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International Journal of Scientific and technical research in engineering (IJSTRE)
www.ijstre.com Volume 1 Issue 5 ǁ August 2016.
Manuscript id. 450750616 www.ijstre.com Page 58
Canonical pair of electric flux and magnetic flux in Bohr atom
Hector Torres-Silva,
EIEE,Universidad de Tarapacá, Arica-Chile, Casilla 6-D, htorres@uta.cl
Abstract : The quantum electromagnetic flux is studied as operators for magnetic flux quantization in the
Bohr atom. We find that this quantization rule can be found from an elementary analysis of a Bohr electric
oscillator treated like an L-C circuit. The electromagnetic flux quantization agrees for instanton configuration
so there is no radiation in the Bohr atom and we have a stable atomic system .
Keywords :Quantum optics, L-C circuit quantization, Bohr model
I. Introduction
The magnetic flux quantization ( M.F.Q) was studied by London about the properties of the wave function
phase [1, 2], leading to the experimental discovery of the M.F.Q [3]. Here, the wave function phase is given by
an integration of the vector potential along a path with arbitrary initial point, and end point exactly where we
have the argument of the wave function [4]. In a ring this approach gives the magnetic flux quantization
2
A.dr n
e

  n 1, 2,....   (1)
One of the most important effects of equation (1) is the Aharonov-Bohm effect [5], where two-slit interference
patterns of electrons show the action of the electromagnetic field in regions where it is absent. The clear
interpretation of this phenomenon is by the non local character of the electromagnetic interaction [5].
Here, we adopt the point of view that the electromagnetic flux quantization is a natural consequence of the
principles of quantum electrodynamics. It was suggested that the magnetic flux may be considered as an
operator 
b , whose canonical pair is the electric flux 
e , and that both are linked in a ring by the commutation
rule.
 
e b, i   
 
 (2)
Using this equation and applying a boundary condition on 
e that reflects the charge quantization one arrives at
Eq. (I) [1].
In this paper, section 2 we introduce the electromagnetic field like a wave and we obtain equation (2). In
section3, we show how to derive equation (2) from the quantization of Bohr model like a LC electric oscillator.
In section 4 Energy transformation and conversion in hydrogen atom is discussed.
II. The Electromagnetic Flux Quantization
We will show here how equation (2) can be deduced from the principles of quantum eletrodynamics. Let us take
the usual electromagnetic Lagrangian [1].
1
L F F
4

  (3)
With F A A      
from which we immediately we obtain
0L / A 0  and k 0k kL / A F E   (4)
The quantization of the temporal term will not concern us here. The spatial quantization rule is given by
  3
i j i,jE (x,t),A (y,t) i (x y)     
 
   
(5)
We define the electric flux and magnetic flux operators by
 
ew 1E.dS   (6)
Canonical pair of electric flux and magnetic flux in Bohr atom
Manuscript id. 450750616 www.ijstre.com Page 59
 
bw 2B.dS   (7)
Using equation (5), we obtain
    i j
i jew bw 1 2, E (x,t),A (y,t) dS (x)dl i     
    
  
 (8)
3 i j
i,j 1 2i (x y)dS (x)dl i    
  
 (9)
where we adopted the repeated index sum rule convention.
Here, we claim that the electromagnetic flux quantization is suitable to study non local aspects of
electrodynamics.
This Electromagnetic Flux Quantization (EFQ), corresponds to the configuration  E B , where the Poynting
vector is nonzero so that the Bohr atom would be unstable if we include equation (8) in the original Bohr model.
So what type of wave configuration is suitable for the Bohr model? In reference [6], the author consider that
0
0 0
0


E H when  E B which is wrong as we will see in the next section.
III. Formulation of the Problem of Bohr model like a L- C circuit
In the Bohr model, the radiant electromagnetic field is not considered because the electron to radiate energy fall
spiral into the nucleus. Bohr thought that the atom was stable if electromagnetic wave should not radiate being
the Poynting vector equal to zero, so he does not consider the electromagnetic wave on its own model, [7, 8].
The Born atom like a closed system can be analyzed in terms of capacitive and inductive elements, such as the
classical L-C circuit. The energy stored in C is given by
2
C
Q
U
2C
 (10)
where Q is the charge in the capacitor. But ,Q = 
eQ   where 
e is the electric flux in the capacitor, and 
is the dielectric constant of the capacitor medium. Therefore,
2
2
C eU
2C

  (11)
In the same way, the energy stored in L is given by
2
L
Li
U
2
 (12)
However, from b Li  , where i is the current in the circuit, we have
2
L b
1
U
2L
  (13)
If we consider the photon energy interacting with the system electron-ion, (see section 2)
2 2
w ew bw
1 1
U I
2 2
     (14)
Where I is the interaction between the electron-ion Bohr system and the wave
configuration (photon). Adding (11), (13) and (14), we get the total energy stored in the system.
2
2 2 2 2
e b ew bw
0 0
1 1 1
H I
2C 2L 2 2

        
 
(15)
Using the energy conservation we are led to
2 . . . . .
e b ew bwe b ew bw
0 0
1 1 1
I 0
C L

            
 
(16)
which can be solved by
.
E EW
B BW
H



 

and
.
B BW
E EW
H



  

(17)
Canonical pair of electric flux and magnetic flux in Bohr atom
Manuscript id. 450750616 www.ijstre.com Page 60
This implies that the system described by (15) is Hamiltonian, and the new variables e ew and b bw form a
canonical pair. Since they have, in this system, a role analogous to the (p, q) variables in classical mechanics.
Therefore, the quantization of this system requires
 
e ew b bw, i 
   
 
 (18)
However for an electromagnetic waves the maximum electric field energy is
2
0
1
2
ew WU dv  E and the
maximum magnetic energy is
2
0
1
2
mw WU dv  H with the Maxwell condition  E H . Here, equation (18) is
not satisfied because the terms
. . .
ew bwew bw
0 0
1 1
I     
 
(19)
are not constants so equation (18)is not satisfied.
In reference [6], the author Huang considers that 0
0 0
0


E H when  E B , then equation (18) is not
satisfied. According to our proposal Huang's solution is incorrect or wrong as we will see in the next section
because the atom is unstable.
We intend to use and apply here the E.F.Q presented above before showing how it develops from quantum
electrodynarnics. We think that its "deduction" from the quantization of an L-C circuit is convincing enough to
carry out an immediate study of its applications.
From equation (10) we will build up an approach of the EFQ in which the states will be described in the electric
flux representation. That means that the wave function will be given by
e ew   (20)
and, in order to satisfy equation (10), we make

b bw
e ew
i


  

 (21)
where 
e ew and 
b bw are respectively the total electric and magnetic flux operators.
IV. Energy transformation and conversion in hydrogen atom
In quantum circuit [9], for a lossless LC quantum circuit, which is composed of an inductance L and a
capacitance C , the charge q on the capacitance and the variable p satisfy the commutation relation  Q,p i 
, where p is given by
q
p(t) L
t



. Because the magnetic flux through the inductance
q
p(t) L
t

  

, and
the voltage across the inductance (or the capacitance)
Q
U
C
 , the commutation relation between U and  is:
 C U, i   . (Here, Q , p ,U , are operators in quantum mechanics, C and L are constants ). It means that
any measurement on the magnetic flux  through a solenoid must be with a perturbation on its voltage U.
It should be pointed out that Eq. (18) to (21) are the foundation of our study.
The energy of the electromagnetic wave is
2 2
0 0
1
( )
2
w f w wU U dv    E H (22)
Which diverges when  E B , so equations (18) and (19) are not satisfied because the total energy electron-ion
+ electromagnetic energy +I is not a constant, and the electron emits radiation and spiraling into the
Canonical pair of electric flux and magnetic flux in Bohr atom
Manuscript id. 450750616 www.ijstre.com Page 61
nucleus.These two equations together must indicate a process of perfect periodically transformation of two
forms of energy (kinetic energy
2
/ 2k e LU m u U  and field energy
2
2
f C
Q
U U
C
  ) inside the atom and
the conservation of energy in the system
total C LU U U  (23)
Recall the macroscopic harmonic LC oscillator where two forms of energy, the maximum field energy
2
2
C
Q
U
C
 of the capacitor C (carrying a charge Q ) and the maximum magnetic energy
2
2
L
L
U
L
 of the
inductor L, are mutually interchangeable ( total C LU U U  ) with a exchange periodic 2T LC .
To satisfy equation (21), which is the Bohr equation, the microscopic photon or electromagnetic wave must be
considered as a stationary wave in instanton configuration [8, 9].
The maximum field energy
2
0
1
2
fw wU dv  E (24)
and the maximum magnetic energy
2
0
1
2
mw wU dv  H (25)
must satisfy
0totalw fw kwU U U   , (26)
so the interaction must be
0I  (27)
and
0
0
W Wi


E H . (28)
In this configuration with WE II WH the Pointing vector is 0W W W  P E H , so the Bohr atom is stable.
Following [9], in this reference we show that the quantization appears for the Bohr atom with n as the principal
quantization number.
Based on the above energy relationship for three totally different systems and the requirement of the
electromagnetic interaction (by exchanging photon) between electron and nuclei, we assure that the kinetic
energy of electron, Eq. (21) is a kind of magnetic energy and the hydrogen atom is a natural microscopic LC
oscillator [10].
The Bohr’s model seems newly reconciled with quantum mechanics and yields surprisingly accurate predictions
for hydrogen and other small molecules. Even today the Bohr model has valid roles in describing highly exited
Ryberg atoms cavity quantum electrodynamics and quasi-Ridberg states in graphene. [11]
Conclusion
The quantum approach to the electric and magnetic fluxes was reconsidered. These quantities was treated as
operators, and we discuss how this approach takes into account of the magnetic flux quantization in the Bohr
atom. We discuss the derivation of the electromagnetic flux quantization. We also show that this quantization
rule can be found from an elementary analysis of a Bohr electric oscillator like an L-C circuit including the
electromagnetic wave like an instanton configuration.
References
[1] I.Ventura, Rev. Bras. de Fisica. 19, 45 (1989)
[2] F. London, Super-uids (Wiley, N.Y., 1950), p.152.
[3] R. Do1 and M. Nabauer Phys. Rev. Lett. 7, 51(1961)
[4] P.A.M. Dirac, Proc. Roy. Soc. A 133,60 (1931).
[5] Y. Aharonov and D. Bohm, Phys. Rev. 115, 485 (1959).
[6] X.Q. Huang, arXiv :physics/0601169.
[7] N. Bohr, Phil.Mag. 26, 576 (1913)
Canonical pair of electric flux and magnetic flux in Bohr atom
Manuscript id. 450750616 www.ijstre.com Page 62
[8] H. Torres-Silva, “Chiral Transverse Electromagnetic Standing Waves with E II H in the Dirac Equation
and the Spectra of the Hydrogen Atom,” In: A. Akdagli, Ed., Behavior of Electromagnetic Waves in
Different Media and Structures, Book Intech, 2011, pp. 301-324.
[9] W. H. Louisell Quantum Statistical Properties of Radiation John Wiley & Sons. Inc, 1973.
[10] H. Torres-Silva, A. Souza de Assis, G. Leija-Hernandez and J. Lopez-Bonilla, “Number-phase
quantization for the Bohr atom”, Prespacetime Journal, 2016, vol 7, pp 500-505.
[11] A Svidzinsky et al, “Bohr’s molecular model”. Physics Today, 2014, 33-39.

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Canonical pair of electric flux and magnetic flux in Bohr atom

  • 1. International Journal of Scientific and technical research in engineering (IJSTRE) www.ijstre.com Volume 1 Issue 5 ǁ August 2016. Manuscript id. 450750616 www.ijstre.com Page 58 Canonical pair of electric flux and magnetic flux in Bohr atom Hector Torres-Silva, EIEE,Universidad de Tarapacá, Arica-Chile, Casilla 6-D, htorres@uta.cl Abstract : The quantum electromagnetic flux is studied as operators for magnetic flux quantization in the Bohr atom. We find that this quantization rule can be found from an elementary analysis of a Bohr electric oscillator treated like an L-C circuit. The electromagnetic flux quantization agrees for instanton configuration so there is no radiation in the Bohr atom and we have a stable atomic system . Keywords :Quantum optics, L-C circuit quantization, Bohr model I. Introduction The magnetic flux quantization ( M.F.Q) was studied by London about the properties of the wave function phase [1, 2], leading to the experimental discovery of the M.F.Q [3]. Here, the wave function phase is given by an integration of the vector potential along a path with arbitrary initial point, and end point exactly where we have the argument of the wave function [4]. In a ring this approach gives the magnetic flux quantization 2 A.dr n e    n 1, 2,....   (1) One of the most important effects of equation (1) is the Aharonov-Bohm effect [5], where two-slit interference patterns of electrons show the action of the electromagnetic field in regions where it is absent. The clear interpretation of this phenomenon is by the non local character of the electromagnetic interaction [5]. Here, we adopt the point of view that the electromagnetic flux quantization is a natural consequence of the principles of quantum electrodynamics. It was suggested that the magnetic flux may be considered as an operator  b , whose canonical pair is the electric flux  e , and that both are linked in a ring by the commutation rule.   e b, i       (2) Using this equation and applying a boundary condition on  e that reflects the charge quantization one arrives at Eq. (I) [1]. In this paper, section 2 we introduce the electromagnetic field like a wave and we obtain equation (2). In section3, we show how to derive equation (2) from the quantization of Bohr model like a LC electric oscillator. In section 4 Energy transformation and conversion in hydrogen atom is discussed. II. The Electromagnetic Flux Quantization We will show here how equation (2) can be deduced from the principles of quantum eletrodynamics. Let us take the usual electromagnetic Lagrangian [1]. 1 L F F 4    (3) With F A A       from which we immediately we obtain 0L / A 0  and k 0k kL / A F E   (4) The quantization of the temporal term will not concern us here. The spatial quantization rule is given by   3 i j i,jE (x,t),A (y,t) i (x y)            (5) We define the electric flux and magnetic flux operators by   ew 1E.dS   (6)
  • 2. Canonical pair of electric flux and magnetic flux in Bohr atom Manuscript id. 450750616 www.ijstre.com Page 59   bw 2B.dS   (7) Using equation (5), we obtain     i j i jew bw 1 2, E (x,t),A (y,t) dS (x)dl i               (8) 3 i j i,j 1 2i (x y)dS (x)dl i         (9) where we adopted the repeated index sum rule convention. Here, we claim that the electromagnetic flux quantization is suitable to study non local aspects of electrodynamics. This Electromagnetic Flux Quantization (EFQ), corresponds to the configuration  E B , where the Poynting vector is nonzero so that the Bohr atom would be unstable if we include equation (8) in the original Bohr model. So what type of wave configuration is suitable for the Bohr model? In reference [6], the author consider that 0 0 0 0   E H when  E B which is wrong as we will see in the next section. III. Formulation of the Problem of Bohr model like a L- C circuit In the Bohr model, the radiant electromagnetic field is not considered because the electron to radiate energy fall spiral into the nucleus. Bohr thought that the atom was stable if electromagnetic wave should not radiate being the Poynting vector equal to zero, so he does not consider the electromagnetic wave on its own model, [7, 8]. The Born atom like a closed system can be analyzed in terms of capacitive and inductive elements, such as the classical L-C circuit. The energy stored in C is given by 2 C Q U 2C  (10) where Q is the charge in the capacitor. But ,Q =  eQ   where  e is the electric flux in the capacitor, and  is the dielectric constant of the capacitor medium. Therefore, 2 2 C eU 2C    (11) In the same way, the energy stored in L is given by 2 L Li U 2  (12) However, from b Li  , where i is the current in the circuit, we have 2 L b 1 U 2L   (13) If we consider the photon energy interacting with the system electron-ion, (see section 2) 2 2 w ew bw 1 1 U I 2 2      (14) Where I is the interaction between the electron-ion Bohr system and the wave configuration (photon). Adding (11), (13) and (14), we get the total energy stored in the system. 2 2 2 2 2 e b ew bw 0 0 1 1 1 H I 2C 2L 2 2             (15) Using the energy conservation we are led to 2 . . . . . e b ew bwe b ew bw 0 0 1 1 1 I 0 C L                 (16) which can be solved by . E EW B BW H       and . B BW E EW H        (17)
  • 3. Canonical pair of electric flux and magnetic flux in Bohr atom Manuscript id. 450750616 www.ijstre.com Page 60 This implies that the system described by (15) is Hamiltonian, and the new variables e ew and b bw form a canonical pair. Since they have, in this system, a role analogous to the (p, q) variables in classical mechanics. Therefore, the quantization of this system requires   e ew b bw, i         (18) However for an electromagnetic waves the maximum electric field energy is 2 0 1 2 ew WU dv  E and the maximum magnetic energy is 2 0 1 2 mw WU dv  H with the Maxwell condition  E H . Here, equation (18) is not satisfied because the terms . . . ew bwew bw 0 0 1 1 I        (19) are not constants so equation (18)is not satisfied. In reference [6], the author Huang considers that 0 0 0 0   E H when  E B , then equation (18) is not satisfied. According to our proposal Huang's solution is incorrect or wrong as we will see in the next section because the atom is unstable. We intend to use and apply here the E.F.Q presented above before showing how it develops from quantum electrodynarnics. We think that its "deduction" from the quantization of an L-C circuit is convincing enough to carry out an immediate study of its applications. From equation (10) we will build up an approach of the EFQ in which the states will be described in the electric flux representation. That means that the wave function will be given by e ew   (20) and, in order to satisfy equation (10), we make  b bw e ew i        (21) where  e ew and  b bw are respectively the total electric and magnetic flux operators. IV. Energy transformation and conversion in hydrogen atom In quantum circuit [9], for a lossless LC quantum circuit, which is composed of an inductance L and a capacitance C , the charge q on the capacitance and the variable p satisfy the commutation relation  Q,p i  , where p is given by q p(t) L t    . Because the magnetic flux through the inductance q p(t) L t      , and the voltage across the inductance (or the capacitance) Q U C  , the commutation relation between U and  is:  C U, i   . (Here, Q , p ,U , are operators in quantum mechanics, C and L are constants ). It means that any measurement on the magnetic flux  through a solenoid must be with a perturbation on its voltage U. It should be pointed out that Eq. (18) to (21) are the foundation of our study. The energy of the electromagnetic wave is 2 2 0 0 1 ( ) 2 w f w wU U dv    E H (22) Which diverges when  E B , so equations (18) and (19) are not satisfied because the total energy electron-ion + electromagnetic energy +I is not a constant, and the electron emits radiation and spiraling into the
  • 4. Canonical pair of electric flux and magnetic flux in Bohr atom Manuscript id. 450750616 www.ijstre.com Page 61 nucleus.These two equations together must indicate a process of perfect periodically transformation of two forms of energy (kinetic energy 2 / 2k e LU m u U  and field energy 2 2 f C Q U U C   ) inside the atom and the conservation of energy in the system total C LU U U  (23) Recall the macroscopic harmonic LC oscillator where two forms of energy, the maximum field energy 2 2 C Q U C  of the capacitor C (carrying a charge Q ) and the maximum magnetic energy 2 2 L L U L  of the inductor L, are mutually interchangeable ( total C LU U U  ) with a exchange periodic 2T LC . To satisfy equation (21), which is the Bohr equation, the microscopic photon or electromagnetic wave must be considered as a stationary wave in instanton configuration [8, 9]. The maximum field energy 2 0 1 2 fw wU dv  E (24) and the maximum magnetic energy 2 0 1 2 mw wU dv  H (25) must satisfy 0totalw fw kwU U U   , (26) so the interaction must be 0I  (27) and 0 0 W Wi   E H . (28) In this configuration with WE II WH the Pointing vector is 0W W W  P E H , so the Bohr atom is stable. Following [9], in this reference we show that the quantization appears for the Bohr atom with n as the principal quantization number. Based on the above energy relationship for three totally different systems and the requirement of the electromagnetic interaction (by exchanging photon) between electron and nuclei, we assure that the kinetic energy of electron, Eq. (21) is a kind of magnetic energy and the hydrogen atom is a natural microscopic LC oscillator [10]. The Bohr’s model seems newly reconciled with quantum mechanics and yields surprisingly accurate predictions for hydrogen and other small molecules. Even today the Bohr model has valid roles in describing highly exited Ryberg atoms cavity quantum electrodynamics and quasi-Ridberg states in graphene. [11] Conclusion The quantum approach to the electric and magnetic fluxes was reconsidered. These quantities was treated as operators, and we discuss how this approach takes into account of the magnetic flux quantization in the Bohr atom. We discuss the derivation of the electromagnetic flux quantization. We also show that this quantization rule can be found from an elementary analysis of a Bohr electric oscillator like an L-C circuit including the electromagnetic wave like an instanton configuration. References [1] I.Ventura, Rev. Bras. de Fisica. 19, 45 (1989) [2] F. London, Super-uids (Wiley, N.Y., 1950), p.152. [3] R. Do1 and M. Nabauer Phys. Rev. Lett. 7, 51(1961) [4] P.A.M. Dirac, Proc. Roy. Soc. A 133,60 (1931). [5] Y. Aharonov and D. Bohm, Phys. Rev. 115, 485 (1959). [6] X.Q. Huang, arXiv :physics/0601169. [7] N. Bohr, Phil.Mag. 26, 576 (1913)
  • 5. Canonical pair of electric flux and magnetic flux in Bohr atom Manuscript id. 450750616 www.ijstre.com Page 62 [8] H. Torres-Silva, “Chiral Transverse Electromagnetic Standing Waves with E II H in the Dirac Equation and the Spectra of the Hydrogen Atom,” In: A. Akdagli, Ed., Behavior of Electromagnetic Waves in Different Media and Structures, Book Intech, 2011, pp. 301-324. [9] W. H. Louisell Quantum Statistical Properties of Radiation John Wiley & Sons. Inc, 1973. [10] H. Torres-Silva, A. Souza de Assis, G. Leija-Hernandez and J. Lopez-Bonilla, “Number-phase quantization for the Bohr atom”, Prespacetime Journal, 2016, vol 7, pp 500-505. [11] A Svidzinsky et al, “Bohr’s molecular model”. Physics Today, 2014, 33-39.