Experimental Study of Some Agro-Industrial Residues Targeted As Partial Substitutes to Fuel-Oil Conventional Burnt Into the Clinker Kiln of Onigbolo-Cement-Complex (Benin)
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Experimental Study of Some Agro-Industrial Residues Targeted As Partial Substitutes to Fuel-Oil Conventional Burnt Into the Clinker Kiln of Onigbolo-Cement-Complex (Benin)
1. ISSN (e): 2250 – 3005 || Volume, 06 || Issue, 06|| June – 2016 ||
International Journal of Computational Engineering Research (IJCER)
www.ijceronline.com Open Access Journal Page 50
Experimental Study of Some Agro-Industrial Residues Targeted
As Partial Substitutes to Fuel-Oil Conventional Burnt Into the
Clinker Kiln of Onigbolo-Cement-Complex (Benin)
Sanya Emile A1
, Chaffa Gédéon2
, Houngbédji F. Martin3
, Djima M.A.Bassitou4
1
Laboratory of Applied Energetic and Mechanics (LEMA) – Polytechnic School of Abomey-Calavi (EPAC) -
University of Abomey- Calavi (UAC) 01 POB: 2009 Cotonou, BENIN
2
Laboratory of Applied Energetic and Mechanics (LEMA) – Polytechnic School of Abomey-Calavi (EPAC) -
University of Abomey- Calavi (UAC) 01 POB: 2009 Cotonou, BENIN
3
Cement-Complex of Onigbolo (CCO) - SCB-LAFARGE Cement Company of Bénin,
POB: 61 Pobè, BENIN. Tel: +229 20 25 04 25 - Fax: +229 20 25 03 02
4
Benin Petro s.a., Cotonou, BENIN, Tel. +22921 311 671 Fax. +229 21 311 673
I. NOMENCLATURE
a: correction constant necessitated by acids formation;
b: correction constant necessitated by combustion heat of the firing or igniting wire;
c: temperature correction constant necessitated by exchange heat with outside (zero if using adiabatic jacket),
C: carbon symbol (carbon content of any considered fuel i in %);
CODA-Benin s.a: Oil-mill Complex of Agonvy (an Anonym Society located at Ikpinlè (South-West Benin)
COFRAC: French Accreditation Committee;
CCO: Cement Complex of Onigbolo, a factory located at Pobè (South-West City of Benin);
E: calorimetric bomb water equivalent, accessories and contained water (g);
εr: waste to fuel-oil equivalent ratio (no unity);
Fludor-Benin s.a: Anonym Oil-mill Company (Centre Benin);
H: hydrogen symbol, hydrogen content of any fuel i (%);
HHV: Higher Heating Value also called Higher Calorific Value (HCV) (kcal/kg);
IBCG: Fats Industry of Benin (an Oil-mill) located at Cotonou;
INSAE: National Institute of Statistics and Economic Analysis of Benin;
kF: kilo-Franc, MF (CFA): mega-Franc, both money unities of African Financial Community (CFA):
L/h: liter per hour (fuel-oil flow unity);
LHV: Lower Heating Value also Lower Calorific Value (LCV) (kcal/kg);
M: mass of sample (g);
ABSTRACT
Cement industry belonged to the largest energy consumers’ factories in Benin. The Cement
Complex of Onigbolo (CCO) had particularly undergone the disconcert effects of petroleum blaze
costs of last years. This paper dealt with experimental investigations on agricultural/industrial
wastes as fractional substitutes of the 7,000 L/h fuel-oil burnt in CCO-clinker furnace. Combustion
of about 58 tons of five targeted agro-wastes and worn-tires, up to now ignored or forsaken in situ,
even incinerated in open-air because unwieldy, made it possible saving more than 1.5 MF(CFA) in
only 100-hours running. Experimental results also showed how far the cement process could
contribute to towns/villages/cities cleanup (environmental problems reduction) combined with
energy needs fulfillment. Among the studied agro-wastes and in expectation of adequate control
and optimization of the convenient pretreatment for improving worn-tires’ combustion, results
revealed that wood-sawdust was the alternate-fuel technically and economically well adapted to
this tested furnace, better than cottonseeds-hulls preferred by CCO-authorities. Compatibility of
the burnt wood-sawdust with cement quality characteristics, relatively high calorific value,
availability and abundance throughout the year at existent sawmills, technically justified its
choice. Conversely, results furthermore proved that no significant substitution rate can be reached,
using only one kind agro-waste: therefore cottonseeds-hulls can be combined to sawdust.
Keywords: alternate-fuels, cotton-fibers waste, cottonseed hulls, clinker kiln/furnace, worn-tires,
wood-chips, wood sawdust.
2. Experimental Study Of Some Agro-Industrial Residues Targeted As Partial Substitutes To Fuel-Oil…
www.ijceronline.com Open Access Journal Page 51
ONAB: National Wood Office of Benin;
Q: mass flow-rate (kg/h) or ton/hour (t/h)
SHB: Oil-mill Society of Benin located at Bohicon (center of Benin);
SOCOR s.a: French Company Control and Receiving Combustibles at Douai (France)
SODECO: Cotton Development Corporation (Benin)
SONACOP: National Society of Petroleum Products Marketing (Benin);
σr: substitution ratio (%);
th/t (= kcak/kg): thermal per ton (industrial unity: 1 th = 1.163 kWh);
T: temperature (°C) with respective indexes: initial (Tin) and maximal (Tmax);
WW (i): water content of crude sample i (%), WD (i): water content (%) of dry agro-waste sample i.
II. INTRODUCTION
The primary goal of any industrial business is to increase productivity, whilst minimizing energy consumption,
for ensuring competitive products and achieving greater profitability. This vision is shared by leaders of
Onigbolo-Cement-Complex (CCO), a big energy consumer Company of Benin. Indeed, energy was and remains
the major cost factor in cement production: 40-60% [1, 2, 3, 4, 5, 6]
. The required temperature, for conversion of the
raw materials, consisting mainly of limestone, clay and shale (in powder form), into clinker that gives access to
cement, is around 1450 °C [1, 2, 3, 4, 5]
. The difficulties for petroleum fuels and electricity supply oblige to take
into account some cautions. If nothing is done, this important factor of production might penalize the company
in its quest for competitiveness. Dependency on foreign petroleum products, including diesel fuel with transport
difficulties and introduced uncertainty by instability of purchase costs, especially the recorded latest outbreaks,
combined to daily load shedding, have stimulated industrial glimpse for alternate energy solutions [6, 7, 8]
.
Onigbolo-Cement-Complex managers are now fond of redefining their company’s energy strategy. So, they’ve
decided to search for alternate combustibles for partially substituting the classical fuel-oil. Some agricultural
and industrial residues were chiefly targeted. However, every fuel substitution requires removal of some
constraints which consist on providing clear answers to general, technical and technological, financial and
socio-economical questions [9, 10, 11]
. Substantially, analysis of general context concerns the search for adequate
solutions to various expressed issues such as: whether or not to use the selected residue(s) in clinker-furnace,
acceptance of choice by industrial unit authorities and workers, availability of the targeted residue(s) for short,
medium and long terms, the chosen fuels location (concentrated in one place or dispersed), initial use and
prospects of residue(s) producers, number of potential users, competitors or suppliers and fluctuations related to
their supply, collection and acquisition conditions (seasonal or continuous). Technical and technological aspects
chiefly are based on physicochemical and energetic analyses of the targeted alternate combustibles. Particular
attention shall be paid to control of the required pre-treatment/modifications linked with adoption of any agro-
residue. Final choice is specifically based on criteria that are: compatibility of combustion products of the
selected residue with chemical composition and quality of the manufactured clinker, a high value of the lower
calorific power of the adopted agricultural / industrial residue, its ability to develop a combination of
spontaneous and rapid combustion (high heat provider), collection, storage and easy handling.
This article is focused on development of the performed technical experiments by proceeding to true
combustion of each of the targeted agro-waste and worn tires in the clinker furnace of CCO. Apart from the
difficulties inherent in the handling of different residues tested, the quality of cements obtained was compared
to that of standardized reference 2004 actually used to date.
III. MATERIALS AND METHODS
3.1. Materials
The explored agro-wastes derived from three vegetable species (cotton, oil-palm tree and wood) to which was
added one imported residue as worn-tires. The targeted agro-wastes consisted of the cotton by-products as
fibers, seeds-hulls, cotton fibers waste and entire seeds, the oil-palm tree empty bunches, the wood chips and
sawdust. Of these, the effectively reported six (06) tested combustible residues in this paper included the cotton
fibers waste supplied by industrial cotton-gins plants in Benin, cottonseed hulls from Fludor-Benin oil-mill,
wood chips and wood-sawdust delivered by Saclo sawmill industry of Bohicon (Center Benin), empty bunches
of oil-palm tree recovered at CODA-Benin oil-mill of Pobè and the worn tires collected from various cars in
Cotonou and Porto-Novo, two great cities of Benin, added to those belonging to the CCO motorized vehicles.
Chemical and energetic characterization of the studied agro-wastes was performed using PARR Instrument
Carbon and Hydrogen Analyzers from SOCOR laboratory at Douai in France. This latter is an agreed and
specialized society, holder of ISO-17025 accreditation awarded by the French Accreditation Committee.
All the performed experimental combustions were really done using these targeted agro-wastes in the rotating
clinker kiln of CCO industrial cement entity. Chemical constituents of the ensued clinkers were determined with
the aid of fluorescence X-rays Spectrometer of CCO integrated laboratory [2-6, 23]
. This apparatus usually
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allowed for online data monitoring on the produced cements quality in accordance with cement industry
standards. In view of well ensuring quality for the obtained cements, mortar specimens from resulting cements
were also realized and submitted to resistance evaluation, mainly for breaking strength, in classical compression
testing.
3.2. Methods
3.2.1. Wastes energetic characteristics. Determination of energetic characteristics was done on only two (02)
samples per each of all those selected agricultural and industrial wastes. The reasons were linked, not only with
the well reproducibility of tests results, but also to the high unit cost. The realized analyses focused on
determination of respectively, the carbon C(i) and hydrogen H(i) contents (in samples weight percentages)
according to standard NF-M03-032, the moisture content W(i) according to European EN-14346-PR standard,
the higher calorific value HCV(i) on dry matter basis and the lower calorific value LCV(i) on dry and also wet
matter bases of each alternate combustible (i) according to NF-ISO-1928 standard. The HCV(i) at constant
volume and the deduced LCV(i) at constant pressure were generally calculated by means of equations similar to
those of the followed respective expressions [9,10,11,12,13, 23, 29]
:
iW100Mb)(ac)
in
Tmax(TE)(4.1868iW100iHCV (1)
D(i)
W/100
D(i)
W100
W(i)
W8.93725.1iHCViLCV (2)
in which E signified the equivalent water capacity of bomb calorimeter, accessories and the contained water (g),
Tin initial temperature (°C), Tmax maximal temperature (°C), a correction constant necessitated by acids
formation, b correction constant necessitated by the ignition wire combustion heat, c temperature correction
constant necessitated by exchange heat with exterior (zero, if adiabatic jacket was use), M mass of sample i (g),
WW(i) gross moisture of sample i (%) and WD(i) water content of dry waste sample i (%, NF-M03-037).
The SOCOR laboratory also used an analogous approximate equation for LCV calculation from the measured
HCV-value by bomb calorimeter and the obtained mass percentages of carbon (%C), hydrogen (%H) and
humidity (%W). These chemical contents of the studied agro-wastes were determined using a (C, H, W)-Parr
Analyzer. The adopted values were arithmetical mean of the two results for HCV(i) on dry, in one side, and the
LCV(i) on crude, on the other. The LCV(i) values on crude basis have finally been chosen pursuing the current
investigation for simply accounting for the fact that, all the testing alternate combustibles truly burned in situ, in
their raw state, because no treatment was applied.
As it’s clearly known, the produced heat from combustion must be sufficient for covering the needs in heat for
cooking clinker, including that part for preheating raw material, from the disposed cyclones upstream of furnace
which, under the nominal running conditions, consumed about 7,200 L/h of fuel-oil [1, 7]
. For that reason, it’s
convenient to prior choose a target of a partial fuel-oil substitution and secondly adopt usage of a higher
alternate waste ratio as possible, in order achieving a significant reduction of the petroleum products
consumption rate by furnace. Subsequently, the experimental procedure itself had consisted effectively on
introducing each of the chosen waste/residue into the clinker furnace, at the same time as continuing to provide
a compulsory permanent proportion of the classical fuel-oil as balance. Corresponding fraction of fuel-oil mass
flow-rate (QAFOF), to be added to that of a selected agricultural residue/waste (QAW), could then be calculated
from the established heat balance between the two combustibles kinds. The derived equation was expressed as
following:
FO
/LCV
AW
LCV
AW
ρ
AW
Q
FO
ρ
FO
Q
FO
LCV
AFOF
Q (3)
The selected agro-waste quantity (QAW, kg/h), owning a lower calorific value (LCVAW, kcal/kg) and loose state
density AW (kg/m3
) which combustion must generate the same heat quantity as that provided by the classical
fuel-oil quantity QFO (=7,200 L/h) of density FO (=0.86 kg/L) and LCVFO (=9,700 kcal/kg), had been simulated
using equation (3). This allowed us to deduce the corresponding added fuel-oil flow-rate fraction (QAFOF, kg/h).
3.2.2. Substitution rate estimation. The substitution rate (σr) was defined as percentage ratio, built on basis of
the supplied heat quantity by a chosen alternate combustible only to that delivered by the use of combined agro-
waste and fuel-oil (equivalent to furnished normal fuel-oil heat quantity),. It’s expressed by the derived
following equation from the heat balance:
FO
LCV
AFOF
Q
AW
LCV
AW
Q/
AW
LCV
AW
Q100rσ (%) (4)
It was also important to notice that, effective implementation for testing worn-tires conducted to major changes
in the furnace feeder, as made choice was un-pretreated entire tires use into it. Then, a tires’ conveyor-lift
system coupling to an adequate control locks reassuring the furnace feeding was designed and built.
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3.2.3. Achieved cements quality. Two important parameters have been exclusively evaluated for quality testing
of the reached cements using these targeted agricultural and industrial residues.
3.2.4. Cements mechanical resistance. It’s important that the derived cements be mechanically certified. The
breaking strength measurement, through standardized compression, was the elected mechanical method of
evaluation applied to normalized mortar specimens from the achieved cements from these studied
agricultural/industrial wastes/residues. Mortar specimens of 40x40x160 mm dimensions have been realized and
conditioned according to NF-EN196-1 standards. Natural sand of 2,600 kg/m3
absolute density interred the
specimen’s realization on weight basis of 1,350 g for 450 g of cement and 225 g of water (ratio
Water/Cement=0.50). Built specimens were submitted to compression test exploiting the
Universal SATEC MKIII-60TVL press type having maximal capacity 5,000 N, belonging to Civil Engineering
Research Entity of LEMA.
3.2.5. Cement's quality at composition's point of view. The X-fluorescence spectrometry (FX), reference for
nondestructive elemental analysis in many applications, such as cement, mining and food products, was used in
this study. Percentages of various components of the produced cements from the selected agricultural wastes
and worn tires were determined. A comparison has finally been realized between these different percentages
and that of classical cement produced without any incorporation of agricultural waste or worn tires, but simply
on basis of the applied production practices at CCO until there, i.e., according to the standardized reference of
2004.
IV. RESULTS AND DISCUSSION
The realized physicochemical and energetic analyses, on different studied agro-wastes and industrial residues,
have yielded the constituents percentages and LCV-values gathered in Table 1.
Table 1- Physicochemical and energetic characteristics of the studied wastes and references
Parameters ► Carbon Hydrogen Humidity Others *
LCV
(kcal/kg)Viewed wastes► (% mass)
Cotton-fibers waste 33.7 4.57 6.15 55.58 2,814
Cottonseeds waste 52.4 7.09 6.8 33.71 4,784
Cottonseeds hulls 46.8 5.58 10.9 36.72 3,738
Wood-sawdust 51.55 6.12 11.6 30.74 4,271
Wood-chips 51.7 6.05 8.7 33.55 4,279
Cotton fibers 44.7 6.11 6.2 42.99 3,953
Oil-palm bunches As determined by authors [10, 16]
3,000
Worn-tires with textile reinforcement [17]
8,600
Worn-tires with feeble metallic reinforcement [17]
8,500
Worn-tires with high metallic reinforcement [17]
5,900
Gas oil (Sonacop) As determined by authors [10, 11, 21]
10,300
Heavy fuel-oil n°2 As determined by authors [10, 20, 21]
9,700
* Values in labeled column as “Others” are those deduced from 100 % after summing values of
measured constituents that not interred the LCV expression
In the last two rows of Table 1 were indicated the LCV-values of conventionally used heavy fuel-oil and diesel
(gas oil) at CCO factory. Finally, apart from tests on tires, that have lasted up to 48 hours continuously, the done
others on the agro-wastes were not as long: experimental times ranging from 02 hours 30 minutes to 06 hours.
The reasons of these limitations were particular, either to the small amount of stored agro-wastes for
investigation or to the recorded poor performance during some experiments which have been stopped sooner
than stipulated. This fact was also justified by the associated difficulties with the storage means of these
identified residues (chiefly the lack of storage spaces) and technical problems, essentially due to the occurred
failures on combustible forklift and furnace’s feeder-valve during these done tests.
4.1. Cotton-fibers wastes
Results from the performed energetic analyzes for cotton-fibers waste revealed an average LCV-value of
2,813kcal/kg. This was very low in comparison with the furnished classical LCV-values respectively for fuel-oil
9,700kcal/kg and diesel or gas-oil with 10,300kcal/kg. These accomplished practical tests in situ showed that
the cotton-fibers could be burnt in cement furnace but more elevated quantity must be provided for reaching the
same heat capacity level as that of classically used fuel-oil. It then remained how to ensure the availability,
required quantity and sustainability of the cotton-fiber wastes. Indeed, the recorded data on evolution of the
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produced cotton-crops in Benin, during different cotton campaigns, from 1995 to 2015, were depicted on Figure
1.
Figure 1- Evolution of the produced cotton crops from 1995 to 2015 campaigns in Benin (Inter professional
Cotton Association of Bénin: http: //www.aic.org.bj)
Analysis of evolution of the produced cotton-crops data (Figure 1) reveals a polynomial tendency with feeble
regression coefficient (R2
= 0.78). These shown data let us known about the existing very unstable situation in
cotton production in Benin. Cotton-crops production restarts with new rise, from only the three last campaigns,
without however reaching the greatest value ever obtained up to now: that of 2004-2005 campaign. This raw
material (crude cotton in seeds) underwent the first industrial transformation in, at means, fifteen cotton-gins
spreading on all the national territory. All these cotton-gins factories spit two (02) kinds of cotton-wastes: the
fiber wastes for about 0.5% of yearly crops and the gin-mot for 2%, both these two residues amount being of
2.5% of yearly crops. Average quantities of the combined two cotton-wastes kinds, on basis of the determined
2.5% cotton-crops values, from 1995 to 2015 campaigns, were those listed in columns 2 and 4 of Table 2.
The mean-value of the produced cotton-fibers waste in Benin, from 1995 to 2015 cotton-crops campaigns, was
then estimated to 6,146±1,802 tons/year. It must be underlined that, such the shown annual quantities of cotton
residues were truly underestimated. These wastes/residues amounts have been usually released in the surround
environment if not incinerated outdoors. A relative small or insignificant part of these cotton-waste kinds was
often recovered by mattress makers for manufacturing their sold various articles. These cotton-fibers waste
continued to suffer a decline at the same rate as done the annual crude cotton crops from 2004-2005 seasons.
This same tendency was also observed in all the West African sub-region. In recent years, the cotton market had
fluctuated and the effects were severely felt by African producers. Despite the initiated stimulus by Beninese
government towards the cotton producers and creation of the Cotton Development Corporation (SODECO), the
downward tendency seemed unlikely to change, especially because of the low cotton price on international
market. In other words, there existed an effective energy source in cotton-fibers waste, but not sufficient for
supplying the clinker furnace. In addition, it was spread over the existent fifteen ginning machines on national
territory and availability also seasonal. A large stock of cotton-fibers waste was therefore needed for covering
peak periods. However, if this possible, through efforts to enhance cotton-seeds production, increasing the
amount of fibers-waste should rather reflect poor quality of the global produced cotton-crops. Such a thing
could not be desired by actors of the cotton sector.
Table 2- Estimated quantities of cotton-fibers wastes (tons) by campaigns from 1995 to 2015 in Benin
Campaigns Cotton-Fibers wastes Campaigns Cotton-Fibers wastes
1995-1996 7,356 2005-2006 4,000
1996-1997 7,340 2006-2007 5,049
1997-1998 7,543 2007-2008 5,641
1998-1999 7,037 2008-2009 4,424
1999-2000 7,651 2009-2010 4,215
2000-2001 7,062 2010-2011 2,940
2001-2002 8,723 2011-2012 3,654
2002-2003 7,015 2012-2013 5,040
2003-2004 6,981 2013-2014 6,447
2004-2005 8,951 2014-2015 8,253
Mean-value of estimated quantity of cotton-fibers wastes: 6,146 ± 1,802 tons/year
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It followed nevertheless that, the fibers-waste could then be supplemented by another residue type: cottonseeds-
hulls. The latter ensued from cottonseeds crushing at oil-mills. It was quantitatively more important than fibers-
waste and certainly as appropriate as fibers for the clinker furnace feeding.
4.2. Cotton-seeds hulls
Results from chemical and energetic analyses of cottonseeds hulls were shown in line 4 of Table 1. It must be
noticed that these obtained values were consistent with those found in literature [9, 10, 11]
and in Fludor-Benin
archives [12]
. In fact, the shell (hull) represented 19% by weight of fresh cotton-seed, had a density of 130-160
kg/m3
, provided a LCV-value of 3,895kcal/kg and contained 3.4% of minerals. Cottonseeds-hulls were
energetically best than that of cotton-fibers waste with 3,738 kcal/kg against 2,813 kcal/kg. Already used for
feeding boilers at Fludor-Benin s. a Company, these shells/hulls could also be efficiently used in the clinker
furnace. In fact, the seeds were considered as the by-products or wastes of cotton ginning. But, the cottonseeds
constituted the raw material for crushing plants like those of Fludor-Benin s. a, the Benin Oils Society at
Bohicon (SHB) and the Benin Fats Materials Industry (IBCG) at Cotonou. Annual excesses of cottonseeds-
hulls, which represented the difference between the real quantity of hulls from the crushed seeds and the
reserved part for internal self-consumption of these companies (exclusively devoted to boilers and livestock
feed mill units), were estimated to 35,000 t for Fludor-Benin [12]
and 40,000 t for SHB [13,14]
and therefore
judged substantial. These values did not integrate that of cotton-whole-seeds resulting from the excess
uncrushed quantity of oil-mills which was usually rejected in the open air.
4.3. Wood-chips and wood-sawdust
The recorded results from chemical and energetic analyses of the wood-sawdust and wood-chips were those
gathered in the respective lines 5 and 6 of Table 1.
It could be observed that the LCV-value of wood-sawdust was of the same order as wood-chips, two considered
wastes from the same wood substance: 4,272-4,279 kcal/kg. Both these two results showed that, values of LCV
of the wood wastes were higher than those of cotton-fibers / cotton-fibers wastes (3,953 / 2,814 kcal/kg) and
cottonseeds-hulls (3,738 kcal/kg), but not that of entire cottonseeds (4,784 kcal/kg). Of course, the noticed
differences linked with the fact that the cottonseeds or seeds-hulls contained relative oil percentages which
consisted on hydrocarbon substances known as veritable fuel. Knowledge of these data offered the advantage
for helping guide the eventual choice towards wood-wastes (chips or sawdust) at the expense of cotton-wastes.
Indeed, respective quantities of the really tested wastes or residues (QAW, column 2) and those of equal fuel-oil
(QFO, column 4), for generating the same heat power (column 3), have been experimentally evaluated. The
results were also expressed in form of the called equivalent ratios ( ►r) which values gathered in Table 3
(column 5, accompanied with inverse 1/ ►r in brackets). It could be underlined that, for producing the same heat
energy amount as that of commonly used fuel-oil in the clinker kiln, approximately 9,700 kcal/kg, it must be
consumed 2.40 tons of wood-sawdust against 4.20 tons of cotton-fibers waste or 2.03 tons of cottonseeds-hulls.
The wood-sawdust and wood-chips were two residue types from wood sawing and wood planning processes
respectively. The sawmill plant of Saclo (Bohicon) at the National Wood Office of Benin (ONAB), operated
eight (08) hours per day and delivered approximately 2,000 m3
of wood. The generated residues consisted of
falling trunks and branches of trees, wood-chips and wood-sawdust. Quantity of these residues had been
reasonably estimated to about half of the wood total production: 1,000 m3
a day.
Table 3- Calculated equivalent ratio from each quantity of the tested wastes and that of the burnt fuel-oil
Falling logs were retrieved and used as wood or charcoal in cooking. The wood chips and sawdust spilled loose
near the sawmill site. According to existent literature, the amount of sawdust averaged 12% of initial volume of
the wood residues against 32% for the finest particles of the woodworks [9]
. At Saclo sawmill, the excess teak
sawdust alone was estimated at 3,500 m3
per year. A tiny amount, not as much as 0.5% of previous value, was
recovered by local residents for domestic usages [9, 10, 23]
. The energetic valuation of the remnant sawdust,
through an industrial kiln, required that annual stock higher than estimated and conditioning to dry.
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4.4. Oil-palm bunches
Literature provided globally the LCV-values of 1,100 - 3,800 kcal/kg for oil-palm wastes [11, 15]
. The oil-palm
bunches at Agonvy displayed an average LCV-value 3,996 kcal/kg, for annual production amount of more than
8,000 tons [16]
. In this study, we’ve chosen to adopt an average value of LCV 3,000 kcal/kg. The use of oil-palm
bunches had led to difficulties for conducting the kiln. It effectively caused a slight production decrease due to
the generated lower combustion temperatures linked to the trouble burning of palm bunches at the kiln entrance.
In other words, the amount of produced heat by the oil-palm bunches failed compensating the connected
fraction to the fuel-oil reduction. This poor combustion of oil-palm bunches was due, not only to waste kind
higher humidity and ashes contents, but also to the residue handling difficulties and especially congestion of
feeder airlock, all things leading to a very low exchange ratio. It was also suitable to emphasize the required
delicacy for oil-palm bunches storage. In reality, the storage required not only, availability of an important heat
source for drying bunches, but also subsequent realization of suitable devices without which breakdown was
unavoidable.
4.5. Worn tires testing
Determination of LCV value of the used worn tires in the current investigation had not been realized. The
reasons are related to diversity of the collected tires for this experiments campaign, but also at high cost of
analysis and at insufficient of financial resources. In the absence of such analysis, indicative data on tires LCV
values were taken from literature [17]
.
The results on Figure 2 clearly showed that the published values for the Lower Calorific Value of cars' tires
varied as function of tires constitution, including mainly the types of structure reinforcements.
Figure 2- Values of LCV (kcal/kg) for some materials showing that worn tires LCV vary according to
structural reinforcement types [17]
Table 4- Indicative data on mean-values for chemical composition of the cars worn-tires [17]
Depending on whether the tires belonged to ordinary cars, buses and heavy equipments, the metallic
reinforcement, expressed as a percentage of tires mass, changed from respectively, less than 5%, between 5 and
25%, to over 25%. As part of this investigation, a mixture of different tires kinds was used. Thus, the considered
LCV value for this work was arithmetic mean of those from the four (04) tires varieties shown in Figure 2:
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7,550kcal/kg. It outcame that, this adopted tires LCV-value was not very far from the often cited one in
literature: 8,000kcal/kg. If excluding, from Figure 2, the data relating to the high metallic reinforced tires that
belonging to heavy equipments (less interesting tires category for feeding the tested clinker kiln), reached
average LCV value of 8,100 kcal/kg then fairly closed to that of literature: 8,000 kcal/kg.
Indicative values on chemical composition of the motorcars overall tires were depicted in Table 4. These shown
components values in table 4 truly proved that, the worn tires, due to their high carbon and hydrogen contents,
constituted a very usable energy source in the cement process for the required cooking of clinker.
4.6. X-Fluorescence Spectrometry Analyses
Basic chemical constituents of the burned alternate combustibles could produce ashes and other by-components
that might contribute to changes some of the cementing indexes, such as the alumina-ironic modulus (AFM)
and silicate modulus (SM) provided respectively by their iron and silica contents. Such the changes exerted
effects, not only on the quality of clinkers, but also on energetic consumption and the tenacity of refractors
bricks for the furnace’s inner isolation [25, 27, 28]
. The alkaline degrading attacks of refractory bricks, due to Na
and K components, might be recorded. Increasing of the thermal conductivity of isolating bricks, that provoking
excessive heating of furnace envelop, could sometimes be observed under diffusion and attacks from defined
salts like NaCl, KCl and K2SO4. To discomfit this possible occurrence, results of the performed X-fluorescence
spectrometry analyzes, on the one hand (Figure 3) and those from the compatibility study of the burned tires
and wood-sawdust with the obtained cements quality, on the other hand, clearly showed that the chemical
compositions of resultant clinkers were not significantly affected by combustion of added worn tires,
cottonseeds wastes or oil-palm bunches in clinker furnace. When comparison is made with the current reference
2004 in cement field, one can clearly observe and satisfactorily, that the obtained values, for different
constitutive oxides of the produced clinkers using the selected wastes or residues as alternate combustibles to
fuel-oil (Figure 3), are truly consistent with the technical normative values. Everything that ensures process
feasibility and justifies of the best quality of the derived clinkers from agricultural and industrial waste
valorization in cement filed.
Figure 3- Chemical compositions of obtained various clinkers from the studied alternate wastes (legend) using
X-fluorescence spectrometer analysis compared to standardized reference 2004
The noticed slight differences in monitored values could be attributed to low free-CaO contents of the produced
cements from the burnt wastes in comparison with that of Reference standard 2004. In fact, free-CaO values of
1.38±0.90 to 1.59±0.05% cement mass proportions have been quantified contrary to about 3.28±0.50% for the
standardized reference 2004, excepted for that of wood-sawdust which showed more important value of 2.03%.
At this level of chemical composition, these recorded data on the resulting cements characteristics from the
selected wastes led to the conclusion that they were as good quality as the reference standard 2004.
This furnished chemical behavior really justified the found complementary and practical chosen mechanical
analysis. As said and its methodology described above, the adopted mechanical measurement was that of
compression testing on built mortar specimen from obtained cements using the mixes of agro-wastes and fuel-
oil burned in clinker furnace.
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4.7. Mortar specimens’ breaking strength
In order to better confirm the previous chemical quality of the derived cements, standard specimens of cement
mortar have been realized and submitted to compression testing for breaking strength determination. The results
of the performed mechanical tests, using obtained respective cements from combustion of worn-tires on one
hand, and wood-sawdust on the other, attested of their very good resistances in compression test. Indeed, the
recorded data from mechanical measurements showed very interesting resistance values for the ensued cements
which effectively exposed, at only two (02) days old, respectively compressive strength values of 22±0.64 MPa
and 25.79±0.11 MPa. For a brief comparison, usually published values, at 28-days old, were of order of 15-18
MPa [2-6, 24, 26]
. The explanation attempt to this developed behavior by obtained cements from the burnt wastes
had not yet been completed. It’s first thought that these monitored higher values of breaking strength were
linked with iron content and derived constitutive metallic oxides from tires reinforcement. In that, they could
probably contribute to reinforcing of resultant materials and thus justified the observed favorably high
difference at contrary to produced cement-mortar specimens using classical fuel-oil alone. The performed
analysis on constitutive oxides of these clinkers clearly proved that all of their metallic oxides mass percentages
were practically of the same values order: 3.35 to 3.48 for Fe2O3, 4.76 to 5.99 for Al2O3 and 1.91 to 2.0 for
MgO. However, apart from the wood-sawdust for which CaO (66.38%) and free-CaO (2.03%) percentages were
fairly of the same order values as for standardized reference ones (65.41%) and (3.28±0.50%), those from the
obtained other cements seemed slightly feeble (63.42 to 63.86%) and (1.38±0.90 to 1.59±0.05%), Further
analysis of the recorded data revealed that carbon components as C2S, C3S, free-C3S, C3A and C4AF of cements
from the burnt wastes were relatively higher than those for standardized reference 2004. Finally, the noticed
high resistance for cement-mortar specimen in compression had therefore been attributed to higher values of
cements contents relative to their carbon components and free-CaO. These technical results were considered
sufficiently relevant, inspiring and encouraging to rather convincing the CCO authorities to put their first choice
on worn tires at expense of the other targeted agro-wastes, as it was possible to have quantitatively tires. Seeing
the amount of consumed fuel-oil by the clinker kiln, it could a priori assume that the available quantity of tires
in the long term was very low or insignificant to meet energy needs. In fact, worn tires from cars or other
moving equipments were non-biodegradable industrial wastes. No statistics on available worn-tires currently
existed on their end use limited in Benin. The assessment of effective annual quantity of damaged tires was not
really possible without knowledge of habits of the vehicle owners. However, it could be estimated to hundreds
of thousands of tons scattered mainly in the big cities of country where worn tires were cluttered including some
sidewalks and roundabouts where vulcanization handicrafts worker installed. Some of these damaged tires
often, but in very insignificant quantity, also served as ballasts to the local built canoes in lagoon areas. For a
developed country, such as France and Germany, the average rate of wear tire was about one (01) tire
per/car/year. Under the pressure of motor vehicles and reshaped tires markets, one could reasonably adopt, for
West African sub-regional countries, a status of order of 0.5 worn tires per car yearly. This estimation did not
preclude the use of additional import tires, if the make choice was for sustainable supply of the kiln. It would
then remain solutions to problems of tires collection, mainly from existing sprinkled locations to factory
destination.
V. BRIEF ECONOMIC ANALYSIS
In the Table 5 were gathered results from the realized experiments on clinker furnace using the cited wastes,
their regular attained substitution ratios, the produced energy and expensed financial costs, equivalent and
corresponding fuel-oil costs that allowed us deducing financial and fuel-oil equivalent quantity reductions.
Table 5- Recorded data from experimental combustion of different targeted alternate agro-industrial wastes in
rotating clinker furnace of Onigbolo Cement Complex
Targeted
alternate
wastes
types
Burned
wastes
quantities
(tons)
Obtained
substitutio
n ratio (%)
Produce
d energy
(kWh)
Expensed
agro-waste
costs (kF)
Equivalen
t fuel-oil
costs
(kF)
Financial
reduction
per ton of
waste (kF)
Fuel-oil
equivalent
quantity
(tons)
Worn-tires 18.65 5.2 173,557 1,879.90 2,540.71 34,43 4.002
Cotton-
fibers waste
13.56 4.8 36,398 440.80 532.75 6,78 0.557
Whole
cottonseeds
5.40 6.8 30,042 427.40 439.77 2,29 0.075
Oil-palm
bunches
8.17 4.6 28,496 258.96 417.15 18,51 0.916
Wood-
sawdust
12.20 9.5 57,782 337.75 845.86 41,682 3.078
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From those technical and economical recorded data, it ensued that the wood sawdust constituted the potentially
most important alternative agro-waste convenient for rotating clinker furnace of Onigbolo Cement Complex.
The production of thermal energy from 12.195 t of wood sawdust, at substitution rate of about 9.5%, allowed
generating a financial economy of 508.31 kF (CFA) corresponding to 3.08 t of equivalent fuel-oil in only 8.5
hours testing. The figure 4 disclosed the results of the comparative analysis made on basis of the reached
substitution rates for different experimented agro-wastes. It’s also shown the corresponding reduction values of
financial cost looking upon to the burned classical fuel-oil. Indeed, these reductions expressed the equivalent
fuel-oil quantities that have been economized on various wastes at these shown substitution ratio levels. A more
high value of substitution ratio of 11.97% had also been attained for the wood-sawdust, at flow-rate value of
1.86t/h and 3 hours 30 min experimental running. The limited stock of available wood sawdust in furnace site
did not allowed pursuing the flow-rate increase for this alternate agro-waste. It’s clear that, other waste kind
should be associated to wood-sawdust for obtaining higher substitution rate than the one actually reached:
cottonseeds or cottonseeds-hulls might be combined to wood-sawdust.
Figure 4- Financial costs reduction for each ton of the tested alternate agro/industrial wastes (kF/ton) and
corresponding reached substitution ratios (%).
The production of thermal energy from 18.654 t worn tires, at substitution ratio of minus 5.2%, permitted of
course an economy of 660.81 kF(CFA) corresponding to 4.002 tons of equivalent fuel-oil for 48.5 hours testing.
It’s also clear that, an appropriate pretreatment should be applied to the worn-tires, for combustion
improvement, like cutting them into particles of very small sizes against their actual use in the whole state.
V. WASTES COLLECTION
The supply of alternative wastes to clinker kiln should not be steady if an effective strategy for collection was
not established. This could be developed in two phases: the agro-industrial residues (cotton, wood, shells and
stalks) on the one hand, and worn tires, without forgetting the waste oil from draining engines and gearboxes,
on the other hand.
6.1. Selected agro-industrial wastes
The problem was relatively easy to solve in case of industrial agro-wastes for wood, cottonseeds and oil-palm
bunches. In principle, the signing of partnership agreements for the removal of wastes and residues between the
Cement Complex of Onigbolo and the waste generators might be sufficient. One indexed the wood sawmills of
Saclo, the cotton ginning and seeds crushing factories, without ignoring the oil-palm mills of Agonvy and Hinvi
added to the generated wood sawdust by small private sawmill units. The transport was then managed by the
CCO sales department. After delivery of cement, the latter should directed its trucks towards wastes/residues
pick-up points, on returning to the cement factory location.
Another type of usable residue as complementary was one consisting on shells from oil-palm kernels with a
LCV value 3,500 kcal/kg. These shells were generated by Agonvy and Hinvi oil-palm mills: 17.5
tons/week/plant. Part of this kind oil-palm waste, added to a mixture of dry cakes and fibers, was classically
used for autonomously feeding boilers of the mills [15]
. In addition, there was a third type of cotton residue, the
stems, non-targeted in this work. It was available in Benin as by-products [18, 19]
and its LCV-value of 4,108
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kcal/kg indicated that it was energy recoverable [9-11, 20, 23]
. However, the use of cotton stems in clinker kiln was
much more difficult compared to the selected two previous cotton wastes. These underlined difficulties for
stems were related to the rods shape, their collection (because widely dispersed) and especially their handling
which required pretreatment as cutting before being introducing in the kiln feeder. The average annual
production of cotton stalks, on the basis of unit weight of dry stem (23.8 g/stem) [18]
and the covered area over
the past decade (320,000 ha) [19]
, was estimated at 460,000 tons. Based on recorded statistics on the cotton
marketing from 1995 to 2011, the annual amount of stems essentially recoverable by energy way could be
estimated at 280,000 tons.
6.2. Worn tires collection
For deteriorated worn tires, the collection management was a far more difficult to solve. Here, the abundance of
tires was necessary but insufficient for warranting the sustainable supply of clinker furnace. Appropriate
awareness campaigns towards populations were then needed to get them joining organization for the collection
of this industrial type waste. Involvement of the governing class was pleasing at this level to ensure that the
existent worn tires have been effectively delivered to CCO factory for the kiln feeding. It was only after such an
accession that the responsibility for organizing the collection might be entrusted to an efficient private
company.
VI. CONCLUSION
Consumption’s reduction of petroleum products in cement industry, through the substitution of agricultural or
industrial residues, had been studied. The energetic analyzes results of residues, on the one hand, and testing in
the cement furnace, on the other hand, showed that the cement process was conducive to energy recovery from
wastes. The recorded data, on the lower heating values of studied residues, were all often low compared to that
of reference fuel-oil. It followed that the amounts of required waste to sustainably producing an equivalent
energy quantity to that of fuel-oil were relatively huge and also depended on the types of residues. These results
proved that none of the tested alternative combustibles could alone be sufficient to meet the needed energy for
the process. A significant substitution ratio was then possible by combining different kinds of residues with the
fuel-oil, especially since some residues were seasonal, cases for cotton-wastes and oil-palm bunches. However,
results of post-manufacture analyses, mainly by spectrometry X-fluorescence and compression test, for quality
certification of obtained various cements, showed that no significant change was detected in the composition of
the obtained clinkers compared to the normative value, on the one hand, and very good resistances in
compression testing, with respectively 22±0.64 MPa from worn tires and 25.79±0.11 MPa for sawdust, on the
other. Used worn-tires or wood-sawdust in addition induced a significant and beneficial effect on short-term
strength of the ensued cements. An improvement in this achieved good performance with worn-tires was
feasible and could be linked to a pre-cut into particles of convenient small sizes. Attained technical and
economical performances led to conclusion that wood-sawdust remained the best alternate agro-waste to burn in
the CCO rotating clinker furnace as substitute to fuel-oil prior to the tested other wastes. Experimentations,
using depleted oils, as well as the extracted ones from non-food crops, such as Jatropha oil, constituted a
perspective study. The cement manufacture, through effective use of the selected residues in clinker furnace,
could greatly contribute to pollutants reduction and subsequently help to improve environment cleaning.
ACKNOWLEDGEMENTS
The authors express their gratitude to the authorities of Cement-Complex-Onigbolo, for allowing and then
physically accompanied effective realization of these life-size experiments in their clinker-furnace and
recruitment of Mr. Houngbédji Martin at CCO, following this research work.
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