This study investigates how ambient temperature affects the performance of a standalone photovoltaic solar system at Nnamdi Azikiwe University, Nigeria, revealing an indirect relationship where power output decreases as temperature increases. Results indicated optimal power generation occurs in cooler conditions, particularly during the rainy season, while high temperatures in the dry season lead to decreased efficiency and energy loss. The findings suggest that PV systems should be installed in well-ventilated areas to maintain lower temperatures for better performance.