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4Methods to Control Corrosion
 Use of Corrosion resistant materials (plastic, stainless alloys, fiberglass).
 Use of the same or similar metals per the galvanic series.
 Altering the environment (utilizing homogeneous high resistivity backfill or
inhibitors).
 Utilize coatings and linings that electrically insulate the structure from the
electrolyte (paints, plastic films, etc)
Cathodic Protection (CP)
Cathodic protection (CP) is a technique to
control the corrosion of a metal surface by
making it work as a cathode of an
electrochemical cell.
or
Minimize corrosion by utilizing an external
source of electrical current which forces the
entire structure to become a cathode.
 Sir Humphrey Davy’s work on
protecting the copper sheathing on
wooden hulls in the British(London)
Navy by sacrificial zinc or iron anodes
in 1824.
 Firstly Considered impressed current
process.
In USA by 1945 CP was applied to oil &
natural gas industry.
Earliest practical use of cathodic protection
History
Quay structures and sheet pile curtains
Concrete bridges placed in seawater
Water or Fuel Pipelines buried in soil
Vessels/tanks buried in soil
Oil Platforms in steel and concrete
Subsea Pipelines
Hull
storage tanks
steel pier piles
offshore oil platforms
onshore oil well casings
Cathodic protection systems are most commonly used to protect
Applications of cathodic protection
Commonly Affected Structures
 Buried Piping
 Steel Piles
 Storage Tanks - Above Ground / Underground
 Reinforcing Steel in Concrete
 Ships/Boats
 Hulls
 Jetties
 Offshore and onshore platforms
Commonly Affected Structures
Why Need Cathodic Protection
LET’S SEE A VIDEO
Cathodic Protection Types
1. Use of sacrificial anodes (Galvanic Action)
2. Impressed currents
Sacrificial Anodes or Galvanic Action
sacrificial anodes (zinc, magnesium or aluminum)
• The sacrificial anodes are more active (more negative potential) than the
metal of the structure they’re designed to protect.
• The anode pushes the potential of the steel structure more negative and
therefore the driving force for corrosion halts.
• The anode continues to corrode until it requires replacement
Sacrificial or Galvanic System Deficiencies
 Anode ribbons are too far apart
 Anode ribbons do not deliver sufficient current
 Sand used as fill is conductive and corrosive
 Water enters sand causing it to become corrosive
 Galvanic anode ribbons are depleted
 Reference cells are inaccurate or inoperable Let’s see a video
Application Of Cathodic protection by Sacrificial anodes
Anodes Used for Sacrificial/Galvanic CP
 Magnesium – Magnesium is often used in soil to
protect small electrically isolated structures, such as
underground storage tanks, and well coated
pipelines.
 Zinc – Zinc is often used in marine environments.
They are commonly found on boats.
 Aluminum – Aluminum can be used for a variety of
marine applications.
Visualization of Sacrificial anode process
Advantages of Sacrificial anode process
 Inexpensive
 Little Maintenance cost
 No external Power source
 A variety of install methods can be used or simple to install
 Suitable for localized protection
 Independent of any source of electric power
Impressed Current CP
Pros of Impressed Current CP
 Unlimited driving potential.
 Capable of protecting large steel structures when designed
properly.
 Requires less anodes then a galvanic system.
 Output can be controlled using a permanent reference electrode,
desirable when the electrolyte resistivity is known to change.
Done for large structures (pipes, offshore platforms, etc) where a
galvanic (or sacrificial) anode can not economically deliver enough
current.
Impressed Current Deficiencies
 Rectifier inoperable or not properly adjusted
 Cables between rectifier and anode box are severed
 Anodes are spaced too far apart
 Anode ratings are too low
 Anodes are grounded to tank bottom
 Reference cells are inacurate or inoperable
 Positive and negative cables are connected with the wrong polarity
 Sand is too dry
Application of cathodic protection by an impressed current
Visualization of Sacrificial anode process
Pros & Cons of Impressed Current CP
 Initial costs can be more expensive.
 Requires an external DC power source along with an AC
supply.
 System requires routine maintenance and monitoring.
 Anode wires can be susceptible to damage.
 Comparatively few anodes are needed.
 The voltage may be adjusted to allow for environment and
coating change.
Pros & Cons of Impressed Current CP
 Initial costs can be more expensive.
 Requires an external DC power source along with an AC
supply.
 System requires routine maintenance and monitoring.
 Anode wires can be susceptible to damage.
 Comparatively few anodes are needed.
 The voltage may be adjusted to allow for environment and
coating change.
Choise of Cathodic Protection System
Which method is superior
Generally,
 sacrificial anode schemes have found favour for well-
coated low current demand structure,
 Impressed current being utilized for large complex
structure which may be poorly coated.
Morever,
 sacrificial anodes offer easily installed but Impressed
current is complex process.
So, sacrificial anode is Superior
Effect of cathodic protection by akmol-48
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Effect of cathodic protection by akmol-48

  • 1.
  • 2.
  • 3.
  • 4. 4Methods to Control Corrosion  Use of Corrosion resistant materials (plastic, stainless alloys, fiberglass).  Use of the same or similar metals per the galvanic series.  Altering the environment (utilizing homogeneous high resistivity backfill or inhibitors).  Utilize coatings and linings that electrically insulate the structure from the electrolyte (paints, plastic films, etc)
  • 5. Cathodic Protection (CP) Cathodic protection (CP) is a technique to control the corrosion of a metal surface by making it work as a cathode of an electrochemical cell. or Minimize corrosion by utilizing an external source of electrical current which forces the entire structure to become a cathode.
  • 6.  Sir Humphrey Davy’s work on protecting the copper sheathing on wooden hulls in the British(London) Navy by sacrificial zinc or iron anodes in 1824.  Firstly Considered impressed current process. In USA by 1945 CP was applied to oil & natural gas industry. Earliest practical use of cathodic protection History
  • 7. Quay structures and sheet pile curtains Concrete bridges placed in seawater Water or Fuel Pipelines buried in soil Vessels/tanks buried in soil Oil Platforms in steel and concrete Subsea Pipelines Hull storage tanks steel pier piles offshore oil platforms onshore oil well casings Cathodic protection systems are most commonly used to protect Applications of cathodic protection
  • 8. Commonly Affected Structures  Buried Piping  Steel Piles  Storage Tanks - Above Ground / Underground  Reinforcing Steel in Concrete  Ships/Boats  Hulls  Jetties  Offshore and onshore platforms
  • 10. Why Need Cathodic Protection LET’S SEE A VIDEO
  • 11. Cathodic Protection Types 1. Use of sacrificial anodes (Galvanic Action) 2. Impressed currents
  • 12. Sacrificial Anodes or Galvanic Action sacrificial anodes (zinc, magnesium or aluminum) • The sacrificial anodes are more active (more negative potential) than the metal of the structure they’re designed to protect. • The anode pushes the potential of the steel structure more negative and therefore the driving force for corrosion halts. • The anode continues to corrode until it requires replacement
  • 13. Sacrificial or Galvanic System Deficiencies  Anode ribbons are too far apart  Anode ribbons do not deliver sufficient current  Sand used as fill is conductive and corrosive  Water enters sand causing it to become corrosive  Galvanic anode ribbons are depleted  Reference cells are inaccurate or inoperable Let’s see a video
  • 14. Application Of Cathodic protection by Sacrificial anodes
  • 15. Anodes Used for Sacrificial/Galvanic CP  Magnesium – Magnesium is often used in soil to protect small electrically isolated structures, such as underground storage tanks, and well coated pipelines.  Zinc – Zinc is often used in marine environments. They are commonly found on boats.  Aluminum – Aluminum can be used for a variety of marine applications.
  • 17. Advantages of Sacrificial anode process  Inexpensive  Little Maintenance cost  No external Power source  A variety of install methods can be used or simple to install  Suitable for localized protection  Independent of any source of electric power
  • 18. Impressed Current CP Pros of Impressed Current CP  Unlimited driving potential.  Capable of protecting large steel structures when designed properly.  Requires less anodes then a galvanic system.  Output can be controlled using a permanent reference electrode, desirable when the electrolyte resistivity is known to change. Done for large structures (pipes, offshore platforms, etc) where a galvanic (or sacrificial) anode can not economically deliver enough current.
  • 19. Impressed Current Deficiencies  Rectifier inoperable or not properly adjusted  Cables between rectifier and anode box are severed  Anodes are spaced too far apart  Anode ratings are too low  Anodes are grounded to tank bottom  Reference cells are inacurate or inoperable  Positive and negative cables are connected with the wrong polarity  Sand is too dry
  • 20. Application of cathodic protection by an impressed current
  • 22. Pros & Cons of Impressed Current CP  Initial costs can be more expensive.  Requires an external DC power source along with an AC supply.  System requires routine maintenance and monitoring.  Anode wires can be susceptible to damage.  Comparatively few anodes are needed.  The voltage may be adjusted to allow for environment and coating change.
  • 23. Pros & Cons of Impressed Current CP  Initial costs can be more expensive.  Requires an external DC power source along with an AC supply.  System requires routine maintenance and monitoring.  Anode wires can be susceptible to damage.  Comparatively few anodes are needed.  The voltage may be adjusted to allow for environment and coating change.
  • 24. Choise of Cathodic Protection System Which method is superior Generally,  sacrificial anode schemes have found favour for well- coated low current demand structure,  Impressed current being utilized for large complex structure which may be poorly coated. Morever,  sacrificial anodes offer easily installed but Impressed current is complex process. So, sacrificial anode is Superior