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Energy Resources 
Fossil Fuels 
Supervisor: PhD. Bùi Trọng Vinh 
By: Kiều Nhật Nam
Contents 
I. Introduction 
II. Oil and Natural Gas 
III. Coal 
IV. Oil shale 
V. Tar sand
Introduction
Introduction 
The fossil fuels are those energy sources that formed from the remains of 
once-living organisms. When we burn them, we are using that stored energy 
( Energy is stored in the chemical bonds of the organic compounds of living 
organisms )
Oil and Natural Gas 
1. Formation of Oil and Natural Gas Deposits 
2. Supply and Demand for Oil and Natural Gas 
3. Future Prospects 
4. Enhanced Oil Recovery 
5. Alternate Natural Gas Sources 
6. Oil Spill
Oil and Natural Gas 
1/ Formation of Oil and Natural Gas Deposits
Oil and Natural Gas 
Commercially, the most valuable deposits are those in which a large quantity of oil and/or gas has been 
concentrated and confined (trapped) by impermeable rocks in geologic structures. The reservoir rocks in 
which the oil or gas has accumulated should be relatively porous if a large quantity of petroleum is to be 
found in a small volume of rock and should also be relatively permeable so that the oil or gas flows out readily 
once a well is drilled into the reservoir. If the reservoir rocks are not naturally very permeable, it may be 
possible to fracture them artificially with explosives or with water or gas under high pressure to increase the 
rate at which oil or gas flows through them.
Oil and Natural Gas 
The amount of time required for oil and gas to form is not known precisely. Since virtually no 
petroleum is found in rocks younger than 1 to 2 million years old, geologists infer that the 
process is comparatively slow. Even if it took only a few tens of thousands of years (a 
geologically short period), the world’s oil and gas is being used up far faster than significant 
new supplies could be produced. Therefore, oil and natural gas are among the 
nonrenewable energy sources. We have an essentially finite supply with which to work.
Oil and Natural Gas 
2/ Supply and Demand for Oil and Natural Gas 
* Oil: 
Oil is commonly discussed in units of 
barrels (1 barrel = 5.42 gallons ~ 20.52 
liter). Worldwide, over one trillion 
barrels of oil have been consumed, 
according to estimates by the U.S. 
Geological Survey. The estimated 
remaining reserves are about 1.2 
trillion barrels. That does not sound too 
ominous until one realizes that close to 
half of the consumption has occurred 
in the last quarter-century or so. Also, 
global demand continues to increase 
as more countries advance 
technologically.
Oil and Natural Gas 
Oil supply and demand are 
very unevenly distributed 
around the world. Some 
low population, low-technology, 
oil-rich 
countries (Libya, for 
example) maybe 
producing fifty or a 
hundred times as much oil 
as they themselves 
consume. 
At the other extreme are 
countries like Japan, 
highly industrialized and 
energy-hungry, with no 
petroleum reserves at all.
Oil and Natural Gas 
Both U.S. and world oil supplies could be nearly exhausted within decades , 
especially considering the probable acceleration of world energy demands. On 
occasion, explorationists do find the rare, very large concentrations of petroleum 
Yet even these make only a modest difference in the long-term picture. The 
Prudhoe Bay oil field, for instance, represented reserves of only about 13 billion 
barrels, a great deal for a single region, but less than two years’ worth of U.S. 
consumption.
Oil and Natural Gas 
Concern about dependence on imported oil led to the establishment of the 
Strategic Petroleum Reserve in 1977, but the amount of oil in the SPR 
stayed at about 550 million barrels from 1980 to 2000, while the number of 
days’ worth of imports that it represents has declined from a high of 115 in 
1985 to 50 in 2002. Only renewed addition of imported oil, to raise SPR 
stocks to about 697 million barrels in 2007, reversed the decline in the 
number of days of imports held in the SPR, but that figure was still only 58 
in 2008. Such facts increase pressure to develop new domestic oil sources
Natural Gas: 
Global demand for natural gas is 
expected to expand significantly as 
more nations adopt environmentally 
cleaner fuels to meet future 
economic growth and prioritize 
alternatives to minimize the impact 
of increasing oil – based energy 
costs. The environmental benefits of 
natural gas are clear. Natural gas 
emits 43% fewer carbon emissions 
than coal, and 30% fewer emissions 
than oil, for each unit of energy 
delivered. Many of the most rapidly 
growing gas markets are in emerging 
economies in Asia, particularly India 
and China, the Middle East and 
South America, economies which 
battle the balance between air quality 
and living standards on a daily basis. 
Oil and Natural Gas
Oil and Natural Gas 
3/ Future Prospects 
Some such areas are now being explored, but with limited success. Other, more promising areas may be 
protected or environmentally sensitive. The costs of exploration have gone up, drilling for oil or gas in 2006 
cost an average of $324 per foot. The average oil or natural gas well drilled was over 6400 feet deep (it was 
about 3600 feet in 1949); even with increasingly sophisticated methods of exploration to target areas most 
likely to yield economic hydrocarbon deposits. Costs for drilling offshore are substantially higher than for 
land-based drilling. Yield from producing wells is also declining, from a peak average of 18.6 barrels of oil 
per well per day in 1972 to 10.2 barrels in 2007.
Oil and Natural Gas 
Despite a quadrupling in oil prices between 1970 and 1980 (after adjustment for 
inflation), U.S. proven reserves continued to decline. They are declining still, 
despite oil prices recently at record levels. This is further evidence that higher 
prices do not automatically lead to proportionate, or even appreciable, increases in 
fuel supplies. Also, many major oil companies have been branching out into other 
energy sources beyond oil and natural gas, suggesting an expectation of a shift 
away from petroleum in the future.
Oil and Natural Gas 
4/ Enhanced Oil Recovery 
A few techniques are being developed to increase petroleum production from known deposits. 
An oil well initially yields its oil with minimal pumping, or even “gushes” on its own, because the 
oil and any associated gas are under pressure from overlying rocks, or perhaps because the 
oil is confined like water in an artesian system. Recovery using no techniques beyond pumping 
is primary recovery. When flow falls off, water may be pumped into the reservoir, filling empty 
pores and buoying up more oil to the well (secondary recovery). Primary and secondary 
recovery together extract an average of one-third of the oil in a given trap
Oil and Natural Gas 
On average, then, two-thirds of the oil in each deposit has historically been left in the ground. 
Thus, additional enhanced recovery methods have attracted much interest. 
Enhanced recovery comprises a variety of methods beyond conventional secondary 
recovery. Permeability of rocks may be increased by deliberate fracturing, using explosives 
or even water under very high pressure. Carbon dioxide gas under pressure can be used to 
force out more oil. Hot water or steam may be pumped underground to warm thick, viscous 
oils so that they flow more easily and can be extracted more completely. 
There have also been experiments using detergents or other substances to break up the oil.
Oil and Natural Gas
Oil and Natural Gas 
However, be kept in mind that enhanced recovery may involve increases in 
problems such as ground subsidence or groundwater pollution that arise also with 
conventional recovery methods. Even conventional drilling uses large volumes of 
drilling mud to cool and lubricate the drill bits. The drilling muds may become 
contaminated with oil and must be handled carefully to avoid polluting surface or 
ground water. When water is more extensively used in fracturing rock or warming 
the oil, the potential for pollution is correspondingly greater.
Oil and Natural Gas 
5/ Alternate Natural Gas Sources: 
During coal formation, quantities of methane-rich gas are also produced. Most coal deposits contain 
significant amounts of coal-bed methane . Historically, this methane has been treated as a hazardous 
nuisance, potentially explosive, and its incidental release during coal mining has contributed to rising 
methane concentrations in the atmosphere. However, an estimated 100 trillion cubic feet of methane that 
would be economically recoverable with current technology exists in-place in U.S. coal beds. If it could 
be extracted for use rather than wasted, it could contribute significantly to U.S. gas reserves.
Oil and Natural Gas 
Some evidence suggests that additional natural gas reserves exist at very great depths in the earth. Thousands 
of meters below the surface, conditions are sufficiently hot that any oil would have been broken down to 
natural gas. This natural gas, under the tremendous pressures exerted by the overlying rock, may be dissolved 
in the water filling the pore spaces in the rock, much as carbon dioxide is dissolved in a bottle of soda. 
Pumping this water to the surface is like taking off the bottle cap: The pressure is released, and the gas 
bubbles out. Enormous quantities of natural gas might exist in such geopressurized zones ; recent estimates 
of the amount of potentially recoverable gas in this form range from 150 to 2000 trillion cubic feet.
Oil and Natural Gas 
Still more recently, the significance of methane hydrates has been increasingly discussed. 
Gas (usually methane) hydrates are crystalline solids of gas and water molecules. These 
hydrates have been found to be abundant in arctic regions and in marine sediments. The U.S. 
Geological Survey has estimated that the amount of carbon found in gas hydrates may be 
twice that in all known fossil fuels on earth, and a 2008 study suggested a probable 85 trillion 
cubic feet of (yet-undiscovered) methane in gas hydrates of Alaska’s North Slope alone. 
Methane in methane hydrate thus represents a huge potential natural gas resource. Just how 
to tap methane hydrates safely for their energy is not yet clear.
Oil and Natural Gas 
6/ Oil spills: 
Most oils and all natural gases are less dense than water, so they tend to rise as well as to migrate laterally 
through the water-filled pores of permeable rocks. Unless stopped by impermeable rocks, oil and gas may 
keep rising right up to the earth’s surface. At many known oil and gas seeps, these substances escape into the 
air or the oceans or flow out onto the ground. These natural seeps, which are one of nature’s own pollution 
sources, are not very efficient sources of hydrocarbons for fuel if compared with present drilling and extraction 
processes.
Oil and Natural Gas 
In fact, it is estimated that oil rising up through permeable rocks escapes into the 
ocean at the rate of 600,000 tons per year, though many natural seeps seal 
themselves as leakage decreases remaining pressure. Tankers that flush out their 
holds at sea continually add to the oil pollution of the oceans and, collectively, are a 
significant source of such pollution. The oil spills about which most people have 
been concerned, however, are the large, sudden, catastrophic spills that occur in 
two principal ways: from accidents during drilling of offshore oil wells and from 
wrecks of oil tankers at sea.
Oil and Natural Gas 
Oil spills represent the largest negative impacts from the extraction and 
transportation of petroleum, although as a source of water pollution, they are 
less significant volumetrically than petroleum pollution from careless disposal of 
used oil, amounting to only about 5% of petroleum released into the 
environment. And although we tend to hear only about the occasional massive, 
disastrous spill, there are many more that go unreported in the media: The U.S. 
Coast Guard reports about 10,000 spills in and around U.S. waters each year, 
totaling 15 to 25 million gallons of oil annually.
Oil and Natural Gas 
Exxon Valdez oil spill: 
The Exxon Valdez oil spill occurred in Prince William Sound, Alaska, on 
March 24, 1989, when Exxon Valdez, an oil tanker bound for Long Beach, 
California, struck Prince William Sound's Bligh Reef . More than 10 million 
gallons of oil escaped, eventually to spread over more than 900 square miles 
of water. The various cleanup efforts cost Exxon an estimated $2.5 billion 
(the worst oil spill yet in U.S. waters).
Oil and Natural Gas 
• Skimmers recovered relatively little of the oil, as is typical: Three weeks after the 
accident, only about 5% of the oil had been recovered. Chemical dispersants were 
not very successful (perhaps because their use was delayed by concerns over their 
impact on the environment), nor were attempts to burn the spill. Four days after the 
accident, the oil had emulsified by interaction with the water into a thick, mousse-like 
substance, difficult to handle, too thick to skim, impossible to break up or burn 
effectively
Oil and Natural Gas 
• Oil that had washed up on shore had coated many miles of beaches and rocky coast 
Thousands of birds and marine mammals died or were sickened by the oil. The 
annual herring season in Valdez was cancelled, and salmon hatcheries were 
threatened. When other methods failed, it seemed that only slow degradation over 
time would get rid of the oil. Given the size of the spill and the cold Alaskan 
temperatures, prospects seemed grim; microorganisms that might assist in the 
breakdown grow and multiply slowly in the cold. It appeared highly likely that the 
spill would be very persistent.
Oil and Natural Gas 
• So, in a $10-million experiment, Exxon scientists sprayed miles of beaches in 
the Sound with a fertilizer solution designed to stimulate the growth of 
naturally occurring microorganisms that are known to “eat” oil, thereby 
contributing to its decomposition. Within two weeks, treated beaches were 
markedly cleaner than untreated ones. Five months later, the treated beaches 
still showed higher levels of those microorganisms than did untreated beaches. 
This type of treatment isn’t universally successful. The fertilizer solution runs 
off rocky shores, so this treatment won’t work on rocky stretches of the oil 
contaminated coast; nor is it as effective once the oil has seeped deep into 
beach sands. But microorganisms may indeed be the future treatment of 
choice.
Oil and Natural Gas 
• In 2006, a study done by the National Marine Fisheries Service in 
Juneau found that about 9.6 kilometres of shoreline around Prince 
William Sound was still affected by the spill, with 101.6 tonnes of 
oil remaining in the area. Exxon Mobil denied any concerns over 
any remaining oil, stating that they anticipated a remaining fraction 
that they assert will not cause any long-term ecological impacts, 
according to the conclusions of the studies they had done: "We've 
done 350 peer-reviewed studies of Prince William Sound, and those 
studies conclude that Prince William Sound has recovered, it's 
healthy and it's thriving. However, in 2007 a NOAA study 
concluded that this contamination can produce chronic low-level 
exposure, discourage subsistence where the contamination is heavy, 
and decrease the "wilderness character" of the area.
Coal 
1. Formation of Coal Deposits 
2. Coal Reserves and Resources 
3. Limitations on Coal Use 
4. Environmental Impacts of Coal Use
Coal 
1/ Formation of Coal Deposits:
Coal 
The first combustible product formed under suitable conditions is peat. Further burial, with 
more heat, pressure, and time, gradually dehydrates the organic matter and transforms the 
spongy peat into soft brown coal (lignite) and then to the harder coals (bituminous/anthracite)
Coal 
2/ Coal Reserves and Resources 
The estimated world reserve of coal is about 
one trillion tons; total resources are estimated 
at over 10 trillion tons. The United States is 
particularly well supplied with coal, possessing 
about 25% of the world’s reserves, over 270 
billion tons of recoverable coal. Total U.S. coal 
resources may approach ten times that 
amount, and most of that coal is yet unused 
and unmined. At present, coal provides 
between 20 and 25% of the energy used in the 
United States. While the United States has 
consumed probably half of its total petroleum 
resources, it has used up only a few percent of 
its coal. Even if only the reserves are counted, 
the U.S. coal supply could satisfy U.S. energy 
needs for more than 200 years at current 
levels of energy use, if coal could be used for 
all purposes.
Coal 
3/ Limitations on Coal Use 
A primary limitation of coal use is that solid coal is simply not as versatile a substance as petroleum 
or natural gas. A major shortcoming is that it cannot be used directly in most forms of modern 
transportation. Coal is also a dirty and inconvenient fuel for home heating, which is why it was 
abandoned in favor of oil or natural gas. Therefore, given present technology, coal simply cannot be 
adopted as a substitute for oil in all applications.
Coal 
Coal can be converted to liquid or gaseous hydrocarbon fuels by causing the coal to react 
with steam or with hydrogen gas at high temperatures. The conversion processes are called 
gasification (when the product is gaseous) and liquefaction (when the product is liquid fuel). 
Both processes are intended to transform coal into a cleaner burning, more versatile fuel, 
thus expanding its range of possible applications.
Coal 
Commercial coal gasification has existed on some scale for 150 years. Current gasification processes 
yield a gas that is a mixture of carbon monoxide and hydrogen with a little methane. The heat derived 
from burning this mix is only 15 to 30% of what can be obtained from burning an equivalent volume of 
natural gas. Because the low heat value makes it uneconomic to transport this gas over long distances, it 
is typically burned only where produced. Technology exists to produce high-quality gas from coal, 
equivalent in heat content to natural gas, but it is presently uneconomical when compared to natural gas.
Coal 
Pilot projects are also underway to study in situ underground coal gasification, through which coal 
would be gasified in place and the gas extracted directly. The expected environmental benefits of not 
actually mining the coal include reduced land disturbance, water use, air pollution, and solid waste 
produced at the surface. Potential drawbacks include possible groundwater pollution and surface 
subsidence over gasified coal beds. Underground gasification may provide a means of using coals that 
are too thin to mine economically or that would require excessive land disruption to extract. However, 
in the near future, simple extraction of coal-bed methane is likely to yield economical gas more readily.
Coal
Coal 
Like gasification, the practice of generating liquid fuel from coal has a longer history than 
many people realize. The Germans used it to produce gasoline from their then-abundant 
coal during World War II; South Africa has a liquefaction plant in operation now, producing 
gasoline and fuel oil. Even so, their liquid fuel products have not historically been 
economically competitive with conventional petroleum. The higher gasoline prices rise, of 
course, the more economically viable coal liquefaction becomes. The most obvious 
advantage is that it would allow us to use our plentiful coal resources to meet a need now 
satisfied by petroleum, much of it imported
Coal 
4/ Environmental Impacts of Coal Use 
*Gases 
A major problem posed by coal is the pollution associated with its mining and use. Like all fossil fuels, 
coal produces carbon dioxide (CO2) when burned. In fact, it produces significantly more carbon dioxide 
per unit energy released than oil or natural gas. (It is the burning of the carbon component—making 
CO2— that is the energy-producing reaction when coal is burned; when hydrocarbons are burned, the 
reactions produce partly CO2, partly H2O as their principal by-products, the proportions varying with 
the ratio of carbon to hydrogen in the particular hydrocarbon(s).)
Coal 
The additional pollutant 
that is of special concern 
with coal is sulfur. The 
sulfur content of coal can 
be more than 3%, some in 
the form of the iron sulfide 
mineral pyrite (FeS2), 
some bound in the 
organic matter of the coal 
itself. When the sulfur is 
burned along with the 
coal, sulfur gases, notably 
sulfur dioxide (SO2), are 
produced. These gases 
are poisonous and are 
extremely irritating to eyes 
and lungs. 
60% 
7% 
5% 
15% 
3% 
10% 
Carbon 
Sulfur 
Nitrogen 
Hydrogen 
Oxygen 
Ash
Coal 
The gases also react with water in the atmosphere to produce sulfuric acid, a very strong acid. 
This acid then falls to earth as acid rainfall. Acid rain falling into streams and lakes can kill fish 
and other aquatic life. It can acidify soil, stunting plant growth. It can dissolve rock; in areas 
where acid rainfall is a severe problem, buildings and monuments are visibly corroding away 
because of the acid. The geology of acid rain is explored further in chapter 18. 
Another toxic substance of growing concern with increasing coal use is mercury. A 
common trace element in coal, mercury is also a very volatile (easily-vaporized) metal, 
so it can be released with the waste gases.
Coal 
*Ash 
Coal use also produces a great deal of solid 
waste. The ash residue left after coal is 
burned typically ranges from 5 to 20% of 
the original volume. The ash, which 
consists mostly of noncombustible silicate 
minerals, also contains toxic metals. If 
exposed at the surface, the fine ash, with its 
proportionately high surface area, may 
weather very rapidly, and the toxic metals 
such as selenium and uranium can be 
leached from it, thus posing a water-pollution 
threat. Uncontrolled erosion of 
the ash could likewise cause sediment 
pollution. The magnitude of this waste-disposal 
problem should not be 
underestimated.
Coal 
There is no obvious safe place to dump all that waste. Some is used to make 
concrete, and it has been suggested that the ash could actually serve as a useful 
source of some of the rarer metals concentrated in it. At present, however, much of 
the ash from coal combustion is deposited in landfills.
Coal 
Between combustion and disposal, the ash may be stored wet, in containment ponds. These, 
too, can pose a hazard: In December 2008, a containment pond along the Emory River in 
Tennessee failed, releasing an estimated 5.4 million cubic meters of saturated ash from the 
Kingston Fossil Plant into the river . The surge of sludge buried nearly half a square mile of 
land, damaged many homes, and released such pollutants as arsenic, chromium, and lead into 
the water. It was originally estimated, optimistically, that cleanup might take 4 to 6 weeks. It 
now appears that the process will take years, and projections of total cleanup costs range up 
to $1 billion.
Coal 
*Coal-mining hazard 
Coal mining poses further problems. Underground mining of coal is notoriously 
dangerous, as well as expensive. Mines can collapse; miners may contract black lung 
disease from breathing the dust; there is always danger of explosion from pockets of 
natural gas that occur in many coal seams. A tragic coal-mine fire in Utah in December 
1984 and a methane explosion in a Chinese coal mine in 2004 that killed over 100 people 
were reminders of the seriousness of the hazards. Recent evidence further suggests that 
coal miners are exposed to increased cancer risks from breathing the radioactive gas 
radon, which is produced by natural decay of uranium in rocks surrounding the coal seam.
Coal 
An underground fire that may have 
been started by a trash fire in an 
adjacent dump has been burning 
under Centralia, Pennsylvania, since 
1962; over 1000 residents have 
been relocated, at a cost of more 
than $40 million, and collapse and 
toxic fumes threaten the handful of 
remaining residents resisting 
evacuation. And while Centralia’s 
fire may be among the most famous, 
it is by no means the only such fire, 
and they are a problem in other 
nations as well. China relies heavily 
on coal for its energy; uncontrolled 
coal-mine fires there have cost over 
$100 million in lost coal, the carbon-dioxide 
emissions from them are 
estimated to account for several 
percent of global CO2 emissions
Coal 
• Centralia photography
Coal 
Acid Mine Drainage (AMD) 
Acid mine drainage - refers to the outflow of 
acidic water from metal mines or coal mines. 
AMD occurs naturally within some environments 
as part of the rock weathering process but is 
exacerbated by large-scale earth disturbances 
characteristic of mining and other large 
construction activities, usually within rocks 
containing an abundance of sulfide minerals. 
Areas where the earth has been disturbed (e.g. 
construction sites, subdivisions,and transportation 
corridors) may create acid rock drainage. In many 
localities, the liquid that drains from coal stocks, 
coal handling facilities, coal washeries, and coal 
waste tips can be highly acidic, and in such cases 
it is treated as acid rock drainage. 
The same type of chemical reactions and 
processes may occur through the disturbance of 
acid sulfate soils formed under coastal or 
estuarine conditions after the last major sea level 
rise, and constitutes a similar environmental 
hazard.
Coal 
Because plants grow poorly in very acid conditions, this acid slows revegetation 
of the area by stunting plant growth or even preventing it altogether. The acid 
runoff can also pollute area ground and surface waters, killing aquatic plants 
and animals in lakes and streams and contaminating the water supply. Very 
acidic water also can be particularly effective at leaching or dissolving some 
toxic elements from soils, further contributing to water pollution.
Oil shale 
Oil shale, also known as kerogen shale, is an organic-rich fine-grained sedimentary rock containing 
kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons called shale 
oil (not to be confused with tight oil—crude oil occurring naturally in shales) can be produced. Shale 
oil is a substitute for conventional crude oil; however, extracting shale oil from oil shale is more costly 
than the production of conventional crude oil both financially and in terms of its environmental impact. 
Deposits of oil shale occur around the world, including major deposits in the United States. Estimates 
of global deposits range from 4.8 to 5 trillion barrels of oil in place.
Oil shale 
For a number of reasons, the United States is not yet using this apparently vast resource to any 
significant extent, and it may not be able to do so in the near future .One reason for this is that 
much of the kerogen is so widely dispersed through the oil shale that huge volumes of rock must be 
processed to obtain moderate amounts of shale oil. Even the richest oil shale yields only about 
three barrels of shale oil per ton of rock processed. The cost is not presently competitive with that 
of conventional petroleum, except when oil prices are extremely high. The cost of producing a 
barrel of oil at a surface retorting complex in the United States (comprising a mine, retorting plant, 
upgrading plant, supporting utilities, and spent shale reclamation), would range between US$70–95
Oil shale 
Mining oil shale involves a number of environmental impacts, more pronounced in surface mining than in 
underground mining. These include acid drainage induced by the sudden rapid exposure and subsequent 
oxidation of formerly buried materials, the introduction of metals including mercury into surface-water and 
groundwater, increased erosion, sulfur-gas emissions, and air pollution caused by the production of particles 
during processing, transport, and support activities. In 2002, about 97% of air pollution, 86% of total waste and 
23% of water pollution in Estonia came from the power industry, which uses oil shale as the main resource for its 
power production. Oil-shale extraction can damage the biological and recreational value of land and the 
ecosystem in the mining area. Combustion and thermal processing generate waste material. In addition, the 
atmospheric emissions from oil shale processing and combustion include carbon dioxide, a greenhouse gas. 
Environmentalists oppose production and usage of oil shale, as it creates even more greenhouse gases than 
conventional fossil fuels.
Tar sand 
WHAT ARE THE TAR-SANDS ? 
Tar sands , also known as oil sands , are sedimentary rocks containing a very thick, semisolid, 
tar like petroleum called bitumen. The heavy petroleum in tar sands is believed to be formed 
in the same way and from the same materials as lighter oils. Tar-sand deposits may represent 
very immature petroleum deposits, in which the breakdown of large molecules has not 
progressed to the production of the lighter liquid and gaseoushydrocarbons. Alternatively, the 
lighter compounds may have migrated away, leaving this dense material behind. Either way, 
the bitumen is too thick to flow out of the rock.
Tar sand 
TAR SAND RESERVES 
Natural bitumen deposits 
are reported in many 
countries, but in particular 
are found in extremely large 
quantities in Canada. Other 
large reserves are located 
in Russia. The estimated 
worldwide deposits of oil 
are more than 2 trillion 
barrels, and 70.8%, are in 
Canada. 
Global oil sand reserves 
Canada Russia Other countries 
71% 
12% 
17%
Tar sand 
Mining Bitumen 
There are two different methods of producing oil from the oil sands: open-pit mining ( for 
Bitumen that is close to the surface is mined ) and in situ ( for Bitumen that occurs deep 
within the ground is produced in situ using specialized extraction techniques.)
Tar sand 
Open-pit mining is similar to many coal mining operations – large shovels scoop the oil sand into 
trucks that then take it to crushers where the large clumps of earth are broken down. This mixture is 
then thinned out with water and transported to a plant, where the bitumen is separated from the 
other components and upgraded to create synthetic oil. This technique is sometimes 
misrepresented as the only method of mining oil sands. Just 20 per cent of the oil sands are 
recoverable through open-pit mining.
Tar sand 
In Situ Drilling 80 per cent of oil sands reserves (which underly approximately 97 per cent of 
the oil sands surface area) are recoverable through in situ technology, with limited surface 
disturbance.Advances in technology, such as directional drilling, enable in situ operations to 
drill multiple wells (sometimes more than 20) from a single location, further reducing the 
surface disturbance. The majority of in situ operations use steam-assisted gravity drainage 
(SAGD). This method involves pumping steam underground through a horizontal well to 
liquefy the bitumen that is then pumped to the surface through a second well.
Tar sand 
Enviromental impacts: The scale of operations is large and growing, as is 
the scale of corresponding environmental impacts, including land disturbance by 
mining; accumulation of oily tailings that leave oil slicks on tailings ponds, which 
can endanger migrating birds; and the fact that processing tar sand releases 
two to three times as much in CO2 emissions as extracting conventional oil via 
wells. Those environmental impacts cause serious concern, but the resource is 
too large and too valuable to ignore.
Source 
• Environmental Geology - Carla W Montgomery 
• American Association of Petroleum Geologists 
• Canadian Association of Petroleum Producers 
• U.S Enegry Information Administration 
• The Geological Society 
• National Geographic 
• Pembina Institute 
• Etc…
Fossil fuels

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Fossil fuels

  • 1. Energy Resources Fossil Fuels Supervisor: PhD. Bùi Trọng Vinh By: Kiều Nhật Nam
  • 2. Contents I. Introduction II. Oil and Natural Gas III. Coal IV. Oil shale V. Tar sand
  • 4. Introduction The fossil fuels are those energy sources that formed from the remains of once-living organisms. When we burn them, we are using that stored energy ( Energy is stored in the chemical bonds of the organic compounds of living organisms )
  • 5. Oil and Natural Gas 1. Formation of Oil and Natural Gas Deposits 2. Supply and Demand for Oil and Natural Gas 3. Future Prospects 4. Enhanced Oil Recovery 5. Alternate Natural Gas Sources 6. Oil Spill
  • 6. Oil and Natural Gas 1/ Formation of Oil and Natural Gas Deposits
  • 7. Oil and Natural Gas Commercially, the most valuable deposits are those in which a large quantity of oil and/or gas has been concentrated and confined (trapped) by impermeable rocks in geologic structures. The reservoir rocks in which the oil or gas has accumulated should be relatively porous if a large quantity of petroleum is to be found in a small volume of rock and should also be relatively permeable so that the oil or gas flows out readily once a well is drilled into the reservoir. If the reservoir rocks are not naturally very permeable, it may be possible to fracture them artificially with explosives or with water or gas under high pressure to increase the rate at which oil or gas flows through them.
  • 8. Oil and Natural Gas The amount of time required for oil and gas to form is not known precisely. Since virtually no petroleum is found in rocks younger than 1 to 2 million years old, geologists infer that the process is comparatively slow. Even if it took only a few tens of thousands of years (a geologically short period), the world’s oil and gas is being used up far faster than significant new supplies could be produced. Therefore, oil and natural gas are among the nonrenewable energy sources. We have an essentially finite supply with which to work.
  • 9. Oil and Natural Gas 2/ Supply and Demand for Oil and Natural Gas * Oil: Oil is commonly discussed in units of barrels (1 barrel = 5.42 gallons ~ 20.52 liter). Worldwide, over one trillion barrels of oil have been consumed, according to estimates by the U.S. Geological Survey. The estimated remaining reserves are about 1.2 trillion barrels. That does not sound too ominous until one realizes that close to half of the consumption has occurred in the last quarter-century or so. Also, global demand continues to increase as more countries advance technologically.
  • 10. Oil and Natural Gas Oil supply and demand are very unevenly distributed around the world. Some low population, low-technology, oil-rich countries (Libya, for example) maybe producing fifty or a hundred times as much oil as they themselves consume. At the other extreme are countries like Japan, highly industrialized and energy-hungry, with no petroleum reserves at all.
  • 11. Oil and Natural Gas Both U.S. and world oil supplies could be nearly exhausted within decades , especially considering the probable acceleration of world energy demands. On occasion, explorationists do find the rare, very large concentrations of petroleum Yet even these make only a modest difference in the long-term picture. The Prudhoe Bay oil field, for instance, represented reserves of only about 13 billion barrels, a great deal for a single region, but less than two years’ worth of U.S. consumption.
  • 12. Oil and Natural Gas Concern about dependence on imported oil led to the establishment of the Strategic Petroleum Reserve in 1977, but the amount of oil in the SPR stayed at about 550 million barrels from 1980 to 2000, while the number of days’ worth of imports that it represents has declined from a high of 115 in 1985 to 50 in 2002. Only renewed addition of imported oil, to raise SPR stocks to about 697 million barrels in 2007, reversed the decline in the number of days of imports held in the SPR, but that figure was still only 58 in 2008. Such facts increase pressure to develop new domestic oil sources
  • 13. Natural Gas: Global demand for natural gas is expected to expand significantly as more nations adopt environmentally cleaner fuels to meet future economic growth and prioritize alternatives to minimize the impact of increasing oil – based energy costs. The environmental benefits of natural gas are clear. Natural gas emits 43% fewer carbon emissions than coal, and 30% fewer emissions than oil, for each unit of energy delivered. Many of the most rapidly growing gas markets are in emerging economies in Asia, particularly India and China, the Middle East and South America, economies which battle the balance between air quality and living standards on a daily basis. Oil and Natural Gas
  • 14. Oil and Natural Gas 3/ Future Prospects Some such areas are now being explored, but with limited success. Other, more promising areas may be protected or environmentally sensitive. The costs of exploration have gone up, drilling for oil or gas in 2006 cost an average of $324 per foot. The average oil or natural gas well drilled was over 6400 feet deep (it was about 3600 feet in 1949); even with increasingly sophisticated methods of exploration to target areas most likely to yield economic hydrocarbon deposits. Costs for drilling offshore are substantially higher than for land-based drilling. Yield from producing wells is also declining, from a peak average of 18.6 barrels of oil per well per day in 1972 to 10.2 barrels in 2007.
  • 15. Oil and Natural Gas Despite a quadrupling in oil prices between 1970 and 1980 (after adjustment for inflation), U.S. proven reserves continued to decline. They are declining still, despite oil prices recently at record levels. This is further evidence that higher prices do not automatically lead to proportionate, or even appreciable, increases in fuel supplies. Also, many major oil companies have been branching out into other energy sources beyond oil and natural gas, suggesting an expectation of a shift away from petroleum in the future.
  • 16. Oil and Natural Gas 4/ Enhanced Oil Recovery A few techniques are being developed to increase petroleum production from known deposits. An oil well initially yields its oil with minimal pumping, or even “gushes” on its own, because the oil and any associated gas are under pressure from overlying rocks, or perhaps because the oil is confined like water in an artesian system. Recovery using no techniques beyond pumping is primary recovery. When flow falls off, water may be pumped into the reservoir, filling empty pores and buoying up more oil to the well (secondary recovery). Primary and secondary recovery together extract an average of one-third of the oil in a given trap
  • 17. Oil and Natural Gas On average, then, two-thirds of the oil in each deposit has historically been left in the ground. Thus, additional enhanced recovery methods have attracted much interest. Enhanced recovery comprises a variety of methods beyond conventional secondary recovery. Permeability of rocks may be increased by deliberate fracturing, using explosives or even water under very high pressure. Carbon dioxide gas under pressure can be used to force out more oil. Hot water or steam may be pumped underground to warm thick, viscous oils so that they flow more easily and can be extracted more completely. There have also been experiments using detergents or other substances to break up the oil.
  • 19. Oil and Natural Gas However, be kept in mind that enhanced recovery may involve increases in problems such as ground subsidence or groundwater pollution that arise also with conventional recovery methods. Even conventional drilling uses large volumes of drilling mud to cool and lubricate the drill bits. The drilling muds may become contaminated with oil and must be handled carefully to avoid polluting surface or ground water. When water is more extensively used in fracturing rock or warming the oil, the potential for pollution is correspondingly greater.
  • 20. Oil and Natural Gas 5/ Alternate Natural Gas Sources: During coal formation, quantities of methane-rich gas are also produced. Most coal deposits contain significant amounts of coal-bed methane . Historically, this methane has been treated as a hazardous nuisance, potentially explosive, and its incidental release during coal mining has contributed to rising methane concentrations in the atmosphere. However, an estimated 100 trillion cubic feet of methane that would be economically recoverable with current technology exists in-place in U.S. coal beds. If it could be extracted for use rather than wasted, it could contribute significantly to U.S. gas reserves.
  • 21. Oil and Natural Gas Some evidence suggests that additional natural gas reserves exist at very great depths in the earth. Thousands of meters below the surface, conditions are sufficiently hot that any oil would have been broken down to natural gas. This natural gas, under the tremendous pressures exerted by the overlying rock, may be dissolved in the water filling the pore spaces in the rock, much as carbon dioxide is dissolved in a bottle of soda. Pumping this water to the surface is like taking off the bottle cap: The pressure is released, and the gas bubbles out. Enormous quantities of natural gas might exist in such geopressurized zones ; recent estimates of the amount of potentially recoverable gas in this form range from 150 to 2000 trillion cubic feet.
  • 22. Oil and Natural Gas Still more recently, the significance of methane hydrates has been increasingly discussed. Gas (usually methane) hydrates are crystalline solids of gas and water molecules. These hydrates have been found to be abundant in arctic regions and in marine sediments. The U.S. Geological Survey has estimated that the amount of carbon found in gas hydrates may be twice that in all known fossil fuels on earth, and a 2008 study suggested a probable 85 trillion cubic feet of (yet-undiscovered) methane in gas hydrates of Alaska’s North Slope alone. Methane in methane hydrate thus represents a huge potential natural gas resource. Just how to tap methane hydrates safely for their energy is not yet clear.
  • 23. Oil and Natural Gas 6/ Oil spills: Most oils and all natural gases are less dense than water, so they tend to rise as well as to migrate laterally through the water-filled pores of permeable rocks. Unless stopped by impermeable rocks, oil and gas may keep rising right up to the earth’s surface. At many known oil and gas seeps, these substances escape into the air or the oceans or flow out onto the ground. These natural seeps, which are one of nature’s own pollution sources, are not very efficient sources of hydrocarbons for fuel if compared with present drilling and extraction processes.
  • 24. Oil and Natural Gas In fact, it is estimated that oil rising up through permeable rocks escapes into the ocean at the rate of 600,000 tons per year, though many natural seeps seal themselves as leakage decreases remaining pressure. Tankers that flush out their holds at sea continually add to the oil pollution of the oceans and, collectively, are a significant source of such pollution. The oil spills about which most people have been concerned, however, are the large, sudden, catastrophic spills that occur in two principal ways: from accidents during drilling of offshore oil wells and from wrecks of oil tankers at sea.
  • 25. Oil and Natural Gas Oil spills represent the largest negative impacts from the extraction and transportation of petroleum, although as a source of water pollution, they are less significant volumetrically than petroleum pollution from careless disposal of used oil, amounting to only about 5% of petroleum released into the environment. And although we tend to hear only about the occasional massive, disastrous spill, there are many more that go unreported in the media: The U.S. Coast Guard reports about 10,000 spills in and around U.S. waters each year, totaling 15 to 25 million gallons of oil annually.
  • 26. Oil and Natural Gas Exxon Valdez oil spill: The Exxon Valdez oil spill occurred in Prince William Sound, Alaska, on March 24, 1989, when Exxon Valdez, an oil tanker bound for Long Beach, California, struck Prince William Sound's Bligh Reef . More than 10 million gallons of oil escaped, eventually to spread over more than 900 square miles of water. The various cleanup efforts cost Exxon an estimated $2.5 billion (the worst oil spill yet in U.S. waters).
  • 27. Oil and Natural Gas • Skimmers recovered relatively little of the oil, as is typical: Three weeks after the accident, only about 5% of the oil had been recovered. Chemical dispersants were not very successful (perhaps because their use was delayed by concerns over their impact on the environment), nor were attempts to burn the spill. Four days after the accident, the oil had emulsified by interaction with the water into a thick, mousse-like substance, difficult to handle, too thick to skim, impossible to break up or burn effectively
  • 28. Oil and Natural Gas • Oil that had washed up on shore had coated many miles of beaches and rocky coast Thousands of birds and marine mammals died or were sickened by the oil. The annual herring season in Valdez was cancelled, and salmon hatcheries were threatened. When other methods failed, it seemed that only slow degradation over time would get rid of the oil. Given the size of the spill and the cold Alaskan temperatures, prospects seemed grim; microorganisms that might assist in the breakdown grow and multiply slowly in the cold. It appeared highly likely that the spill would be very persistent.
  • 29. Oil and Natural Gas • So, in a $10-million experiment, Exxon scientists sprayed miles of beaches in the Sound with a fertilizer solution designed to stimulate the growth of naturally occurring microorganisms that are known to “eat” oil, thereby contributing to its decomposition. Within two weeks, treated beaches were markedly cleaner than untreated ones. Five months later, the treated beaches still showed higher levels of those microorganisms than did untreated beaches. This type of treatment isn’t universally successful. The fertilizer solution runs off rocky shores, so this treatment won’t work on rocky stretches of the oil contaminated coast; nor is it as effective once the oil has seeped deep into beach sands. But microorganisms may indeed be the future treatment of choice.
  • 30. Oil and Natural Gas • In 2006, a study done by the National Marine Fisheries Service in Juneau found that about 9.6 kilometres of shoreline around Prince William Sound was still affected by the spill, with 101.6 tonnes of oil remaining in the area. Exxon Mobil denied any concerns over any remaining oil, stating that they anticipated a remaining fraction that they assert will not cause any long-term ecological impacts, according to the conclusions of the studies they had done: "We've done 350 peer-reviewed studies of Prince William Sound, and those studies conclude that Prince William Sound has recovered, it's healthy and it's thriving. However, in 2007 a NOAA study concluded that this contamination can produce chronic low-level exposure, discourage subsistence where the contamination is heavy, and decrease the "wilderness character" of the area.
  • 31. Coal 1. Formation of Coal Deposits 2. Coal Reserves and Resources 3. Limitations on Coal Use 4. Environmental Impacts of Coal Use
  • 32. Coal 1/ Formation of Coal Deposits:
  • 33. Coal The first combustible product formed under suitable conditions is peat. Further burial, with more heat, pressure, and time, gradually dehydrates the organic matter and transforms the spongy peat into soft brown coal (lignite) and then to the harder coals (bituminous/anthracite)
  • 34. Coal 2/ Coal Reserves and Resources The estimated world reserve of coal is about one trillion tons; total resources are estimated at over 10 trillion tons. The United States is particularly well supplied with coal, possessing about 25% of the world’s reserves, over 270 billion tons of recoverable coal. Total U.S. coal resources may approach ten times that amount, and most of that coal is yet unused and unmined. At present, coal provides between 20 and 25% of the energy used in the United States. While the United States has consumed probably half of its total petroleum resources, it has used up only a few percent of its coal. Even if only the reserves are counted, the U.S. coal supply could satisfy U.S. energy needs for more than 200 years at current levels of energy use, if coal could be used for all purposes.
  • 35. Coal 3/ Limitations on Coal Use A primary limitation of coal use is that solid coal is simply not as versatile a substance as petroleum or natural gas. A major shortcoming is that it cannot be used directly in most forms of modern transportation. Coal is also a dirty and inconvenient fuel for home heating, which is why it was abandoned in favor of oil or natural gas. Therefore, given present technology, coal simply cannot be adopted as a substitute for oil in all applications.
  • 36. Coal Coal can be converted to liquid or gaseous hydrocarbon fuels by causing the coal to react with steam or with hydrogen gas at high temperatures. The conversion processes are called gasification (when the product is gaseous) and liquefaction (when the product is liquid fuel). Both processes are intended to transform coal into a cleaner burning, more versatile fuel, thus expanding its range of possible applications.
  • 37. Coal Commercial coal gasification has existed on some scale for 150 years. Current gasification processes yield a gas that is a mixture of carbon monoxide and hydrogen with a little methane. The heat derived from burning this mix is only 15 to 30% of what can be obtained from burning an equivalent volume of natural gas. Because the low heat value makes it uneconomic to transport this gas over long distances, it is typically burned only where produced. Technology exists to produce high-quality gas from coal, equivalent in heat content to natural gas, but it is presently uneconomical when compared to natural gas.
  • 38. Coal Pilot projects are also underway to study in situ underground coal gasification, through which coal would be gasified in place and the gas extracted directly. The expected environmental benefits of not actually mining the coal include reduced land disturbance, water use, air pollution, and solid waste produced at the surface. Potential drawbacks include possible groundwater pollution and surface subsidence over gasified coal beds. Underground gasification may provide a means of using coals that are too thin to mine economically or that would require excessive land disruption to extract. However, in the near future, simple extraction of coal-bed methane is likely to yield economical gas more readily.
  • 39. Coal
  • 40. Coal Like gasification, the practice of generating liquid fuel from coal has a longer history than many people realize. The Germans used it to produce gasoline from their then-abundant coal during World War II; South Africa has a liquefaction plant in operation now, producing gasoline and fuel oil. Even so, their liquid fuel products have not historically been economically competitive with conventional petroleum. The higher gasoline prices rise, of course, the more economically viable coal liquefaction becomes. The most obvious advantage is that it would allow us to use our plentiful coal resources to meet a need now satisfied by petroleum, much of it imported
  • 41. Coal 4/ Environmental Impacts of Coal Use *Gases A major problem posed by coal is the pollution associated with its mining and use. Like all fossil fuels, coal produces carbon dioxide (CO2) when burned. In fact, it produces significantly more carbon dioxide per unit energy released than oil or natural gas. (It is the burning of the carbon component—making CO2— that is the energy-producing reaction when coal is burned; when hydrocarbons are burned, the reactions produce partly CO2, partly H2O as their principal by-products, the proportions varying with the ratio of carbon to hydrogen in the particular hydrocarbon(s).)
  • 42. Coal The additional pollutant that is of special concern with coal is sulfur. The sulfur content of coal can be more than 3%, some in the form of the iron sulfide mineral pyrite (FeS2), some bound in the organic matter of the coal itself. When the sulfur is burned along with the coal, sulfur gases, notably sulfur dioxide (SO2), are produced. These gases are poisonous and are extremely irritating to eyes and lungs. 60% 7% 5% 15% 3% 10% Carbon Sulfur Nitrogen Hydrogen Oxygen Ash
  • 43. Coal The gases also react with water in the atmosphere to produce sulfuric acid, a very strong acid. This acid then falls to earth as acid rainfall. Acid rain falling into streams and lakes can kill fish and other aquatic life. It can acidify soil, stunting plant growth. It can dissolve rock; in areas where acid rainfall is a severe problem, buildings and monuments are visibly corroding away because of the acid. The geology of acid rain is explored further in chapter 18. Another toxic substance of growing concern with increasing coal use is mercury. A common trace element in coal, mercury is also a very volatile (easily-vaporized) metal, so it can be released with the waste gases.
  • 44. Coal *Ash Coal use also produces a great deal of solid waste. The ash residue left after coal is burned typically ranges from 5 to 20% of the original volume. The ash, which consists mostly of noncombustible silicate minerals, also contains toxic metals. If exposed at the surface, the fine ash, with its proportionately high surface area, may weather very rapidly, and the toxic metals such as selenium and uranium can be leached from it, thus posing a water-pollution threat. Uncontrolled erosion of the ash could likewise cause sediment pollution. The magnitude of this waste-disposal problem should not be underestimated.
  • 45. Coal There is no obvious safe place to dump all that waste. Some is used to make concrete, and it has been suggested that the ash could actually serve as a useful source of some of the rarer metals concentrated in it. At present, however, much of the ash from coal combustion is deposited in landfills.
  • 46. Coal Between combustion and disposal, the ash may be stored wet, in containment ponds. These, too, can pose a hazard: In December 2008, a containment pond along the Emory River in Tennessee failed, releasing an estimated 5.4 million cubic meters of saturated ash from the Kingston Fossil Plant into the river . The surge of sludge buried nearly half a square mile of land, damaged many homes, and released such pollutants as arsenic, chromium, and lead into the water. It was originally estimated, optimistically, that cleanup might take 4 to 6 weeks. It now appears that the process will take years, and projections of total cleanup costs range up to $1 billion.
  • 47. Coal *Coal-mining hazard Coal mining poses further problems. Underground mining of coal is notoriously dangerous, as well as expensive. Mines can collapse; miners may contract black lung disease from breathing the dust; there is always danger of explosion from pockets of natural gas that occur in many coal seams. A tragic coal-mine fire in Utah in December 1984 and a methane explosion in a Chinese coal mine in 2004 that killed over 100 people were reminders of the seriousness of the hazards. Recent evidence further suggests that coal miners are exposed to increased cancer risks from breathing the radioactive gas radon, which is produced by natural decay of uranium in rocks surrounding the coal seam.
  • 48. Coal An underground fire that may have been started by a trash fire in an adjacent dump has been burning under Centralia, Pennsylvania, since 1962; over 1000 residents have been relocated, at a cost of more than $40 million, and collapse and toxic fumes threaten the handful of remaining residents resisting evacuation. And while Centralia’s fire may be among the most famous, it is by no means the only such fire, and they are a problem in other nations as well. China relies heavily on coal for its energy; uncontrolled coal-mine fires there have cost over $100 million in lost coal, the carbon-dioxide emissions from them are estimated to account for several percent of global CO2 emissions
  • 49. Coal • Centralia photography
  • 50. Coal Acid Mine Drainage (AMD) Acid mine drainage - refers to the outflow of acidic water from metal mines or coal mines. AMD occurs naturally within some environments as part of the rock weathering process but is exacerbated by large-scale earth disturbances characteristic of mining and other large construction activities, usually within rocks containing an abundance of sulfide minerals. Areas where the earth has been disturbed (e.g. construction sites, subdivisions,and transportation corridors) may create acid rock drainage. In many localities, the liquid that drains from coal stocks, coal handling facilities, coal washeries, and coal waste tips can be highly acidic, and in such cases it is treated as acid rock drainage. The same type of chemical reactions and processes may occur through the disturbance of acid sulfate soils formed under coastal or estuarine conditions after the last major sea level rise, and constitutes a similar environmental hazard.
  • 51. Coal Because plants grow poorly in very acid conditions, this acid slows revegetation of the area by stunting plant growth or even preventing it altogether. The acid runoff can also pollute area ground and surface waters, killing aquatic plants and animals in lakes and streams and contaminating the water supply. Very acidic water also can be particularly effective at leaching or dissolving some toxic elements from soils, further contributing to water pollution.
  • 52. Oil shale Oil shale, also known as kerogen shale, is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons called shale oil (not to be confused with tight oil—crude oil occurring naturally in shales) can be produced. Shale oil is a substitute for conventional crude oil; however, extracting shale oil from oil shale is more costly than the production of conventional crude oil both financially and in terms of its environmental impact. Deposits of oil shale occur around the world, including major deposits in the United States. Estimates of global deposits range from 4.8 to 5 trillion barrels of oil in place.
  • 53. Oil shale For a number of reasons, the United States is not yet using this apparently vast resource to any significant extent, and it may not be able to do so in the near future .One reason for this is that much of the kerogen is so widely dispersed through the oil shale that huge volumes of rock must be processed to obtain moderate amounts of shale oil. Even the richest oil shale yields only about three barrels of shale oil per ton of rock processed. The cost is not presently competitive with that of conventional petroleum, except when oil prices are extremely high. The cost of producing a barrel of oil at a surface retorting complex in the United States (comprising a mine, retorting plant, upgrading plant, supporting utilities, and spent shale reclamation), would range between US$70–95
  • 54. Oil shale Mining oil shale involves a number of environmental impacts, more pronounced in surface mining than in underground mining. These include acid drainage induced by the sudden rapid exposure and subsequent oxidation of formerly buried materials, the introduction of metals including mercury into surface-water and groundwater, increased erosion, sulfur-gas emissions, and air pollution caused by the production of particles during processing, transport, and support activities. In 2002, about 97% of air pollution, 86% of total waste and 23% of water pollution in Estonia came from the power industry, which uses oil shale as the main resource for its power production. Oil-shale extraction can damage the biological and recreational value of land and the ecosystem in the mining area. Combustion and thermal processing generate waste material. In addition, the atmospheric emissions from oil shale processing and combustion include carbon dioxide, a greenhouse gas. Environmentalists oppose production and usage of oil shale, as it creates even more greenhouse gases than conventional fossil fuels.
  • 55. Tar sand WHAT ARE THE TAR-SANDS ? Tar sands , also known as oil sands , are sedimentary rocks containing a very thick, semisolid, tar like petroleum called bitumen. The heavy petroleum in tar sands is believed to be formed in the same way and from the same materials as lighter oils. Tar-sand deposits may represent very immature petroleum deposits, in which the breakdown of large molecules has not progressed to the production of the lighter liquid and gaseoushydrocarbons. Alternatively, the lighter compounds may have migrated away, leaving this dense material behind. Either way, the bitumen is too thick to flow out of the rock.
  • 56. Tar sand TAR SAND RESERVES Natural bitumen deposits are reported in many countries, but in particular are found in extremely large quantities in Canada. Other large reserves are located in Russia. The estimated worldwide deposits of oil are more than 2 trillion barrels, and 70.8%, are in Canada. Global oil sand reserves Canada Russia Other countries 71% 12% 17%
  • 57. Tar sand Mining Bitumen There are two different methods of producing oil from the oil sands: open-pit mining ( for Bitumen that is close to the surface is mined ) and in situ ( for Bitumen that occurs deep within the ground is produced in situ using specialized extraction techniques.)
  • 58. Tar sand Open-pit mining is similar to many coal mining operations – large shovels scoop the oil sand into trucks that then take it to crushers where the large clumps of earth are broken down. This mixture is then thinned out with water and transported to a plant, where the bitumen is separated from the other components and upgraded to create synthetic oil. This technique is sometimes misrepresented as the only method of mining oil sands. Just 20 per cent of the oil sands are recoverable through open-pit mining.
  • 59. Tar sand In Situ Drilling 80 per cent of oil sands reserves (which underly approximately 97 per cent of the oil sands surface area) are recoverable through in situ technology, with limited surface disturbance.Advances in technology, such as directional drilling, enable in situ operations to drill multiple wells (sometimes more than 20) from a single location, further reducing the surface disturbance. The majority of in situ operations use steam-assisted gravity drainage (SAGD). This method involves pumping steam underground through a horizontal well to liquefy the bitumen that is then pumped to the surface through a second well.
  • 60. Tar sand Enviromental impacts: The scale of operations is large and growing, as is the scale of corresponding environmental impacts, including land disturbance by mining; accumulation of oily tailings that leave oil slicks on tailings ponds, which can endanger migrating birds; and the fact that processing tar sand releases two to three times as much in CO2 emissions as extracting conventional oil via wells. Those environmental impacts cause serious concern, but the resource is too large and too valuable to ignore.
  • 61. Source • Environmental Geology - Carla W Montgomery • American Association of Petroleum Geologists • Canadian Association of Petroleum Producers • U.S Enegry Information Administration • The Geological Society • National Geographic • Pembina Institute • Etc…

Editor's Notes

  1. only energy source used by primitive people was the food they ate. Then, wood-fueled fires produced energy for cooking, heat, light, and protection from predators. As hunting societies became agricultural, people used energy provided by animals—horsepower and ox power. The world’s total energy demands were quite small and could readily be met by these sources. Gradually, animals’ labor was replaced by that of machines, new and more sophisticated technologies were developed, and demand for manufactured goods rose. These factors all greatly increased the need for energy and spurred the search for new energy sources
  2. When an oil spill occurs, the oil, being less dense than water, floats. The lightest, most volatile hydrocarbons start to evaporate initially, decreasing the volume of the spill somewhat but polluting the air. Then a slow decomposition process sets in, due to sunlight and bacterial action. After several months, the mass may be reduced to about 15% of the starting quantity, and what is left is mainly thick asphalt lumps. These can persist for many months more.
  3. negative environmental impacts were still detectable seven years later