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International Journal of EngineeringScience and Computing, March 2017 4970 http://ijesc.org/
ISSN XXXX XXXX ©2017 IJESC
Fly ASH–A Boon for Concrete
Raj Premani
B.Tech
Department of Civil Engineering
Career Point University, Kota, Rajasthan, India
Abstract:
Electricity is a critical input needed for the development of any country. In India, coal is the main source of generating power at
present and likely to remain in the future too. India is the world’s second largest producer after china and fourth largest consumer of
electricity. In India, 60% of the electricity is generated through coal fired thermal power plant and in this production of electricity
70% of the coal produced in India is used. India need more energy to meet the rapidly growing demand, hence the use of coal will
continue to increase. Electricity produced through coal is cheap, reliable and most widely used all over the world but it has much bad
impact on the environment and human health, the main reason of concern is dispos al of fly ash. In the past fly ash was generally
released into the atmosphere, but this leads to air pollution but later on it was collected by pollution control equipment like
electrostatic precipitator prior to its release to control the air pollution. So this leads to the problem of fly ash disposal. Fly ash are
generally deposited in ash ponds which require large area but this leads to bad impact on environment and human health so rec ycling
of fly ash has become an increasing concern.
Keywords: fly ash, fly ash disposal, electricity, cement, concrete, bricks, PPC.
I. INTRODUCTION
Fly ash is very fine powder like material obtained from burning
of pulverized coal in an electricity generation power plant
transported by the flue gases and collected by electrostatic
precipitator. Fly ash is a artificial pozzolanic material.
Pozzolanic materials are siliceous or siliceous and aluminous
material which in themselves posses little or no cementitious
value but when it come in contact with moisture it posses
cementitious properties. Fly ash is the most widely used
pozzolanic material all over the world. Fly ash when comes in
contact with lime and water it produces a product that is very
similar to Portland cement. Depending upon the source and
makeup of the coal being burned, the component of fly ash
varies but all fly ash include silicon dioxide (both amorphous
and crystalline), aluminum oxide and calcium oxide. The use of
fly ash as concrete admixture not only extends technical
advantage to the properties of concrete but also contributes to the
environmental pollution control. In India, we produce more than
about 100 million tons of fly ash per year, the disposal of which
has become a serious environmental problem. The effective
utilization of fly ash in concrete making is, therefore, attracting
serious consideration of concrete technologist and government
departments. There are two ways that the fly ash can be used:
one way is to use certain percentage of fly ash with cement
clinker at the factory to produce Portland pozzolana cement and
the second way is to use the fly ash as an admixture at the time
of making concrete at the site of work. In both ways fly ash is
advantageous. High fineness, low carbon content, good
reactivity are the essence of good fly ash. Since fly ash is
produced by rapid cooling and solidification of molten ash, a
large portion of components comprising fly ash particles are in
amorphous state. One of the most important characteristics of fly
ash is the spherical form of the particle; this shape of particle
improves the flow ability and reduces the water demand.
Typically fly ash is used 15% to 35% by weight of cement in
concrete for normal works and 70% by weight of cement in mass
concrete construction such as dams. Fly ash is broadly classified
into two classes:
1. CLASS F: - Fly ash normally produced by burning of
anthracite or bituminous coal. Class F are generally low-calcium
fly ash with carbon contents less than 5% but sometime as high
as 10%. Class F fly ash has pozzolanic properties only. Class F
fly ash, with particles covered in a kind of melted glass, greatly
reduces the risk of expansion due to sulfate attack as may occur
in fertilized soil or near coastal areas. It has more glass, alumino
silicate glass, quartz. Class F fly ash requires a cementing agent
such as Portland cement, quicklime, or hydrated lime – mixed
with water to react and produce cementitious compounds.
2. CLASS C: - Fly ash normally produced by burning
lignite or sub bituminous coal. Some Class C fly ash may have
more than 10% CaO content. In addition to pozzolanic
properties, class C fly ash also posses cementitious properties.
Class C fly ash has about 35% silica and much lower carbon
dioxide than Portland cement. Class C fly ash is also resistant to
expansion from chemical attack, has a higher percentage of
calcium oxide, and is more commonly used for structural
concrete. Class C fly ash is typically composed of high calcium
fly ash with carbon content less than 2 percent. Class C fly ash
does not require an activator. Fly ash can be used as prime
material in blocks, tiles, paving or bricks; however one of the
most important application is PCC pavement. PCC pavement use
a large amount of concrete and substituting fly ash not only
provides significant economic benefits but also control
environmental pollution as we are using a waste or unwanted
material that has bad impact on environment and also we are
Research Article Volume 7 Issue No.3
International Journal of EngineeringScience and Computing, March 2017 4971 http://ijesc.org/
reducing the use of cement that is responsible for emission of
carbon dioxide gas –a greenhouse gas . It can also be used in
road pavement and as embankment and mine fills.
II. FLY ASH IN CEMENT MANUFACTURING (PPC)
Fly ash can also be use as a ingredient for the production of
cement, the cement produced by using fly ash is termed as
Portland pozzolana cement (PPC). PPC is manufactured by the
intergrinding of OPC clinker with 15-35% of pozzolanic
material i.e. fly ash along with gypsum. Generally in the
production of ordinary Portland cement the raw material are
burned for the formation of clinkers which contain calcium
silicate (tri calcium silicate and dicalcium silicate) which when
comes in contact with water form calcium silicate hydrates and
calcium hydroxide. Calcium hydroxide is not a desirable product
in the concrete mass, it is soluble in water and gets leached out
making the concrete porous and thus decreases the strength and
durability of concrete. Also calcium hydroxide reacts with
sulphates present in soil or water to form calcium sulphate which
further reacts with calcium aluminate and cause deterioration of
concrete. This is known as sulphate attack. If such useless
product could be converted into a useful cementitious product it
will improve the quality of concrete. The use of fly ash performs
such a role and improves the strength and durability of concrete.
Portland pozzolana cement produces less heat of hydration and
offers greater resistance to the attack of aggressive waters than
ordinary Portland cement. It is particularly useful in marine,
hydraulic construction, mass concrete structure like dam, bridges
and thick foundations. Can also be used in sewers and sewage
disposal works. In PPC, costly clinkers are replaced by cheaper
fly ash hence it is economical. It is finer than ordinary Portland
cement so it reduces micro cracks at the transition zone and also
results in reduction of permeability. In 1998 due to lack of
awareness and fear of trying something different among the
users, the Portland Pozzolana cement was not common. In India
only 19% of total cement production was PPC. But in 2010 the
story was different as concrete made with PPC or fly ash amount
up to 60% of the total concrete made and according to reports
the use of Portland pozzolana cement in the recent years has
steadily increased to about 67% while the production of ordinary
Portland cement in India now stands only 25%. In addition to
conservation of natural resources, fuel, and reduction of green
house gas it has several more advantages like:
 Low heat of hydration.
 Superior performance under elevated temperature.
 Good long term strength.
 Control of alkali – silica reaction.
 Resistance to acids and sulphate.
 Reduced permeability.
 Reduced chlorine diffusivity.
III. FLY ASH IN MANUFACTURING OF BRICKS
Fly ash can also be used in the manufacturing of bricks. In fact,
we can say the fly ash bricks are the best replacement of clay
bricks. Class C fly ash are used in the manufacturing of bricks
because it posses cementitious property due to the presence of
calcium oxide (more than 10%). The manufacture of
conventional clay bricks requires the consumption of large
amount of clay. This depletes the top soil and leads to
degradation of land and makes the soil infertile so this land can’t
be used in agriculture now. According to the study, 180 Billon
tones of clay brick production per year consume 540 million
tones of clay, makes 65,000 acres of land barren. Also the clay
bricks are burned at high temperature to gain the strength,
durability, density and red color appearance. Clay bricks are
burned in the kiln at a temperature of 1100 degree for 3 to 5 days
so this consumes 30 million of coal for the production of 180
billion tones of clay bricks. This coal not only produce solid
waste nut also generates 26 million tons of carbon dioxide. A
10% switchover to fly ash bricks will use 30 million tones of fly
ash every year, save environment and coal. Fly ash bricks do not
require clay so this serves dual purpose of conserving the top
soil and at the same time constructive utilization of fly ash. Use
of fly ash in bricks manufacturing not only protect the
environment but also make profit for the industry. A report
suggests that if we do 10% switchover to fly ash bricks it will
yield a benefit of 300 crores by way of reduction in brick cost
production. Fly ash is increasingly being used throughout the
world as ingredient for brick and varieties of recipes have
emerged. Fly ash gets their strength and durability from the
chemical reaction of fly ash with water. Fly ash is combined
with sand and pigment and bricks are formed by hydraulic and
vibratory press and cured with steam for two days and not fired.
This method uses 85% less energy than traditional kiln firing.
CALSTAR is a company stated in 2006, in Silicon Valley with
production in Wisconsin that is producing fly ash bricks. They
claim their bricks require 81% less energy to manufacture;
incorporate 37% recycled fly ash and emit 84% less carbon
dioxide during production. Lower energy use and inexpensive
raw material allow them to offer competitive pricing and high
margins. Fly ash is beneficial in all ways. According to MoEF
notification, every construction agency engaged in the
construction of building within a radius of 100 km froma coal or
lignite based power plant shall use only fly ash bricks for
construction. NTPC has manufactured more than 54 crores ash
bricks in its various thermal power plants and utilized in
construction activities.
Table.1 Comparison between clay bricks and fly ash bricks
PROPERTIES CLAY
BRICKS
FLY ASH
BRICKS
REMARKS
Density 1600-1750
kg/m3
1700-1850
kg/m3
Higher load
bearing
Compressive
strength
30-35
kg/cm2
90-100
kg/cm2
Higher load
bearing
Absorption 15-25% 10-14% Less dampness
Dimensional
stability
Very low
tolerance
High
tolerance
Saving mortar
up to 25%
Wastage during
transit
Up to 10% Less than
2%
Saving in cost
up to 8%
Plastering Thickness
vary on the
both sides
of wall
Even on
both sides
Saving in
plaster up to
15%
Advantages of fly ash bricks:
 These bricks are environmental friendly as they use fly
ash, saves agricultural land which is used for
International Journal of EngineeringScience and Computing, March 2017 4972 http://ijesc.org/
manufacturing of clay bricks and emits very less carbon
dioxide.
 It reduces dead load on structures due to light weight.
 Same number of bricks will cover more area than clay
bricks.
 High fire insulation.
 Due to its high strength, practically no breakage during
transportation and use.
 These bricks due not require soaking in water for 24
hours.
IV. FLY ASH IN CONCRETE
Fly ash is also very useful in concrete as it increase the durability
and strength of the concrete along with it, it decreases the
percentage of cement used in concrete. Fly ash can be used in
Plain cement concrete to enhance the performance of the
concrete. Portland cement is manufactured with calcium oxide,
some of which is released in a free state during hydration. As
much as 20 pounds of free lime is released during hydration of
100 pounds of cement. This liberated lime forms the necessary
ingredient for reaction with fly ash silicate to form strong and
durable cementing compound thus improving many of the
properties of concrete. Typically 15-30% of Portland cement is
replaced by fly ash, this result in net reduction in energy use and
green house gas and other emissions. Study show that one ton of
Portland cement production discharges 0.87 tons of carbon
dioxide in the environment. Japanese study indicate that every
year barren land approximately 1.5 times of Indian territories
need to be afforested to compensate for the total global
accumulation of carbon dioxide discharge into the atmosphere
because of the total global cement production, utilization of fly
ash in cement concrete minimize carbon dioxide emission
problem. Since a huge quantity of cement is used in mass
concrete and the cost of fly ash is negligible as compared to that
of cement, the use of fly ash in concrete not only saves the
cement consumption and cost but also provide high strength. Fly
ash can substitute up to 66% of cement in the construction of
dams. 90 days strength of fly ash concrete may be more than
140% of plain concrete. Use of fly ash concrete in R.C.C
structure provides more strength without any risk of steel
corrosion. High Volume Fly Ash Concrete (HVFAC) was coined
by VM Malhotra in the late 1980s. this concrete has very low
water content and at least 50% of the Portland cement by mass is
replaced by class F fly ash. Because of the very low water
content, superplasticizer is generally used to achieve slump
ranges from 150 to 200 mm. but if high early strength and high
slump is not required then the use of superplasticizer is not
required. The HVFA concrete has excellent workability, low
heat of hydration, low drying shrinkage and excellent durability
that are necessary to call it high performance concrete. It was
first developed for mass concrete application where low heat of
hydration was required. Subsequent work has demonstrated that
this type of concrete showed excellent mechanical and durability
properties required for structural application and pavement
construction. HVFA can be used in water front structures,
industrial structure and roller compacted concrete dams- an
innovative dam technology developed as a result of effort to
design more economical concrete dams that could be constructed
rapidly with designed performance.
BENEFITS OF FLY ASHWHEN USED IN CONCRETE:
 Produce various set times.
 Increase durability.
 Reduce alkali silica reactivity.
 Increase ease of pumping and improves flow – ability.
 Reduce segregation and slump loss.
 Reduce water demand.
 Cold weather resistance.
 Higher strength gains.
 Can be used as a admixture.
 Reduces cost.
 Increases the modulus of elasticity of concrete when
concrete of same strength with and without fly ash are
compared.
 Improved sulphate resistance.
 Can substitute for Portland cement.
 Considered a non-shrink material.
 Produces denser concrete and a smoother surface with
sharper details.
 Great workability.
 Reduces crack problems, permeability and bleeding.
 Reduces heat of hydration.
 Produces lower water cement ration for similar slumps
when compared to no fly ash mixes.
 Reduces CO2 emissions.
V. OTHER USES OF FLY ASH
 Fly ash holds a potential to improve the physical health
of the soil. It can serve as a soil modifier and also enhance the
water retaining capacity and fertility of the soil. It improves the
plants water and nutrients uptake, helps in development of roots
and soil binding, stores carbohydrates and oil for use when
needed, protect soil from soil borne disease. Use of fly ash in
agriculture can increase the yield of cereals, oil seeds, pulses,
cotton and sugarcane by 10-15%, vegetables by 20-25% and root
vegetables by 30-40%. Fly ash application to sandy soil could
permanently alter soil texture, increase micro porosity and water
holding capacity. Lime in fly ash readily reacts with acidic
components in soil and releases nutrients such as S, B and Mo in
the form and amount beneficial to crops plants. It also improves
the nutrient status of soil. Also use of fly ash instead of lime as
soil ameliorant can reduce net carbon dioxide emission and
thereby lessen global warming.
 Soil stabilization is the permanent physical and
chemical alteration of soil to enhance their physical properties.
Addition of fly ash in soil will increase the physical as well as
chemical properties of the soil. Some expecting properties to be
improved are CBR (California bearing ratio) value, shear
strength, liquidity index, plasticity index, unconfined
compressive strength, control shrinkage and bearing capacity etc
thus improving the load bearing capacity of a sub grade to
support pavement and foundation.
 Fly ash is also used as an embankment material. As it is
a light weight material as compared to natural soils and posses
high angle of shearing resistance, greater stability of slopes
hence suitable as embankment fill over soft compressible
ground. The compaction curve of fly ash is relatively flat,
showing that the degree of compaction is less sensitive to water
International Journal of EngineeringScience and Computing, March 2017 4973 http://ijesc.org/
content and fly ash can be used even in wet condition as an
embankment material.
 The fly ash, being cementitious coal combustion by
product, promises high volume utilization in grouting
application. The fly ash grouts provide required engineering
performance in improving ground stability by increasing
strength and shearing resistance as well as reducing the
permeability of soil treated with enhanced technical, rheological,
durability and economic advantage over sand and cement grouts.
 Fly ash is also used in road sub base construction
because of its light weight and low cost. And also it provides
greater strength.
 Also may be used in cosmetic, toothpaste, kitchen
counter top, floor, utensils, floatation devices, PVC pipes,
railway sleeper, doors, window frames, mail boxes, metal
casting, sign posts, auto bodies, picture frames, running tracks,
park benches, binding agents, paints and filler in wood and
plastic products.
VI. CONCLUSION
Fly ash should now not be considered as a waste product it
should be now considered as a resource material. Many
researches and experiments have been done on fly ash, and fly
ash has succeeded everywhere so the use of fly ash is
continuously increasing. Government is also trying to promote
fly ash use in construction works, Maharashtra Government
makes fly ash mandatory in all government infrastructures and
also the state government has made it mandatory for all
companies and developers located in a 300 km from a power
plant to use fly ash in construction. It has been made mandatory
for the use of fly ash in government projects such as construction
of roads, dams, housing schemes etc. In the construction of
Ghatghar dam situated in Ghatghar village in Ahmednagar
district 70% of cement by mass was replaced by fly ash. It not
only provides strength to the dambut also reduces the cost of the
construction. The use of fly ash in Nizamuddin bridge road
embankment in Delhi for about 2 km and height of 8m in a flood
zone has demonstrated the use of fly ash in adverse condition.
This has not only saved the top soil and used fly ash which was
otherwise a waste but also saved 1.4 crore in a total project of 10
crore. Fly ash is very beneficial the use of fly ash bricks over
clay bricks not only prevent the top soil but also saves
environment by emitting very less carbon dioxide as compare to
clay bricks. Fly ash is the best replacement of cement. The use of
fly ash in concrete improves the strength and durability of the
concrete by converting calcium hydroxide into calcium silicate
hydrate gel (C-S-H gel). Along with the use of fly ash in
construction works, fly ash is also used in agriculture to improve
the physical and chemical strength of the soil. It can serve as a
soil modifier and also enhance the water retaining capacity and
fertility of the soil and increase the yield of the crops. So fly has
got several advantages in every field.
VII. REFERENCES
[1]. QUALITY TREND IN INDIAN CEMENTS- A DECADE
APPRAISAL BY U S SINHA, K BHATNAGAR, R GUPTA
AND M M ALI.
[2]. CONCRETE TECHNOLOGY – M.S. SHETTY.
[3]. USE OF FLY ASH IN AGRICULTURE- A WAY TO
IMPROVE SOIL FERTILITY AND ITS PRODUCTIVITY BY
PREM KISHOR, A.K GHOSH AND DILEEP KUMAR.
[4]. http://www.thebalance.com/fly-ash-applications-844761
[5]. SOIL STABILASTION BY USING FLY ASH –
KARTHIK.S, ASHOK KUMAR.E, GOWTHAM.P,
ELANGO.G, GOKUL.D, THANGARAJ.S
[6]. ENVIRONMETAL IMPACTS OF ELECTRICITY
GENERATION CASE STUDY FROM INDIA USING LIFE
CYCLE ASSEMENT APPORACH- SHAH B
[7]. FLY ASH – WIKIPEDIA
[8]. http://www.ecobrick.in/waste_utilization_in_brick_mak
ing.aspx
[9]. INDUSTRIAL APPLICATION OF FLY ASH – A
REVEW- DR.SUHAS V.PATIL, SURYAKANT C.NAWLE,
SUNIL J.KULKARNI
[10]. ASH UTILISATION- NTPC
[11]. A WASTE: FLY ASH UTILISATION IN DIFFERENT
AREAS- RAMJI PORWAL, SAURAV DUBEY

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fly ash a_boon_for_concrete BY RAJ PREMANI

  • 1. International Journal of EngineeringScience and Computing, March 2017 4970 http://ijesc.org/ ISSN XXXX XXXX ©2017 IJESC Fly ASH–A Boon for Concrete Raj Premani B.Tech Department of Civil Engineering Career Point University, Kota, Rajasthan, India Abstract: Electricity is a critical input needed for the development of any country. In India, coal is the main source of generating power at present and likely to remain in the future too. India is the world’s second largest producer after china and fourth largest consumer of electricity. In India, 60% of the electricity is generated through coal fired thermal power plant and in this production of electricity 70% of the coal produced in India is used. India need more energy to meet the rapidly growing demand, hence the use of coal will continue to increase. Electricity produced through coal is cheap, reliable and most widely used all over the world but it has much bad impact on the environment and human health, the main reason of concern is dispos al of fly ash. In the past fly ash was generally released into the atmosphere, but this leads to air pollution but later on it was collected by pollution control equipment like electrostatic precipitator prior to its release to control the air pollution. So this leads to the problem of fly ash disposal. Fly ash are generally deposited in ash ponds which require large area but this leads to bad impact on environment and human health so rec ycling of fly ash has become an increasing concern. Keywords: fly ash, fly ash disposal, electricity, cement, concrete, bricks, PPC. I. INTRODUCTION Fly ash is very fine powder like material obtained from burning of pulverized coal in an electricity generation power plant transported by the flue gases and collected by electrostatic precipitator. Fly ash is a artificial pozzolanic material. Pozzolanic materials are siliceous or siliceous and aluminous material which in themselves posses little or no cementitious value but when it come in contact with moisture it posses cementitious properties. Fly ash is the most widely used pozzolanic material all over the world. Fly ash when comes in contact with lime and water it produces a product that is very similar to Portland cement. Depending upon the source and makeup of the coal being burned, the component of fly ash varies but all fly ash include silicon dioxide (both amorphous and crystalline), aluminum oxide and calcium oxide. The use of fly ash as concrete admixture not only extends technical advantage to the properties of concrete but also contributes to the environmental pollution control. In India, we produce more than about 100 million tons of fly ash per year, the disposal of which has become a serious environmental problem. The effective utilization of fly ash in concrete making is, therefore, attracting serious consideration of concrete technologist and government departments. There are two ways that the fly ash can be used: one way is to use certain percentage of fly ash with cement clinker at the factory to produce Portland pozzolana cement and the second way is to use the fly ash as an admixture at the time of making concrete at the site of work. In both ways fly ash is advantageous. High fineness, low carbon content, good reactivity are the essence of good fly ash. Since fly ash is produced by rapid cooling and solidification of molten ash, a large portion of components comprising fly ash particles are in amorphous state. One of the most important characteristics of fly ash is the spherical form of the particle; this shape of particle improves the flow ability and reduces the water demand. Typically fly ash is used 15% to 35% by weight of cement in concrete for normal works and 70% by weight of cement in mass concrete construction such as dams. Fly ash is broadly classified into two classes: 1. CLASS F: - Fly ash normally produced by burning of anthracite or bituminous coal. Class F are generally low-calcium fly ash with carbon contents less than 5% but sometime as high as 10%. Class F fly ash has pozzolanic properties only. Class F fly ash, with particles covered in a kind of melted glass, greatly reduces the risk of expansion due to sulfate attack as may occur in fertilized soil or near coastal areas. It has more glass, alumino silicate glass, quartz. Class F fly ash requires a cementing agent such as Portland cement, quicklime, or hydrated lime – mixed with water to react and produce cementitious compounds. 2. CLASS C: - Fly ash normally produced by burning lignite or sub bituminous coal. Some Class C fly ash may have more than 10% CaO content. In addition to pozzolanic properties, class C fly ash also posses cementitious properties. Class C fly ash has about 35% silica and much lower carbon dioxide than Portland cement. Class C fly ash is also resistant to expansion from chemical attack, has a higher percentage of calcium oxide, and is more commonly used for structural concrete. Class C fly ash is typically composed of high calcium fly ash with carbon content less than 2 percent. Class C fly ash does not require an activator. Fly ash can be used as prime material in blocks, tiles, paving or bricks; however one of the most important application is PCC pavement. PCC pavement use a large amount of concrete and substituting fly ash not only provides significant economic benefits but also control environmental pollution as we are using a waste or unwanted material that has bad impact on environment and also we are Research Article Volume 7 Issue No.3
  • 2. International Journal of EngineeringScience and Computing, March 2017 4971 http://ijesc.org/ reducing the use of cement that is responsible for emission of carbon dioxide gas –a greenhouse gas . It can also be used in road pavement and as embankment and mine fills. II. FLY ASH IN CEMENT MANUFACTURING (PPC) Fly ash can also be use as a ingredient for the production of cement, the cement produced by using fly ash is termed as Portland pozzolana cement (PPC). PPC is manufactured by the intergrinding of OPC clinker with 15-35% of pozzolanic material i.e. fly ash along with gypsum. Generally in the production of ordinary Portland cement the raw material are burned for the formation of clinkers which contain calcium silicate (tri calcium silicate and dicalcium silicate) which when comes in contact with water form calcium silicate hydrates and calcium hydroxide. Calcium hydroxide is not a desirable product in the concrete mass, it is soluble in water and gets leached out making the concrete porous and thus decreases the strength and durability of concrete. Also calcium hydroxide reacts with sulphates present in soil or water to form calcium sulphate which further reacts with calcium aluminate and cause deterioration of concrete. This is known as sulphate attack. If such useless product could be converted into a useful cementitious product it will improve the quality of concrete. The use of fly ash performs such a role and improves the strength and durability of concrete. Portland pozzolana cement produces less heat of hydration and offers greater resistance to the attack of aggressive waters than ordinary Portland cement. It is particularly useful in marine, hydraulic construction, mass concrete structure like dam, bridges and thick foundations. Can also be used in sewers and sewage disposal works. In PPC, costly clinkers are replaced by cheaper fly ash hence it is economical. It is finer than ordinary Portland cement so it reduces micro cracks at the transition zone and also results in reduction of permeability. In 1998 due to lack of awareness and fear of trying something different among the users, the Portland Pozzolana cement was not common. In India only 19% of total cement production was PPC. But in 2010 the story was different as concrete made with PPC or fly ash amount up to 60% of the total concrete made and according to reports the use of Portland pozzolana cement in the recent years has steadily increased to about 67% while the production of ordinary Portland cement in India now stands only 25%. In addition to conservation of natural resources, fuel, and reduction of green house gas it has several more advantages like:  Low heat of hydration.  Superior performance under elevated temperature.  Good long term strength.  Control of alkali – silica reaction.  Resistance to acids and sulphate.  Reduced permeability.  Reduced chlorine diffusivity. III. FLY ASH IN MANUFACTURING OF BRICKS Fly ash can also be used in the manufacturing of bricks. In fact, we can say the fly ash bricks are the best replacement of clay bricks. Class C fly ash are used in the manufacturing of bricks because it posses cementitious property due to the presence of calcium oxide (more than 10%). The manufacture of conventional clay bricks requires the consumption of large amount of clay. This depletes the top soil and leads to degradation of land and makes the soil infertile so this land can’t be used in agriculture now. According to the study, 180 Billon tones of clay brick production per year consume 540 million tones of clay, makes 65,000 acres of land barren. Also the clay bricks are burned at high temperature to gain the strength, durability, density and red color appearance. Clay bricks are burned in the kiln at a temperature of 1100 degree for 3 to 5 days so this consumes 30 million of coal for the production of 180 billion tones of clay bricks. This coal not only produce solid waste nut also generates 26 million tons of carbon dioxide. A 10% switchover to fly ash bricks will use 30 million tones of fly ash every year, save environment and coal. Fly ash bricks do not require clay so this serves dual purpose of conserving the top soil and at the same time constructive utilization of fly ash. Use of fly ash in bricks manufacturing not only protect the environment but also make profit for the industry. A report suggests that if we do 10% switchover to fly ash bricks it will yield a benefit of 300 crores by way of reduction in brick cost production. Fly ash is increasingly being used throughout the world as ingredient for brick and varieties of recipes have emerged. Fly ash gets their strength and durability from the chemical reaction of fly ash with water. Fly ash is combined with sand and pigment and bricks are formed by hydraulic and vibratory press and cured with steam for two days and not fired. This method uses 85% less energy than traditional kiln firing. CALSTAR is a company stated in 2006, in Silicon Valley with production in Wisconsin that is producing fly ash bricks. They claim their bricks require 81% less energy to manufacture; incorporate 37% recycled fly ash and emit 84% less carbon dioxide during production. Lower energy use and inexpensive raw material allow them to offer competitive pricing and high margins. Fly ash is beneficial in all ways. According to MoEF notification, every construction agency engaged in the construction of building within a radius of 100 km froma coal or lignite based power plant shall use only fly ash bricks for construction. NTPC has manufactured more than 54 crores ash bricks in its various thermal power plants and utilized in construction activities. Table.1 Comparison between clay bricks and fly ash bricks PROPERTIES CLAY BRICKS FLY ASH BRICKS REMARKS Density 1600-1750 kg/m3 1700-1850 kg/m3 Higher load bearing Compressive strength 30-35 kg/cm2 90-100 kg/cm2 Higher load bearing Absorption 15-25% 10-14% Less dampness Dimensional stability Very low tolerance High tolerance Saving mortar up to 25% Wastage during transit Up to 10% Less than 2% Saving in cost up to 8% Plastering Thickness vary on the both sides of wall Even on both sides Saving in plaster up to 15% Advantages of fly ash bricks:  These bricks are environmental friendly as they use fly ash, saves agricultural land which is used for
  • 3. International Journal of EngineeringScience and Computing, March 2017 4972 http://ijesc.org/ manufacturing of clay bricks and emits very less carbon dioxide.  It reduces dead load on structures due to light weight.  Same number of bricks will cover more area than clay bricks.  High fire insulation.  Due to its high strength, practically no breakage during transportation and use.  These bricks due not require soaking in water for 24 hours. IV. FLY ASH IN CONCRETE Fly ash is also very useful in concrete as it increase the durability and strength of the concrete along with it, it decreases the percentage of cement used in concrete. Fly ash can be used in Plain cement concrete to enhance the performance of the concrete. Portland cement is manufactured with calcium oxide, some of which is released in a free state during hydration. As much as 20 pounds of free lime is released during hydration of 100 pounds of cement. This liberated lime forms the necessary ingredient for reaction with fly ash silicate to form strong and durable cementing compound thus improving many of the properties of concrete. Typically 15-30% of Portland cement is replaced by fly ash, this result in net reduction in energy use and green house gas and other emissions. Study show that one ton of Portland cement production discharges 0.87 tons of carbon dioxide in the environment. Japanese study indicate that every year barren land approximately 1.5 times of Indian territories need to be afforested to compensate for the total global accumulation of carbon dioxide discharge into the atmosphere because of the total global cement production, utilization of fly ash in cement concrete minimize carbon dioxide emission problem. Since a huge quantity of cement is used in mass concrete and the cost of fly ash is negligible as compared to that of cement, the use of fly ash in concrete not only saves the cement consumption and cost but also provide high strength. Fly ash can substitute up to 66% of cement in the construction of dams. 90 days strength of fly ash concrete may be more than 140% of plain concrete. Use of fly ash concrete in R.C.C structure provides more strength without any risk of steel corrosion. High Volume Fly Ash Concrete (HVFAC) was coined by VM Malhotra in the late 1980s. this concrete has very low water content and at least 50% of the Portland cement by mass is replaced by class F fly ash. Because of the very low water content, superplasticizer is generally used to achieve slump ranges from 150 to 200 mm. but if high early strength and high slump is not required then the use of superplasticizer is not required. The HVFA concrete has excellent workability, low heat of hydration, low drying shrinkage and excellent durability that are necessary to call it high performance concrete. It was first developed for mass concrete application where low heat of hydration was required. Subsequent work has demonstrated that this type of concrete showed excellent mechanical and durability properties required for structural application and pavement construction. HVFA can be used in water front structures, industrial structure and roller compacted concrete dams- an innovative dam technology developed as a result of effort to design more economical concrete dams that could be constructed rapidly with designed performance. BENEFITS OF FLY ASHWHEN USED IN CONCRETE:  Produce various set times.  Increase durability.  Reduce alkali silica reactivity.  Increase ease of pumping and improves flow – ability.  Reduce segregation and slump loss.  Reduce water demand.  Cold weather resistance.  Higher strength gains.  Can be used as a admixture.  Reduces cost.  Increases the modulus of elasticity of concrete when concrete of same strength with and without fly ash are compared.  Improved sulphate resistance.  Can substitute for Portland cement.  Considered a non-shrink material.  Produces denser concrete and a smoother surface with sharper details.  Great workability.  Reduces crack problems, permeability and bleeding.  Reduces heat of hydration.  Produces lower water cement ration for similar slumps when compared to no fly ash mixes.  Reduces CO2 emissions. V. OTHER USES OF FLY ASH  Fly ash holds a potential to improve the physical health of the soil. It can serve as a soil modifier and also enhance the water retaining capacity and fertility of the soil. It improves the plants water and nutrients uptake, helps in development of roots and soil binding, stores carbohydrates and oil for use when needed, protect soil from soil borne disease. Use of fly ash in agriculture can increase the yield of cereals, oil seeds, pulses, cotton and sugarcane by 10-15%, vegetables by 20-25% and root vegetables by 30-40%. Fly ash application to sandy soil could permanently alter soil texture, increase micro porosity and water holding capacity. Lime in fly ash readily reacts with acidic components in soil and releases nutrients such as S, B and Mo in the form and amount beneficial to crops plants. It also improves the nutrient status of soil. Also use of fly ash instead of lime as soil ameliorant can reduce net carbon dioxide emission and thereby lessen global warming.  Soil stabilization is the permanent physical and chemical alteration of soil to enhance their physical properties. Addition of fly ash in soil will increase the physical as well as chemical properties of the soil. Some expecting properties to be improved are CBR (California bearing ratio) value, shear strength, liquidity index, plasticity index, unconfined compressive strength, control shrinkage and bearing capacity etc thus improving the load bearing capacity of a sub grade to support pavement and foundation.  Fly ash is also used as an embankment material. As it is a light weight material as compared to natural soils and posses high angle of shearing resistance, greater stability of slopes hence suitable as embankment fill over soft compressible ground. The compaction curve of fly ash is relatively flat, showing that the degree of compaction is less sensitive to water
  • 4. International Journal of EngineeringScience and Computing, March 2017 4973 http://ijesc.org/ content and fly ash can be used even in wet condition as an embankment material.  The fly ash, being cementitious coal combustion by product, promises high volume utilization in grouting application. The fly ash grouts provide required engineering performance in improving ground stability by increasing strength and shearing resistance as well as reducing the permeability of soil treated with enhanced technical, rheological, durability and economic advantage over sand and cement grouts.  Fly ash is also used in road sub base construction because of its light weight and low cost. And also it provides greater strength.  Also may be used in cosmetic, toothpaste, kitchen counter top, floor, utensils, floatation devices, PVC pipes, railway sleeper, doors, window frames, mail boxes, metal casting, sign posts, auto bodies, picture frames, running tracks, park benches, binding agents, paints and filler in wood and plastic products. VI. CONCLUSION Fly ash should now not be considered as a waste product it should be now considered as a resource material. Many researches and experiments have been done on fly ash, and fly ash has succeeded everywhere so the use of fly ash is continuously increasing. Government is also trying to promote fly ash use in construction works, Maharashtra Government makes fly ash mandatory in all government infrastructures and also the state government has made it mandatory for all companies and developers located in a 300 km from a power plant to use fly ash in construction. It has been made mandatory for the use of fly ash in government projects such as construction of roads, dams, housing schemes etc. In the construction of Ghatghar dam situated in Ghatghar village in Ahmednagar district 70% of cement by mass was replaced by fly ash. It not only provides strength to the dambut also reduces the cost of the construction. The use of fly ash in Nizamuddin bridge road embankment in Delhi for about 2 km and height of 8m in a flood zone has demonstrated the use of fly ash in adverse condition. This has not only saved the top soil and used fly ash which was otherwise a waste but also saved 1.4 crore in a total project of 10 crore. Fly ash is very beneficial the use of fly ash bricks over clay bricks not only prevent the top soil but also saves environment by emitting very less carbon dioxide as compare to clay bricks. Fly ash is the best replacement of cement. The use of fly ash in concrete improves the strength and durability of the concrete by converting calcium hydroxide into calcium silicate hydrate gel (C-S-H gel). Along with the use of fly ash in construction works, fly ash is also used in agriculture to improve the physical and chemical strength of the soil. It can serve as a soil modifier and also enhance the water retaining capacity and fertility of the soil and increase the yield of the crops. So fly has got several advantages in every field. VII. REFERENCES [1]. QUALITY TREND IN INDIAN CEMENTS- A DECADE APPRAISAL BY U S SINHA, K BHATNAGAR, R GUPTA AND M M ALI. [2]. CONCRETE TECHNOLOGY – M.S. SHETTY. [3]. USE OF FLY ASH IN AGRICULTURE- A WAY TO IMPROVE SOIL FERTILITY AND ITS PRODUCTIVITY BY PREM KISHOR, A.K GHOSH AND DILEEP KUMAR. [4]. http://www.thebalance.com/fly-ash-applications-844761 [5]. SOIL STABILASTION BY USING FLY ASH – KARTHIK.S, ASHOK KUMAR.E, GOWTHAM.P, ELANGO.G, GOKUL.D, THANGARAJ.S [6]. ENVIRONMETAL IMPACTS OF ELECTRICITY GENERATION CASE STUDY FROM INDIA USING LIFE CYCLE ASSEMENT APPORACH- SHAH B [7]. FLY ASH – WIKIPEDIA [8]. http://www.ecobrick.in/waste_utilization_in_brick_mak ing.aspx [9]. INDUSTRIAL APPLICATION OF FLY ASH – A REVEW- DR.SUHAS V.PATIL, SURYAKANT C.NAWLE, SUNIL J.KULKARNI [10]. ASH UTILISATION- NTPC [11]. A WASTE: FLY ASH UTILISATION IN DIFFERENT AREAS- RAMJI PORWAL, SAURAV DUBEY