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Chemistry
Chapter 2
Chapter 3
“The beauty of a living thing
is not the atoms that go into it
but the way those atoms
are put together...”


                                   Cosmos:
                                   A Personal
                                   Voyage
The Huber
Experiments,
volume 1
http://youtu.be/
xf5QQ3UADRQ
Atoms
The smallest constituent
of matter that has
chemical properties.
Cosmos
PBS, 1980
Protons
Neutrons
Electrons
Isotopes
Isotopes of an element have the same
chemical properties but different nuclear
properties.
The neutron number has drastic effects
on nuclear properties, but its effect on
chemical properties is negligible in
most elements, and still quite small in the case
of the very lightest elements, where it does matter
slightly.



                                   http://en.wikipedia.org/
                                   wiki/Isotopes
Uranium-235
Uranium-238
Electrons are
arranged into shells.
Electrons in the
outermost shell determine
the chemical properties of
the atom.

              http://en.wikipedia.org/wiki/
              Electron_shell
Figure 2-7 Essential Cell Biology (© Garland Science 2010)
Ions
Chemical Substances
“...a form of matter that has constant
chemical composition and characteristic
properties.”



                      http://en.wikipedia.org/wiki/
                      Chemical_substance
Chemical
Bonds
Outer-Shell Electrons
The Octet Rule
Na?Cl?
H?O?
K?O?     Mg?Cl?
         Mg?Br?
         C?O?
         C?S? Ca?
         Cl?
Covalent bond


      –


H
      –
            H             H2, hydrogen gas
       Shared electrons
H2O, water
NaCl
H2O
K2O    MgCl2
       MgBr2
       CO2 / CO
       CS2
       CaCl2
Ionic
Bonds
“...formed through an
electrostatic interaction between
two oppositely charged ions.”


                      http://en.wikipedia.org/
                      wiki/Ionic_bond
http://en.wikipedia.org/
wiki/Potassium_oxide
Covalent
Bonds
a pair of shared electrons
Molecules
Groups of atoms
held together
by covalent bonds.
Covalent bond


                                                                                                   –


                                  H                            H                      H                    H
                                                                                                   –

                                 Hydrogen gas (H2)

                                                                                                   Shared electrons

                                                                       Single
                                               H                       covalent
                                                                       bond
       H                                   –       –

                                       –
                                   –
                                   –                           –

H      C         H           H                 C                        H
                                   –                           –
                                                       –

                                           –       –
       H
                                               H
Methane gas (CH4)                                                                             Double
                                                                                              covalent
                                                                                              bond
                                                                   –                           –
                                                                         –                –
                                                           –                                           –
                                                                                  –
                                                                                  –
             O        O                                                 O         –    O
                                                                                  –
                                                           –                                           –       61
           Oxygen gas (O2)                                         –
                                                                         –                –
                                                                                               –
Polar Covalent Bonds
Intermolecular Forces
van der Waals forces
Hydrogen Bonds
A hydrogen bond is the attractive
interaction of a hydrogen atom with an
electronegative atom, such as nitrogen,
oxygen or fluorine, that comes from
another molecule or chemical group.


                   http://en.wikipedia.org/wiki/
                   Hydrogen_bond
Properties of Water
Hydrophilic
Substances
ethanol
Cohesion
Adhesion
Hydrophobic
Substances
Life
BBC, 2009
Boiling Point
Single
                H               covalent
                                bond
            –       –                           O
        –
    –
    –                       –

H               C                H
    –                       –
                        –                  H              H
            –       –



                H
                                               Single
                                               covalent
                                               bonds
Acids and Bases
H2O     OH-         +    H+

Water   Hydroxide       Hydrogen Ion
pH
pH = -log [H+]
Pure Water
[H+] = 0.0000001 M
     = 10 -7 M

pH = 7
M = moles / liter
1 mole = 6.022 x   1023
        atoms or molecules
Black Coffee
[H+] = 0.00001 M
     = 10 -5 M

pH = 5
Pure Water
pH = 7
Black Coffee
pH = 5
Pure Water
[H+] = 0.0000001 M
     = 10 -7 M

pH = 7
Black Coffee
[H+] = 0.00001 M
     = 10 -5 M

pH = 5
Acids
“Any substance that
dissociates in water
to increase
the concentration of H+...”
Do acids raise or lower
the pH value of a solution?
Aqueous Acids
and
Acidic Solutions
pH < 7
Bases
“A substance that
combines with H+
when dissolved in water...”
Do bases raise or lower
the pH value of a solution?
Aqueous Bases
and
Basic Solutions
pH > 7
Buffers
a substance that
takes up or releases H+ into
solution as the
[H+] of the solution changes
Homeostasis

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Basic Chemistry