment Hydrogen Peroxide
  • 12. Ultraviolet (UV) Radiation UV-radiation is electro- Visible light 200 magnetic energy between and 400 nm 200 and 400 nm
  • 13. UV Radiation UV Radiation UV-A UV-B 315-400 nm 290-315 nm Smog, fades Effects plants fabrics and animals UV-C 220-290 Movie courtesy of the NASA/Goddard Space Flight Absorbed by Center Scientific Visualization Studio ozone layer
  • 14. UV-C Sterilization UV-C dose assuming Plant Diseases 25% clarity Priva@ Vialux system Bacteria, nematodes Pythium, Phytophthora 80 and Fusarium Pepino mosaic virus 150 Other viruses 250 0 50 100 150 200 250 2 UV-C dose (mJ/cm ) H 310 Greenhouse Management
  • 15. UV-C for Greenhouse Irrigation H 310 Greenhouse Management
  • 16. Vialux Disinfection System H 310 Greenhouse Management
  • 17. Vialux Disinfection System Multimedia Acid injection filter H 310 Greenhouse Management
  • 18. Vialux Disinfection System UV-C Lamp chamber H 310 Greenhouse Management
  • 19. Issues With UV-C Disinfection Issues: • Turbidity • Scale • No residual disinfection H 310 Greenhouse Management
  • 20. Heat Pasteurization of Water Heat Pasteurization 203 F for 30 seconds H 310 Greenhouse Management
  • 21. Heat Pasteurization of Water Hot water pasteurization for greenhouse irrigation water H 310 Greenhouse Management
  • 22. Cost of Heat Pasteurization Natural Gas Consumption 270-530 ft3 fuel / 100 gallons water or 3-5 therms / 100 gallons water H 310 Greenhouse Management
  • 23. Oxidation Reduction Oxidation is defined as an increase in the positive oxidation number with a corresponding loss of electrons Reduction is a decrease in the positive number of ions with a corresponding gain in electrons H 310 Greenhouse Management
  • 24. Industrial Oxidizing Compounds Common industrial oxidizers and their potential relative to chlorine Oxidation potential Oxidation relative Oxidant (mV) to chlorine Fluorine 3,050 2.25 Ozone 2,070 1.52 Hydrogen peroxide 1,780 1.31 Potassium permanganate 1,680 1.25 Chlorine dioxide 1,570 1.15 Chlorine 1,360 1.00 Bromine 1,070 0.70 H 310 Greenhouse Management
  • 25. Hypochlorous Acid and pH Water solutions of sodium hypochlorite and its impact on oxidation reduction potential and pH Oxidation potential NaOCl (%) (mV) pH Water 210 6.8 0.3 715 8.9 0.5 690 9.6 1.0 655 10.1 1.5 630 10.6 2.0 599 11.2 3.0 570 11.7 H 310 Greenhouse Management
  • 26. Oxidation Reduction and pH OCl- pH HOCl H 310 Greenhouse Management
  • 27. Oxidation Reduction and pH Acid injection Regal geranium stock plants ------------------ Hypochlorous acid injected into irrigation water H 310 Greenhouse Management
  • 28. Oxidation Reduction and Cl Colorado Greenhouse Example --------------------- With acid injection ORP=825 mV Free Cl=1.4 Total Cl=2.25 H 310 Greenhouse Management
  • 29. ORP and Pathogen Survival Pathogen survival from laboratory simulations and hydrocooler studies according to Suslow (2003) Survival at ORP (mV) Pathogen < 485 550<X<620 >665 E. coli O157:H7 > 300 s < 60 s < 10 s Salmonella spp. > 300 s > 300 s < 20 s L. monocytogenes > 300 s > 300 s < 20 s Thermotolerant coliform > 48 hr > 48 hr < 30 s H 310 Greenhouse Management
  • 30. ORP Measurement and Chlorine Panel Mount with Installed Handheld ORP Electrode ORP Meter $135-$150 Free Chlorine H 310 Greenhouse Management
  • 31. Chlorine Sources Sources Chlorine reaction in water Chlorine gas Cl2 + H2O 4 HCl + HOCl Sodium hypochlorite NaOCl + H2O 4 NaOH + HOCl Calcium hypochlorite Ca(OCl)2 + 2 H2O 4 Ca(OH)2 + 2 HOCl Chlorine dioxide HOCl+HCl+2NaClO2 4 2ClO2+2NaCl+H2O H 310 Greenhouse Management
  • 32. Chlorine Gas Chlorine Gas -------------------------- Cheapest source Inject at 25-200 ppm Most active pH 6-7.5 Dangerous to handle H 310 Greenhouse Management
  • 33. Sodium Hypochlorite Chemical Injectors H 310 Greenhouse Management
  • 34. Hypochlorous Acid (OxcideTM) Metering Pumps H 310 Greenhouse Management
  • 35. Calcium Hypochlorite High volume system Tablet reservoir HOCl concentrate H 310 Greenhouse Management
  • 36. Calcium Hypochlorite Medium volume system Water Storage Tablet feeder H 310 Greenhouse Management
  • 37. Chlorine Dioxide Gas pure membrane Sodium chlorite from storage 25x more active + than chlorate No Cell Water trihalomethanes Water Pump Weak caustic Control - soda system H 310 Greenhouse Management
  • 38. Ozonation of Irrigation Water Ozone occurs naturally ------------------------------- Lightening Automobile exhaust Arc welders Copy machines Single bond of ozone is unstable and will oxidize organic materials H 310 Greenhouse Management
  • 39. Ozone Generator Electrode chambers Air inlet O3 outlet Air pump H 310 Greenhouse Management
  • 40. Ozone Generator H 310 Greenhouse Management
  • 41. Hydrogen Peroxide Common industrial oxidizers and their potential relative to chlorine Oxidation potential Oxidation relative Oxidant (mV) to chlorine Fluorine 3,050 2.25 Ozone 2,070 1.52 Hydrogen peroxide 1,780 1.31 Potassium permanganate 1,680 1.25 Chlorine dioxide 1,570 1.15 Chlorine 1,360 1.00 Bromine 1,070 0.70 H 310 Greenhouse Management
  • 42. Hydrogen Peroxide 3% as a disinfectant 10% for hair treatment 35% for greenhouse and industrial H 310 Greenhouse Management
  • 43. Hydrogen Peroxide  ZeroTol (hydrogen dioxide) – Contaminated water • 1:500 dilution • 540 ppm H2O2 – Clean water • 1:10,000 dilution • 27 ppm H2O2 H 310 Greenhouse Management
  • 44. Water in the West With water, the law of the West is simple: The first one to use it gets it. This doctrine, known as "prior appropriation," originated during the California Gold Rush days, with miners who needed water for their placer operations on public lands. To this day, prior appropriation governs water in nine Western Frederick Remington’s 1903 painting “Fight for the Water Hole” states.
  • 45. Western Water Rights "Farms and friendships have been lost over water rights, and the tension it creates is more real than in any Hollywood Western." Elizabeth Arnold National Public Radio 28 Aug 2003 Discussing Water Rights, A Western Pastime Duckboy Cards – Paul Stanton
  • 46. Developing Water in the West In 1878, explorer and scientist John Wesley Powell published a report, which laid out a concrete strategy for settling the West without fighting over scarce water. He wanted to stall the waves of homesteaders moving across the plains and mountains. He proposed planned settlements based in part on the cooperative model practiced in Utah by Mormon settlers. “If Congress had listened to Powell 125 years ago, the American West today might be an entirely different place.” Howard Berkes National Public Radio 26 Aug 2003