Test bank for chemistry atoms first 2nd edition by burdgeQuick12874
Test Bank for Chemistry Atoms First 2nd Edition by Burdge
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Test bank for chemistry atoms first 2nd edition by burdgeQuick12874
Test Bank for Chemistry Atoms First 2nd Edition by Burdge
Full download: https://goo.gl/Z56fCq
People also search:
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Hello everyone, I am Dr. Ujwalkumar Trivedi, Head of Biotechnology Department at Marwadi University Rajkot. I teach Molecular Biology to the students of M.Sc. Microbiology and Biotechnology.
The current presentation is about the historical perspectives of the discovery of atoms and subatomic particles. The later part of the presentation describes various atomic models and the properties of subatomic particles with a description of commonly used terms like molecules, ions and compounds.
ATOMIC STRUCTURE
1. ATOM & MOLECULES
(a) The smallest particle of a matter that takes part in a chemical reaction is called an atom. The atom of all gases except those of noble gases, cannot exist in free state. These exist in molecular form. The molecules of hydrogen, nitrogen, oxygen and halogens are diatomic (H2, N2). Phosphorus molecule is tetratomic and that of
sulphur is octa atomic.
(b) The smallest particle of a matter that can exist in free state in nature, is known as a molecule.
(c) Some molecules are composed of homoatomic atom, e.g., H2, O2, N2, Cl2, O3 etc., while the molecules of compounds are made up of two or more heteroatomic atoms e.g., HCl, NaOH, HNO3, CaCO3, etc.
2. DALTON’S ATOMIC THEORY
The concepts put forward by John Dalton regarding the composition of matter are known as Dalton’s atomic theory. Its important points are as follows.
(a) Every matter is composed of very minute particles, called atoms that take part in chemical reactions.
(b) Atoms cannot be further subdivided.
(c) The atoms of different elements differ from each other in their properties and masses, while the atoms of the same element are identical in all respects.
(d) The atoms of different elements can combine in simple ratio to form compounds. The masses of combining elements represent the masses of combining atoms.
(e) Atom can neither be created nor destroyed.
2.1 Modern Concept :
Many of the concepts of Dalton’s atomic theory cannot be explained. Therefore, foundation of modern atomic theory was laid down by the end of nineteenth century. The modern theory is substantiated by the existence of isotopes, radioactive disintegration, etc. The important points of the modern atomic theory are as follows.
(a) Prof. Henri Bacquerel discovered the phenomenon of radioactivity and found that an atom is divisible.
(b) An atom is mainly composed of three fundamental particles, viz. electron, proton and neutron.
(c) Apart from the aforesaid three fundamental particles, many others have also been identified, viz. positron, meson, neutrino, antiproton, etc.
(d) Soddy discovered the existence of isotopes, which were atom of the same element having different masses. For example, protium, deuterium and tritium are atoms of hydrogen having atomic masses 1, 2 and 3 a.m.u. respectively.
(e) Atoms having same mass may have different atomic numbers. These are known as isobars. For example,
40 Ar and 40 Ca .
18 20
(f) Atoms of elements combines to form molecules.
(g) It is not necessary that the atoms should combine in simple ratio for the formation of compounds. The atoms in non-stoichiometric compounds are not present in simple ratio. For example, in ferrous sulphide crystals, iron and sulphur atoms are present in the ratio of 0.86 : 1.00.
(h) Atoms participate in chemical reactions.
3. CATHODE RAYS (DISCOVERY OF ELECTRON)
Dry gases are normally bad conductors of electricity. But under low pressure, i.e., 0.1 mm of mercury or lower, electric current can pass thro
NCERT solutions for class 10 science chapter 5 (Periodic Classification of El...DebarajBag
Answer: The first ten elements in modern periodic table are hydrogen, helium, lithium, beryllium, boron, carbon, nitrogen, oxygen, fluorine and ...for more reading click here,https://bidyashramodia.blogspot.com/2022/06/ncert-solutions-for-class-10-science_24.html
1. Chemistry I Course Review Key
The Basics
1. a) Goggles must be worn any time there is an open flame or hazardous chemicals in the lab.
b) Chemicals should be handled with care; lids should be returned when a bottle is finished;
chemicals should never be eaten or tasted unless directed by the teacher. Students should pour
form larger stock bottles into smaller containers that will be used in the lab. Any leftover
waster should be disposed of according to teacher direction, but NEVER poured back into the
stock solution.
c) When heating a chemical in a test tube, the open end of the test tube should be aimed
towards a wall, away from any people.
d) Report cuts and burns to a teacher immediately who will start first aid if necessary and
contact the health room.
e) If an odor is to be detected, the fumes should be wafted towards the nose, not snorted in a
large amount.
f) If a fire alarm sounds during lab, all electrical equipment, water, and gas should be shut off
before the room is evacuated as normal.
2. a) Football fields can be measured in meters. A paperclip can be measured in cm. Length
should best be measured with a metric ruler or meter stick.
b) The volume of a bottle of soda could be measured in liters (2L soda) or mL (20oz size) with
a graduated cylinder. Raindrops can be measured using a graduated cylinder mL A rectangular
solid can be measured with a metric ruler.
c) The mass of a human being would be measured in kilograms on a balance. A penny would
also be measured on a balance however it would be measured on a balance however it would be
measured in grams.
d) Temperature should best be measured with a thermometer.
3. a) 80.2 b) 2.41.3 x 1023 c) 1.3 x 1023 d) 1.8 x 106
e) 0.01628 f) 0.0012
4. a) kilo- b) hector- c) deka- d) deci-
e) centi- f) milli-
5. a) 0.0045 kg b) 8.5 x 105 mm c) 5.4 x 105 mL d) 0.64512 L
e) 3.25 x 10-4 mm
6. Precision is how close a group of measurements are to each other; accuracy is how close a
measurement is to the accepted or true value.
The Atom
7. a) Each shell (energy level) would hold 2,8,18,32 electrons respectively. Each subshell would
hold s(2), p(6), d(10), f(14).
b) i) 1s22s2p63s1; Lewis Dot Structure (LDS) is Na with a single dot.
ii) 1s22s22p3; LDS is N with one pair of dots and three single dots.
iii) 1s22s22p63s23p64s23d104p5; LDS is Br with a single dot and three pairs.
c) An ion is a atom or molecule with an overall positive or negative charge.
d) A sodium atom becomes an ion by losing its single outer shell electron. It would therefore
have a positive one (+1) charge.
e) A sulfur atom becomes an ion by gaining two electrons to complete its outer shell. It would
therefore have a negative two (-2) charge.
2. Chemistry I Course Review Key
f) Carbon-14 has 6 protons, 6 electrons and 8 neutrons.
g) U-238 has 146 neutrons.
h) Dalton’s model consisted of solid spheres of matter. Thomson’s model had a ball of
positively charged matter with negatively charged “bits” inside of it. Rutherford/Bohr’s model
had a dense positive core (the nucleus) with electrons in perfect circular orbits around it.
Schrodinger’s model had a dense positive core with electrons orbiting in orbital’s (three-
dimensional, mathematically-defined zones of space.)
8. a) Natural radioactivity is radiation that exists on its own in nature. Induced radioactivity is
radiation that has been created in a laboratory (man-made).
b) The three basic types of radiation are: alpha (α) in which a helium nucleus (alpha particle)
breaks off from the unstable atom; beta (β) in which an electron produced from the breakup of
a neutron (a beta particle) is shot from the nucleus; and gamma (γ) in which a burst of high
energy light (a gamma ray) is emitted from the nucleus.
c) Penetrating ability: least is alpha, then beta, and gamma has the most.
d) Fission is when a large unstable nucleus splits into two new nuclei. Fusion is when two
smaller nuclei are fused together to make a single nucleus.
e) An isotope is a group of elements with the same number of protons (same element) and the
same number of neutrons (same mass).
f) Half-life is the time it takes for half of radioactive sample to decay.
g) 8.25 x 10 -27 g
h) 52.00 amu
The Periodic Table
9. a) The periodic table is arranged such that the elements are in order of increasing atomic
number, and elements of similar chemical properties are grouped in columns together. This is
different than Mendeleev’s table which was organized by atomic mass.
b) A group is a vertical column on the periodic table, containing elements of similar chemical
properties. A period is a horizontal row on the periodic table.
c) The metals are to the left and below the “stair-step” on the periodic table. The nonmetals are
to the right and above.
d) Metals: shiny; good conductors of heat & electricity; malleable & ductile.
Nonmetals: dull; insulators of heat & electricity; brittle.
Metalloids: elements with some metal properties and some nonmetal properties
e) Group 1: alkali metals; Group 2: alkaline earth metals; Group 17: halogens; Group 18: noble
gases; Groups 3-12: transition metals
f) Ionization energy is the amount of energy required to remove the outer most electron from an
atom. Electronegativity is a measure of an atom’s ability to draw electrons towards itself in a
covalent bond.
g) Electronegativity increases across a period and decreases down a family. Ionization energy
does the same thing.
h) Elements in a family have similar chemical properties.
i) Atomic radius decreases across a period and increases down a family.
j) V has the highest ionization energy.
k) Fr is the most metallic of all the elements. It has the lowest ionization energy, the lowest
electro negativity, and is the most reactive metal. It has the largest atomic radius. F is the most
non-metallic of all the elements. It has the highest ionization energy and the highest
electronegative and is the most reactive non-metal. These two elects are the “most” of their
group (metal versus non-metal).
3. Chemistry I Course Review Key
l) Even though both Be and He have two outer shell electrons, Helium’s electrons fill the first
energy level (shell) completely while Be has two more electrons that are in the next sub shell
causing an incomplete outermost shell.
Compounds and Bonding
10. a) An ionic bond is the electrostatic attraction between two oppositely charged ions. A covalent
bond is a shared pair(s) of electrons between two atoms. They are different chiefly in that an
ionic bond doesn’t need to exist in order for the atoms to have a complete outer shell (they
already have transferred electrons) but a covalent bond must stay whole for all of the atoms to
keep their stable full outer shells.
b) Metallic bonds are bonds that occurs the result of free floating valence electrons for
positively charged metal ions. Metallic bonds help explain why metals conduct heat and
electricity so easily as the heat (increased motion) moves easily from one electron to another.
c) i) potassium sulfate ii) aluminum chloride hexahydrate
iii) hydrobromic acid iv) tin(IV) nitrate
v) carbon monoxide vi) nitrous acid
d) i) Ag3PO4 ii) CCl4
iii) Fe2O3 iv) K2CrO4
v) Cu(NO3)2 x 3H2O vi) H2SO4
e) A roman numeral in a chemical’s name tells the charge on the positive ion (ex: “iron (III)
oxide” means that the iron ion’s charge is +3).
f) i) ii) O=C=O iii)
g) i) linear ii) tetrahedral iii) bent
Matter and Energy
11. a) 4650 J
b) 360 g (358.5 g rounded to two sig figs)
c) Copper would be heated faster than water of the same mass from room temp to 56 degrees C
because metals (like copper) have smaller specific heats that water does, so it takes less energy
(and therefore less time) to heat them.
d) Heat of fusion is the amount of heat energy needed to melt 1 g of substance. Heat of
vaporization is the amount of heat energy needed to vaporize 1 g of a substance.
e) 4540 J (4536 J rounded to 3 sig figs)
f) Temperature is the average kinetic energy of all the particles in a sample. Absolute zero is
the theoretical lowest temperature possible (O K).
g) Temperature is an average kinetic energy of the particles, where heat is the total kinetic
energy of the particles.
h) i) endothermic ii) endothermic iii) exothermic iv) exothermic
i) Intensive properties are ones that do not depend on the size of the sample (ex: density,
freezing point) while extensive properties are ones that do depend on the size of the sample (ex:
mass, volume).
j) Salt and sand could be separated by dissolving the salt in water, filtering out the sand, then
boiling the water away from the salt. Alcohol and water could be separated by distillation
(boiling the alcohol away form the water and collecting and recondensing the vapors).
4. Chemistry I Course Review Key
The Mole
12. a) i) 110.26 g/mol ii) 253 g/mol iii) 342.3 g/mol
b) i) 29.1% K ii) 25.3% K iii) 28.1% K
c) i) 0.136 mol K2S ii) 0.0593 mol Ba(SCN)2 iii) 0.0438 molAl2(SO4)3
d) 3.39 x 1024 molecules O2
e) 126 L O2
f) Sn3N2
Chemical Reactions
13. a) i) 2,2,2,1 ii)2,2,3 iii)1,6,2,3
b) i) single replacement ii) decomposition iii) double replacement(ionic)
c) i) Zinc+ copper(II) sulfate copper+ zinc sulfate
Zn+ CuSO4 Cu + ZnSO4
ii) lead(II) nitrate+ sodium sulfate sodium nitrate+ lead (II) sulfate
Pb(NO3)2 + Na2SO4 2 NaNO3+ PbSO4
iii) ethane+ oxygen carbon dioxide+ water
2 C2H6+ 7 O2 4 CO2+ 6 H2O
Stoichiometry
14. a) i) 10 mol NaCl ii) 5 formula units Na2SO4
b) i) 9 molecules CO2 ii) 25 mol O2 iii) 13 L CO2
c) 24.9 g MgO
d) 4.3 g Al2O3
e) 22.8 g PbI2; lead(II) nitrate is the limiting reactant
Acids, Bases, and Salts
15. a) i) S ii) A iii) B iv) A v) B vi) B vii) S viii) S
b) A solution’s acidity (or basicity) can be generally tested by litmus paper (litmus turning
red indicates an acid, litmus turning blue indicates a base). More specifically, pH paper (or a
pH meter) can be used to determine the solution’s pH (pH below 7 is acidic, above 7 is basic).
c) A strong acid ionizes 100% in water. A weak acid ionizes less than 100%.
d) When an acid and a base react, the reaction is called a neutralization reaction, and the
products will be water and a salt.
Gas Laws
16. a) Pressure is the force applied per unit area.
b) At constant pressure, temperature and volume are directly proportional (if one goes up
the other goes up). This is Charles’s Law.
c) At constant temperature, pressure and volume are inversely proportional (if goes up the
other goes down). This is Boyle’s Law.
d) A constant volume, pressure and temperature are directly proportional (if one goes up the
other goes up). This is Gay-Lussac’s Law.
e) PV = nRT
f) V2 = 1.10 L
g) V2 = 0.549 L
h) T2 = 526 K
5. Chemistry I Course Review Key
Solutions
17. a) A solution is a homogeneous mixture. A solute is the substance being dissolved in a solution.
A solvent is the substance that does the dissolving. In salt water, salt is the solute and water is the
solvent.
b) To make a solid dissolve faster in a liquid you could: stir the mixture; heat the mixture; grind
up the solid into smaller pieces.
c) Molarity measures the concentration of a solution; specifically it measure the number of
moles of solute in every liter of solution. It’s units are “molar”, M, or mol/L.
d) 2.5 M CuSO4
e) 4.28 M NaCl
f) 2 mol CaCl2 (1.75 mol rounded to 1 sig fig)
g) Solutions that are high in electrolytes will conduct electricity. If a solution does not contain
dissolved ions then it will not conduct electricity. Molten ionic compounds (which may not be true
solutions) will also conduct electricity.