This document discusses reaction rates and factors that affect reaction rates. It begins by explaining what reaction rate means and how it can be measured by determining the amount of product formed, reactant used, or time taken for a reaction to complete. It then discusses several factors that affect reaction rates, including temperature, concentration, particle size, and catalysts. Higher temperatures, concentrations, smaller particle sizes, and the presence of catalysts generally increase reaction rates by increasing the frequency and success of particle collisions. The document provides examples and experiments to illustrate these concepts.
This is a summary of the topic "Speed of reactions" in the GCE O levels subject: Chemistry. Students taking either the combined science (chemistry/physics) or pure chemistry will find this useful. These slides are prepared according to the learning outcomes required by the examinations board.
The rate of reaction is the speed at which a reaction proceeds. The factors that affect the rate of a chemical reaction are : nature of reactants, temperature, concentration, size of particle and catalyst.
CONVERSION OF DIMETHYL-NITROBENZENE TO DIMETHY L ANILINE, EFFECT OF SOME PROC...Berklin
The catalytic transfer hydrogenation of dimethyl-nitrobenzene (DN) to Dimethyl-aniline (DA) was studied
in the temperature range 343–403 K
o
, pressure range of 4–10 bar H2 and ethanol as solvent using Pd/C
as catalyst above agitation speed 800 rpm. The substrate feed concentration was varied in the range from
0.124 to 0.745 kmol/m3
while catalyst loading was in the range 4–12% (w/w) of dimethyl-nitrobenzene.
Dimethyl-aniline was the only reaction product, generated through the hydrogenation of the Nitro group of
dimethyl-nitrobenzene. The effects of hydrogen partial pressure, catalyst loading, dimethyl-nitrobenzene
concentration and temperature on the reaction conversion have been reported. Near first-order
dependence on dimethyl-nitrobenzene concentration and hydrogen pressure were observed for the initial
rate of dimethyl-nitrobenzene hydrogenation over the 5% Pd/C catalyst. Furthermore, an increase in the
catalytic activity as the reaction temperature, pressure and weight of catalysts was observed. Conventional
Arrhenius behavior was exhibited by catalyst, Pd/C showed activation energies of 614 J/mol.
This set of powerpoint slides revolves around the topic of chemical kinetics. Are you looking for notes on factors affecting speed of reaction? Looking for foolproof ways to calculate the rate of reaction? You have come to the right place!
Excellent as a chemistry study material and as an examination revision tool :) A short and sweet O level topic guide with the things you need to ace in chemical kinetics!
This is a summary of the topic "Speed of reactions" in the GCE O levels subject: Chemistry. Students taking either the combined science (chemistry/physics) or pure chemistry will find this useful. These slides are prepared according to the learning outcomes required by the examinations board.
The rate of reaction is the speed at which a reaction proceeds. The factors that affect the rate of a chemical reaction are : nature of reactants, temperature, concentration, size of particle and catalyst.
CONVERSION OF DIMETHYL-NITROBENZENE TO DIMETHY L ANILINE, EFFECT OF SOME PROC...Berklin
The catalytic transfer hydrogenation of dimethyl-nitrobenzene (DN) to Dimethyl-aniline (DA) was studied
in the temperature range 343–403 K
o
, pressure range of 4–10 bar H2 and ethanol as solvent using Pd/C
as catalyst above agitation speed 800 rpm. The substrate feed concentration was varied in the range from
0.124 to 0.745 kmol/m3
while catalyst loading was in the range 4–12% (w/w) of dimethyl-nitrobenzene.
Dimethyl-aniline was the only reaction product, generated through the hydrogenation of the Nitro group of
dimethyl-nitrobenzene. The effects of hydrogen partial pressure, catalyst loading, dimethyl-nitrobenzene
concentration and temperature on the reaction conversion have been reported. Near first-order
dependence on dimethyl-nitrobenzene concentration and hydrogen pressure were observed for the initial
rate of dimethyl-nitrobenzene hydrogenation over the 5% Pd/C catalyst. Furthermore, an increase in the
catalytic activity as the reaction temperature, pressure and weight of catalysts was observed. Conventional
Arrhenius behavior was exhibited by catalyst, Pd/C showed activation energies of 614 J/mol.
This set of powerpoint slides revolves around the topic of chemical kinetics. Are you looking for notes on factors affecting speed of reaction? Looking for foolproof ways to calculate the rate of reaction? You have come to the right place!
Excellent as a chemistry study material and as an examination revision tool :) A short and sweet O level topic guide with the things you need to ace in chemical kinetics!
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This unit includes: rate of a chemical reaction, graphs,, unit of rate, average rate& instantaneous rate,. factors influuncing rate of a reaction, Rate expression & rate constant, Order & molecularity of a reaction,, initiall rate method & integrated rate law equations, numerical problems,, Half life period, Pseudo first order reaction, Temperature of rate of reaction, Activation energy, collision frequency & effective collision, Collision theory, Arrhenius equation,, effect of catalyst on rate of reaction, numerical problems
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An EFL lesson about the current events in Palestine. It is intended to be for intermediate students who wish to increase their listening skills through a short lesson in power point.
Biological screening of herbal drugs: Introduction and Need for
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The Roman Empire, a vast and enduring power, stands as one of history's most remarkable civilizations, leaving an indelible imprint on the world. It emerged from the Roman Republic, transitioning into an imperial powerhouse under the leadership of Augustus Caesar in 27 BCE. This transformation marked the beginning of an era defined by unprecedented territorial expansion, architectural marvels, and profound cultural influence.
The empire's roots lie in the city of Rome, founded, according to legend, by Romulus in 753 BCE. Over centuries, Rome evolved from a small settlement to a formidable republic, characterized by a complex political system with elected officials and checks on power. However, internal strife, class conflicts, and military ambitions paved the way for the end of the Republic. Julius Caesar’s dictatorship and subsequent assassination in 44 BCE created a power vacuum, leading to a civil war. Octavian, later Augustus, emerged victorious, heralding the Roman Empire’s birth.
Under Augustus, the empire experienced the Pax Romana, a 200-year period of relative peace and stability. Augustus reformed the military, established efficient administrative systems, and initiated grand construction projects. The empire's borders expanded, encompassing territories from Britain to Egypt and from Spain to the Euphrates. Roman legions, renowned for their discipline and engineering prowess, secured and maintained these vast territories, building roads, fortifications, and cities that facilitated control and integration.
The Roman Empire’s society was hierarchical, with a rigid class system. At the top were the patricians, wealthy elites who held significant political power. Below them were the plebeians, free citizens with limited political influence, and the vast numbers of slaves who formed the backbone of the economy. The family unit was central, governed by the paterfamilias, the male head who held absolute authority.
Culturally, the Romans were eclectic, absorbing and adapting elements from the civilizations they encountered, particularly the Greeks. Roman art, literature, and philosophy reflected this synthesis, creating a rich cultural tapestry. Latin, the Roman language, became the lingua franca of the Western world, influencing numerous modern languages.
Roman architecture and engineering achievements were monumental. They perfected the arch, vault, and dome, constructing enduring structures like the Colosseum, Pantheon, and aqueducts. These engineering marvels not only showcased Roman ingenuity but also served practical purposes, from public entertainment to water supply.
Acetabularia Information For Class 9 .docxvaibhavrinwa19
Acetabularia acetabulum is a single-celled green alga that in its vegetative state is morphologically differentiated into a basal rhizoid and an axially elongated stalk, which bears whorls of branching hairs. The single diploid nucleus resides in the rhizoid.
2024.06.01 Introducing a competency framework for languag learning materials ...Sandy Millin
http://sandymillin.wordpress.com/iateflwebinar2024
Published classroom materials form the basis of syllabuses, drive teacher professional development, and have a potentially huge influence on learners, teachers and education systems. All teachers also create their own materials, whether a few sentences on a blackboard, a highly-structured fully-realised online course, or anything in between. Despite this, the knowledge and skills needed to create effective language learning materials are rarely part of teacher training, and are mostly learnt by trial and error.
Knowledge and skills frameworks, generally called competency frameworks, for ELT teachers, trainers and managers have existed for a few years now. However, until I created one for my MA dissertation, there wasn’t one drawing together what we need to know and do to be able to effectively produce language learning materials.
This webinar will introduce you to my framework, highlighting the key competencies I identified from my research. It will also show how anybody involved in language teaching (any language, not just English!), teacher training, managing schools or developing language learning materials can benefit from using the framework.
Read| The latest issue of The Challenger is here! We are thrilled to announce that our school paper has qualified for the NATIONAL SCHOOLS PRESS CONFERENCE (NSPC) 2024. Thank you for your unwavering support and trust. Dive into the stories that made us stand out!
Welcome to TechSoup New Member Orientation and Q&A (May 2024).pdfTechSoup
In this webinar you will learn how your organization can access TechSoup's wide variety of product discount and donation programs. From hardware to software, we'll give you a tour of the tools available to help your nonprofit with productivity, collaboration, financial management, donor tracking, security, and more.
1. LEARNING OUTCOMES
Explain what is meant by “rate of reaction”;
Interpret graphical diagrammatic presentation of
data obtained in studying rates of reactions
Identify the factors which affect the rate of
reaction
Predict the effect of factors on rates of reaction
from given data
RATES OF REACTIONS
Chapter 14
2. Measuring the Speed of Reaction
Different kinds of reactions take place at different speeds.
Some reactions are very fast e.g. explosion of gases and
chemicals.
On the other hand, some reactions are slow e.g. rusting of
iron and fermentation of sugar to form ethanol.
RATES OF REACTIONS
Chapter 14
3. Rate of reaction
The rate of a reaction tells us how fast or slow a reaction
is taking place.
We can measure the rate of a reaction in 3 ways:
2. Measuring the amount of product formed per unit time
3. Measuring the amount of reactant used up or
remaining per unit time
1. Measuring the time taken for a reaction to complete
RATES OF REACTIONS
Chapter 14
4. Measuring the Rate of Reaction
An experiment was set up to measure the rate of reaction between
magnesium and two different solutions of dilute hydrochloric acid.
hydrochloric acid
(2 mol/dm3
)
hydrochloric acid
(1 mol/dm3
)
magnesium ribbon magnesium ribbon
Experiment I Experiment II
RATES OF REACTIONS
Chapter 14
5. Measuring the time taken for a reaction to complete
If the time taken in Experiment 1 for the magnesium to completely dissolve
in the acid was 60 s, and the time taken in Experiment II was 30 s, then
the speed of the reaction in Experiment II was two times as fast as in
Experiment I.
hydrochloric acid
(2 mol/dm3
)
hydrochloric acid
(1 mol/dm3
)
magnesium ribbon magnesium ribbon
Experiment I Experiment II
RATES OF REACTIONS
Chapter 14
6. It can be seen that the shorter the time
taken for a reaction to complete, the faster
the speed of the reaction.
Thus the speed of a reaction is inversely
proportional to the time taken:
Reaction Rate (speed ) = ___1____
Time taken
Measuring the time taken for a reaction to be
complete
RATES OF REACTIONS
Chapter 14
7. Measuring the amount of product formed in a reaction
An experiment was set up to measure
the rate of reaction between calcium
carbonate and dilute hydrochloric acid.
The CO2 produced is collected in a
gas syringe.
The speed of the reaction can be determined by measuring the
volume of carbon dioxide produced at regular time intervals
during the reaction.
A graph of the volume of gas formed is plotted against time taken.
RATES OF REACTIONS
Chapter 14
8. The gradient becomes zero at 2.5 minutes, showing that no more gas is
produced and the reaction has stopped.
The gradient of the graph is greatest
at the start of the experiment, showing
that the rate of the reaction is fastest at
the start of the experiment.
Measuring the amount of product formed in a reaction
The gradient decreases with time, showing that the rate of the
reaction is decreasing over time.
RATES OF REACTIONS
Chapter 14
9. Rate (Speed) of reaction = Quantity of product formed
Time taken
The rate of reaction at a particular
point P on the graph is given by the
gradient of the graph at P.
Rate of reaction at P = Gradient
= y
x
= 26 cm3
/min
The average rate of reaction over a time interval is given by the formula:
For e.g. average rate for the first 2.5 minutes of the reaction = (70 – 0) cm3
2.5 min
= 28 cm3
/min
Measuring the amount of product formed in a reaction
RATES OF REACTIONS
Chapter 14
10. Measuring the amount of reactant left
The change in mass of the reaction mixture can be read off
from the electronic top pan balance and a graph of mass of
the flask with its contents is plotted against time.
The speed of reaction
between calcium carbonate
and hydrochloric acid can also
be determined by measuring
the loss of mass of the flask as
carbon dioxide escapes from
the reaction mixture.
RATES OF REACTIONS
Chapter 14
11. The gradient of the graph is greatest at the start
of the experiment, hence the speed of the
reaction is greatest at the start of the experiment.
The gradient decreases with time, showing that
the speed of the reaction decreases as time
proceeds.
The gradient is zero after about 4.2 min, showing
that the reaction has stopped.
The reaction has stopped because one of the
reactants (either HCl or CaCO3 ) has been used
up in the reaction.
Measuring the amount of reactant left
RATES OF REACTIONS
Chapter 14
12. Quick check 1
1. Explain what is meant by the “rate of reaction”. How is the reaction
rate related to the time taken for a reaction to complete?
2. How may the speed of chemical reactions be measured
experimentally? Give two examples to illustrate your answer.
3. The graph shows the total volume of
hydrogen produced plotted against
time in a reaction.
Calculate the average rate of the
production of hydrogen.
Solution
RATES OF REACTIONS
Chapter 14
13. 1. The “rate of reaction” tells us how fast or slow a reaction is taking place.
The reaction rate is inversely proportional to the time taken.
2. The speed of a chemical reaction can be measured by:
(i) determining the quantity of product formed per unit time;
E.g. to find the speed of reaction between magnesium and hydrochloric acid, we
can measure the volume of hydrogen produced over a period of time and
determine from the gradient of the volume-time graph, the speed of the reaction
at any particular time interval.
(ii) determining the quantity of reactant used up per unit time.
E.g. to find the speed of reaction between dilute hydrochloric acid and calcium
carbonate, we can measure the loss of mass form the reacting mixture over a
period of time. From the gradient of the mass-time graph, the speed of reaction
can be obtained at any particular time interval.
3. Average rate of the production of hydrogen = 32 cm3
80 s
= 0.4 cm3
/s
Return
Solution to Quick check 1
RATES OF REACTIONS
Chapter 14
14. Effect of Temperature on the Speed of Reactions
We know that food cooks faster when the temperature is
higher. For this reason, a pressure cooker is able to
cook red beans in 30 minutes compared to an ordinary
cooker which may take more than 2 hours. The
temperature in a pressure cooker is about 120 ºC
compared to 100 ºC in an ordinary cooker.
Temperature is a very important factor in the speed of
reaction. In general, the rate of reaction increases two
times for about every 10 ºC rise in temperature.
RATES OF REACTIONS
Chapter 14
Factors Affecting the Speed of Reactions
15. How temperature affects the Speed of Reactions
At higher temperature, the reacting particles move at higher
speeds as they have more kinetic energy.
At higher speeds, the particles collide more often and with
greater force. This leads to more successful collisions and
hence increases the rate of reaction.
RATES OF REACTIONS
Chapter 14
16. Effect of particle size on the speed of reactions
We know that meat and vegetables can be cooked more quickly
by cutting them into smaller pieces.
This is because the smaller the size of the particles, the faster
the rate of a chemical reaction.
When a solid is broken into smaller sizes, the surface area of
the solid is increased, thus exposing more particles of the solid
to the reactant, and more reactions can occur.
RATES OF REACTIONS
Chapter 14
17. Effect of Concentration on Speed of Reactions
We all know that concentrated acids react more vigorously and faster
than dilute acids with metals and other reactants.
Experiment I Experiment II
The speed of reaction in Experiment II was about two times as fast as in
Experiment I. This is because the concentration of the hydrochloric acid in
Experiment II was higher than that of Experiment I.
RATES OF REACTIONS
Chapter 14
18. Effect of concentration on the speed of reaction
In general, the rate of reaction increases when the
concentration of one or more of the reactants is
increased.
This is because a more concentrated solution contains
more particles per unit volume, so there will be more
particles to react with one another.
RATES OF REACTIONS
Chapter 14
19. Effect of pressure on the speed of reactions
Pressure has very little effect on the rate of reactions in solids and liquids, because
they cannot be compressed.
Pressure is important in gases because it has a great effect on the volume of gases.
At higher pressure, gas particles are compressed closer together so there are more
particles per unit volume. This is equivalent to increasing its concentration thus
increasing the rate of reaction.
RATES OF REACTIONS
Chapter 14
20. The Collision Theory
A chemical reaction only occurs when two particles (atoms
or molecules) collide into each other and bond together by
chemical forces.
In order for the particles to be bonded together, the force
of collision must be great enough to overcome the initial
repulsive forces (the activation energy of the reaction).
We can use the collision theory to explain the effect of
temperature and concentration on the rate of reaction.
Pow!Pow! CompoundCompound
formedformed
RATES OF REACTIONS
Chapter 14
21. How concentration affects the speed of reactions
At higher concentration, the number of reacting particles
increases.
The reacting particles are more crowded and there will be
a greater chance for them to meet, therefore resulting in
more collisions.
RATES OF REACTIONS
Chapter 14
22. Some everyday applications of the speed of reactions
When cooking food, we cut them into smaller pieces and use
a higher temperature to make the food cook faster.
To slow down the process of decay, food is kept at a low
temperature in a refrigerator.
To make certain medicines work faster, they are often taken
in powder form and with warm water.
Precaution must be taken in coal mines and flour mills to
prevent explosions due to the fine coal or flour dust particles.
RATES OF REACTIONS
Chapter 14
23. Quick check 2
1. State 3 factors which affect the rate of reactions.
2. The graph below shows the results of an experiment done to compare the
rate of reaction between marble chips and marble powder with dilute
hydrochloric acid.
Graph
A
Graph B
VolofCO2
(a) Which graph shows the reaction between
the acid and (i) marble chips, (ii) marble
powder?
(b) Which graph shows that the rate of
reaction is faster? Explain why.
(c) At what time does the reaction between the marble chips and the acid stop?
(d) State one variable that must be kept constant when carrying out the experiment.
0 1 2 3 4 5 6 7 8 Time/ min
Solution
RATES OF REACTIONS
Chapter 14
24. 3. The following table shows the results of an experiment done to compare
the effect of concentration of sulphuric acid on magnesium.
Test tube No. 1 2 3 4 5
Volume of HCl/ cm3
50 40 30 20 10
Volume of H2O/ cm3
0 10 20 30 40
Total volume/ cm3
50 50 50 50 50
Time taken/ s 10 12 18 25 50
(a) Why are different volumes of water added to each test tube of acid?
(b) In which test tube is the concentration of the acid most concentrated?
(c) In which test tube is the concentration of the acid least concentrated?
(d) Plot a graph of the time taken for the magnesium to dissolve with the volume
of the acid used.
(e) What conclusion can you get from your graph? Solution
RATES OF REACTIONS
Chapter 14
25. 1. Concentration of reactants, temperature and particle size.
2. (a) (i) Marble chips: graph B, (ii) Marble
powder: graph A
(b) Graph A is faster because it has a steeper gradient.
(c) 8 minutes after the start of the reaction.
(d) Concentration of the acid/ Temperature/ Mass of the
calcium carbonate.
Return
Solution to Quick check 2
RATES OF REACTIONS
Chapter 14
26. (a) To make the total volume of each acid solution equal to 50 cm3
.
(b) Most concentrated - Test tube 1
(c) Least concentrated - Test tube 5
(d) A curve with decreasing gradient is obtained.
(e) The speed of the reaction decreases as the concentration of the acid
is decreased.
Graph of Vol. of acid vs Time taken
0
10
20
30
40
50
60
0 10 20 30 40 50 60
Time/s
Vol.ofAcid/cm3
3.
Return
RATES OF REACTIONS
Chapter 14
27. What is a catalyst?
A catalyst is a substance which changes the speed of
a chemical reaction, but is itself chemically unchanged
at the end of the reaction.
Catalysts are very important for making slow chemical
reactions go faster.
RATES OF REACTIONS
Chapter 14
28. A catalyst works by one or both
ways:
1. It provides an alternative
reaction pathway with lower
activation energy. More
particles are able to react
because of the lower activation
energy required.
2. A catalyst (often in finely
divided form) provides a large
surface area for the reactants
to adsorb and brings them into
close contact with one another.
How does a catalyst work?
RATES OF REACTIONS
Chapter 14
29. The chemical industry depends on catalysts for many of
the industrial processes.
Examples are:
Manufacture of ammonia: iron catalyst;
Manufacture of sulphuric acid: vanadium(V) oxide;
Manufacture of margarine: nickel catalyst;
Catalytic converter in motorcars: platinum.
Importance of catalysts
RATES OF REACTIONS
Chapter 14
30. Enzymes
Enzymes are biological catalysts found in plants and
animals. They are mainly made up of proteins.
The enzymes in our bodies enable us to carry out our
bodily functions such as digestion of food and
absorption of nutrients.
E.g. the enzyme amylase catalyses the conversion of
starch that we eat into sugars;
Enzymes present in yeast are used in the making of
bread and wine.
RATES OF REACTIONS
Chapter 14
31. Catalytic decomposition of hydrogen peroxide
We can show the effect of a catalyst
on the speed of a chemical reaction
by carrying out the experiment as
shown in the diagram.
Hydrogen peroxide decomposes
rapidly when a little manganese(IV)
oxide is added as a catalyst.
2H2O2 2H2O + O2
This process is usually used in the
preparation of oxygen in the
laboratory.
H2O2 + MnO2
oxygen
RATES OF REACTIONS
Chapter 14
32. Quick check 3
1. What is a catalyst? Give an example
of the use of a catalyst in a particular
chemical reaction.
2. The graph shows the catalytic
decomposition of hydrogen
peroxide.
2H2O2 2H2O + O2
(a) Which reaction is faster? State two
ways how
you can make the reaction faster.
(b) What is the total volume of oxygen
produced? Calculate the mass of
hydrogen peroxide decomposed.
Solution
RATES OF REACTIONS
Chapter 14
33. 1. A catalyst is a substance which changes the speed of a chemical reaction, but is itself
unchanged after the reaction. E.g. iron in the manufacture of ammonia in the Haber
process.
2.
(a) Reaction A is faster. (i) Use manganese(IV) oxide as catalyst, (ii) Heat the
reacting mixture.
(b) Total volume of oxygen produced = 48 cm3
(0.002 mol)
Mass of hydrogen peroxide = 0.002 mol x 2 x 34 g mol-1
= 0.136 g
Solution to Quick check 3
RATES OF REACTIONS
Chapter 14