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Drinking Water Quality AssessmentDrinking Water Quality Assessment
in the Communities Affected by Leadin the Communities Affected by Lead
Poisoning in Zamfara State, NigeriaPoisoning in Zamfara State, Nigeria
Dogara Bashir
National Water Resources Institute,
Kaduna
Paper presented at the Stakeholders’ Sensitization Forum
on Sustainable Mining in Zamfara State held at J.B.
Yakubu Conference Centre, Gusau, Nigeria on 12th
August,
2010
o Outbreak of acute lead
poisoning in Zamfara State
o Joint CDC and WHO
investigation reported
illness and deaths among
children mostly under 5
years old in some
communities in Bukkuyum
and Anka LGAs
o Based on consultations
with UNICEF and Zamfara
State Ministry of Water
Resources, NWRI
mobilsed a technical team
to carry out an
assessment survey of
drinking water quality in
the affected communities
Introduction
2
Introduction
o The study included:
o Drinking Water Quality Assessment (on-site
and laboratory analyses);
o Participatory Rapid Appraisal (sanitary
inspection, health issues, socio-economic
impacts); and
o Geo-chemical assessment of the mined rocks
being processed in the communities
o Based on consultation with Zamfara State
MWR and RWSSA and available logistics, 4
affected villages were assessed:
o ‘Yargalma and Tungan Guru (Bukkuyum LGA)
o Dareta, and Abare (Anka LGA)
3
o Socio-economic assessment included:
o Demography (estimated population, number of
compounds, range of households per
compound, range of population per
household);
o Available infrastructure (schools, clinics,
roads, water supply sources, etc.);
o Gold processing activities (sources of the
mined rocks, processing procedures, costs of
the various processes, income from the
processing activities, etc.); and
o Number of children that died from this crisis
and when the current crisis began.
Methodology
4
o Water Quality
Assessment:
o 18 water sources were
sampled;
o 2 boreholes in Abare
o 2 streams (1 each in
‘yargalma and Abare)
o 2 concrete wells (1 each in
Dareta and Abare)
o 11 unprotected dug-wells (4
in ‘yargalma, 2 in Tungar
Guru, 3 in Dareta and 2 in
Abare)
o 1 in Rumbuki, an unaffected
village in between ‘Yargalma
and Tungar Guru
Methodology
5
o Water Quality Assessment:
o 22 parameters were measured
o 9 on the sites
o 7 in Gusau (within 24 hrs of sampling)
o 6 in NWRI Lab, Kaduna (samples preserved by
acidification on site)
o Methodologies for measurements and
analyses;
o Various instruments by different manufacturers
were used in the course of measurement of
parameters and analyses of the samples
o The analytical methods adopted were based on
international acceptable methods and analytical
application principles
Methodology
6
o Sanitary inspection
and hygiene practices
assessment
o Sanitary risk level for
each selected water
well was determined
from the answers to
the standard sanitary
risk inspection
questions
o Focus interviews were
carried out on the
hygiene practices of
the community
members especially
women and children
Methodology
7
Methodology
o Geochemical Assessment
and Inspection of Mines
o geology and hydrogeology of
the area were rapidly
appraised
o Samples of the rock
materials (from different
mines) processed were
collected
o Lambargudu mine was
visited and assessed
o Rock samples were
subjected to the following:
o Thin section – to determine the
major mineralogical
constituents of the rocks
o Geochemical analyses – to
determine the major elements 8
Findings
o Demography
o Based on average of 4 HH/compound and
average of 8 persons/HH, estimated populations
were:
o ‘Yargalma = 1,760; Tungar guru = 928
o Dareta = 3,040; Abare = 4,032
9
Available Infrastructural Facilities
S/N Community Road
Primary
Schools
Qur'anic
Schools
Islamiyya
Schools
Dispen-
sary
Bore-
holes
Concrete
Wells
1 Yargalma L & S 1+
3 - 1 1* -
2 Tungan Guru - - 2 - - - -
3 Dareta L & S 1 4 - 1 - 1
4 Abare L 1 3 - - 3 5
Note: L & S = laterite and seasonal; L = laterite
+ = Primary School is a community effort and is made-up of used zinc roofing sheets with virtually no furniture
* = Bore was drilled by Zamfara State RWSSA with UNICEF support but was not activated
10
Processing of Mined Rocks
11
Cost/Benefit of Mined Rocks Processing
12
Geology and Hydrogeology
o The areas lie within the basement
rocks of the Anka schist belts
o quartzites, schist and phyllites as
the dominate rocks of the areas
o Occurrence of gold in placers and
primary veins of quartzites, phyllite
and schists are quite common at
Kwali and Gwashi (Bukkuyyum LGA)
and Sunke and Lambargudu (Anka
LGA)
o Lambargudu mine is
primarily a mixed quartzite,
phyllites and schists mixed
with dark shinning galena
crystals and reddish brown
sulphide and iron
o The aquifers are mainly the weathered
regoliths and the fractures in the
transmission zone
o They are quite productive and highly
sustainable for domestic water supply fitted
with hand pumps and moderate submersible
pumps capacity 13
Drinking Water Quality
Aesthetic
Parameters
S/N Parameter Range
NSDWQ
MAL
%
Compliance
1 Appearance Clear - Dirty Clear 50
2 Turbidity (NTU) 2.11 - 753.00 5.00 22
3 EC (µS/cm) 40.3 - 1135.0 1000 89
4 TDS (mg/l) 20.3 - 568.0 500 89
Chemical Non-toxic
ParametersS/N Parameter (mg/l) Range NSDWQ MAL % Compliance
1 pH 5.8 - 7.5 6.5 - 8.5 39
2 Iron (Fe) 0.01 -5.6 0.30 78
3 Fluoride (F) 0.22 - 1.39 1.50 100
4 Manganese (Mn) 0.0 - 6.9 0.2 72
5 Calcium (Ca) 4.01 - 25.73 75.00 100
6 Magnesium (Mg) 0.71 - 4.35 20.00 100
7 Nitrate (NO3) 0.11 - 52.80 50.00 94
8 Bicarbonate (HCO3) 26 - 406 250 83
9 Sulphate (SO4) 0 - 140 100 94
14
Drinking Water Quality
Bacteriological
Parameters
Chemical (Toxic)
Parameters
S/N Parameter (mg/l) Range
NSDWQ
MAL
%
Compliance
1 Lead (Pb) 0.004 - 0.062 0.010 83
2 Cromium (Cr) 0.00 - 0.05 0.05 100
3 Arsenic (As) 0.00 - 0.00 0.01 100
S/N Parameter (cfu/100 ml) Range
NSDWQ
MAL
%
Compliance
1 Total Coliforms (TC) 0 - TNTC <10 19
2
Thermotolerant
Coliforms (TTC) 0 - 560 0 83
o Most wells have high lead content
o May be as a result of gold processing activities
within compounds
o Low lead conc. in well at Rumbuki village
o This increases lead intake apart from the
processing dust
15
Sanitary Risk Levels
o 9 (56%) out of the 16 sampled
points had a medium risk
o seven (44%) of the points had high
risk levels
o 0 (0%) fell within the low risk
score
o Sanitary risk inspection also
shows pollution of the environment
around the water points by:
o animals,
o faulty or lack of drainage,
o poor well construction,
o absent of cover,
o poor sanitation practices, and
o defective hygiene practices.
16
Observations
1. The water sample analyses indicated presence of lead in
the water samples collected from the handdug wells,
boreholes and the stream where the mining materials are
being washed in the affected communities.
2. The primary raw materials for the gold mining collected
from the mining sites indicate the occurrence of chromium,
lead, silver and other trace metals associated with the gold
mineralization.
3. Community members involved in the mining activities
undertake the processing of the mining materials within
and outside their households.
4. It was noted that both Adults and children are involved in
the mining processing of the gold.
5. The processing of the mining materials includes the
crushing, grinding and washing with the resultant high dust
of the materials being processed. However, most of the
washing activity takes place in the close by stream during
the rainy season and the hand dug wells are used during
the dry season when the stream are completely dry.
17
Recommendations
1. In order to discourage the further use of the contaminated
wells in the affected communities, Government should
provide as a matter of urgency, appropriate number of
boreholes (3 in ‘Yargalma, 2 in Tungar Guru, 4 in Dareta,
and 2 in Abare) without delay.
2. All the wells in the communities should be redeveloped and
flushed to eliminate further contamination of groundwater
in the areas.
3. There is the need for community sensitization and
mobilization on hygiene and sanitation practices.
4. Establishment of WASHCOM should be highly encouraged
among the community members.
5. There is the urgent need for quarterly assessment,
monitoring and evaluation of activities in these
communities.
6. A special conference should be organized for all
stakeholders to strategize and come out with resolutions
that will assist in addressing the identified challenges and
to avoid reoccurrence of such incidences in the future. 18
19

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Drinking water quality assessment in lead affected communities in zamfara state, Nigeria

  • 1. Drinking Water Quality AssessmentDrinking Water Quality Assessment in the Communities Affected by Leadin the Communities Affected by Lead Poisoning in Zamfara State, NigeriaPoisoning in Zamfara State, Nigeria Dogara Bashir National Water Resources Institute, Kaduna Paper presented at the Stakeholders’ Sensitization Forum on Sustainable Mining in Zamfara State held at J.B. Yakubu Conference Centre, Gusau, Nigeria on 12th August, 2010
  • 2. o Outbreak of acute lead poisoning in Zamfara State o Joint CDC and WHO investigation reported illness and deaths among children mostly under 5 years old in some communities in Bukkuyum and Anka LGAs o Based on consultations with UNICEF and Zamfara State Ministry of Water Resources, NWRI mobilsed a technical team to carry out an assessment survey of drinking water quality in the affected communities Introduction 2
  • 3. Introduction o The study included: o Drinking Water Quality Assessment (on-site and laboratory analyses); o Participatory Rapid Appraisal (sanitary inspection, health issues, socio-economic impacts); and o Geo-chemical assessment of the mined rocks being processed in the communities o Based on consultation with Zamfara State MWR and RWSSA and available logistics, 4 affected villages were assessed: o ‘Yargalma and Tungan Guru (Bukkuyum LGA) o Dareta, and Abare (Anka LGA) 3
  • 4. o Socio-economic assessment included: o Demography (estimated population, number of compounds, range of households per compound, range of population per household); o Available infrastructure (schools, clinics, roads, water supply sources, etc.); o Gold processing activities (sources of the mined rocks, processing procedures, costs of the various processes, income from the processing activities, etc.); and o Number of children that died from this crisis and when the current crisis began. Methodology 4
  • 5. o Water Quality Assessment: o 18 water sources were sampled; o 2 boreholes in Abare o 2 streams (1 each in ‘yargalma and Abare) o 2 concrete wells (1 each in Dareta and Abare) o 11 unprotected dug-wells (4 in ‘yargalma, 2 in Tungar Guru, 3 in Dareta and 2 in Abare) o 1 in Rumbuki, an unaffected village in between ‘Yargalma and Tungar Guru Methodology 5
  • 6. o Water Quality Assessment: o 22 parameters were measured o 9 on the sites o 7 in Gusau (within 24 hrs of sampling) o 6 in NWRI Lab, Kaduna (samples preserved by acidification on site) o Methodologies for measurements and analyses; o Various instruments by different manufacturers were used in the course of measurement of parameters and analyses of the samples o The analytical methods adopted were based on international acceptable methods and analytical application principles Methodology 6
  • 7. o Sanitary inspection and hygiene practices assessment o Sanitary risk level for each selected water well was determined from the answers to the standard sanitary risk inspection questions o Focus interviews were carried out on the hygiene practices of the community members especially women and children Methodology 7
  • 8. Methodology o Geochemical Assessment and Inspection of Mines o geology and hydrogeology of the area were rapidly appraised o Samples of the rock materials (from different mines) processed were collected o Lambargudu mine was visited and assessed o Rock samples were subjected to the following: o Thin section – to determine the major mineralogical constituents of the rocks o Geochemical analyses – to determine the major elements 8
  • 9. Findings o Demography o Based on average of 4 HH/compound and average of 8 persons/HH, estimated populations were: o ‘Yargalma = 1,760; Tungar guru = 928 o Dareta = 3,040; Abare = 4,032 9
  • 10. Available Infrastructural Facilities S/N Community Road Primary Schools Qur'anic Schools Islamiyya Schools Dispen- sary Bore- holes Concrete Wells 1 Yargalma L & S 1+ 3 - 1 1* - 2 Tungan Guru - - 2 - - - - 3 Dareta L & S 1 4 - 1 - 1 4 Abare L 1 3 - - 3 5 Note: L & S = laterite and seasonal; L = laterite + = Primary School is a community effort and is made-up of used zinc roofing sheets with virtually no furniture * = Bore was drilled by Zamfara State RWSSA with UNICEF support but was not activated 10
  • 12. Cost/Benefit of Mined Rocks Processing 12
  • 13. Geology and Hydrogeology o The areas lie within the basement rocks of the Anka schist belts o quartzites, schist and phyllites as the dominate rocks of the areas o Occurrence of gold in placers and primary veins of quartzites, phyllite and schists are quite common at Kwali and Gwashi (Bukkuyyum LGA) and Sunke and Lambargudu (Anka LGA) o Lambargudu mine is primarily a mixed quartzite, phyllites and schists mixed with dark shinning galena crystals and reddish brown sulphide and iron o The aquifers are mainly the weathered regoliths and the fractures in the transmission zone o They are quite productive and highly sustainable for domestic water supply fitted with hand pumps and moderate submersible pumps capacity 13
  • 14. Drinking Water Quality Aesthetic Parameters S/N Parameter Range NSDWQ MAL % Compliance 1 Appearance Clear - Dirty Clear 50 2 Turbidity (NTU) 2.11 - 753.00 5.00 22 3 EC (µS/cm) 40.3 - 1135.0 1000 89 4 TDS (mg/l) 20.3 - 568.0 500 89 Chemical Non-toxic ParametersS/N Parameter (mg/l) Range NSDWQ MAL % Compliance 1 pH 5.8 - 7.5 6.5 - 8.5 39 2 Iron (Fe) 0.01 -5.6 0.30 78 3 Fluoride (F) 0.22 - 1.39 1.50 100 4 Manganese (Mn) 0.0 - 6.9 0.2 72 5 Calcium (Ca) 4.01 - 25.73 75.00 100 6 Magnesium (Mg) 0.71 - 4.35 20.00 100 7 Nitrate (NO3) 0.11 - 52.80 50.00 94 8 Bicarbonate (HCO3) 26 - 406 250 83 9 Sulphate (SO4) 0 - 140 100 94 14
  • 15. Drinking Water Quality Bacteriological Parameters Chemical (Toxic) Parameters S/N Parameter (mg/l) Range NSDWQ MAL % Compliance 1 Lead (Pb) 0.004 - 0.062 0.010 83 2 Cromium (Cr) 0.00 - 0.05 0.05 100 3 Arsenic (As) 0.00 - 0.00 0.01 100 S/N Parameter (cfu/100 ml) Range NSDWQ MAL % Compliance 1 Total Coliforms (TC) 0 - TNTC <10 19 2 Thermotolerant Coliforms (TTC) 0 - 560 0 83 o Most wells have high lead content o May be as a result of gold processing activities within compounds o Low lead conc. in well at Rumbuki village o This increases lead intake apart from the processing dust 15
  • 16. Sanitary Risk Levels o 9 (56%) out of the 16 sampled points had a medium risk o seven (44%) of the points had high risk levels o 0 (0%) fell within the low risk score o Sanitary risk inspection also shows pollution of the environment around the water points by: o animals, o faulty or lack of drainage, o poor well construction, o absent of cover, o poor sanitation practices, and o defective hygiene practices. 16
  • 17. Observations 1. The water sample analyses indicated presence of lead in the water samples collected from the handdug wells, boreholes and the stream where the mining materials are being washed in the affected communities. 2. The primary raw materials for the gold mining collected from the mining sites indicate the occurrence of chromium, lead, silver and other trace metals associated with the gold mineralization. 3. Community members involved in the mining activities undertake the processing of the mining materials within and outside their households. 4. It was noted that both Adults and children are involved in the mining processing of the gold. 5. The processing of the mining materials includes the crushing, grinding and washing with the resultant high dust of the materials being processed. However, most of the washing activity takes place in the close by stream during the rainy season and the hand dug wells are used during the dry season when the stream are completely dry. 17
  • 18. Recommendations 1. In order to discourage the further use of the contaminated wells in the affected communities, Government should provide as a matter of urgency, appropriate number of boreholes (3 in ‘Yargalma, 2 in Tungar Guru, 4 in Dareta, and 2 in Abare) without delay. 2. All the wells in the communities should be redeveloped and flushed to eliminate further contamination of groundwater in the areas. 3. There is the need for community sensitization and mobilization on hygiene and sanitation practices. 4. Establishment of WASHCOM should be highly encouraged among the community members. 5. There is the urgent need for quarterly assessment, monitoring and evaluation of activities in these communities. 6. A special conference should be organized for all stakeholders to strategize and come out with resolutions that will assist in addressing the identified challenges and to avoid reoccurrence of such incidences in the future. 18
  • 19. 19