Dental
waxes
Presented by
Dr jitendra khetan
Contents
• Introduction
• Components of dental waxes
• Properties of waxes
• Classification of waxes
-According to origion
-According to use and application
• Conclusion
• References
Introduction
• Waxes were first used in dentistry in early
eighteenth century………..edentulous
impressions.
• Waxes are still employed in large
quantities in various clinical and lab
procedure………patterns for cast
restoration, bite registration.
• Dr William.H.Taggart of Chicago
formulated a wax pattern compound of
excellent properties.
• He also described an investment
technique ,developed an investment
material and even invented an air pressure
casting machine.
Waxes are organic polymers consisting of
hydrocarbons and their derivative (eg
ester and alcohol).
ACCORDING TO GPT Casting waxes can
be defined as a composition containing
various waxes with desired properties for
making wax patterns to be formulated into
metal casting.
Dental waxes
• Waxes have several applications in
dentistry.
Components of dental waxes
Natural
waxes
Synthetic
waxes
Additives
•Mineral
•Plant
•Insect
•Animal
•Acrawax C
•Aerosol OT
•Castorwax
•Aldo 33
•Stearic acid
•Oils
•Colorants
•Resins
Natural waxes
 Complex combination of organic
compounds of high molecular weights.
 It’s the primary components of dental wax.
 The dental manufacturers must blend the
particular batches of waxes to obtain the
properties desired for a particular
application.
Natural waxes
• Mineral waxes
• Parrafin
• Microcrystalline
• Barnsdahl
• Ozokerite
• Ceresin
• Montan
Synthetic waxes
• High degree of refinement,no
contamination.
 Polyethylene waxes
 Polyoxyethylene glycol waxes
 Halogenated hydrocarbon waxes
 Hydrogenated waxes
 Waxes ester (fatty alcohol + acid)
Fats
• Increase the melting range and the
hardness of compound waxes.
• Hydrocarbon oils - soften mixture of
waxes.
• Silicone oils - improve the ease of
polishing with waxes.
Resins
• Most natural resins are obtained from
trees and plants.
• Insoluble in water
• improve toughness, hardness,
melting range of waxes
Properties
of
waxes
Melting range
• Waxes consist of similar type of
molecules of different molecular
weight.
• They may contain several types of
molecules
• They have melting range rather than
melting point.
Thermal expansion
• Expand when temperature is risen
• Contract when temperature is decreased
• Dental waxes have the largest
coefficient of thermal expansion.
• Temp. change in wax patterns may be
a major contributing factor in inaccuracy
of the finished restoration.
Mechanical properties
• The elastic modulus, proportional limit
and compressive strength of waxes
are low compare with those of other
materials and these properties depend
strongly on the temperature.
Flow
• Flow is decidedly dependent on the
temperature of the waxes.
• Flow is greatly increase as the melting
point of the wax is approached.
Residual
stress
Ductility
• Ductility increase as the temp of a wax
is increase.
• Waxes with lower melting temp. have
a greater ductility.
• The ductility of a blended waxes
wide melting range > narrow melting
range
• The highly refined waxes is quite brittle
CLASSIFICATION OF WAXES
1)According to origin
2)According to use and application
ACCORDING TO ORIGIN
Natural Synthetic
Mineral
Paraffin, microcrystalline, ceresin Polyethylene waxes
Montan, Polyoxyethylene glycol
waxes
Plant
Carnauba, candelilla
Insect
Beeswax
Animal
Spermaceti wax
• Pattern waxes
• Processing waxes
• Impression waxes
According to use and application
Pattern wax
• Used to form the general
predetermined size and contour of
artificial dental restoration , which is
to be constructed of a more durable
material.
Pattern waxes
1.Inlay waxes
3.Baseplate waxes
2.Casting waxes
Processing wax
• Used primarily as auxillary aids in
the construction a variety of
restorations and appliances either
clinically or in the laboratory
Processing waxes
1.Boxing waxes
2.Utility waxes
3.Sticky waxes
4.Carding waxes
5.Blockout wax
6.White wax
Impression waxes
• Used for taking impression within
the mouth.
–Bite registration waxes
–Corrective waxes
Korecta wax
Alu wax
Inlay pattern wax
• A pattern of the wax is first constructed
that duplicates the shape and contour of
the desired casting .
Inlay pattern wax
• The pattern then is embedded in a
gypsum-silica investment material to
form a mold with an ingate or sprue
leading from the outer surface of the
investment mold to the pattern.
Inlay pattern wax
• The wax is subsequently eliminated by
heating & softening and the mold is
further conditioned to receive the
molten metal.
Inlay pattern wax
Inlay wax : Composition
Paraffin (major
portion)
Microcrystalline
wax
Ceresin
Carnauba
Candelilla
Beeswax
Inlay waxes generally are
produced in deep blue, green, or
purple rods or sticks.
The flow can be reduced by adding
more carnauba wax or by selecting
higher melting paraffin waxes.
Inlay waxes : Properties
ANSI/ADA Specification No. 4 for
dental inlay casting wax.
Type I wax = a hard wax that is
prescribed for forming direct patterns in
the mouth.
Type II wax = a softer wax that is used
as an indirect technique wax.
Thermal
expansion
Flow
The working temperature for making
direct wax pattern must not to be so high
as to cause damage to the vital tooth
structure.
At mouth temp., direct inlay wax must
have essentially no flow to minimize the
possibility of distortion of the pattern
during removal from the tooth cavity.
Casting wax
The pattern for the metallic framework of
removable partial denture and other
similar structures is fabricated from the
casting waxes.
Casting wax : Composition
The ingredients are similar to
those found in inlay waxes.
Casting wax : Properties
Federal specification No U-W -140 for
casting wax
Flow : 35
o
C - maximum, 10 %
38
o
C - minimum, 60 %
Breaking point : no fracture at 23
o
+1
o
Pliable and readily adaptable at
40o
to 45o
C
Copy accurately surface against
which it pressed
Shall not be brittle on cooling
Vaporize at 500o
C, leaving no
film other than carbon
Working properties
Baseplate wax
Baseplate wax derives its name
from its use on the baseplate tray
in the technique for complete
denture restoration.
It’s normally pink color.
serves as the material to produce the
desired contour of the denture after the
teeth are set in position
Baseplate wax
Baseplate wax : Composition
70-80 % paraffin or ceresin
small quantities of other waxes &
additives.
typical composition
– 80% ceresin - 12% beeswax
– 2.5% carnuaba
– 3% natural or synthetic resins
– 2.5% microcrystalline or synthetic wax
Baseplate wax : Properties
ANSI/ADA Specification No.24
– Type I - Soft, building contours and
veneers
– Type II - Medium, patterns in mouth,
temperate
– Type III - Hard, patterns in mouth,
hot weather
Linear thermal expansion from 25
o
-40
o
C <
0.8%
Softened sheets shall cohere readily
without becoming flaky or adhering to
fingers
No irritation of oral tissue
trim easily with a sharp instrument at 23
o
C
Practical requirements
Smooth surface after gentle flaming
No residue on porcelain or plastic teeth
Coloring shall not separate or
impregnate plaster during processing
No adhesion to other sheets of wax or
separating paper on storage
Practical requirements
Boxing wax
Use to form a plaster or stone cast from
an impression of the edentulous arch
Boxing wax: Working properties
Federal specification No U-W -138
Smooth, glossy surface on flaming
Pliable at 21
o
C, retain shape at 35
o
C
Seals easily to plaster with hot spatula
Utility wax
Used in numerous instance
most likely consists of beeswax,
petrolatum and other soft waxes
Utility wax: Working properties
Federal Specification No U-W- 156
Pliable at 21
o
to 24
o
C
Tacky at 21
o
to 24
o
C, sufficient adhesion
to build up
Sticky wax
It is sticky when melt and adheres closely
to the surface on which it is applied.
It is firm, free from tackiness and brittle
at room temp.
Rosin & yellow beeswax are the usual
major constituents.
Sticky wax : Working properties
Federal Specification No.U-W-00149a
Sticky when melt
Adhere closely
Not more than 0.2% residue on burnout
Not more than 0.5% shrinkage from
43
o
to 28 C
o
Blockout wax:- is used to fill voids and
undercuts for R.P.D
white wax :- for making patterns to
stimulate a veneer facing.
Corrective impression wax
Used as a wax veneer over an original
impression to contact and register the
detail of the soft tissue .
Formulated from hydrocarbon waxes
such as paraffin,ceresin & beeswax and
may contain metal particles
The flow at 37
o
C is 100 %
Corrective impression wax
Bite registration wax
Used to accurately articulate
certain models of opposing
quadrant
Formulated from beeswax or
hydrocarbon waxes such as
paraffin or ceresin and contain
alumina or copper particle
Bite registration wax
• Alu wax
Bite registration wax
• Occlusal indicator wax
Paraffin wax(mineral wax)
• Generally the main ingredient of inlay
waxes.
• Obtained from high boiling fractions of
petrolem(methane series)
• Mixture of hydrocarbons
• Melting range 40-71o C. increases with
increasing molecular wt.
• Paraffin waxes have less than 0.5% oil.
• Presence of oil lowers melting temp.
• During solidification and cooling a
volumetric contraction in the range 11%-
15%.
• This is not uniform ,since it is a mixture of
hydrocarbons.
• Likely to flake when trimmed.
• Does not present smooth, glossy surface
• Consequently other waxes and natural
resins are added.
Carnauba wax (plant wax)
• Derived from tropical palms
• It is quite hard, melting range 84-910C
• Combined with paraffin to-
- Decrease flow at mouth temp
- increase the hardness
• It contributes to glossiness of the wax surface,
even more than dammar resin.
(Addition of 10 % carnauba wax to paraffin wax
with a melting range of 200C will increase the
melting range to 460C.)
Ceresin wax (mineral wax)
• May replace part of paraffin to modify toughness
and carving characteristic.
• Like microcrystalline waxes they are branched
chain and straight chain paraffin.
• They have higher mol wt and greater hardness
than hydrocarbon waxes
• These waxes also may be used to increase the
melting range of paraffin waxes.
Beeswax (insect wax)
• Complex mixture of esters, consisting mainly of
myricyl palmitate, plus saturated and
unsaturated hydrocarbons and high molecular
wt organic acids.
• Melting range 63-700C
• Brittle at room temp, becomes plastic at body
temperature.
• Used to modify the properties of paraffin wax
(also the main component of sticky wax)
Natural resin (gum dammer)
• Added to paraffin to improve its
smoothness in molding
• It renders it more resistant to cracking and
flaking
• Increases the toughness of the wax and
enhances the smoothness and lusture of
the wax.
Microcrystalline waxes(mineral)
• Similar to paraffin waxes, but obtained
from heavier oil fractions.
• It has a higher melting range 60-910C
• It is tougher and more flexible than paraffin
• It has less volumetric shrinkage during
solidification than paraffin.
Candelilla wax (plant wax)
• Same qualities as carnauba wax
• Added to paraffin to partially or entirely
replace carnauba wax.
• Its melting point is lower, and it is not as
hard as carnauba wax.
Other polymers in dentistry
 Gutta-percha
 Filling material
:composite resin
 Dental cement
Gutta-percha
 A polyisoprene with the same empirical
formular as rubber (20-30%)
 various natural resin
(soften the gutta-percha)
 filler : ZnO,waxes
Composition
Gutta-percha
• Used to fill in the root canal
• Soften at 60-70
o
C
• Viscoelastic material which is extremely
sensitive to the rate of straining.
• The best adaptation to the root canal is
achieve when maximum pressure is
applied over an extended period of time.
Gutta-percha
CONCLUSION
• Waxes have been popular and useful dental material.
• Easily manipulated
• Low in cost and serve variety of purposes
• Nevertheless use of dental waxes is associated with
control of certain characteristics that affect their
applicability, such as
-Effect of heating on flow
-Thermal expansion
-Distortion
• Way back in 1939 Hollenback et al published the results
of their extensive work on properties of waxes.
They concluded that waxes are
sufficiently stable material if handled properly.
• REFERENCES
 -Kenneth j. Anusavice ; Phillips Science of dental
material .Eleventh edition, Elsevier,2004.
 -Jack L. Ferracane ; Materials in Dentistry principles and
application. Second edition ,Lippincot williams, 1995.
 -William J. O’Brien; Dental materials and their selection.
Third edition, quintessence Publishing co. 2002.
 -Robert C. Craig John M. Powers, John C.Wataha
;Dental materials properties and manipulation,. Eight
edition,2004.
 -Marcia gladwin; clinical aspects of dental materials
Lippincott Williams 2000
 -E.C.Combe; Notes on dental materials, sixth edition
Churchill livingstone 1992
 -Revised ADA specification No 4 for dental casting
wax,JADA Vol 90 Feb 1975
Thank you

dental waxes.ppt

  • 1.
  • 2.
    Contents • Introduction • Componentsof dental waxes • Properties of waxes • Classification of waxes -According to origion -According to use and application • Conclusion • References
  • 3.
    Introduction • Waxes werefirst used in dentistry in early eighteenth century………..edentulous impressions. • Waxes are still employed in large quantities in various clinical and lab procedure………patterns for cast restoration, bite registration.
  • 4.
    • Dr William.H.Taggartof Chicago formulated a wax pattern compound of excellent properties. • He also described an investment technique ,developed an investment material and even invented an air pressure casting machine.
  • 5.
    Waxes are organicpolymers consisting of hydrocarbons and their derivative (eg ester and alcohol). ACCORDING TO GPT Casting waxes can be defined as a composition containing various waxes with desired properties for making wax patterns to be formulated into metal casting.
  • 6.
    Dental waxes • Waxeshave several applications in dentistry.
  • 8.
    Components of dentalwaxes Natural waxes Synthetic waxes Additives •Mineral •Plant •Insect •Animal •Acrawax C •Aerosol OT •Castorwax •Aldo 33 •Stearic acid •Oils •Colorants •Resins
  • 9.
    Natural waxes  Complexcombination of organic compounds of high molecular weights.  It’s the primary components of dental wax.  The dental manufacturers must blend the particular batches of waxes to obtain the properties desired for a particular application.
  • 10.
    Natural waxes • Mineralwaxes • Parrafin • Microcrystalline • Barnsdahl • Ozokerite • Ceresin • Montan
  • 11.
    Synthetic waxes • Highdegree of refinement,no contamination.  Polyethylene waxes  Polyoxyethylene glycol waxes  Halogenated hydrocarbon waxes  Hydrogenated waxes  Waxes ester (fatty alcohol + acid)
  • 12.
    Fats • Increase themelting range and the hardness of compound waxes. • Hydrocarbon oils - soften mixture of waxes. • Silicone oils - improve the ease of polishing with waxes.
  • 13.
    Resins • Most naturalresins are obtained from trees and plants. • Insoluble in water • improve toughness, hardness, melting range of waxes
  • 14.
  • 15.
    Melting range • Waxesconsist of similar type of molecules of different molecular weight. • They may contain several types of molecules • They have melting range rather than melting point.
  • 17.
    Thermal expansion • Expandwhen temperature is risen • Contract when temperature is decreased • Dental waxes have the largest coefficient of thermal expansion. • Temp. change in wax patterns may be a major contributing factor in inaccuracy of the finished restoration.
  • 19.
    Mechanical properties • Theelastic modulus, proportional limit and compressive strength of waxes are low compare with those of other materials and these properties depend strongly on the temperature.
  • 21.
    Flow • Flow isdecidedly dependent on the temperature of the waxes. • Flow is greatly increase as the melting point of the wax is approached.
  • 23.
  • 24.
    Ductility • Ductility increaseas the temp of a wax is increase. • Waxes with lower melting temp. have a greater ductility. • The ductility of a blended waxes wide melting range > narrow melting range • The highly refined waxes is quite brittle
  • 25.
    CLASSIFICATION OF WAXES 1)Accordingto origin 2)According to use and application
  • 26.
    ACCORDING TO ORIGIN NaturalSynthetic Mineral Paraffin, microcrystalline, ceresin Polyethylene waxes Montan, Polyoxyethylene glycol waxes Plant Carnauba, candelilla Insect Beeswax Animal Spermaceti wax
  • 27.
    • Pattern waxes •Processing waxes • Impression waxes According to use and application
  • 28.
    Pattern wax • Usedto form the general predetermined size and contour of artificial dental restoration , which is to be constructed of a more durable material.
  • 29.
  • 30.
    Processing wax • Usedprimarily as auxillary aids in the construction a variety of restorations and appliances either clinically or in the laboratory
  • 31.
    Processing waxes 1.Boxing waxes 2.Utilitywaxes 3.Sticky waxes 4.Carding waxes
  • 32.
  • 33.
    Impression waxes • Usedfor taking impression within the mouth. –Bite registration waxes –Corrective waxes Korecta wax Alu wax
  • 34.
  • 35.
    • A patternof the wax is first constructed that duplicates the shape and contour of the desired casting . Inlay pattern wax
  • 36.
    • The patternthen is embedded in a gypsum-silica investment material to form a mold with an ingate or sprue leading from the outer surface of the investment mold to the pattern. Inlay pattern wax
  • 37.
    • The waxis subsequently eliminated by heating & softening and the mold is further conditioned to receive the molten metal. Inlay pattern wax
  • 39.
    Inlay wax :Composition Paraffin (major portion) Microcrystalline wax Ceresin Carnauba Candelilla Beeswax
  • 40.
    Inlay waxes generallyare produced in deep blue, green, or purple rods or sticks. The flow can be reduced by adding more carnauba wax or by selecting higher melting paraffin waxes.
  • 41.
    Inlay waxes :Properties ANSI/ADA Specification No. 4 for dental inlay casting wax. Type I wax = a hard wax that is prescribed for forming direct patterns in the mouth. Type II wax = a softer wax that is used as an indirect technique wax.
  • 42.
  • 43.
    Flow The working temperaturefor making direct wax pattern must not to be so high as to cause damage to the vital tooth structure. At mouth temp., direct inlay wax must have essentially no flow to minimize the possibility of distortion of the pattern during removal from the tooth cavity.
  • 44.
    Casting wax The patternfor the metallic framework of removable partial denture and other similar structures is fabricated from the casting waxes.
  • 46.
    Casting wax :Composition The ingredients are similar to those found in inlay waxes.
  • 47.
    Casting wax :Properties Federal specification No U-W -140 for casting wax Flow : 35 o C - maximum, 10 % 38 o C - minimum, 60 % Breaking point : no fracture at 23 o +1 o
  • 48.
    Pliable and readilyadaptable at 40o to 45o C Copy accurately surface against which it pressed Shall not be brittle on cooling Vaporize at 500o C, leaving no film other than carbon Working properties
  • 49.
    Baseplate wax Baseplate waxderives its name from its use on the baseplate tray in the technique for complete denture restoration.
  • 50.
  • 54.
    serves as thematerial to produce the desired contour of the denture after the teeth are set in position Baseplate wax
  • 55.
    Baseplate wax :Composition 70-80 % paraffin or ceresin small quantities of other waxes & additives. typical composition – 80% ceresin - 12% beeswax – 2.5% carnuaba – 3% natural or synthetic resins – 2.5% microcrystalline or synthetic wax
  • 56.
    Baseplate wax :Properties ANSI/ADA Specification No.24 – Type I - Soft, building contours and veneers – Type II - Medium, patterns in mouth, temperate – Type III - Hard, patterns in mouth, hot weather
  • 57.
    Linear thermal expansionfrom 25 o -40 o C < 0.8% Softened sheets shall cohere readily without becoming flaky or adhering to fingers No irritation of oral tissue trim easily with a sharp instrument at 23 o C Practical requirements
  • 58.
    Smooth surface aftergentle flaming No residue on porcelain or plastic teeth Coloring shall not separate or impregnate plaster during processing No adhesion to other sheets of wax or separating paper on storage Practical requirements
  • 59.
    Boxing wax Use toform a plaster or stone cast from an impression of the edentulous arch
  • 60.
    Boxing wax: Workingproperties Federal specification No U-W -138 Smooth, glossy surface on flaming Pliable at 21 o C, retain shape at 35 o C Seals easily to plaster with hot spatula
  • 61.
    Utility wax Used innumerous instance most likely consists of beeswax, petrolatum and other soft waxes
  • 62.
    Utility wax: Workingproperties Federal Specification No U-W- 156 Pliable at 21 o to 24 o C Tacky at 21 o to 24 o C, sufficient adhesion to build up
  • 63.
    Sticky wax It issticky when melt and adheres closely to the surface on which it is applied. It is firm, free from tackiness and brittle at room temp. Rosin & yellow beeswax are the usual major constituents.
  • 64.
    Sticky wax :Working properties Federal Specification No.U-W-00149a Sticky when melt Adhere closely Not more than 0.2% residue on burnout Not more than 0.5% shrinkage from 43 o to 28 C o
  • 65.
    Blockout wax:- isused to fill voids and undercuts for R.P.D white wax :- for making patterns to stimulate a veneer facing.
  • 66.
    Corrective impression wax Usedas a wax veneer over an original impression to contact and register the detail of the soft tissue . Formulated from hydrocarbon waxes such as paraffin,ceresin & beeswax and may contain metal particles The flow at 37 o C is 100 %
  • 67.
  • 68.
    Bite registration wax Usedto accurately articulate certain models of opposing quadrant Formulated from beeswax or hydrocarbon waxes such as paraffin or ceresin and contain alumina or copper particle
  • 69.
  • 70.
    Bite registration wax •Occlusal indicator wax
  • 71.
    Paraffin wax(mineral wax) •Generally the main ingredient of inlay waxes. • Obtained from high boiling fractions of petrolem(methane series) • Mixture of hydrocarbons • Melting range 40-71o C. increases with increasing molecular wt. • Paraffin waxes have less than 0.5% oil.
  • 72.
    • Presence ofoil lowers melting temp. • During solidification and cooling a volumetric contraction in the range 11%- 15%. • This is not uniform ,since it is a mixture of hydrocarbons. • Likely to flake when trimmed. • Does not present smooth, glossy surface • Consequently other waxes and natural resins are added.
  • 73.
    Carnauba wax (plantwax) • Derived from tropical palms • It is quite hard, melting range 84-910C • Combined with paraffin to- - Decrease flow at mouth temp - increase the hardness • It contributes to glossiness of the wax surface, even more than dammar resin. (Addition of 10 % carnauba wax to paraffin wax with a melting range of 200C will increase the melting range to 460C.)
  • 74.
    Ceresin wax (mineralwax) • May replace part of paraffin to modify toughness and carving characteristic. • Like microcrystalline waxes they are branched chain and straight chain paraffin. • They have higher mol wt and greater hardness than hydrocarbon waxes • These waxes also may be used to increase the melting range of paraffin waxes.
  • 75.
    Beeswax (insect wax) •Complex mixture of esters, consisting mainly of myricyl palmitate, plus saturated and unsaturated hydrocarbons and high molecular wt organic acids. • Melting range 63-700C • Brittle at room temp, becomes plastic at body temperature. • Used to modify the properties of paraffin wax (also the main component of sticky wax)
  • 76.
    Natural resin (gumdammer) • Added to paraffin to improve its smoothness in molding • It renders it more resistant to cracking and flaking • Increases the toughness of the wax and enhances the smoothness and lusture of the wax.
  • 77.
    Microcrystalline waxes(mineral) • Similarto paraffin waxes, but obtained from heavier oil fractions. • It has a higher melting range 60-910C • It is tougher and more flexible than paraffin • It has less volumetric shrinkage during solidification than paraffin.
  • 78.
    Candelilla wax (plantwax) • Same qualities as carnauba wax • Added to paraffin to partially or entirely replace carnauba wax. • Its melting point is lower, and it is not as hard as carnauba wax.
  • 79.
    Other polymers indentistry  Gutta-percha  Filling material :composite resin  Dental cement
  • 80.
    Gutta-percha  A polyisoprenewith the same empirical formular as rubber (20-30%)  various natural resin (soften the gutta-percha)  filler : ZnO,waxes Composition
  • 81.
  • 82.
    • Used tofill in the root canal • Soften at 60-70 o C • Viscoelastic material which is extremely sensitive to the rate of straining. • The best adaptation to the root canal is achieve when maximum pressure is applied over an extended period of time. Gutta-percha
  • 83.
    CONCLUSION • Waxes havebeen popular and useful dental material. • Easily manipulated • Low in cost and serve variety of purposes • Nevertheless use of dental waxes is associated with control of certain characteristics that affect their applicability, such as -Effect of heating on flow -Thermal expansion -Distortion • Way back in 1939 Hollenback et al published the results of their extensive work on properties of waxes. They concluded that waxes are sufficiently stable material if handled properly.
  • 84.
    • REFERENCES  -Kennethj. Anusavice ; Phillips Science of dental material .Eleventh edition, Elsevier,2004.  -Jack L. Ferracane ; Materials in Dentistry principles and application. Second edition ,Lippincot williams, 1995.  -William J. O’Brien; Dental materials and their selection. Third edition, quintessence Publishing co. 2002.  -Robert C. Craig John M. Powers, John C.Wataha ;Dental materials properties and manipulation,. Eight edition,2004.  -Marcia gladwin; clinical aspects of dental materials Lippincott Williams 2000  -E.C.Combe; Notes on dental materials, sixth edition Churchill livingstone 1992  -Revised ADA specification No 4 for dental casting wax,JADA Vol 90 Feb 1975
  • 85.

Editor's Notes