DENTAL WAXES
PRESENTED BY:
ANUKRITYCHANDRA
MDS 1ST
YEAR
GUIDED BY:
Dr. SUDHEER ARUNACHALAM
Dr. TUSHAR TANWANI
Dr. ANUPAM PURAWAR
Dr. SUDEEPTI SONI
2.
CONTENTS
INTRODUCTION
DESIRABLEPROPERTIES OF WAXES
PHYSICAL PROPERTIES.
COMPOSITION OF WAXES
COMPONENTS OF WAXES
CLASSIFICATION
DENTAL WAXES.
CONCLUSION
REFERENCES
3.
INTRODUCTION
WAXES arethermoplastic materials which are normally solids at room
temperature but melt without decomposition to form mobile liquids.
They are essentially, soft substances with poor mechanical
properties.
Primarily used in dentistry to form patterns of appliances prior to
casting
Other uses: impression making , bite registration, and in processing of
laboratory procedures.
4.
DEFINITION
A thermoplastic moldingmaterial that is solid at room
temperature and when subjected to moderate
temperatures become low viscosity liquid. Waxes are
esters of fatty acid, alcohol, or hydrocarbons. They are
insoluble in water but soluble in most organic solvents.
5.
Dental wax
Alow molecular weight ester of fatty acids derived from natural or
synthetic components, such as petroleum derivatives , that soften to
a plastic state at relatively low temperature.
A mixture of two or more waxes and additives used as an aid for the
production of gypsum casts, productions of non-metallic denture
bases, registering jaw relation, and laboratory work
-Phillip’s science of dental materials, 12th
edition
DESIRABLE PROPERTIES OFWAXES
When softened , the wax should be uniform.
The colour should be contrast with die material.
No flakiness or surface roughening.
Wax should burnout completely – leave no residue.
Completely rigid and dimensionally stable.
Allow careful handling – show less distortion.
9.
PROPERTIES OF WAXES
1.MELTING RANGE
2. FLOW
3. COEFFICIENT OF THERMAL EXPANSION
4. RESIDUAL STRESS
5. DUCTILITY
10.
MELTING RANGE
Waxesdo not melt at a single temperature . So they do not have a
melting point ,they have a melting range.
The lower limit of melting range controls the applicability.
Paraffin wax – 50˚C - 70˚C
Bees wax - 60˚C - 70˚C
Carnauba wax- 65˚C - 90˚C
Microcrystalline waxes- 65˚C - 90˚C
11.
SOLID- SOLID TRANSITIONTEMPERATURE
Temperature at which a sharp increase in coefficient of thermal
expansion occurs indicating increased molecular mobility
Also called softening temperature or glass transition temperature.
In waxes, at this temperature , transition from a stable crystal lattice
(orthorhombic) to hexagonal form occurs which is present below the
melting point of wax and thus it allows the wax to be manipulated
easily without flaking or tearing.
Wax is soft (not melted) at this temperature.
12.
Coefficient of thermalexpansion
THERMAL EXPANSION is the tendency of matter to change in volume in
response to a change in temperature, through heat transfer.
Linear coefficient of expansion –change in length per unit of the
original length of a material when its temperature is raised by 1˚C
For most solid materials, the volumetric coefficient of thermal
expansion can be considered to be thrice of that linear CTE
13.
Waxes havevery high CTE, particularly around the melting range, and
very high residual stress ; they have the highest CTE as compared to all
other materials used in dentistry.
CTE of typical pattern wax is 323x10/ C but that the dental porcelain is
20 times less 14x10/C
Small changes in temperature can cause a sufficient change in dimension
to make the pattern inaccurate
14.
Thermal conductivity
Thethermal conductivity of the waxes is low, and
sufficient time must be allowed both to heat them
uniformly throughout and to cool them to body or room
temperature
15.
Mechanical properties
Modulusof elasticity, proportional limit and compressive
strength are less for waxes
All these factors depend on temperature.
16.
Flow
Flow ofwaxes is desirable as a part of moulding process
but becomes undesirable after the wax pattern or
impression has been made
Mineral waxes – paraffin, ceresin- 50% flow at mouth
temperature
Yellow bees wax – No flow at 32˚c
70% flow at 40c
17.
Residual stress
Itis the stress remaining in a wax as a result of
manipulation during heating, cooling, bending, carving or
other manipulation
The release of residual stress at higher temperature
causes an irreversible deformation that can destroy the fit
of a wax pattern
The warpage is due to the residual stresses which result
from the heating of a wax specimens formed under
compression or tension
18.
It willresult in a dimensional inaccuracy and is undesirable . The longer the
wax pattern is left before being invested , the greater the distortion that
must be result
Crystalline waxes develop more internal stresses when manipulated below the
transition temperature
Extent of change in thermal expansion depends upon
Magnitude of residual stresses
Time and
Temperature of storage specimen
19.
Minimizing the warpage
Use higher temperature at the time of formation – less
force to shape less residual stresses
Soften the wax uniformly at 50 degree Celsius for 15 min.
Warmed carving instrument and die.
Adding wax to die in small increments
20.
Ductility
The ductilityof a material represents its ability to be
drawn into wire under a force of tension
It is a property related to the workability of a material in
the mouth
Highly refined waxes are quite brittle.
Wide melting ranges – greater ductility.
eg: Microcrystalline mineral waxes.
21.
Composition
The dentalwaxes are composed of natural waxes and
synthetic waxes, gums, fats, fatty acids, oils.
Natural waxes are derived from mineral , vegetable and
animal origins
Synthetic waxes are chemically synthesized from natural
wax molecules and are typically composed of hydrogen,
carbon, oxygen and chlorine
Colouring agents are added for contrast of wax patterns
against tooth, die, and model surfaces
Most dentalwaxes contain 40%- 60% paraffin by weight ,
which is derived from high boiling fraction of petroleum
They are composed mainly of a complex mixture of
hydrocarbons together with minor amounts of amorphous
and microcrystalline phases
The melting temperature generally increases with
increasing molecular weight
Paraffin wax is likely to flake when it is trimmed , and it
does not produce a smooth, glossy surface which is
desirable for an inlay wax
24.
Gum dammar– or dammar resin is a natural resin. It is added to
the paraffin to improve the smoothness in moulding and to render it
more resistant to cracking and flaking.
It also increases the toughness of the wax and enhances the
smoothness and lustre of the surface.
Carnauba wax occurs as a fine powder on the leaves of certain
topical palms. This wax is very hard , and it has a relatively high
melting point and has an agreeable odour
It is combined with paraffin to decrease flow at mouth temperature.
25.
Candelilla waxcan also be added partially or entirely to replace
carnauba wax. Candelilla wax provides the same general qualities as
carnauba wax but its melting point is lower and it is not as hard as
carnauba wax.
Ceresin is typically a white wax extracted from ozokerite, a waxy
mineral mixture of hydrocarbons that is colourless or white when pure
but it has a somewhat unpleasant odour.
This may be used to increase the melting range of paraffin waxes.
Montan waxes are hard brittle and lustrous ; they blend with other
waxes and therefore often substitute to increase the melting range of
paraffin waxes.
Pattern waxes
Inlay wax:
ADA specification no 4
Supplied in the form of small pellets and cones
Uses:
It is used to make pattern for metallic restoration
Pattern for inlay
Crown and bridges are first made in wax and then converted into metal or ceramic by
casting
28.
Ideal requirement ofinlay waxes
When softened the wax should be uniform. There should be no granules on the
surface and hard spots within the surface when the wax is softened.
The colour should be contrast with the die or prepared teeth. A defined colour
contrast helps in identifying and finishing.
The wax should not chip, flake or tear during carving.
The wax should be able to disintegrate and volatilize so that it could be eliminated
completely without residue during burn out or wax elimination procedure.
The wax pattern should be completely rigid and dimensionally stable at all times
until it is eliminated
29.
Composition
Inlay waxis composed of paraffin wax, gum dammar, carnauba or
candelilla and colouring agent.
Paraffin wax is the main component (40% - 60%) which is used to
establish the melting range
Being the main component ,gum dammar, carnauba , candeililla wax
are added to modify its properties
Colouring agents are added for contrast of wax patterns against the
tooth, die or model surface.
30.
Classification
TYPE I: Medium wax employed in direct technique
TYPE II : Soft wax used for indirect technique , for inlays and
crowns.
DIRECT TECHNIQUE- A wax pattern made in the mouth for
producing wax inlay patterns within prepared teeth.
Because the thermal expansion coefficient of wax is extremely
high compared with the values for other dental materials, a
wax pattern made in mouth will shrink appreciably as it cooled
to room temperature
31.
Indirect technique: The cavity is prepared in the tooth and the pattern is
carved directly on a die that is a reproduction of the prepared tooth and
dental tissues.
A regular or soft type of a wax is typically used for indirect work at room
temperature or in a cool weather. A harder or medium type with a flow
property is indicated for use in warmer climates.
A pattern made by the indirect method may not shrink as much.
32.
The firstprocedure in casting of an inlay or crown for the lost wax process is the
preparation of dental wax pattern by direct or indirect technique.
The wax pattern forms the outline of the mould into which an alloy is cast or a ceramic
is hot-isostatically pressed.
The pattern should be well adapted to the prepared cavity or replica cavity and
properly carved without any significant distortion.
Before the adaptation of the wax pattern within a tooth or a die, a separating medium
must be used
After the pattern is removed from the prepared cavity, it is encased in a gypsum or
phosphate- based refractory material known as an investment which is called investing
the pattern.
33.
After investinganatomically accurate wax or resin patterns for inlays, onlays, crowns,
bridges and framework for removal partial dentures, the invested material must be
eliminated completely before molten metal is cast or core ceramic is hot- pressed into
the mould cavity.
34.
Manipulation of Inlaywax
Waxes oxidizes on heating, and on prolonged heating some waxes
evaporate, so that the storage container for melted wax will be
coated by gummy deposits.
Therefore care should be exercised to use the lowest temperature
possible and to clean the wax pot and replace the wax periodically.
To manipulate inlay wax , dry heat is preferred to the use of water
bath
The later can result in the inclusion of droplets of water, which can
splatter on flaming , smear the wax surface during polishing, and
distort the pattern during temperature changes
To avoid distortion during removal of the pattern, it should be
penetrated slightly with an explorer point and carefully removed from
the cavity
35.
After removaltouching the pattern with fingers should be avoided as
much as possible to prevent any temperature changes and distortion.
To fabricate indirect patterns, the die should be lubricated preferably
with a lubricant containing a wetting agent.
Any excess must be avoided because it will prevent intimate
adaptation to the die.
The melted wax may be added in layers with spatula or a waxing
instrument.
The prepared cavity should be overfilled and the wax then carved to
the proper contour.
A silk or other fine cloth may be used for a final polishing of the
pattern, rubbing towards the margin.
36.
Some clinicianprefer to apply finger pressure as the wax is cooling to
help fill the cavity and prevent distortion during cooling. The fingers
also accelerate the cooling rate.
Regardless of the method chosen , the most practical method for
avoiding any possible delayed distortion is to invest the pattern
immediately after removal from the mouth or die.
Once the investment hardens (sets), no distortion of the pattern will
occur
37.
Wax Distortion
Distortionof a wax pattern results from occluded air in the pattern,
physical deformation ( during moulding, carving or removal) release
of stresses “trapped” during previous cooling, excessive storage time,
and extreme temperature changes during storage.
It is important that the wax pattern be retained on the die for several
hours to avoid distortion and ensure that equilibrium condition are
established.
Waxes tend to return partially to their original shape after
manipulation. This is known as elastic memory.
38.
Casting wax
Itis a type of pattern wax
Classification according to FDI specification no. 140
USES:
To make patterns of the metallic framework and sprues of
removable partial denture
SUPPLIED AS:
● sheets of thickness 0.3-0.4mm
● Preformed shapes
● Bulk form
●Rolls or coils of various diameters ranging from 2-5 mm for forming
sprue
39.
CLASSIFICATION:
Class I: (28 gauze)
Class II: ( 30 gauze)
Class III: ( readymade shapes)
COMPOSITION:
Paraffin, ceresin , beeswax and resins
PROPERTIES:
These waxes are highly ductile
Pliable and readily available at 40- 50˚C
Do not become brittle on cooling
40.
Baseplate waxes
ADAspecification no 24
USES:
To establish the initial arch form in construction of complete denture and used to produce
desired contour of the denture after teeth set in position
It establish the pattern for final denture.
SUPPLIED AS
Sheets of pink or red color having 1-2 mm thickness
COMPOSITION
Paraffin wax -75%
Beeswax and other resins and waxes
Both to set denture teeth and to adapt around these teeth and to develop proper contour
41.
Wax rim (bite rim)
It is a type of pattern wax
It is tough and resist fracture during removal from the cast.
USES:
Restoring the occlusal relationship
Arrangement of teeth
Checking the denture inside the patient mouth.
43.
Processing waxes
Boxingwax and beading wax
It is a type of processing wax.
USES
Beading was is adapted around the impression borders to create the
land area of the cast.
Boxing wax is used to build up vertical walls around the impression in
order to pour the gypsum product to make a cast base
SUPPLIED AS:
Boxing wax as sheets
Beading wax as strips
44.
Advantages of beadingand boxing
Preserve the extension and landmarks.
Controls the thickness of the borders.
Controls the form and thickness of the base of cast.
Conserve the artificial stone.
Properties:
They are pliable and can be adapted easily.
A slight tackiness allows it to stick to the impression
45.
Utility wax
Composition:
Consist mainly of beeswax and petrolatum and soft waxes in varying
proportion.
Supplied as:
It is available in the form of sticks and sheets . Orange or dark red in
colour.
Flow at 37.5˚C – minimum 65% and maximum 80%
Pliable and tacky at 21-24˚C
USES:
It can be used to alter the stock tray extension.
It is pliable and can easily be molded
It is adhesive and can stick to the tray
46.
Sticky wax
Itis a type of processing wax.
It is sticky when melted with a max 5% flow at 30˚c and 90% flow
at 43˚c and adheres closely to the surfaces when applied to it
If movement occurs the wax tends to fracture then distort
USES:
It is used to align fracture parts of acrylic dentures.
It is used to align fixed partial denture units before soldering.
47.
Sticky waxis used to join and stabilize temporarily the components of
a bridge before soldering and also to stabilize pieces of a broken
denture before the repair
It is quite tacky when melted , but firm and brittle when cooled.
Sticky wax adheres closely to the surfaces on which it is applied.
Should fracture rather than flow if it is deformed during deformed
during soldering and repair procedure
48.
Carding wax
Itis used by manufacturers for the packaging of acrylic or
porcelain teeth.
They are soft tacky and pliable at room temperature.
They are available as sheets
49.
Impression waxes
Correctivewax:
Wax in combination with resins of low melting range can be used in
corrective impression technique in partial and complete denture
prosthesis
The peculiarity of impression wax is that they flow at mouth
temperature.
It records mucous membrane and underlying tissue in functional
state in which movable tissue is displaced in such a degree that
functional contact with the base of denture is obtained.
Available as: sheets or cakes
Its main disadvantage is that it is distorted.
It flows 100% at 37˚C
50.
Bite registration wax
It is used to record relationship of the upper and lower teeth in
dentulous patient.
Wax is softened under hot running water.
Full arch quadrant or just a few teeth can be taken.
28 gauze casting wax or hard base plate wax , bees wax ,
hydrocarbons are used in bite registration wax.
It flows 2.5%- 22% at 37 C
Susceptible to distortion from removal from mouth.
Occlusal registration made from addition silicon, elastomers
become more popular because of their high elastic recovery and
dimensional stability.
51.
Conclusion
Waxes areuse in restorative dentistry like forming an inlay patterns,
registration of occlusal bite relationship, boxing an impression and other
processing steps, each requires a specially formulated wax.
And have different features of every wax. So proper knowledge in needed of
their characteristics.
For proper handling and manipulation.