This document presents an algorithmic framework for large-scale time-domain circuit simulation using exponential integrators, which improves simulation efficiency by avoiding Newton-Raphson iterations and reducing LU decomposition operations. The proposed method, which employs an Invert Krylov Subspace method for matrix exponential and vector product calculations, is capable of handling stiff nonlinear circuit systems and demonstrates enhanced performance compared to conventional methods. Experimental results indicate that this approach accelerates simulation and effectively deals with challenging test cases where traditional methods may fail.