Darcy's Law describes the flow of fluids through porous media. It states that the flow rate is proportional to the pressure gradient across the medium and its permeability, and inversely proportional to the fluid viscosity. Darcy discovered this relationship through experiments measuring the flow of water through sand. He showed that flow rate depends on factors like cross-sectional area, length, and the difference in water levels at either end of the sand pack. This relationship forms the basis for analyzing fluid flow in porous materials like soils.