This document summarizes a study on using biomass gasification to capture CO2 from engine exhaust. Experiments were conducted introducing 0-15% CO2 into a gasifier along with oxygen and nitrogen. Higher CO2 fractions decreased bed temperature but increased CO production from 13.1% to 16.3% due to the endothermic reaction of char and CO2. Over 55% of input CO2 was converted. Cold gas efficiency increased 30% with higher char conversion. Using engine exhaust eliminates the cost of separating and storing CO2, as condensing water and mixing with oxygen is sufficient. The paper addresses using biomass gasification to capture CO2 from engine exhaust via recycling into the gasification process.
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Presentation: DOE Stetsoon Hydrogen Storage technologieschrisrobschu
Hydrogen Storage Technologies –
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U. S. Department of Energy
1000 Independence Ave., SW
Washington, DC 20585
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Cocoa Beach, FL
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• Physical storage technologies
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Doe stetson hydrogen_storage_technologies_tutorial
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Achieving the target set during COP21 will require the deployment of a diverse portfolio of solutions, including fuel switching, improvements in energy efficiency, increasing use of nuclear and renewable power, as well as carbon capture and storage (CCS).
It is in the context of CCS that carbon capture and utilisation (CCU), or conversion (CCC), is often mentioned. Once we have captured and purified the CO2, it is sometimes argued that we should aim to convert the CO2 to useful products such as fuels or plastics, or otherwise use the CO2 in processes such as enhanced oil recovery (CO2-EOR). This is broadly referred to as CCU.
In this webinar, Niall Mac Dowell, Senior Lecturer (Associate Professor) in the Centre for Process Systems Engineering and the Centre for Environmental Policy at Imperial College London, presented about the scale of the challenge associated with climate change mitigation and contextualise the value which CO2 conversion and utilisation options can provide.
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Welcome to International Journal of Engineering Research and Development (IJERD)IJERD Editor
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Metal Oxides as Catalyst/Supporter for CO2 Capture and Conversionssuser7bc3591
Various carbon dioxide (CO2) capture materials and processes have been developed in recent years. The absorption-based capturing process is the most significant among other processes, which is widely recognized because of its effectiveness. CO2 can be used as a feedstock for the production of valuable chemicals, which will assist in alleviating the issues caused by excessive CO2 levels in the atmosphere. However, the interaction of carbon dioxide with other substances is laborious because carbon dioxide is dynamically relatively stable. Therefore, there is a need to develop types of catalysts that can break the bond in CO2 and thus be used as feedstock to produce materials of economic value. Metal oxide-based processes that convert carbon dioxide into other compounds have recently attracted attention. Metal oxides play a pivotal role in CO2 hydrogenation, as they provide additional advantages, such as selectivity and energy efficiency. This review provides an overview of the types of metal oxides and their use for carbon dioxide adsorption and conversion applications, allowing researchers to take advantage of this information in order to develop new catalysts or methods for preparing catalysts to obtain materials of economic value.
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In the history of internal combustion engine development, hydrogen has been considered at several phases as a substitute of hydrocarbon-based fuels. Starting from the 70’s, there have been several attempts to convert engines for hydrogen operation. Together with the development in gas injector technology it has become possible to control precisely the injection of hydrogen for safe operation. Here we are using stainless steel plate as electrode in the electrolytic cell, the electrolyte being water and NACL salt. The electrolytic cell we used is a 12V battery case made of plastic. The cross sectional layers are cut such that the stainless steel plate fix in the battery case. The plates are separated by very small distance and the plates are given parallel holes for electron flow to be uniform. The power source to the kit is provided by a 12V and 9Ams battery. We used a transparent tube to supply the hydrogen produced in the kit to the air hose tube of our motor cycle. In order to keep the battery charged we used two 6 Amp diode to power the battery while running. There is a separate switch to power the kit and to protect the battery from getting drained. The stainless steel plates are of 50cm length, 25cm height, 2 millimeter thickness. The battery case can hold up to 5 liters of electrolyte. The use of hydrogen with petrol to power the vehicle has resulted in increase in vehicle mileage, accelerating speed with most important task of reduction in exhaust emission.
Chemical Looping Combustion of Rice HuskIJERA Editor
A thermodynamic investigation of direct chemical looping combustion (CLC) of rice husk is presented in this paper. Both steam and CO2 are used for gasification within the temperature range of 500–1200˚C and different amounts of oxygen carriers. Chemical equilibrium model was considered for the CLC fuel reactor. The trends in product compositions of the fuel reactor, were determined. Rice husk gasification using 3 moles H2O and 0 moles CO2 per mole carbon (in rice husk) at 1 bar pressure and 900˚C was found to be the best operating point for hundred percent carbon conversion in the fuel reactor. Such detailed thermodynamic studies can be useful to design chemical looping combustion processes using different fuels.
Chemical Looping Combustion of Rice HuskIJERA Editor
A thermodynamic investigation of direct chemical looping combustion (CLC) of rice husk is presented in this paper. Both steam and CO2 are used for gasification within the temperature range of 500–1200˚C and different amounts of oxygen carriers. Chemical equilibrium model was considered for the CLC fuel reactor. The trends in product compositions of the fuel reactor, were determined. Rice husk gasification using 3 moles H2O and 0 moles CO2 per mole carbon (in rice husk) at 1 bar pressure and 900˚C was found to be the best operating point for hundred percent carbon conversion in the fuel reactor. Such detailed thermodynamic studies can be useful to design chemical looping combustion processes using different fuels.
2. CARBON DIOXIDE CAPTURE THROUGH BIOMASS GASIFICATION
Sandeep K 1
, Snehesh S 1
, S Dasappa 2
1
Research scholar, Centre for Sustainable Technologies, sandeepk@cgpl.iisc.ernet.in
2
Faculty, Centre for Sustainable Technologies
Indian Institute of Science, Bangalore 560012, India
ABSTRACT: Gasification, a thermo-chemical process, is explored as a promising technology towards carbon capture.
The present work focuses on using CO2, from a typical flue of combustion of fuels in an engine or a combustion device,
as a co-reactant along with other reacting media. Experiments were conducted with CO2 volume fraction varied from 0 to
15% in a mixture of O2 and N2. Increase in CO2 fraction resulted in decrease in bed temperature, primarily due to
reduction in O2 fraction, in the gasifying medium, and the endothermic reaction of char and CO2. Low bed temperature
was addressed by maintaining the O2 volume fraction in the input at 21% by introducing additional oxygen. At 15% CO2
injection, the CO fraction increased from 13.1% to 16.3% and over 55% of the input CO2 conversion was noted.
Recorded an increase in cold gas efficiency by 30% owing to higher conversion rate of char. Working with the engine
exhaust also eliminates the cost incurred in separation of CO2 and makes the system less complicated.
Keywords: CO2 capture, CO2 reduction, gasification, CO2 emissions
1 INTRODUCTION
Ever increasing energy demands have become a
primary concern, and meeting this escalating energy need
has resulted in renewed interest in alternatives to fossil
fuels. The interest amongst all the climate change
mitigation researchers is in addressing the reduction of
emissions and also attempt sequester the carbon. Amongst
the technologies receiving the most such attention to reduce
CO2's impacts is CO2 capture and sequestration. CO2
sequestration involves removing CO2 from the fuel, either
before, during, or after combustion, and then capturing and
converting it, to avoid its release to the atmosphere. While
other greenhouse gases (e.g., methane) are more potent in
terms of global warming effects per unit of mass, the CO2
emissions of industrialized economies are so great as to
dwarf the contributions from other gases in terms of overall
impact on global warming. Hence, the focus is on CO2
sequestration technologies.
The relative contributions of different fossil fuels to
total energy-related carbon dioxide emissions have changed
over time. In 1990, carbon dioxide emissions associated
with liquid fuels made up an estimated 42 percent of the
world total; in 2007, their share was 38 percent. The pursuit
of greenhouse gas emissions reductions has the potential by
reducing global coal use significantly. Limitations on
carbon dioxide emissions will raise the cost of coal relative
to the costs of other fuels. Under such circumstances, the
degree to which energy use shifts away from coal to other
fuels will largely depend on the costs of reducing carbon
dioxide emissions from coal-fired plants relative to the
costs of using other, low-carbon or carbon-free energy
source [1].
Amongst the emerging CO2 capture technologies,
absorption of CO2 has received considerable attention.
Absorption processes use a suitable solvent to separate CO2
from the flue gas stream. Alkanoamines (e.g., MEA -
Mono-ethanol amine, and diethanolamine) are typically
used in chemical absorption, whereas methanol,
dimethylether, polyethylene glycol, and sulfolane are
employed in physical absorption [2]. The major issues with
MEA and other solvents include equipment corrosion in the
presence of O2, and the energy-intensive solvent
regeneration. The presence of common flue gas
contaminants, such as SOx, and NOx, also has a negative
impact on solvent based process performance.
Comparatively, the ammonia scrubbing technique provides
advantages of lower material costs, higher absorption
efficiency, a greater absorption capacity and less corrosion
to absorber, as well as potential to save energy [3][4]. The
amount of CO2 that can be removed from the exhaust
depends on the size of the absorption unit and the
concentration of CO2 in the exhaust. For a standard plant
the economical recovery limit is approximately 85% for
3% CO2 in the exhaust, and 90-92% for 8% [5]. Adsorption
processes are based on the selective adsorption of CO2 on a
solid adsorbent, such as zeolites, alumina molecular sieves
and activated carbon. One very promising high temperature
chemical sorbent is that of CaO, which can be used either
directly or in modified form, and is freely obtained from
limestone, which is abundantly available [6]. The sorption
/desorption temperatures of modified CaO are normally in
the range of 650-850 0
C. Porous membranes, which are
capable of separating gas molecules of different molecular
sizes, are available in a variety of forms, including
polymers, metals and rubber composites. The main
disadvantage of membrane separation is its low gas
throughput, and the need for multistage operation or stream
recycling [7]. The development of a membrane separator
for the selective removal of CO2 in the presence of CO, H2,
H2O and H2S (fuel gas) or N2, O2, H2O, SO2, NOx, and HCl
(flue gas) would be of tremendous economic value. A
membrane separation technique requires less maintenance
and energy than a comparable absorption system. Table I
gives a glimpse of carbon capture and separation
technologies with limitations and advantages [8].
3. Table I: Overview of Carbon Capture and Separation (CCS) technologies [8]
Carbon
capture and
separation
technology
Benefits Limitations
Energy cost for
separation
(kW/ ton CO2)
Absorption
(liquid) –
MEA
Solvents can be regenerated
easily. Well established and
widely used for over past 65
yrs.
Desulfurization and removal of NOx,
SOx and particulate matters required.
O2 content in flue gas damages the
system.
309
Adsorption
– CFCMS
Can play significant role in
hybrid system (coupled with
another separation process).
Not capable enough to handle large
concentration of CO2 (>1.5%) – not
suitable for engine exhaust. 617
Adsorption
– PSA
Can play significant role in
hybrid system (coupled with
another separation process).
Not capable enough to handle large
concentration of CO2 (>1.5%) – not
suitable for engine exhaust. 154
Cryogenic
distillation
Product is liquid CO2, ready to
transport.CO2 recovery is very
high compared to other
methods.
All components except N2 and CO2
needs to be filtered from flue gas. 726
Membrane
Separation
Design and construction
simpler and cheaper, as no
requirement for high
temperature or pressure. Flue
gas can be directly used
without SOx/NOx removal.
CO2 separation efficiency is low
(~50%) 610
This work, involves an alternative strategy for dealing
with CO2. This propitious use of CO2 involves its recycling
into the fuel making process. Biomass gasification is
explored as a promising technology to convert CO2 to a
fuel gas, identified as producer gas. CO2, from the engine
exhaust, is used as a co-reactant in the gasification medium,
along with air. This work concentrates on capturing CO2
from a typical combustion system like, engine exhaust
where CO2 fraction varies from 12% (CNG) to 15%
(diesel), on dry basis. Scrubbing of SOx/NOx or particulate
matter is not required. Condensing H2O and mixing exhaust
with proportionate amount of O2, eliminates the cost of
separation and storage of CO2 as well.
With energy consumption expected to double over the
next 40 years and with heightened environmental
consciousness as to the need for limiting CO2 atmospheric
emissions, the feasibility of biomass-derived fuels as one of
the significant carbon neutral energy solutions has
emerged.
The paper addresses use of biomass gasification
process to capture CO2 from a typical combustion system,
say an internal combustion engine. Biomass constitutes one
of the more promising carbon neutral energy sources that
can be part of the solution. Biomass gasifiers converts solid
fuel(biomass) to gaseous fuel through thermochemical
process. It undergoes the process of pyrolysis, oxidation
and reduction under sub-stoichiometric conditions.
Oxidation of pyrolysis products (volatile matter) takes
place which in turn reacts with char to produce H2, CO,
CO2, CH4, H2O and small fractions of higher hydrocarbon
(HHC). It is a heterogeneous reaction between the char and
gaseous species of pyrolysis combustion products. These,
as sources of combustible gas for energizing internal
combustion engines, have been in
existence for nearly a century.
Following are the majorly involved reactions in the
reduction zone:
Oxidation:
kJ/mole8.39322 +⇔+ COOC (1)
Water gas reaction:
kJ/mole4.13122 −+⇔+ COHOHC (2)
Boudouard reaction:
kJ/mole6.17222 −⇔+ COCOC (3)
Water shift reaction:
kJ/mole2.41222 ++⇔+ HCOOHCO (4)
Methane reaction:
kJ/mole752 42 +⇔+ CHHC (5)
Introducing CO2 as a co-reactant, along with air in the
open top downdraft gasifier reduces CO2 to CO, owing to
reactions 3 and 4 above. The CO2 gasification of char has
been extensively studied.
The mechanism of heterogeneous reaction of CO2with
C, proposed by Blackwood and Ingeme has been based on
the adsorption of process where CO2 breaks down at the C
surface to form CO and O in the adsorbed state. The O
atom then reacts with C to form molecular CO [9].The
kinetic mechanism considered for the C + CO2 reaction are
as follows:
4. )(
1
2 OCOCO
k
+→
(6)
COOC
k2
)( →+
(7)
The retarding effect of CO is explained by the competition
of CO with O for the active sites; i.e.
)(
3
4
COCO
K
K
⇔
(8)
CCOCOCO
K
+→+ 2
5
)(
(9)
The reaction 9, involves the introduction of reverse of
C-CO2 reaction by neglecting the adsorption of CO. In the
above set of reactions (O) and (CO) are species in the
adsorbed state at the active sites which are present in
different fractions at each site. Assuming (O) and (CO) to
be in a quasi-steady state, the overall rate expression with
the elementary reactions has been proposed as:
2
2
43
2
21'''
1 COCO
COCO
c
pKpK
pKpk
++
−−
=ω
(10)
k1 = 2.2*109
e-E/RT
mol/cm3
K2 is obtained from equilibrium
K3 = 15.0 atm-1
K4 = 0.25 atm-1
where ὡc
’’’
is the , reaction rate of carbon per unit volume,
k1 is the rate constant, and K2, K3, K4 are obtained from
detailed kinetic steps, with pi being the partial pressure of
the species. This reaction has been extensively studied by
Dasappa et al [15].
Apart from enhancing CO in producer gas, introducing
CO2 as a co-reactant changes the H2/CO ratio as well. In
recent years, the availability of biomass and the successful
research on it have provided momentum in the use of
Fischer Tropsch (FT) technology. Production of syngas
from biomass and its subsequent transformation via FT
synthesis has potential to produce a wide spectrum of linear
and branched chain synthetic hydrocarbons. This process is
called biomass to liquid fuel (BTL) and has become an
excellent option to obtain liquid transportation fuels. These
fuels are ultraclean; contain no aromatics, no sulfur, and no
nitrogen containing compounds. Therefore, they can easily
satisfy the upcoming stricter global environmental
regulations [10]. Presence of CO2 would help in
establishing H2/CO ratio in a syngas generation unit, using
CO2-O2-steam gasification. Using CO2, the opportunity
exists to adjust the ratio of H2 / CO in the syngas produced,
by selecting the concentration of CO2 fed into the reactor
system resulting in operational and economic advantages.
Butterman and Castaldi had done studies on gas
evolution on several biomass and organic compounds with
steam-CO2 gasification in a thermally controlled
environment [11]. Feedstock were heated from 300-1300 K
at rates of 1-100 K/min in H2O, CO2/N2 and 100% CO2
environment. Higher conversion of biomass was reported in
CO2 gasification. Results showed the variation of H2/CO
ratio from 0.25 at 50% CO2 to 5.5 at 0% CO2.
The current work addresses use of biomass gasification
process to capture CO2 from a typical combustion system
in self-sustained manner.
2 METHODOLOGY
The development work at the Indian Institute of
Science has resulted in a design with an open top downdraft
gasifier, with air entering both at the top and at the air
nozzles in the lower part. Stratification of the fuel bed
keeps larger part of the bed volume at higher temperature
and thus helps in maintaining low tar levels. Figure 1
shows the outline of the open top downdraft gasifier,
developed at Indian Institute of Science [12]. Typical
producer gas composition (dry basis) is as follows; CO
(19%), H2 (19%), CH4 (1%), CO2 (11%) and rest N2.
Experiments were conducted initially with air as the
gasification medium, followed by injection of measured
quantities of CO2 along with air, as a co-reactant, to
analyze CO2 conversion levels. During gasification process,
once the hot char bed was established; input air mass flux
rate was fixed to desired value. Producer gas flow rate, gas
composition and bed temperature at different heights were
recorded. After 45 minutes of stable operation, CO2 and O2
were introduced, along with air, maintaining the mass flux
rate. With the introduction of CO2, change in gas
composition and producer gas flow rate were noted. Net
CO2 conversion was obtained from following equations:
)1(
..
)1(
.
bioairPG mmm += (11)
)1(
..
)2(
.
BioairPG mmm += (12)
)1(2)1(
.
)1(2
.
COPGoutCO mm χ×= (13)
)2(2)2(
.
)2(2
.
COpgoutCO mm χ×= (14)
)( )1(2
.
)2(2
.
)(2
.
2 outCOoutCOinCO mmmseqCO −−= (15)
)(2
.
2
2
conversion
(%)conversion
inCOm
CO
CO = (16)
)(
)(
)(
BiomassLHV
PGLHV
Efficiency =η (17)
)1(
))1()2((
η
ηη
η
−
=∆ (18)
where, airm
.
= mass flow rate of air during operation, in
kg/hr
5. Figure 1 Schematic diagram of open top downdraft gasifier
,,,, )1(
..
)1(2)1(
.
BiooutCOPG mandmm are mass flow rate of
producer gas, CO2 in output producer gas and biomass
consumption rate respectively in case 1 (without passing
CO2), in kg/hr. )1(2COχ is mass fraction of CO2 in the
producer gas in case 1.݉ሶ ீ(ଶ), ݉ሶ ைమ(௨௧ ଶ) and ݉ሶ (ଶ), are
mass flow rates of producer gas, CO2 in output producer
gas and biomass consumption rate respectively in case 2
(while passing CO2), in kg/hr.߯ைమ(ଶ) is mass fraction of
CO2 in the producer gas in case 2.
Hence, an attempt has been made to convert CO2 to
CO, which is an active component of producer gas.
3 EXPERIMENTAL SETUP AND MEASUREMENT
SCHEMES
Casuarina wood chips were used as a fuel for gasification.
All the wood chips were dried at 373 K prior to gasification
process. The result of ultimate analysis of dried casuarina
wood samples was obtained from CECRI, India and is
listed in Table II. The chemical composition of sample
wood chip is CH1.62O0.88
Table II Ultimate analysis result of dry casuarina wood
Element Mass fraction (%)
Carbon 42.83
Nitrogen 0.12
Sulphur 0.42
Hydrogen 6.24
Oxygen 50.39
Molecular Weight 27.89
Set of experiments were conducted in a 10 kg/hr open-
top downdraft gasifier. Ash extraction provision was fixed
at the bottom of the reactor. This ensured continuous
operation for longer durations. Bed temperatures were
measured using K-type thermocouples, placed at 100 mm
distance in the reactor. Exit gas composition was measured
using Sick Maihak S 517 gas analyzer. CO, CO2, CH4, O2
and H2 fractions were measured using the gas-analyzer.
The gas analyzer data were taken at an interval of 30 s. Exit
gas flow rate and air flow rate were measured using a pre-
calibrated venturimeters. So, at any point of time any
changes of air flow-rate into the gasifier were adjusted
using a control valve, thus maintaining desired input mass
flux rate of air or mixture of air, CO2 and O2. Char was
loaded initially up to 300 mm height. Dry biomass
(casuarina wood chips with moisture content < 5%) were
fed above the char bed. Char bed was ignited from ignition
ports and a blower was used to induce air flow inside the
reactor. Reactor was kept under negative suction pressure
throughout the experiments to maintain air flow at required
rate. Once flame reached the wood particles; temperature,
flow and gas composition data were recorded. After 45
minutes of air gasification, exact amount of CO2 were
injected through regulated flow meters from pressurized
CO2 cylinders, by mixing with air at the top. As, CO2
participates in endothermic reactions 3 and 4; introduction
of CO2 induces endothermicity in the system, thus reducing
bed temperatures with increased tar levels. Dasappa has
worked on the modeling of biomass char gasification with
O2/CO2/H2O [14]. Hence arrangement was made to
introduce O2 by mixing it with air and CO2. The flow rates
of O2 and CO2 were measured using pre-calibrated flow
meters.
4 RESULTS AND DISCUSSIONS
Chemical equilibrium analysis has been done under
adiabatic conditions for reaction of biomass employing
Gibbs free energy minimization. NASA SP-273 code was
used for chemical equilibrium analysis. Results were
obtained using air as an oxidizer (Φ = 0.25) and
subsequently adding CO2 as a reactant. Over 45% CO2
conversions were obtained from equilibrium studies.
Reduction in adiabatic temperature was also noted with
increase in CO2 fraction. Addition of CO2 along with air
reduces the O2 fraction, leading to reduction in bed
temperatures and thus the reaction rates. Boudouard
reaction is endothermic in nature and conversion of CO2 to
CO requires high bed temperature to be maintained in
reduction zone. Mixing CO2 with air reduces the volume
fraction of O2 which leads to reduced reaction rates and
subsequently lower conversion rates of biomass/char.
6. Rashbash and Langford [13] and Dasappa [14] suggest
similar findings on working with varying fractions of O2
with wood and char respectively, where flame extinction
was observed at 14% O2 fraction. On mixing 10% CO2, O2
fraction reduces to 19%. Hence, O2 was mixed along with
CO2 to maintain O2 fraction as that in air (21%).
Equilibrium analysis, maintaining O2 fraction as 21% in
inlet gas mixture, results in stable adiabatic flame
temperatures at varying CO2 fractions. Figure 2 shows the
equilibrium analysis results for varying CO2 input fraction.
The results suggest reduction in percent of CO2 conversion
with increase in input CO2 fraction.
In gasification system, which involves, diffusion
limited heterogeneous reactions and heat loss, equilibrium
condition is never attained. But, equilibrium studies
provide us the tool to analyze this system, which in turn
suggests the optimum working conditions. Results of
equilibrium analysis were verified in experiments where
drop in bed temperatures were observed with CO2 as
reactant compared with with air alone. A drop in 50 K was
recorded for 8.5% dilution of CO2 with air. This issue of
drop in bed temperature was resolved after increasing the
inlet O2 fraction to 21% (as that in air).
Figure 2 Equilibrium analysis - CO2 conversion, CO2 and
CO output with varying CO2 input fraction
A gas evolution plot showing the distribution of the
three gases (CO, CO2 and H2) that were monitored while
conducting experiments with 15% CO2 input (by volume
fraction), is shown in Figure 3. It represents the air
gasification composition with and without CO2 injection.
Changes in CO and CO2 fractions occur when CO2 and O2
mixture is injected. After steady operation, CO2 and O2
injection is stopped and volume fraction of CO & CO2
return to its original fractions. Figure 3 clearly shows the
enhanced CO fraction which is the outcome of Boudouard
and water shift reactions. Figure 4 summarizes the results at
different CO2 input fractions. Data points obtained, were
averaged through the several experimental data points, and
were checked for consistency through repeated
experiments. CO2 conversion of 52%-55% was recorded
while varying the CO2 input fraction from 8.5 to15%. It
was observed that there was no appreciable change in H2
fraction in the output gas. CO and CO2 fraction followed
the similar trend as shown in figure 3 with varying CO2
fraction. It enhanced relative cold gas efficiency of system
by up to 30%, as evaluated using equations 18 and 19. CO2
conversion rates were calculated on the basis of measured
input air flow rate, output gas flow rate and char left in the
gasification process.
Gas composition was measured on dry basis. To
account for condensed H2O during cleaning and cooling
process, species balance of C, H and O was performed,
based on exit gas composition, which accounted for 10%
H2O in the producer gas. H2O was accounted for all the
calculations of mass balance to calculate total CO2 fraction
converted and captured in process. CO2 conversion to CO
was calculated as described in the methodology section.
Substituting the parameters in equations 11 – 16, result in
the total CO2 percentage converted. Table III shows carbon
balance for all the sequestration experiments. Case 1
considers Carbon input into the system only in the form of
biomass. Case 2, on the other hand, considers Carbon input
into the system in the form of biomass as well as additional
CO2. The input and output mass flow matches quite
reasonably. It indicates that the CO2 measurements are well
accounted, and proves validity of the CO2 conversion
levels. The results of varying CO2 input fraction are
tabulated in Table III. The lower heating value of the gas
varies from 3.8 to 4.3 MJ/Nm3
.
Table III: Mass balance for CO2conversion
CO2 input
fraction (%)
Input Carbon in kg/hr Output Carbon in kg/hr
Biomass CO2
Total
Input
CO CO2 CH4 Char Total Output
15.0
Case-1 (Air) 4.27 0 4.27 1.37 1.5 0.28 0.99 4.14
Case-2(Air+CO2) 3.30 0.88 4.18 1.51 1.9 0.25 0.77 4.43
12.1
Case-1(Air) 3.71 0 3.71 1.43 1.33 0.2 0.86 3.82
Case-2(Air+CO2) 3.67 0.71 4.38 1.69 1.72 0.2 0.85 4.46
8.5
Case-1(Air) 3.31 0 3.31 1.4 1.35 0.32 0.77 3.84
Case-2(Air+CO2) 2.85 0.45 3.3 1.5 1.57 0.28 0.66 4.01
0
10
20
30
40
50
0
5
10
15
20
25
30
35
40
0 10 12 15 20 25
Volumefraction(%CO,%CO2)
CO2conversion(%)
CO2 input fraction (%)
CO2 Conversion(%) CO CO2
7. CO2Conversion(%)
VolumeFraction(%)
CO2COH2
CO2 input fraction (%)
Figure 5 Experimental results with varying CO2 input
fractions
As seen from equation 10, at high CO2 concentrations,
the last term in the denominator becomes large compared
to the other terms and the rate expression is approximated
as:
2
'''
kc −=ω (19)
This is the rate expression for reaction 3, implying
that this reaction becomes the rate limiting step.
Similarly, at low CO2 concentration the expression can be
approximated as
CO
CO
c
p
k
k
pk
4
3
1'''
1
2
+
−=ω (20)
In this case the rate expression is proportional to the
concentration of CO2 [15]. By mixing CO2 with air as a
gasifying medium, pco2 increases and, as the above
reaction states, the reaction rate of carbon (char) per unit
volume changes. This has also been confirmed with the
experiments conducted and are consistent with the
literature [11]. Introduction of CO2 as a gasifying
medium contributes to better char conversion in reduction
zone.
The increase of CO2 fraction and increase in CO
fraction in producer gas with time can be clearly seen in
the Figure 3. Induction of CO2 in input gasifying medium
increases the fraction of CO2 in the gas passing through
the reduction zone, resulting in further drop in bed
temperature of the reduction zone owing to endothermic
reaction with char (reaction 3). Passing 20% of air
through bottom nozzle helped in maintaining the bed
temperature and thus enhancing the CO2 conversion
process.
4 CONCLUSIONS
The present study suggests that using low
concentration CO2 as in a typical flue gas of a
combustion system, can be used to capture CO2 and
convert to energy. The issues with reduction in O2
fraction were addressed and resolved by maintaining O2
level as in ambient (i.e. 21% by volume). CO2 conversion
of as much as 55% was achieved with CO2 input fraction
of 15%. The enhanced cold gas efficiency was observed
owing to higher char conversion rate.
Figure 4 Gas composition of producer gas with and without injection of CO2
50
52
54
56
CO2 conversion (%)
CO2 conversion (%)
10.0
15.0
20.0
25.0
CO2
CO2
10.0
15.0
20.0
25.0
CO
CO
10.0
15.0
20.0
25.0
0.0 8.5 12.1 15.0
H2
H2
10
12
14
16
18
20
22
6.5 12.5 18.5 24.5 30.5 36.5 42.5 48.5 54.5 60.5 66.5 72.5 78.5 84.5 90.5 96.5 102.5 108.5 114.5 120.5 126.5 132.5 138.5 144.5 150.5
Volumefraction(%)
Time(minutes)
CO CO2 H2
8. 5 ACKNOWLEDGEMENTS
The authors wish to thank Indian Institute of Science
for providing oppurtunity to conduct research work and
support and also thank Ministry of New and Renewable
Energy (MNRE), India, for encouragement and funding
the research project.
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