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Entropy And Therapeutic Disorders
Because most natural processes are irreversible in the universe, overall, those processes lead to
greater disorder. This is because it requires energy to reorganize things and reverse processes. Even
as I bring order to a messy room, for example, I am using energy that I release in a disorganized
way. For example, my exertion produces sweat that evaporates. The water molecules from my sweat
are more disordered in the atmosphere than they were inside of my body. So even though the room
is more organized, the overall disorder of the universe has increased. We use the word entropy to
describe disorder. Entropy is the measure of the amount of disorder in a system. Remember, all
systems are trying to reach equilibrium, or the lowest energy
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A Research on Inventory Management
Inventory management is a topic that has been captured the attention of academic and business
communities for long time. Of the most important points that investigated by academicians and
practitioners for decades is the selecting of the Economic Order Quantity (EOQ). As the name
suggests, EOQ is the order quantity that minimizes total inventory cost. Despite the many variants
of the EOQ that have appeared in the literature to fine tune it to reality, it still has limitations. A
major one is that it does not take into account the hidden costs inherent in inventory systems. Some
of these costs relate to sustainability issues including environmental, social labor, and economic
effects. This research proposal considers some of these costs, ... Show more content on
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It "frequently manifests itself as a queue; for example, materials may wait to be processed or a plant
is not fully utilized as it waits for materials; machines wait for service or maintenance men wait to
service machines; finished goods wait for customers' orders or customers wait for goods, etc."
(Drechsler, 1968).
To reduce the effect of entropy, Jaber et al. (2004) suggested adding a third cost component
(entropy) when analyzing production and inventory policies. They found that using the entropy cost
approach leads to higher profits than what the classical EOQ model suggests and recommends
ordering in larger quantities less frequently. Their results also showed that reducing the lot size
without considering entropy cost would have opposite result than expected. Thermodynamically,
entropy is related to another property, which is the exergy. Exergy is defined as the useful amount of
energy available. Generally, entropy generation is proportional to exergy consumption (destruction).
As an indicator, exergy can be considered as a good measure of sustainability for each material used.
"Exergy indicators" are based on the exergy content of a resource and the rate of losing that exergy
to the environment. These indicators can assist in the selection of energy and resources that can
minimize the environmental impact in the long term (Koroneos et al., 2012).
The increasing concerns of human societies about sustainable development have interested
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Energy Is The Material Basis For Human Survival
Energy is the material basis for human survival. The issue of energy is a common concern to all
countries in the world because energy is the driving force of economic development, and is also a
key factor in determining the quality of life. At the same time, the ownership of energy not only
affects the world 's political situation but also changes the world peace and tranquility. Energy is
closely bound up with humans' daily life. The presence of energy meets the demands of people basic
necessities of life so that human beings cannot live without energy. The availability of fossil fuels
enables people to get energy conveniently and cheaply. As a result, people have cars to drive, air
conditioners to use, and lights to brighten rooms when the night falls. When the winter and summer
coming, the energy to bring us warm or cool. Human need consumes a lot of energy to develop. At
the beginning of 19th century, due to the extensive use of heat engine, human want to improve the
heat engine efficiency; however, according to the first law of thermodynamics, it is impossible to
manufacture the circulatory heat engine which has 100% efficiency. Thus, it is envisaged that the
manufacture of the second type of perpetual motion machine, from a heat source heat and heat all
into work. However, numerous attempts to prove that the second type of perpetual motion machine
is not achieved. As a future engineer, we need to understand the order and disorder, the entropy and
the thermodynamics.
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The Most Important Fuel Of The World Is Energy Essay
The most important fuel in the world is energy. Energy is the capability to do work or the power
which can make changes in matter. We can use it in different ways in everyday life such as
transportation, entertainment, communication, personal comfort, agriculture and manufacturing. The
world will come to a standstill without energy. The best thing about energy is it can neither be
created nor be destroyed it just changes from one form of matter into another form.1 We can obtain
energy in a useful form by a system called Energy Harnessing Network. In this complicated system
we extract raw energy in the form of heat energy, light energy, solar energy etc and then transformed
it into fuel for example coal, natural gas, petroleum and electrical energy then stored it and use when
needed. The engineers did a lot of work on it and successfully did what was think impossible in the
earlier time. They harnessed energy in many different forms such as hydropower, solar power, wind
mills and nuclear power etc.
There are two main types of energy that is kinetic energy and potential energy. If the object is at rest
then the energy it possess is called potential energy and if the object is in motion then it possess
kinetic energy. A well–known scientist called Gottfried Wilhelm Leibniz, formulated another theory
of movement (flow) in view of kinetic energy and potential energy, which placed space as relative,
though Newton was altogether persuaded that space was outright. An imperative
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Pynchon's Entropy
"ENTROPY" by Thomas PynchonSummary:Meatball Mulligan throws a lease–breaking party at his
apartment in Washington, D.C. in early February of 1957. His guests are a colorful bunch, including
Sandor Rojas, an "ex–Hungarian Freedom fighter," and the avant–garde Duke di Angelis quartet
comprised of Duke, Vincent, Krinkles and Paco who together perform an original piece in complete
silence. Saul, a neighbor of Mulligan's, comes in through the window after an argument with his
wife concerning communication theory and the tendency for noise to "screw up your signal,"
making for "disorganization in the circuit." The party degenerates during the course of the story into
a chaotic mess: more guests arrive with more booze, drunken Navymen barge in ... Show more
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Pynchon also takes the old adage "Write what you know" and posits an addition to the advice: "So
as a corollary to writing about what we know, maybe we should add getting familiar with our
ignorance and the possibilities therein for ruining a good story." In his discussion of this work,
Pynchon takes much care in attempting to explain the significance of the notion of entropy as he
chose to portray it in his story as well as his general take on the concept. [For more information on
the concept of entropy, click on Entropy.] Pynchon is the first to admit, however, that entropy is a
difficult concept to get one's head around: he writes, "Since I wrote this story I have kept trying to
understand entropy, but my grasp becomes less sure the more I read." He beckons us to research the
subject and come up with an understanding of it on our own, for, like Callisto, Pynchon seems to
feel quite strongly that entropy is a concept metaphorically applicable to many aspects of life.
Pynchon credits his major influences in the formulation of "Entropy" as Henry Adams and Norbert
Wiener, author of Cybernetics and the Human Use of Human Beings. He explains "that the `theme'
of the story is mostly derivative of what these two men had to say." Commentary:"Entropy" is
extremely
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The Heat Death of the Universe
The hypothesis about heat death of the universe
Our knowledge of the universe is still negligible, and we can not confidently assert that the universe
is not under the influence of external forces, or may be considered as a thermodynamic system.
However, it is the concept of heat death was the first step to realize the possible finiteness of the
Universe, although we do not know when and on what scenario will happen of its destruction.
At the present stage of existence (13.72 billion years), the universe radiates as a black body with a
temperature of 2,725 K. Its maximum to the frequency 160.4 GHz (microwave radiation), which
corresponds to a wavelength of 1.9 mm. It is isotropic up to 0,001% – the standard deviation of
temperature is ... Show more content on Helpwriting.net ...
Thus, such a state is not in thermal equilibrium, and in fact there is no thermal equilibrium for such
a system, as it is thermodynamically unstable.[8][9] However, in the heat death scenario, the energy
density is so low that the system can be thought of as non–gravitational, such that a state in which
energy is uniformly distributed is a thermal equilibrium state, i.e., the state of maximal entropy.
The final state of the universe depends on the assumptions made about its ultimate fate, and these
assumptions have varied considerably over the late 20th century and early 21st century. In a
"closed" universe that undergoes recollapse, a heat death is expected to occur, with the universe
approaching arbitrarily high temperature and maximal entropy as the end of the collapse approaches.
[citation needed] In an "open" or "flat" universe that continues expanding indefinitely, a heat death
is also expected to occur[citation needed], with the universe cooling to approach absolute zero
temperature and approaching a state of maximal entropy over a very long time period. There is
dispute over whether or not an expanding universe can approach maximal entropy; it has been
proposed that in an expanding universe, the value of maximum entropy increases faster than the
universe gains entropy, causing the
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The, The Irate Lord Is Thermodynamic Standard
In Rifkin 's cosmology, the irate Lord is thermodynamic standard. The principal law of
thermodynamics holds that all vitality is limited, always showing signs of change structure. The
second law holds that vitality dependably moves toward harmony.
As Rifkin focuses out, water streams toward a typical level, and soon thereafter it can no more fall
through a turbine. On the widespread scale, there apparently are no tides to keep the level oceans in
conceivably helpful movement, nor any vanishing to keep hot air rising and poo spouting
descending in interminability.
The universe is not keep running by the handyman 's proverb by any means. Each time vitality is
utilized, a specific sum is lost as warmth. Heat cools and is gone always, a ... Show more content on
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Entropy is somewhat clearly the primal reason for our vitality emergency: we are blazing fossil
powers we can 't supplant, while the supposed atomic arrangement will require more vitality to
develop and keep up than it can ever be relied upon to come back to us.
Entropy, Rifkin additionally contends, is for the most part in charge of not just social and monetary
issues clearly coming about because of the vitality emergency, additionally for issues felt much
sooner than fossil fills ran rare. Issues of scale, for occurrence: a wrongdoing rate duplicating
geometrically as urban areas increment in size. An educational system weakening subjectively, even
as it quantitatively develops.
Here entropy gets to be not a conspicuous, quickly obvious physical rule, but rather an illustration
for what happens when establishments develop so extensive that, as with some parts of the interstate
thruway framework, a bigger number of assets most be spent on upkeep than upon really doing
whatever they should do in any case. The weapons contest, the populace blast, and our present
malignancy scourge, Rifkin cases, are all entropy exemplified.
Maybe, to a degree, since some entropy is inescapable. Yet, the connection between the amount of
data our schools confer and the amount of vitality their physical upkeep exhausts is dubious, no
doubt. We may take the same assets and contract an individual coach for each tyke on low
maintenance
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The Existence Of Life And Energy
Order Disorder
Daniel Singh
Engineering and the Profession
Dr. Leo Oriet
Friday, November 7, 2014
Singh 2 The existence of life and energy has always been questioned. It is not clear as to how life on
earth is sustained by energy and how that energy is produced. The explanation to all of this lies in
the law of conservation of energy and the amazing work done by many intelligent people. Over
many centuries, the development of new technology has furthered studies in science and advanced
the standard of life for many people. The steam engine is one example of this. The creation of the
theory on energy, the works of many scientists, and the theory of entropy explain how energy is used
to sustain life on earth. Without these ... Show more content on Helpwriting.net ...
Energy is always conserved from one item to another, meaning it cannot be created or destroyed in
any way, shape, or form. This is the law of conservation of energy. Energy from the big blast has
been conserved on the earth in plants, minerals, water, and more. Energy is extremely important to
our everyday lives as it is the basis for all life interaction. All living organisms need energy to
sustain life; this energy can be found in food and water. Plants will receive energy from the sun and
humans and animals will receive energy by eating these plants
Singh 3 as well as meat from other animals. In engineering, energy is what powers machinery,
automobiles, and equipment. Engineers have developed many successful operations to harnessing
and manipulating energy. Fossil fuels, nuclear, hydro, solar, and wind power are commonly used
processes that extract useable energy from the earth. These processes utilize refineries for fuel,
nuclear reactions between atoms, hydroelectric power stations, solar panels, and wind turbines to
convert energy from the earth to useable potential energy. This in turn powers the machinery used to
harvest food, build structures, and travel from point A to point B. The concept of energy was in full
effect for millions of years; however, it took many skilled scientists to actually conceptualize it.
Gottfried Leibniz was a
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The Steam Engines: The Power Of War
The existence of our world and everything within depends on the ability of humans to harness and
manipulate energy. It all began with the first ever discovery of heat energy in its primal state, fire.
The Homo erectus were the first ever human species to discover, control and utilize the fire. This
control of heat energy in form of fire was a turning point in the cultural aspect of human evolution
that allowed them to cook food and obtain warmth and protection. Even today energy is vital to
human existence, powering our transports, being utilized in creating structures that power our home
and protect us and lighting our homes. But the real question here is to think what energy really is
and why is it crucial to us. In attempt to answer these ... Show more content on Helpwriting.net ...
By the mid of 19th century, scientists figured out precisely how different forms of energy relate to
each other. They were able to measure how much of a particular type of energy is needed to make a
certain amount of different kind of energy. This idea came to be known as the first law of
thermodynamics. It tells that energy is never created nor destroyed. It just changes from on form to
the other. However the first law of thermodynamics raised some questions like what is going on
when energy changes from one form to the other and why does it happen at all. Rudolf Clausius, an
extraordinarily brilliant scientist not only found the answer but was also the first to offer a coherent,
full blown mathematical analysis of how thermodynamics works. He realized that energy is
conserved and always flow in one direction, from hot to cold. Although it seemed obvious, it was
crucial to his insights. According to Albert Szent–Gyorgyi "Science is to see what everyone else has
seen but to think what nobody else has thought". And Rudolf Clausius like everyone saw that heat
flowed from hot to cold but unlike others he sat down and thought about it. This led to Clausius
forming a mathematical formula which explains that as heat is transferred from hot to cold objects
entropy is increasing. Clausius was so confident about his mathematical analysis that it was easy for
him to claim
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thermo
Chapter 15 (not much on E) Thermodynamics: Enthalpy, Entropy & Gibbs Free Energy Thermo
2 Thermodynamics: thermo = heat (energy) dynamics = movement, motion Some thermodynamic
terms chemists use: System: the portion of the universe that we are considering open system: energy
& matter can transfer closed system: energy transfers only isolated system: no transfers
Surroundings: everything else besides the system Isothermal: a system that is kept at a constant
temperature by adding or subtracting heat from the surroundings. Heat Capacity: the amount of heat
energy required to raise the temperature of a certain amount of material by 1°C (or 1 K). Specific
Heat Capacity: 1 g by 1°C Molar Heat Capacity: 1 ... Show more content on Helpwriting.net ...
Thermo 9 Standard Enthalpy of Formation –– H  f The amount of heat absorbed (endothermic)
or released (exothermic) in a reaction in which one mole of a substance is formed from its elements
in their standard states, usually at 298 K (25°C). Also called heat of formation. H  = 0 for any
element in its standard state (the f natural elemental form at 1 atm or 1 M) at 298 K. EXAMPLES:
C(graphite, s) + O 2 (g) H° = 0 kJ/mol rxn CO2 (g) 0 kJ/mol elements in their standard states
negative sign heat released –– exothermic rxn 393.5 kJ/mol product (one mole) H° (CO2 ) = f
393.5 kJ/mol Thermo 10 2H2 (g) + O 2 (g) H° = 0 kJ/mol rxn 0 kJ/mol 2H2 O (g) 483.6 kJ/ 2
mol elements in their standard states product (two moles) divide by 2 to put on per mole basis!!
negative sign heat released –– exothermic rxn H° (H2 O) = f 241.8 kJ/mol Note that I usually will
not have you calculate Hfº on homeworks or tests – so you generally don't have to worry about
normalizing your answer to a per mole basis. Hess 's Law –– Adding Reactions The overall heat of
reaction (Hrxn) is equal to the sum of the Hf (products) minus the sum of the Hf (reactants):
H° = rxn  (# eqiv) H° (products)  (# eqiv) H° (reactants) f f Therefore, by knowing Hf of
the reactants and products, we can determine the Hrxn for any reaction that involves
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Thermodynamic Optimization of Flow Over an Isothermal...
Boundary layers are thin regions next to the wall in the flow where viscous forces are important.
The above–mentioned wall can be in various geometrical shapes. Blasius [1] studied the simplest
boundary layer over a flat plate. He employed a similarity transformation which reduces the partial
differential boundary layer equations to a nonlinear third–order ordinary differential one before
solving it analytically. The boundary layer flow over a moving plate in a viscous fluid has been
considered by Klemp and Acrivos [2], Hussaini et al. [3], Fang and Zhang [4] and recently Ishak et
al. [5] and Cortell[6] which is an extension of the flow over a static plate considered by Blasius. A
large amount of literatures on this problem has been cited ... Show more content on Helpwriting.net
...
u=∂ψ/∂y and v=–∂ψ/∂x and ν is the kinematic viscosity of the fluid.
Substituting Eqs.(5) and (6) into Eq.(2) we obtained the following ordinary differential equation. f^'''
(η)+f(η)f''(η)=0 (7)
With these boundary conditions:
f(0)=0 ,f^' (0)=λ (8) lim┬(η→∞)⁡
〖f^' (η)〗 = 1
Where λ=u_w/u_∞ is the plate velocity ratio that represents the direction and magnitude of the
moving plate.
The skin friction coefficient C_f can be defined as:
C_f=τ_w/(ρ〖〖 u〗_∞〗^2 ) (9)
Where τ_w is the surface shear stress which is given by: τ_w=├ μ(∂u/∂y)┤| y=0 (10)
Substituting Eqs.(5),(6) into Eqs. (9) and (10) we obtain:
√(2〖Re〗_x ) C_f=f^'' (0) (11)
Where 〖Re〗_x is the local Reynolds number.
Looking for Similarity solution for energy equation, Eq.3, we obtained: θ^'' (η)+Pr f(η) θ^' (η)=0
(12)
Where θ=(T–T_∞)/(T_w–T_∞ ) (13)
Is dimensionless temperature and Pr=ν/α .
The boundary conditions are:
At η=0: θ(0)=1 (14) lim┬(η→∞)⁡
θ(η) = θ(∞)=0
The local Nusselt number〖 Nu〗_x, is defined as:
〖Nu〗_x=(x q_w)/(k (T_w–T_∞)) (15)
Where q_w is the surface heat flux which is: q_w=–k├ ∂T/∂y┤|_(y=0 ) (16)
Using Eq.(5), (6),(15) and (16) we obtain:
〖[〖Re〗_x/2]〗^( –1/2) 〖 Nu〗_x=–θ^' (0) (17)
Works Cited
[1] H. Blasius, Grenzschichten in FlüssigkeitenmitkleinerReibung. Z. Math. Phys. 56 (1908) 1–37.
[2] J.B. Klemp, A. Acrivos, A method for integrating the
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Entropy Lab
Entropy can be defined as the amount of disorder in a system or how dispersed the energy of a
system is. When describing entropy, processes could be described as spontaneous, which proceed
without outside assistance, or non–spontaneous, which requires outside assistance to proceed. In
regards to chemical reactions, the driving force behind them is Gibbs energy (∆G). Overall, Gibbs
energy allows one to determine whether a reaction is spontaneous or non–spontaneous, and
therefore whether it increases or decreases entropy. Additionally, to help with these experimental
calculations, the MeasureNet device was used to facilitate the collection and recording of data. The
overall purpose of this lab was to explore entropy change for two separate ... Show more content on
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For example, when dissolving the samples, too much liquid could have been added, affecting how
saturated the solution was, and ultimately affecting the accuracy of the results. To prevent such an
error, one could gradually add water and patiently mix the solution to make a saturated solution.
Additionally, errors could have come from not making a solution as close to 1.0 M of the compound.
In order to prevent this possible error, one could have calculated the volume of the water (in mL)
needed to make the 1.0 M solution, which would result in having more precise results. Lastly, being
that there are multiple calculations involved, being careful and observant in correctly recording the
values could prevent simple
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Entropy Research Paper
Entropy and Energy Density in A Finite and Infinite Dimensional Universe
Entropy, or disorder, is increasing in the universe and aims to do so until it reaches its maximum
limit or capacity [1]. Energy density, on the other hand, is the amount of energy stored per a given
volume of space [2]. While the total amount of energy in the universe remains constant [3], energy
density decreases as the universe continues to expand.
In an infinite dimensional universe, meaning the universe will continue to expand indefinitely in all
directions, entropy will continue to increase until it eventually reaches its maximum. When this
happens, all energy would have been transformed into the same type of energy and dispersed
equally throughout the whole universe. This would happen because if entropy has reached its
maximum limit, then everything would have already been disordered to its maximum limit. At this
point, the whole universe would then be in equilibrium: the Heat Death of the Universe [4]. Another
possible outcome is that, as the universe is expanding indefinitely, then entropy will also increase
indefinitely and will not be able to reach its maximum limit.
On the other hand, in a finite dimensional universe, meaning the universe will continue to expand
only until a ... Show more content on Helpwriting.net ...
However, once the universe reaches the maximum limit of its expansion, the energy density of the
universe will reach its minimum in the finite dimensional universe, as there will no longer be space
for the universe to expand. At this time, there will be the Big Crunch. During the Big Crunch, the
energy density of the universe will begin to increase again as the volume of the universe continues
to decrease until it reaches the point where it condenses back into a singularity, such as what it was
before the Big Bang. Once it has achieved singularity, that is also where the energy density of the
universe will be at its
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First And Second Laws Of Thermodynamics For Living Systems
1. Explain the consequences of the first and second laws of thermodynamics for living systems. The
first law of thermodynamics states that all energy is constant, which as a consequence, or result,
means that energy can never be produced or destroyed but rather it is transformed. During the
process of energy being transformed some energy is typically lost as heat. Another result of energy
being transformed is the increase of entropy, or disorder. The increase of entropy and loss of energy
is referred to as the second law of thermodynamics.
2. Explain how life is able to adhere to the laws of thermodynamics and accomplish the following
life processes:
a. Growth Living organisms are able to grow as long as cells grow which survive by several inputs,
such as nutrients and oxygen. When cells grow it is typically referring to amount, not size. Cells
multiply by mitosis or meiosis, which require energy to occur. The first law of thermodynamic is
applied in which energy from macromolecules, such as enzymes, are transferred for the cellular
processes can take place, and thus the organism increases in growth.
b. Increase in Order An increase in order would occur when coupling a process that increases
entropy ... Show more content on Helpwriting.net ...
Explain how environmental conditions can affect enzyme function. Provide examples.
Environmental factors that can affect enzyme function include enzyme and substrate concentration,
temperature, pH, salinity, activators, and inhibitors. For example, the ideal temperature for enzymes
to work properly is the normal body temperature of 37°C (98.6°F) and if the body temperature
increases or decreases at a high rate, the enzymes will change and they will no longer be of any use
to the body. Another example would be the salinity, which is the concentration of salt. Change in
salinity disrupts bonds and enzymes are intolerant of extreme
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Enthalpy & Entropy
Experiment
ENTHALPY AND ENTROPY OF ZINC WITH COPPER SULFATE The CCLI Initiative
Computers in Chemistry Laboratory Instruction
LEARNING OBJECTIVES The learning objectives of this experiment are to. . . ! ! determine
changes in enthalpy and entropy of the reaction of zinc with copper sulfate using two methods:
electrochemistry and calorimetry. compare the enthalpy values obtained by the two methods.
BACKGROUND Thermodynamics is concerned with energy changes that occur in chemical and
physical process es. The enthalpy and entropy changes of a system undergoing such processes are
interrelated by the change in free energy, ªG, according to the equation
ªG
=
ªH – T ªS
(1)
This investigation focuses on the reaction Zn(S ) + ... Show more content on Helpwriting.net ...
Let the set–up stand for 15 minutes until the temperature stabilizes. 4. Pour about 5 ml of 0.1 M
KNO3 into the center well. Pour about 5 ml of 0.50 M ZnSO4 into well #1 and about 5 ml of 0.50
M CuSO4 into well #2. 5. With clean tweezers, take a s trip of filter paper and dip one end into the
central well (where immersion in the KNO3 solution will hold one end); dip the other end into well
#1. Repeat this procedure with another strip of filter paper, dipping the other end into well #2. This
creates the salt bridge for your galvanic cell. 6. With clean tweezers take a zinc metal strip and sand
it (on a piece of paper so as not to scratch the table top) to remove any oxide coating. Bend 2 cm of
one end of the ªS trip and immerse it in the ZnSO4 solution (well #1). The rest of the metal strip
(3cm) extends out to the edge of the cell and should be bent over the rim. Repeat the same procedure
with the copper metal strip and place it in well #2. Later the electrical leads (alligator clips ) from
the interface will be attached to the metal strips. 7. Fasten your temperature probe to the ring stand
with a clamp and adjust the temperature probe such that its tip can be immersed in the central well
(KNO3 solution) of the cell. It is assumed that the temperature of the ZnSO4 solution and CuSO4
solution will be very close to the temperature of the KNO3 solution throughout the experiment. 8.
Start the computer program to
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The Touchstone Of Life By Loewenstein
In "The Touchstone of Life", Loewenstein talked about the concept of entropy from the viewpoint of
"information theory." In the thermodynamic viewpoint, the concept of entropy is the "transformation
of heat to work." However, in general chemistry the viewpoint of entropy is the "measure of
disorder." There are some different and similar between 3 viewpoints. The common in 3 viewpoints
are that they were trying to explain the second the law of thermodynamics. Also, Boltzaman stated
that entropy is the measure of the disordered; it is just like information is a measure of order when
we compare that to information theory.
Besides the similarity, the differences between these 3 viewpoints are that the information theory is
defined entropy in the context of probability model to establish a measure for the amount of
information connect with the message. From Shannon's viewpoint, information becomes
mathematically defines quantity that represents the degree of choice applied in forming a particular
symbol or message sequence out of a number of possible ones, and entropy becomes a measure of
the rate of transfer of the information in the message.
The thermodynamic viewpoint is based on described the system with the macroscopically view, and
what we can measure by thermodynamic variables: temperature, pressure, volume, and number of
particles by observe how temperature and heat and its relation to the observed energy and work
measured for the system. When a closed system holds an
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Maxwell's Experiment To Contradict The Second Law Of...
Maxwell's Demon is a thought experiment created by a mathematician James Clerk Maxwell to
contradict the second law of thermodynamics. For example, you have a box filled with a gas (a
mixture of hot and cold molecules) at the same temperature. This means that the temperature can
have an affect on an average speed of the molecules. Some of the molecules will move slower than
average, and some will move faster than the average. Suppose that a divider is placed in the middle
of the box separating the two sides into left and right compartment. Maxwell imagined a demon at
the door would observe the molecules. When a hot molecule approaches the door, the demon opened
the door and the molecule move from the right to the left. When a cold molecule approaches the
door he do not open the door in order to let it be on the right side. Therefore, when he finished the
operations, he has a box in which all the hot molecules are in the left side and all the cold molecules
are in the right side. A heat engine can be run by allows the heat to flow from the hot side to the cold
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Second law of thermodynamics stated, "In any cyclic process the entropy would either increase or
remain the same." (auburn.edu) To explain Maxwell's Demon paradox, scientists draw out that the
demon still need to use energy to observe the molecules, for example, maybe in the form of photons.
In addition, the demon itself and the trap door mechanism would gain entropy from the gas as it
moved the separate door. Thus, the total entropy of the system still increases (auburn.edu). In
chapter 4 of "The Touchstone of Life," Loewenstein stated that the production of macromolecular
information can be as large as you wish, so long as the gain of molecular information (ΔIm) and the
sum of the production of entropy in the macromolecule (ΔSm) and of the entropy in the
environment (ΔSe) balance out:
ΔIm = ΔSe +
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Magnetic Refrigeration
MAGNETIC MAGNETIC REFRIGERATION a fruitful approach to reduce environmental
pollution...
ABSTRACT :
The objective of this effort is to determine the feasibility of designing, fabricating and testing a
sensor cooler, which uses solid materials as the refrigerant. These materials demonstrate the unique
property known as the magneto caloric effect, which means that they increase and decrease in
temperature when magnetized/demagnetized. This effect has been observed for many years and was
used for cooling near absolute zero. Recently, materials are being developed which have sufficient
temperature and entropy change to make them useful for a wide range of temperature applications.
The proposed effort includes magneto caloric effect material ... Show more content on
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This allows it to absorb more unwanted heat, and the cycle begins again.
Producing very low temperature through the process of adiabatic demagnetization can do
refrigeration. The paramagnetic salt is suspended by a thread in a tube containing a low pressure of
gaseous helium to provide thermal communication with the surrounding bath of pumped helium. In
operation the liquid helium bath is cooled by pumping to the lowest practical pressure, usually
achieving a temperature in the neighborhood of 1oK. The temperature of the paramagnetic salt
approaches that of the helium bath by conduction through the exchange gas.
Next the magnetic field is turned on, causing heating of the salt and a decrease in entropy of the
magnetic ions by virtue of their partial alignment in the direction of the applied field. The heat
produced is conducted to the surrounding bath of liquid helium so that the temperature again
approaches 1oK. If the magnetic field is increased slowly the heat can flow out, as it is generated–
the magnetization being almost isothermal. Next the exchange gas surrounding the sample is
removed by pumping, and now, with the salt thermally isolated, the magnetic field is turned off. The
temperature of the sample decreases markedly as a consequence of the adiabatic demagnetization,
which allows the magnetic ions to regain some of their entropy at the
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Essay On Thermodynamics
An Overview of Thermodynamics and Bioenergetics with respect to Biochemistry
What is Thermodynamics?
It is that field of physical science which describes the relationship between heat and other forms of
mechanical, chemical and electrical energy. It basically deals with the basics of heat to the kinetic
theories to the laws of thermodynamics. Thermodynamics is widely used by biochemists to
understand chemical reactions and processes taking place in an organism. Thermodynamics is based
to three laws, out of which the first two are of importance for the biochemists.
First Law Of Thermodynamics
The first law is also known as the the law of conservation of energy. The law states that the energy
can neither be created nor destroyed but it can be changed from one form to another. Meaning
energy in the universe remains constant but can be changed from one form to another. The transfer
of energy from one form to another is an inefficient process. Energy is lost in many ways when
work is done ... Show more content on Helpwriting.net ...
Entropy is basically the measure of energy which is not available in a closed system for mechanical
work or in easier words the degree of randomness in a system. An good biochemical example is that
of proteins. A polypeptide that is folded into a protein is more confined in orientation that that of
unfolded protein chain, which can be freely undergo into any conformation. The polypeptide chain
that is folded has a negative entropy change and the polypeptide that is unfolded, the entropy
increases and the change is positive. Entropy is can only be measured in a closed system. As the
organism is not a closed system, there are a number of difficulties in measuring entropy changes for
biological processes. The Gibbs Free Energy (G) is a better indicator of spontaneous change, as it
takes the enthalpy change into consideration as
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Evaluation Of Single Cylinder Direct Injection Essay
This paper presents exergetic evaluation of single cylinder direct injection, water cooled diesel
engine at varying operating conditions. Normally, first law of thermodynamics has been used to
analyze the engine cycle process. However recent research indicates that the first law of
thermodynamics is inadequate to study the diesel engine performance. Exergy analysis is used to
determine in detail the amounts of losses in a system and locations where they occur, and the
processes that cause them so the application of exergy analysis for diesel engine allows determining
the sources of irreversibilities and obtaining more accurate information about engine efficiency. An
Exergy–based performance analysis is based on the second law of thermodynamics that overcomes
the limitation of an energy–based analysis.
Consider the advantages of second law of thermodynamics over first law, this study includes exergy
analysis of single cylinder, 4–stroke, water cooled, on a single cylinder 8.1 kW direct injection,
diesel engine. In this study first and second laws of thermodynamics ae applied to analyze the
quantity and quality of energy in diesel engine cycle. The experimental data were collected using
steady state test condition which enables the accurate measurements of air, fuel, and cling water
flow rates, engine load, and all relevant temperatures. Each experiment was performed at five
different speeds between 1300 rev/min and 2400 rev/min at intervals of 300 rev/min for five
different
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Energy Is An Important Part Of Human Evolution
Energy has been an important part of human evolution. Ever since human began development,
energy was a major factor. We need energy for everything we do. Heat is one of many types of
energy, and it is a very important type of energy. We use heat to warm our shelter, drive cars. Heat
transfer is one of the most obvious processes in the nature. It occurs at all the places such as
machine, biological creatures, etc... In engineering this heat transfer is a key part of understanding
heat energy. The study of heat behaviour and harnessing heat energy is called thermodynamics.
Thermodynamics is used for many areas such as nuclear power plant, car engines, etc... This essay
will cover topics such as, what is energy, and what makes it useful? , what is thermodynamics,
success rate for harnessing and manipulating energy and how energy is vital to us all and how we
use it.
Firstly, energy is a power produced from physical or chemical resources, such as heat provided to
work the machines. It defines the capacity for doing the work, generating heat, etc... There are many
types of energies such as mechanical, electrical, thermal, nuclear, etc... This essay will cover thermal
energy. Thermal energy is the random motion of particles in the substance. An example of this
situation would be warming a cup of water, where water particles gets in random motion when
heated. The uses of thermal energy are very broad. Thermal energy is used in simple tasks such as a
coffee maker, to a solar plant. It is
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Thermodynamics Of Mixing Of Poly Essay
Thermodynamics Paper: Thermodynamics of mixing of poly(vinyl chloride) and poly(ethylene–co–
vinyl acetate)
Introduction
The mixing of poly(vinyl chloride) (PVC) and poly(ethylene–co–vinyl acetate) (EVA) is
investigated for its thermodynamic properties such as enthalpy of mixing and glass transition
temperature. Both the two pure polymers and the mixtures are investigated in terms of specific heat
as well. The mixing of PVC and EVA are investigated because of the possible use of EVA as a
plasticizer for PVC. The benefit of an EVA plasticizer would not having the need to introduce low
molecular plasticizers [1]. This paper will explore the enthalpy of mixing found throughout the
various mixtures and the indications of these values as well as the excess specific heats. Some
applications of EVA as a plasticizer is also explored.
Theory and Background
The miscibility of PVC and EVA is an example of a miscible blend of homopolymer–copolymer.
This blend is made despite the immiscible behavior of the homopolymers. It as at certain ranges of
copolymer composition that PVC is able to mix with EVA, while being not doing so with
polyethylene and poly (vinyl acetate). It is possible that the two copolymer units' repulsion forces
influence the miscibility based on copolymer composition [1].
Studies show that EVA is able to mix with PVC with a vinyl acetate content range of 45 to 85 wt%.
Differences in results for the range are considered to be due to when the phase separation
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Fine Tuning Research Paper
Science is defined as knowledge covering general truths of the operation of general laws as obtained
and tested through scientific method and concerned with the physical world. The steps of the
scientific method are defining a problem, forming a hypothesis, collecting research and data,
conducting the experiment, and defining the conclusion. Fine tuning is the precision of the physical
constants of nature, as the beginning of the universe requires extremely precise values. These
constants serve to explain the nature of the universe, theories that potentially point to a divine
creator. Evidenced through the initial conditions of the universe, such as the expansion energy and
rate of the Big Bang, the creation of the universe requires such fine–tuned ... Show more content on
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The likelihood of being able to observe another universe is slim because information probably could
not transfer between universes. Besides these reasons, a universe generator itself, or whatever
universe production process would require many constraints and parameters, fine–tuning(!) as well.
According to probability, small patches of order are far more likely that large ones, so the most
probable observable universe would be a small one inhabited by a single simple observer.
Surprisingly, what is actually observed is a vast and fine–tuned universe inhabited by billions of
observers. The laws of nature are definitely hospitable to life, because humans exist. Otherwise,
humans would not exist to notice this. If both necessity and chance are not indicative of the
existence of the universe, finally, design seems to be the most probable option. As said by Fred
Hoyle, "A common sense interpretation of the facts suggests that a super–intellect has monkeyed
with physics... and that there are no blind forces worth speaking about in nature. The numbers one
calculates from the facts seem to me so overwhelming as to put this conclusion almost beyond
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Entropy
SAFETY HANDBOOK
Student's name
Course title
Date
Safety Handbook
Introduction
Safety is the state of serenity being devoid of harm or any form of event that may be considered
non–desirable. In any type of institution, be it, a business, school, industry, laboratory or even the
common workplace, safety plays a major role in ensuring activities run smoothly and no–one gets
hurt while doing their job. Safety encompasses protection from a wide host of potential hazards
which could be physical, financial, emotional or biological. In the common workplace health is a
major concern and infection control is the main aim of a safety handbook. Biosafety in the work
setup starts by assuming every individual is a potential source of infection. ... Show more content on
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Use different or fresh pair of gloves for each procedure or client handled where necessary.3.
Personal items should not be shared e.g. razors, toothbrushes, towels or clothing. B. Cleanliness:
The workplace should be kept clean by carrying out scheduled cleaning procedures on a regular
basis. Spot cleaning should also be done when necessary. Disinfectants should be utilized when
cleaning up bodily fluids e.g. blood. Wash floors and surfaces with a mixture of warm water and
detergent regularly while walls and ceilings should be cleaned periodically. Special procedures
involving isolation of area, wearing protective attire, disinfecting using chlorine for
10mins,irrigation with water, washing with hot water and detergent followed by drying should be
followed when dealing with bodily fluid spillage. C. Disposal of Waste: During disposal of possible
contaminated infectious waste wear appropriate protective attire including heavy duty gloves. Place
the waste in clearly labeled containers and dispose according to EPA regulations. D. Handling
sharps: Contaminated sharp objects should be handled with care e.g. needles should be handled by
their barrel and you should never attempt to bend or re–cap used ones. They should then be placed
in yellow clearly–labeled containers marked with a biohazard symbol. E. Occupational exposure:
In–case of accidental
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Lab Report On Calorimetry
Calorimetry Lab Calorimetry is the science of measuring the change in heat absorbed or released
during a chemical reaction. The change in heat can tell us if the reaction is either exothermic – it
released or heat into surroundings, or endothermic – it absorbed heat from surroundings. The device
used to measure calorimetry is a calorimeter. A calorimeter can range from very expensive lab ones
to coffee styrofoam cups but they are all tightly sealed in order to prevent heat from escaping.
In order to measure the heats of reactions, add the reactants into the calorimeter and measure the
difference between the initial and final temperature. The temperature difference helps us calculate
the heat released or absorbed by the reaction. The equation for calorimetry is q=mc(ΔT). ΔT is the
temperature change, m is the mass, c is the specific heat capacity of the solution, and q is the heat
transfer. Given that the experiment is operated under constant pressure in the lab, the temperature
change is due to the enthalpy of the reaction, therefore the heat of the reaction can be calculated. In
this lab, there are two days. In the first day, there are is part A and part B. Part A is further divided
into three experiments. In experiment one, we were to figure out the heat capacity of the calorimeter
that we made. The next two experiment's goal was to calculate the enthalpy of 2 reactions and using
hess's law, figure out the heat of formation of magnesium oxide. In a reaction, there are
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The Mathematical Theory Of Communication In Thomas...
According to the Merriam Webster dictionary, entropy can be defined as "the degree of disorder or
uncertainty in a system." In his novel, The Crying of Lot 49, Thomas Pynchon manipulates the
definition of the scientific term "entropy" to manifest the innate chaos and disorder in both a closed
thermodynamic system and in the life of the protagonist: Oedipa Maas. In the novel, Oedipa Maas
explores entropy with respect to the thermodynamic sorting of molecules in Maxwell's Demon, and
the communication information regarding the "Tristero". According to Warren Weaver's, Recent
Contributions to The Mathematical Theory of Communication, there are technical, semantic, and
effectiveness problems that may distort the accuracy of communication, ... Show more content on
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Since entropy prospers in closed environments much like Oedipa's life at the beginning of the novel,
Pynchon develops the idea that the chaos in Oedipa's life is subject to increase with the discovery of
more information pointing to the existence of Tristero. This overload of information Oedipa
experiences serves as a roadblock to her understanding of the true meaning behind the Tristero.
According to Warren Weaver, "the entropy in the channel is determined both by what one attempts
to feed into the channel and by the capabilities of the channel to handle different signal situations"
(Weaver, 10). Thus, when Oedipa is fed copious amounts of symbols, words, and theories, she finds
it hard to handle sorting what is real and unreal. This confusion that Oedipa endures is a direct
consequence of the "noise" created by different people, symbols, and word that disrupt Oedipa's
deciphering of the Tristero. Warren Weaver comments on this "noise" seen in Claude Shannon's
communication transmission model, stating that, "If noise is introduced, then the received message
contains certain distortions...that would certainly lead one to say that the received message exhibits,
because of the effects of the noise, an increased uncertainty... If the information source has any
residual uncertainty...then this must be undesirable uncertainty due to noise" (Weaver, 11). This
"undesirable uncertainty due to noise" leads
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The Between Heat And Energy
The term thermodynamics is known as the branch of physics that covers the relationship between
heat or temperature and all the forms of energy, including mechanical, electrical, or chemical.
Thermodynamics is a combination of four laws, which are known as zeroth law of thermodynamics,
first law of thermodynamics, second law of thermodynamics, and third law of thermodynamics.
According to Wolfram, "The relation between heat and energy was important for the development of
steam engines, and in 1824 Sadi Carnot had captured some of the ideas of thermodynamics in his
discussion of the efficiency of an idealized engine" (1019). After this statement was made, scientist
developed its laws. The term thermal equilibrium is when two bodies are at the same temperature.
Therefore, the zeroth law of thermodynamics states that if two bodies are in thermal equilibrium
with a third body, they are all in thermal equilibrium. In other words, they are all have the same
temperature. Joseph Black was one of the first scientist and physic known as founder of the zeroth
law of thermodynamics in the late 18th century.
The first law of thermodynamics states that heat energy can not be created or destroyed. It can be
just transformed into other forms or transferred into another location. Rudolf Clausius and William
Rankine were the first physics that made a full statement of the first law of thermodynamics in 1850.
It is also known as "another version of the law of conservation of energy."
The
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The Behavior Of Binary Alloys
Abstract
The behavior of binary alloys was investigated by the Metropolis Monte Carlo Simulations in
Matlab. Temperatures, alloy concentrations and interaction parameters are variables being varied in
this simulation. Increases in temperature led to an increase in entropy as well as a decrease in
relative correlation of orders. The entropy and enthalpy of mixing both were affected by the alloy
concentration, with a maximum of 50%. Lastly, the interaction parameter defined the type of bonds
that were energetically favorable: for negative bond energies, the alloy consisted of intermetallic
compounds whereas for positive bond energies, the two types of atoms had a tendency to cluster and
thus phase separation occurred. When the bonding energy ... Show more content on Helpwriting.net
...
Although the substitution occurs randomly, an ordered structure can be obtained under certain
conditions. For a binary alloy of A and B metals, there are two types of order: long range and short
range. The first one measures the fraction of metal A atoms positioned on α sites and the second one
is an indicator of the average number of B atoms surrounding an A atom. Depending on the energy
of the bonds between the two metal atoms with each other and themselves, an alloy's ordered state
will vary. The extent to which an alloy becomes ordered under certain conditions depends on which
arrangement is more energetically favored, given by the state's Gibbs energy. For low temperatures,
the Gibbs energy is proportional to the relative concentrations of the two metals and the bond
strengths. Above a critical temperature, the entropy of the solution is dominant and long range order
disappears while the short range order is present to a certain extent. [2] This temperature
dependence has a significant impact on the applications of a certain material.
The two main methods of studying the order and configuration of alloys are X–rays diffuse
scattering and Monte Carlo simulations. The former can be used to study individual "sections" (i.e.
short range order) but is extensive as individual experiments on single crystals are needed. In order
to study the
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BITS F111 2011 12
BIRLA INSTITUTE OF TECHNOLOGY AND SCIENCE, PILANI
INSTRUCTION DIVISION
FIRST SEMESTER 2011‐2012
Course Handout (Part – II)
Date: 02/08/2011
In addition to Part I (General handout for all course appended to timetable), this portion gives
further specific details regarding the course.
Course No. :
Course Title :
Instructor‐in‐Charge
:
Team of Instructors :
1.
2.
3.
4.
BITS F111
Thermodynamics
M S Soni
Sachin U Belgamwar, Dileep Kumar Gupta, Gudla
Prashanth, Priya C Sande, R J Bhargavi, Varinder
Kumar, Navin Singh, P Srinivasan, Rajeev Sharma,
Satish K Dubey, Utkarsh Maheshwari,
Course Description
Concepts and laws ... Show more content on Helpwriting.net ...
tances
8
Work and heat
Definition of work and its identification, work done at the moving boundary
9‐10
Work and heat
Concept of heat, comparison of heat and work,
Engineering Applications
11‐12
First law for control First law for a cycle as well as for a change of state; mass internal energy &
enthalpy
13‐14
First law for control Specific heats; internal energy, enthalpy & specific heat
Text book
Chap/Sec #
2
3.1‐3.3,3.6,
3.7
3.4
4.1, 4.2,
4.3,4.5
4.6, 4.8, 4.9
5.1‐5.5
5.6‐5.8, 5.10
mass
15‐17
18
19‐23
First law for control volume First law for control volume Second Law of
Thermodynamics
24‐29
Entropy
30‐31
Second law for control volume
Second law for control volume
32‐34
35‐39
Irreversibility and availability 40‐41
Thermodynamic relations of ideal gases; first law as a rate equation; problem analysis & solution
technique, Engineering Applications
Conservation of mass in control volume; first law for control volume; SS process; examples of SS
processes
Transient
processes; examples, Engineering
Applications
Limitations of first law & need for the second law;
Reversible process; heat engine, heat pump, refrigerator;
Carnot cycle; Two prepositions regarding efficiency of
Carnot cycle; energy‐conversion efficiency and COP,
Kelvin‐Planck & Clausius statements, The ideal gas
Carnot Cycle, Engineering Applications
Concept
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A World Of Books By Borges
Disorder In A World of Books
In Borges's Ficciones, it is evident that Borges knew a lot about science and scientific writing and
writers. How we as readers know that, is by way of his writing. In his writing he demonstrates that
scientific knowledge by incorporating some aspects in his stories. One of the biggest scientific ideas
that are seen throughout his stories is the idea of entropy. Entropy, in its simplest definition is
defined as, disorder whether it is in society or anywhere else in the universe. This concept of entropy
plays a huge role in many of the stories; it is a critical concept, without it many of those stories
would no longer have their intended meaning. So in this essay we are going to go in more depth and
find out what entropy it really is, as well as look at how it is used as a basis for some of the stories
by Borges. As expressed before, Borges makes this vast knowledge of scientific knowledge known
in his writing. In his stories Borges also demonstrates his understanding of the laws of
thermodynamics. Thermodynamics is the branch of physical science that deals with the relationship
between heat and other forms of energy such as mechanical, electrical, or chemical energy. In
physics, according to the second law of thermodynamics, the total amount of entropy system will
never decrease because the system will try to strike a balance of Thermal equilibrium or in other
words, it will always find a way to go back to order/peace. The systems that
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The Three Laws Of Thermodynamics
Thermodynamics...
Thermodynamics is a branch in physics that deal with heat and temperature and how they are related
with energy and work. There are 3 laws of thermodynamics which are used almost every day and
some of them are present in our body.
Thermoregulation:
Thermoregulation is process by which our body keeps our internal body temperature constant. Our
optimum body temperature is 37°C to 40°C. Whenever our body temperature increases or decreases
our internal system brings our temperature back to normal.
As the second law of thermodynamics states, "the energy will spread from a high concentration to
low concentration or heat moves from high temperature to low temperature", similarly when our
body temperature increases our internal system tries to ... Show more content on Helpwriting.net ...
Higher the entropy the more disordered is the system. As the second law of thermodynamics states,
"the entropy of a system will either increase or remain the same."
Entropy can be used in monitoring a patient's EEG. EEG is Electroencephalography which is a
method used to record a patient's electric activity of the brain. It measure the voltage fluctuation of
ionic current within the neurons of the brain.
Mainly there are two entropy parameters, the fast–reacting Response Entropy (RE) and the more
steady and robust State Entropy (ST). State entropy consists of the entropy of the EEG signals 32
Hz. Response Entropy includes high frequencies up to 47 Hz.
Advantages:
1. Depth of anesthesia used
2. Possibility for the reduction of anesthetic related side effects.
Disadvantages:
1. It is necessary to understand the theoretical foundations that are associated with the design–
which includes basic understanding the relation between GA and consciousness.
Heat:
Heat is the energy that is transferred to and from its surroundings. In medicine heat is used in
treating cancer in two ways hyperthermia and gold nanoparticles.
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Ap Assignment
Focus On Concepts
Section 15.3 The First Law of Thermodynamics
1. The first law of thermodynamics states that the change U in the internal energy of a system is
given by U = Q – W, where Q is the heat and W is the work. Both Q and W can be positive or
negative numbers. Q is a positive number if ________, and W is a positive number if ________. (a)
the system loses heat; work is done by the system (b) the system loses heat; work is done on the
system (c) the system gains heat; work is done by the system (d) the system gains heat; work is done
on the system
Section 15.4 Thermal Processes
4. The drawing shows the expansion of three ideal gases. Rank the gases according to the work they
do, largest to smallest. (a) A, B, C (b) A and B ... Show more content on Helpwriting.net ...
* 18. When a system changes from A to B along the path shown on the pressure–versus–volume
graph, it gains 2700 J of heat. What is the change in the internal energy of the system?
Section 15.5 Thermal Processes Using an Ideal Gas * 28. An ideal gas is taken through the three
processes shown in the drawing. In general, for each process the internal energy U of the gas can
change because heat Q can be added to or removed from the gas and work W can be done by the gas
or on the gas. For the three processes shown in the drawing, fill in the five missing entries in the
following table. * 29. ssm The drawing refers to one mole of a monatomic ideal gas and shows a
process that has four steps, two isobaric (A to B, C to D) and two isochoric (B to C, D to A).
Complete the following table by calculating DU, W, and Q (including the algebraic signs) for each
of the four steps.
–––––––––––––––––––––––––––––––––––––––––––––––––
W Q A to B B to C C to D
–––––––––––––––––––––––––––––––––––––––––––––––––
D to A * 31. The pressure and volume of an ideal monatomic gas change from A to B to C, as the
drawing shows. The curved line between A and C is an isotherm. (a) Determine the total heat for the
process and (b) state whether the flow of heat is into or out of the gas.
Section 15.8 Heat Engines * 48. A 52–kg mountain climber, starting from rest, climbs a
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A Brief Introduction to the Pinch Analysis
The economics of industrial production, limitation of global energy supply, and the realities of
environmental conservation are an enduring concern for all industries. Wherever you turn, there's
another entreaty to save energy, reduce carbon emissions and protect the environment for posterity.
Pinch analysis is a tools used to design a heat exchanger networks (HEN) that reduce the energy
usage. This paper will be about brief introduction for the pinch analysis, application of the second
law of thermodynamics in design heat exchanger network
Pinch Analysis:
Pinch technology is the technology that provides a systematic methodology for energy saving in
processes and total sites. The methodology is based upon first low and second low of ... Show more
content on Helpwriting.net ...
Minimizing the total entropy produced by heat exchanger network lead to minimizing the use of
high energy quality. The entropy can define for single heat exchanger i.e. exchange heat of one hot
stream with one cold stream as
S=∮▒dS=∫▒dq/T
S=∫_(T_Hi)^(T_Ho)▒(C_H dT_H)/T_H –∫_(T_Ci)^(T_Co)▒(C_C dT_C)/T_C
〖S=C〗_C ln⁡
〖(T_Co/T_Ci 〗)–C_H ln⁡
〖(T_Hi/T_Hi 〗)
Sets of heat exchanger network will have constant total entropy when they use same type and
amount of utilities. On the other hand, the entropy will vary for networks having different types and
amount of utilities. The networks' entropy that is used high energy qualities is higher than the one
that used low energy qualities. The changes come from using high energy qualities, and this lead to
have higher temperature different in some heat exchangers, hence high entropy. Due to that, the total
area of the networks also will vary with the use of different utilities since total area is in related with
temperature different in heat exchanger. As the temperature different increase the area will decrease.
Furthermore, total entropy can be used as objected furcation in mathematical programing. Total
entropy can help to find total energy required with from each energy levels in small code.
Case study:
The objective of this case study is show the change of total entropy when different types of utility
used i.e. LP steam, MP steam and HP steam. The case study has three hot streams and three
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Oedipa's Search For Truth In The Crying Of Lot 49
Oedipa's search for truth is caught in a paradox: On one hand, she is (or at least believes she is) in
search of "absolute" meaning; on the other hand, that meaning is concentrated around herself and is
shutting her off from the world around her in a subjective circle of signification where the
communicational void she wishes to escape is filled with illusions of meaning. Oedipa's search is
fueled by a belief that it will bring to an "end her encapsulation in her tower (Pynchon 31)." The
complication to her journey is that all language (truth, communication, meaning, etc....) is founded
in entropy, on a waste of force that alone makes possible the fictional constitution of abstract truth.
In The Crying of Lot 49, Pynchon uses the ideas of entropy in thermodynamics and information
theory (through Maxwell's Demon) to more fully delve into Oedipa's paradoxical search for
meaning in a world that has created, forgotten, and rediscovered it's own truth.
Thermodynamics is the study of the relationship between heat and other energies. It deals with the
changes within a system if the energy distribution in that system is unbalanced. Thermodynamic
entropy is the measure of this chaos in the universe. In beginning of The Crying of Lot 49, Oedipa
Maas realizes that she exists within "the confinement of [a] tower, (11)" that is similar to a closed
system. Entropy thrives in closed systems; therefore, if she does not open her system she is doomed
to slow degradation, till she is nothing
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The Problem Of Arson Investigation
Arson investigation began sometime in the mid 1970's, and has been a process changed and evolved
ever since. The act of arson consists of purposely setting or starting a fire on someone's property,
and can be for a number of reasons anywhere from vandalism, excitement or serial arson, to
revenge, extremism or crime concealment (Newton, M., 15). Some previously "proven" indicators
pointing as to whether or not a fire is an act of arson has been questioned, further researched and
tested. Many of these theories have stated that certain markings, post–fire, could only appear due an
accelerant being used to help engage the fire or intensify it, though recently many of these theories
have been debunked. The truth behind some of these markings ... Show more content on
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One of the most misleading processes that can lead to a wrongful conviction is a term called
flashover. Flashover is what seemingly happens when an entire room is engulfed in fire, and flames
protrude from openings within the building. The process occurs in an enclosed space when particles
and combustible gases begin to cluster close to the ceiling, and then slowly fall towards the floor. At
this point, it is likely that an accumulation of air would rush into the room through windows, doors
or other cavities, and ignite the muddle of particles and gases (Starr, 2011). As this process was not
realized until later when arson investigation became more developed, many explanations as to
whether an accelerant was used to start a fire have been recently proven to be more than likely due
to the effects of a flashover. Some of these beliefs were that melted metals, especially those in or
near doorways, burn marks under pieces of furniture, or on the floor were a sure sign that a liquid
accelerant was used to start the fire. Detectives believed melted metals were a sign of a liquid
accelerant because they thought that temperatures high enough to melt these types of metals were
unattainable without an accelerant. In reality, wood fires commonly reach and exceed the melting
point of metals, especially once they hit
... Get more on HelpWriting.net ...
The Mathematical Theory Of Communication In Thomas...
According to the Merriam Webster dictionary, entropy can be defined as "the degree of disorder or
uncertainty in a system." In his novel, The Crying of Lot 49, Thomas Pynchon manipulates the
definition of the scientific term "entropy" to manifest the innate chaos and disorder in both a closed
thermodynamic system and in the life of the protagonist: Oedipa Maas. In the novel, Oedipa Maas
explores entropy with respect to the thermodynamic sorting of molecules in Maxwell's Demon, and
the communication information regarding the "Tristero". According to Warren Weaver's, Recent
Contributions to The Mathematical Theory of Communication, there are technical, semantic, and
effectiveness problems that may distort the accuracy of communication, ... Show more content on
Helpwriting.net ...
Since entropy prospers in closed environments much like Oedipa's life at the beginning of the novel,
Pynchon develops the idea that the chaos in Oedipa's life is subject to increase with the discovery of
more information pointing to the existence of Tristero. This overload of information Oedipa
experiences serves as a roadblock to her understanding of the true meaning behind the Tristero.
According to Warren Weaver, "the entropy in the channel is determined both by what one attempts
to feed into the channel and by the capabilities of the channel to handle different signal situations"
(Weaver, 10). Thus, when Oedipa is fed copious amounts of symbols, words, and theories, she finds
it hard to handle sorting what is real and unreal. This confusion that Oedipa endures is a direct
consequence of the "noise" created by different people, symbols, and word that disrupt Oedipa's
deciphering of the Tristero. Warren Weaver comments on this "noise" seen in Claude Shannon's
communication transmission model, stating that, "If noise is introduced, then the received message
contains certain distortions...that would certainly lead one to say that the received message exhibits,
because of the effects of the noise, an increased uncertainty... If the information source has any
residual uncertainty...then this must be undesirable uncertainty due to noise" (Weaver, 11). This
"undesirable uncertainty due to noise" leads
... Get more on HelpWriting.net ...
The First Law Of Thermodynamics
Thermodynamics is the study of heat and energy transfer, more specifically how heat transfer relates
to energy changes within a system. The laws of thermodynamics were developed to predict and
outline behaviors of thermodynamic processes (5). The First Law of Thermodynamics states that
"the change in a system 's internal energy is equal to the difference between heat added to the system
from its surroundings and work done by the system on its surroundings" (5). The idea behind this is
conservation of energy, meaning all energy in and out of a system must be accounted for. If energy
is added to a system in the form of heat, it must be used. If heat is added to a system, the system
either performs work (an exothermic process) or changes internal energy (an endothermic process)
(4). Enthalpy, a thermodynamic potential, is the measure of the energy within this system. The
change in enthalpy, H, must be measured in order to find out how energy is transferred throughout a
system. If H has a positive value, the system is endothermic and it will keep the added heat,
increasing its internal energy. If H has a negative value, it means the system lost heat or "did work"
when energy was put into the system, so the system is exothermic (3). Gibbs Free Energy, G, is the
maximum amount of energy or enthalpy available to do work. The decrease in Gibbs Free Energy is
equivalent to the work done by a system to its surroundings, excluding pressure work (5). A negative
G is required for a
... Get more on HelpWriting.net ...
The Theory Of Classical And Quantum Mechanics
If one thought that time and its direction reduce to some reductive base in fundamental physical
science one would encounter a perceived barrier viz., the fact that the underlying dynamical laws of
fundamental physical theory do not privilege the past or the future. If those laws permit certain
physical processes to be future directed or oriented, then they also allow for those self–same
processes to be past directed or oriented. The dynamical laws are time–reversal invariant. As Roger
Penrose stated, ...the dynamical equations of classical and quantum mechanics are symmetrical
under a reversal of the direction of time! As far as mathematics is concerned, one can just as well
specify final conditions, at some remote future time, and evolve ... Show more content on
Helpwriting.net ...
Moreover, we have experimentally confirmed a violation of time reversal invariance in B0 meson
systems. Weakly interacting systems are anomalous for this reason. I will have more to say about
how to understand such systems in the context of discussing the arrow of time. For now, let's
unashamedly affirm that the fundamental dynamical laws are time–reversal invariant, deliberately
suppressing worries about weakly interacting systems for the purposes of deliberation. Even though
the dynamical laws of our fundamental physical theories are time–reversal invariant, there appear to
be macroscopic energetically isolated processes that are temporally irreversible. So the microphysics
is such that it suggests temporal symmetry, though macroscopic goings–on suggest temporal
asymmetry. To make things worse, given an appropriately robust reductionist story in the
background, macroscopic phenomena depend in some strong sense on underlying microphysical
phenomena. We should now ask: "what could be the source of...[the]...widespread temporal bias in
the" macroscopic "world, if the underlying" microphysical "laws are so even–handed?" This is the
puzzle of the arrow of time. Why isn't the temporal handedness accounted for by the phenomenon of
weakly interacting systems previously discussed? Answer: That phenomenon does not occur
frequently enough to serve as
... Get more on HelpWriting.net ...
Time's Arrow by Martin Amis
Time's Arrow by Martin Amis
The human being is an analytical creature. From scientists to philosophers to star–crossed teenaged
lovers, the human is internally motivated to understand the world around him. That world provides
countless puzzles for the human to solve, whether these puzzles lie in the forests of the heart, the
laws of mathematics or the annals of history. However, some of the most unfathomable aspects of
this world have been entirely created by humans. The Holocaust is one of the most unfathomable
events in human history. Countless documentaries, pieces of literature, psychological analyses and
films have explored the topic in an attempt to understand exactly how humans could commit such
terrible atrocities against ... Show more content on Helpwriting.net ...
S. Eddington awarded the second law of thermodynamics "the supreme position among the laws of
Nature" since it alone was responsible for what he was the first to call "time's arrow"... The
directionality of time that results from entropy's increase, Eddington points out, is intimately
installed in our awareness of ourselves in the world, confirmed by human reason, and dependent
upon the fact that there are multiple parts to be organized or disordered (Menke, 970).
Therefore, Eddington claims that the directionality of time is inherently within the human
awareness. Human beings are essentially rational creatures who have an inborn need to make sense
of the ever–increasing disorder in the world around them. We use the constant forward linear march
of time to establish order in a disordered universe in which entropy continually increases.
The Holocaust threatens our attempts to maintain this illusion of order. The extermination at Nazi
camps like Auschwitz was at the same time the most entropic and ordered event in all of human
history. Never before had death, destruction, and the process of dehumanization (all
... Get more on HelpWriting.net ...

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Entropy And Therapeutic Disorders

  • 1. Entropy And Therapeutic Disorders Because most natural processes are irreversible in the universe, overall, those processes lead to greater disorder. This is because it requires energy to reorganize things and reverse processes. Even as I bring order to a messy room, for example, I am using energy that I release in a disorganized way. For example, my exertion produces sweat that evaporates. The water molecules from my sweat are more disordered in the atmosphere than they were inside of my body. So even though the room is more organized, the overall disorder of the universe has increased. We use the word entropy to describe disorder. Entropy is the measure of the amount of disorder in a system. Remember, all systems are trying to reach equilibrium, or the lowest energy ... Get more on HelpWriting.net ...
  • 2.
  • 3. A Research on Inventory Management Inventory management is a topic that has been captured the attention of academic and business communities for long time. Of the most important points that investigated by academicians and practitioners for decades is the selecting of the Economic Order Quantity (EOQ). As the name suggests, EOQ is the order quantity that minimizes total inventory cost. Despite the many variants of the EOQ that have appeared in the literature to fine tune it to reality, it still has limitations. A major one is that it does not take into account the hidden costs inherent in inventory systems. Some of these costs relate to sustainability issues including environmental, social labor, and economic effects. This research proposal considers some of these costs, ... Show more content on Helpwriting.net ... It "frequently manifests itself as a queue; for example, materials may wait to be processed or a plant is not fully utilized as it waits for materials; machines wait for service or maintenance men wait to service machines; finished goods wait for customers' orders or customers wait for goods, etc." (Drechsler, 1968). To reduce the effect of entropy, Jaber et al. (2004) suggested adding a third cost component (entropy) when analyzing production and inventory policies. They found that using the entropy cost approach leads to higher profits than what the classical EOQ model suggests and recommends ordering in larger quantities less frequently. Their results also showed that reducing the lot size without considering entropy cost would have opposite result than expected. Thermodynamically, entropy is related to another property, which is the exergy. Exergy is defined as the useful amount of energy available. Generally, entropy generation is proportional to exergy consumption (destruction). As an indicator, exergy can be considered as a good measure of sustainability for each material used. "Exergy indicators" are based on the exergy content of a resource and the rate of losing that exergy to the environment. These indicators can assist in the selection of energy and resources that can minimize the environmental impact in the long term (Koroneos et al., 2012). The increasing concerns of human societies about sustainable development have interested ... Get more on HelpWriting.net ...
  • 4.
  • 5. Energy Is The Material Basis For Human Survival Energy is the material basis for human survival. The issue of energy is a common concern to all countries in the world because energy is the driving force of economic development, and is also a key factor in determining the quality of life. At the same time, the ownership of energy not only affects the world 's political situation but also changes the world peace and tranquility. Energy is closely bound up with humans' daily life. The presence of energy meets the demands of people basic necessities of life so that human beings cannot live without energy. The availability of fossil fuels enables people to get energy conveniently and cheaply. As a result, people have cars to drive, air conditioners to use, and lights to brighten rooms when the night falls. When the winter and summer coming, the energy to bring us warm or cool. Human need consumes a lot of energy to develop. At the beginning of 19th century, due to the extensive use of heat engine, human want to improve the heat engine efficiency; however, according to the first law of thermodynamics, it is impossible to manufacture the circulatory heat engine which has 100% efficiency. Thus, it is envisaged that the manufacture of the second type of perpetual motion machine, from a heat source heat and heat all into work. However, numerous attempts to prove that the second type of perpetual motion machine is not achieved. As a future engineer, we need to understand the order and disorder, the entropy and the thermodynamics. ... Get more on HelpWriting.net ...
  • 6.
  • 7. The Most Important Fuel Of The World Is Energy Essay The most important fuel in the world is energy. Energy is the capability to do work or the power which can make changes in matter. We can use it in different ways in everyday life such as transportation, entertainment, communication, personal comfort, agriculture and manufacturing. The world will come to a standstill without energy. The best thing about energy is it can neither be created nor be destroyed it just changes from one form of matter into another form.1 We can obtain energy in a useful form by a system called Energy Harnessing Network. In this complicated system we extract raw energy in the form of heat energy, light energy, solar energy etc and then transformed it into fuel for example coal, natural gas, petroleum and electrical energy then stored it and use when needed. The engineers did a lot of work on it and successfully did what was think impossible in the earlier time. They harnessed energy in many different forms such as hydropower, solar power, wind mills and nuclear power etc. There are two main types of energy that is kinetic energy and potential energy. If the object is at rest then the energy it possess is called potential energy and if the object is in motion then it possess kinetic energy. A well–known scientist called Gottfried Wilhelm Leibniz, formulated another theory of movement (flow) in view of kinetic energy and potential energy, which placed space as relative, though Newton was altogether persuaded that space was outright. An imperative ... Get more on HelpWriting.net ...
  • 8.
  • 9. Pynchon's Entropy "ENTROPY" by Thomas PynchonSummary:Meatball Mulligan throws a lease–breaking party at his apartment in Washington, D.C. in early February of 1957. His guests are a colorful bunch, including Sandor Rojas, an "ex–Hungarian Freedom fighter," and the avant–garde Duke di Angelis quartet comprised of Duke, Vincent, Krinkles and Paco who together perform an original piece in complete silence. Saul, a neighbor of Mulligan's, comes in through the window after an argument with his wife concerning communication theory and the tendency for noise to "screw up your signal," making for "disorganization in the circuit." The party degenerates during the course of the story into a chaotic mess: more guests arrive with more booze, drunken Navymen barge in ... Show more content on Helpwriting.net ... Pynchon also takes the old adage "Write what you know" and posits an addition to the advice: "So as a corollary to writing about what we know, maybe we should add getting familiar with our ignorance and the possibilities therein for ruining a good story." In his discussion of this work, Pynchon takes much care in attempting to explain the significance of the notion of entropy as he chose to portray it in his story as well as his general take on the concept. [For more information on the concept of entropy, click on Entropy.] Pynchon is the first to admit, however, that entropy is a difficult concept to get one's head around: he writes, "Since I wrote this story I have kept trying to understand entropy, but my grasp becomes less sure the more I read." He beckons us to research the subject and come up with an understanding of it on our own, for, like Callisto, Pynchon seems to feel quite strongly that entropy is a concept metaphorically applicable to many aspects of life. Pynchon credits his major influences in the formulation of "Entropy" as Henry Adams and Norbert Wiener, author of Cybernetics and the Human Use of Human Beings. He explains "that the `theme' of the story is mostly derivative of what these two men had to say." Commentary:"Entropy" is extremely ... Get more on HelpWriting.net ...
  • 10.
  • 11. The Heat Death of the Universe The hypothesis about heat death of the universe Our knowledge of the universe is still negligible, and we can not confidently assert that the universe is not under the influence of external forces, or may be considered as a thermodynamic system. However, it is the concept of heat death was the first step to realize the possible finiteness of the Universe, although we do not know when and on what scenario will happen of its destruction. At the present stage of existence (13.72 billion years), the universe radiates as a black body with a temperature of 2,725 K. Its maximum to the frequency 160.4 GHz (microwave radiation), which corresponds to a wavelength of 1.9 mm. It is isotropic up to 0,001% – the standard deviation of temperature is ... Show more content on Helpwriting.net ... Thus, such a state is not in thermal equilibrium, and in fact there is no thermal equilibrium for such a system, as it is thermodynamically unstable.[8][9] However, in the heat death scenario, the energy density is so low that the system can be thought of as non–gravitational, such that a state in which energy is uniformly distributed is a thermal equilibrium state, i.e., the state of maximal entropy. The final state of the universe depends on the assumptions made about its ultimate fate, and these assumptions have varied considerably over the late 20th century and early 21st century. In a "closed" universe that undergoes recollapse, a heat death is expected to occur, with the universe approaching arbitrarily high temperature and maximal entropy as the end of the collapse approaches. [citation needed] In an "open" or "flat" universe that continues expanding indefinitely, a heat death is also expected to occur[citation needed], with the universe cooling to approach absolute zero temperature and approaching a state of maximal entropy over a very long time period. There is dispute over whether or not an expanding universe can approach maximal entropy; it has been proposed that in an expanding universe, the value of maximum entropy increases faster than the universe gains entropy, causing the ... Get more on HelpWriting.net ...
  • 12.
  • 13. The, The Irate Lord Is Thermodynamic Standard In Rifkin 's cosmology, the irate Lord is thermodynamic standard. The principal law of thermodynamics holds that all vitality is limited, always showing signs of change structure. The second law holds that vitality dependably moves toward harmony. As Rifkin focuses out, water streams toward a typical level, and soon thereafter it can no more fall through a turbine. On the widespread scale, there apparently are no tides to keep the level oceans in conceivably helpful movement, nor any vanishing to keep hot air rising and poo spouting descending in interminability. The universe is not keep running by the handyman 's proverb by any means. Each time vitality is utilized, a specific sum is lost as warmth. Heat cools and is gone always, a ... Show more content on Helpwriting.net ... Entropy is somewhat clearly the primal reason for our vitality emergency: we are blazing fossil powers we can 't supplant, while the supposed atomic arrangement will require more vitality to develop and keep up than it can ever be relied upon to come back to us. Entropy, Rifkin additionally contends, is for the most part in charge of not just social and monetary issues clearly coming about because of the vitality emergency, additionally for issues felt much sooner than fossil fills ran rare. Issues of scale, for occurrence: a wrongdoing rate duplicating geometrically as urban areas increment in size. An educational system weakening subjectively, even as it quantitatively develops. Here entropy gets to be not a conspicuous, quickly obvious physical rule, but rather an illustration for what happens when establishments develop so extensive that, as with some parts of the interstate thruway framework, a bigger number of assets most be spent on upkeep than upon really doing whatever they should do in any case. The weapons contest, the populace blast, and our present malignancy scourge, Rifkin cases, are all entropy exemplified. Maybe, to a degree, since some entropy is inescapable. Yet, the connection between the amount of data our schools confer and the amount of vitality their physical upkeep exhausts is dubious, no doubt. We may take the same assets and contract an individual coach for each tyke on low maintenance ... Get more on HelpWriting.net ...
  • 14.
  • 15. The Existence Of Life And Energy Order Disorder Daniel Singh Engineering and the Profession Dr. Leo Oriet Friday, November 7, 2014 Singh 2 The existence of life and energy has always been questioned. It is not clear as to how life on earth is sustained by energy and how that energy is produced. The explanation to all of this lies in the law of conservation of energy and the amazing work done by many intelligent people. Over many centuries, the development of new technology has furthered studies in science and advanced the standard of life for many people. The steam engine is one example of this. The creation of the theory on energy, the works of many scientists, and the theory of entropy explain how energy is used to sustain life on earth. Without these ... Show more content on Helpwriting.net ... Energy is always conserved from one item to another, meaning it cannot be created or destroyed in any way, shape, or form. This is the law of conservation of energy. Energy from the big blast has been conserved on the earth in plants, minerals, water, and more. Energy is extremely important to our everyday lives as it is the basis for all life interaction. All living organisms need energy to sustain life; this energy can be found in food and water. Plants will receive energy from the sun and humans and animals will receive energy by eating these plants Singh 3 as well as meat from other animals. In engineering, energy is what powers machinery, automobiles, and equipment. Engineers have developed many successful operations to harnessing and manipulating energy. Fossil fuels, nuclear, hydro, solar, and wind power are commonly used processes that extract useable energy from the earth. These processes utilize refineries for fuel, nuclear reactions between atoms, hydroelectric power stations, solar panels, and wind turbines to convert energy from the earth to useable potential energy. This in turn powers the machinery used to harvest food, build structures, and travel from point A to point B. The concept of energy was in full effect for millions of years; however, it took many skilled scientists to actually conceptualize it. Gottfried Leibniz was a ... Get more on HelpWriting.net ...
  • 16.
  • 17. The Steam Engines: The Power Of War The existence of our world and everything within depends on the ability of humans to harness and manipulate energy. It all began with the first ever discovery of heat energy in its primal state, fire. The Homo erectus were the first ever human species to discover, control and utilize the fire. This control of heat energy in form of fire was a turning point in the cultural aspect of human evolution that allowed them to cook food and obtain warmth and protection. Even today energy is vital to human existence, powering our transports, being utilized in creating structures that power our home and protect us and lighting our homes. But the real question here is to think what energy really is and why is it crucial to us. In attempt to answer these ... Show more content on Helpwriting.net ... By the mid of 19th century, scientists figured out precisely how different forms of energy relate to each other. They were able to measure how much of a particular type of energy is needed to make a certain amount of different kind of energy. This idea came to be known as the first law of thermodynamics. It tells that energy is never created nor destroyed. It just changes from on form to the other. However the first law of thermodynamics raised some questions like what is going on when energy changes from one form to the other and why does it happen at all. Rudolf Clausius, an extraordinarily brilliant scientist not only found the answer but was also the first to offer a coherent, full blown mathematical analysis of how thermodynamics works. He realized that energy is conserved and always flow in one direction, from hot to cold. Although it seemed obvious, it was crucial to his insights. According to Albert Szent–Gyorgyi "Science is to see what everyone else has seen but to think what nobody else has thought". And Rudolf Clausius like everyone saw that heat flowed from hot to cold but unlike others he sat down and thought about it. This led to Clausius forming a mathematical formula which explains that as heat is transferred from hot to cold objects entropy is increasing. Clausius was so confident about his mathematical analysis that it was easy for him to claim ... Get more on HelpWriting.net ...
  • 18.
  • 19. thermo Chapter 15 (not much on E) Thermodynamics: Enthalpy, Entropy & Gibbs Free Energy Thermo 2 Thermodynamics: thermo = heat (energy) dynamics = movement, motion Some thermodynamic terms chemists use: System: the portion of the universe that we are considering open system: energy & matter can transfer closed system: energy transfers only isolated system: no transfers Surroundings: everything else besides the system Isothermal: a system that is kept at a constant temperature by adding or subtracting heat from the surroundings. Heat Capacity: the amount of heat energy required to raise the temperature of a certain amount of material by 1°C (or 1 K). Specific Heat Capacity: 1 g by 1°C Molar Heat Capacity: 1 ... Show more content on Helpwriting.net ... Thermo 9 Standard Enthalpy of Formation –– H  f The amount of heat absorbed (endothermic) or released (exothermic) in a reaction in which one mole of a substance is formed from its elements in their standard states, usually at 298 K (25°C). Also called heat of formation. H  = 0 for any element in its standard state (the f natural elemental form at 1 atm or 1 M) at 298 K. EXAMPLES: C(graphite, s) + O 2 (g) H° = 0 kJ/mol rxn CO2 (g) 0 kJ/mol elements in their standard states negative sign heat released –– exothermic rxn 393.5 kJ/mol product (one mole) H° (CO2 ) = f 393.5 kJ/mol Thermo 10 2H2 (g) + O 2 (g) H° = 0 kJ/mol rxn 0 kJ/mol 2H2 O (g) 483.6 kJ/ 2 mol elements in their standard states product (two moles) divide by 2 to put on per mole basis!! negative sign heat released –– exothermic rxn H° (H2 O) = f 241.8 kJ/mol Note that I usually will not have you calculate Hfº on homeworks or tests – so you generally don't have to worry about normalizing your answer to a per mole basis. Hess 's Law –– Adding Reactions The overall heat of reaction (Hrxn) is equal to the sum of the Hf (products) minus the sum of the Hf (reactants): H° = rxn  (# eqiv) H° (products)  (# eqiv) H° (reactants) f f Therefore, by knowing Hf of the reactants and products, we can determine the Hrxn for any reaction that involves ... Get more on HelpWriting.net ...
  • 20.
  • 21. Thermodynamic Optimization of Flow Over an Isothermal... Boundary layers are thin regions next to the wall in the flow where viscous forces are important. The above–mentioned wall can be in various geometrical shapes. Blasius [1] studied the simplest boundary layer over a flat plate. He employed a similarity transformation which reduces the partial differential boundary layer equations to a nonlinear third–order ordinary differential one before solving it analytically. The boundary layer flow over a moving plate in a viscous fluid has been considered by Klemp and Acrivos [2], Hussaini et al. [3], Fang and Zhang [4] and recently Ishak et al. [5] and Cortell[6] which is an extension of the flow over a static plate considered by Blasius. A large amount of literatures on this problem has been cited ... Show more content on Helpwriting.net ... u=∂ψ/∂y and v=–∂ψ/∂x and ν is the kinematic viscosity of the fluid. Substituting Eqs.(5) and (6) into Eq.(2) we obtained the following ordinary differential equation. f^''' (η)+f(η)f''(η)=0 (7) With these boundary conditions: f(0)=0 ,f^' (0)=λ (8) lim┬(η→∞)⁡ 〖f^' (η)〗 = 1 Where λ=u_w/u_∞ is the plate velocity ratio that represents the direction and magnitude of the moving plate. The skin friction coefficient C_f can be defined as: C_f=τ_w/(ρ〖〖 u〗_∞〗^2 ) (9) Where τ_w is the surface shear stress which is given by: τ_w=├ μ(∂u/∂y)┤| y=0 (10) Substituting Eqs.(5),(6) into Eqs. (9) and (10) we obtain: √(2〖Re〗_x ) C_f=f^'' (0) (11) Where 〖Re〗_x is the local Reynolds number. Looking for Similarity solution for energy equation, Eq.3, we obtained: θ^'' (η)+Pr f(η) θ^' (η)=0 (12) Where θ=(T–T_∞)/(T_w–T_∞ ) (13) Is dimensionless temperature and Pr=ν/α . The boundary conditions are:
  • 22. At η=0: θ(0)=1 (14) lim┬(η→∞)⁡ θ(η) = θ(∞)=0 The local Nusselt number〖 Nu〗_x, is defined as: 〖Nu〗_x=(x q_w)/(k (T_w–T_∞)) (15) Where q_w is the surface heat flux which is: q_w=–k├ ∂T/∂y┤|_(y=0 ) (16) Using Eq.(5), (6),(15) and (16) we obtain: 〖[〖Re〗_x/2]〗^( –1/2) 〖 Nu〗_x=–θ^' (0) (17) Works Cited [1] H. Blasius, Grenzschichten in FlüssigkeitenmitkleinerReibung. Z. Math. Phys. 56 (1908) 1–37. [2] J.B. Klemp, A. Acrivos, A method for integrating the ... Get more on HelpWriting.net ...
  • 23.
  • 24. Entropy Lab Entropy can be defined as the amount of disorder in a system or how dispersed the energy of a system is. When describing entropy, processes could be described as spontaneous, which proceed without outside assistance, or non–spontaneous, which requires outside assistance to proceed. In regards to chemical reactions, the driving force behind them is Gibbs energy (∆G). Overall, Gibbs energy allows one to determine whether a reaction is spontaneous or non–spontaneous, and therefore whether it increases or decreases entropy. Additionally, to help with these experimental calculations, the MeasureNet device was used to facilitate the collection and recording of data. The overall purpose of this lab was to explore entropy change for two separate ... Show more content on Helpwriting.net ... For example, when dissolving the samples, too much liquid could have been added, affecting how saturated the solution was, and ultimately affecting the accuracy of the results. To prevent such an error, one could gradually add water and patiently mix the solution to make a saturated solution. Additionally, errors could have come from not making a solution as close to 1.0 M of the compound. In order to prevent this possible error, one could have calculated the volume of the water (in mL) needed to make the 1.0 M solution, which would result in having more precise results. Lastly, being that there are multiple calculations involved, being careful and observant in correctly recording the values could prevent simple ... Get more on HelpWriting.net ...
  • 25.
  • 26. Entropy Research Paper Entropy and Energy Density in A Finite and Infinite Dimensional Universe Entropy, or disorder, is increasing in the universe and aims to do so until it reaches its maximum limit or capacity [1]. Energy density, on the other hand, is the amount of energy stored per a given volume of space [2]. While the total amount of energy in the universe remains constant [3], energy density decreases as the universe continues to expand. In an infinite dimensional universe, meaning the universe will continue to expand indefinitely in all directions, entropy will continue to increase until it eventually reaches its maximum. When this happens, all energy would have been transformed into the same type of energy and dispersed equally throughout the whole universe. This would happen because if entropy has reached its maximum limit, then everything would have already been disordered to its maximum limit. At this point, the whole universe would then be in equilibrium: the Heat Death of the Universe [4]. Another possible outcome is that, as the universe is expanding indefinitely, then entropy will also increase indefinitely and will not be able to reach its maximum limit. On the other hand, in a finite dimensional universe, meaning the universe will continue to expand only until a ... Show more content on Helpwriting.net ... However, once the universe reaches the maximum limit of its expansion, the energy density of the universe will reach its minimum in the finite dimensional universe, as there will no longer be space for the universe to expand. At this time, there will be the Big Crunch. During the Big Crunch, the energy density of the universe will begin to increase again as the volume of the universe continues to decrease until it reaches the point where it condenses back into a singularity, such as what it was before the Big Bang. Once it has achieved singularity, that is also where the energy density of the universe will be at its ... Get more on HelpWriting.net ...
  • 27.
  • 28. First And Second Laws Of Thermodynamics For Living Systems 1. Explain the consequences of the first and second laws of thermodynamics for living systems. The first law of thermodynamics states that all energy is constant, which as a consequence, or result, means that energy can never be produced or destroyed but rather it is transformed. During the process of energy being transformed some energy is typically lost as heat. Another result of energy being transformed is the increase of entropy, or disorder. The increase of entropy and loss of energy is referred to as the second law of thermodynamics. 2. Explain how life is able to adhere to the laws of thermodynamics and accomplish the following life processes: a. Growth Living organisms are able to grow as long as cells grow which survive by several inputs, such as nutrients and oxygen. When cells grow it is typically referring to amount, not size. Cells multiply by mitosis or meiosis, which require energy to occur. The first law of thermodynamic is applied in which energy from macromolecules, such as enzymes, are transferred for the cellular processes can take place, and thus the organism increases in growth. b. Increase in Order An increase in order would occur when coupling a process that increases entropy ... Show more content on Helpwriting.net ... Explain how environmental conditions can affect enzyme function. Provide examples. Environmental factors that can affect enzyme function include enzyme and substrate concentration, temperature, pH, salinity, activators, and inhibitors. For example, the ideal temperature for enzymes to work properly is the normal body temperature of 37°C (98.6°F) and if the body temperature increases or decreases at a high rate, the enzymes will change and they will no longer be of any use to the body. Another example would be the salinity, which is the concentration of salt. Change in salinity disrupts bonds and enzymes are intolerant of extreme ... Get more on HelpWriting.net ...
  • 29.
  • 30. Enthalpy & Entropy Experiment ENTHALPY AND ENTROPY OF ZINC WITH COPPER SULFATE The CCLI Initiative Computers in Chemistry Laboratory Instruction LEARNING OBJECTIVES The learning objectives of this experiment are to. . . ! ! determine changes in enthalpy and entropy of the reaction of zinc with copper sulfate using two methods: electrochemistry and calorimetry. compare the enthalpy values obtained by the two methods. BACKGROUND Thermodynamics is concerned with energy changes that occur in chemical and physical process es. The enthalpy and entropy changes of a system undergoing such processes are interrelated by the change in free energy, ªG, according to the equation ªG = ªH – T ªS (1) This investigation focuses on the reaction Zn(S ) + ... Show more content on Helpwriting.net ... Let the set–up stand for 15 minutes until the temperature stabilizes. 4. Pour about 5 ml of 0.1 M KNO3 into the center well. Pour about 5 ml of 0.50 M ZnSO4 into well #1 and about 5 ml of 0.50 M CuSO4 into well #2. 5. With clean tweezers, take a s trip of filter paper and dip one end into the central well (where immersion in the KNO3 solution will hold one end); dip the other end into well #1. Repeat this procedure with another strip of filter paper, dipping the other end into well #2. This creates the salt bridge for your galvanic cell. 6. With clean tweezers take a zinc metal strip and sand it (on a piece of paper so as not to scratch the table top) to remove any oxide coating. Bend 2 cm of one end of the ªS trip and immerse it in the ZnSO4 solution (well #1). The rest of the metal strip (3cm) extends out to the edge of the cell and should be bent over the rim. Repeat the same procedure with the copper metal strip and place it in well #2. Later the electrical leads (alligator clips ) from the interface will be attached to the metal strips. 7. Fasten your temperature probe to the ring stand with a clamp and adjust the temperature probe such that its tip can be immersed in the central well (KNO3 solution) of the cell. It is assumed that the temperature of the ZnSO4 solution and CuSO4 solution will be very close to the temperature of the KNO3 solution throughout the experiment. 8. Start the computer program to
  • 31. ... Get more on HelpWriting.net ...
  • 32.
  • 33. The Touchstone Of Life By Loewenstein In "The Touchstone of Life", Loewenstein talked about the concept of entropy from the viewpoint of "information theory." In the thermodynamic viewpoint, the concept of entropy is the "transformation of heat to work." However, in general chemistry the viewpoint of entropy is the "measure of disorder." There are some different and similar between 3 viewpoints. The common in 3 viewpoints are that they were trying to explain the second the law of thermodynamics. Also, Boltzaman stated that entropy is the measure of the disordered; it is just like information is a measure of order when we compare that to information theory. Besides the similarity, the differences between these 3 viewpoints are that the information theory is defined entropy in the context of probability model to establish a measure for the amount of information connect with the message. From Shannon's viewpoint, information becomes mathematically defines quantity that represents the degree of choice applied in forming a particular symbol or message sequence out of a number of possible ones, and entropy becomes a measure of the rate of transfer of the information in the message. The thermodynamic viewpoint is based on described the system with the macroscopically view, and what we can measure by thermodynamic variables: temperature, pressure, volume, and number of particles by observe how temperature and heat and its relation to the observed energy and work measured for the system. When a closed system holds an ... Get more on HelpWriting.net ...
  • 34.
  • 35. Maxwell's Experiment To Contradict The Second Law Of... Maxwell's Demon is a thought experiment created by a mathematician James Clerk Maxwell to contradict the second law of thermodynamics. For example, you have a box filled with a gas (a mixture of hot and cold molecules) at the same temperature. This means that the temperature can have an affect on an average speed of the molecules. Some of the molecules will move slower than average, and some will move faster than the average. Suppose that a divider is placed in the middle of the box separating the two sides into left and right compartment. Maxwell imagined a demon at the door would observe the molecules. When a hot molecule approaches the door, the demon opened the door and the molecule move from the right to the left. When a cold molecule approaches the door he do not open the door in order to let it be on the right side. Therefore, when he finished the operations, he has a box in which all the hot molecules are in the left side and all the cold molecules are in the right side. A heat engine can be run by allows the heat to flow from the hot side to the cold ... Show more content on Helpwriting.net ... Second law of thermodynamics stated, "In any cyclic process the entropy would either increase or remain the same." (auburn.edu) To explain Maxwell's Demon paradox, scientists draw out that the demon still need to use energy to observe the molecules, for example, maybe in the form of photons. In addition, the demon itself and the trap door mechanism would gain entropy from the gas as it moved the separate door. Thus, the total entropy of the system still increases (auburn.edu). In chapter 4 of "The Touchstone of Life," Loewenstein stated that the production of macromolecular information can be as large as you wish, so long as the gain of molecular information (ΔIm) and the sum of the production of entropy in the macromolecule (ΔSm) and of the entropy in the environment (ΔSe) balance out: ΔIm = ΔSe + ... Get more on HelpWriting.net ...
  • 36.
  • 37. Magnetic Refrigeration MAGNETIC MAGNETIC REFRIGERATION a fruitful approach to reduce environmental pollution... ABSTRACT : The objective of this effort is to determine the feasibility of designing, fabricating and testing a sensor cooler, which uses solid materials as the refrigerant. These materials demonstrate the unique property known as the magneto caloric effect, which means that they increase and decrease in temperature when magnetized/demagnetized. This effect has been observed for many years and was used for cooling near absolute zero. Recently, materials are being developed which have sufficient temperature and entropy change to make them useful for a wide range of temperature applications. The proposed effort includes magneto caloric effect material ... Show more content on Helpwriting.net ... This allows it to absorb more unwanted heat, and the cycle begins again. Producing very low temperature through the process of adiabatic demagnetization can do refrigeration. The paramagnetic salt is suspended by a thread in a tube containing a low pressure of gaseous helium to provide thermal communication with the surrounding bath of pumped helium. In operation the liquid helium bath is cooled by pumping to the lowest practical pressure, usually achieving a temperature in the neighborhood of 1oK. The temperature of the paramagnetic salt approaches that of the helium bath by conduction through the exchange gas. Next the magnetic field is turned on, causing heating of the salt and a decrease in entropy of the magnetic ions by virtue of their partial alignment in the direction of the applied field. The heat produced is conducted to the surrounding bath of liquid helium so that the temperature again approaches 1oK. If the magnetic field is increased slowly the heat can flow out, as it is generated– the magnetization being almost isothermal. Next the exchange gas surrounding the sample is removed by pumping, and now, with the salt thermally isolated, the magnetic field is turned off. The temperature of the sample decreases markedly as a consequence of the adiabatic demagnetization, which allows the magnetic ions to regain some of their entropy at the ... Get more on HelpWriting.net ...
  • 38.
  • 39. Essay On Thermodynamics An Overview of Thermodynamics and Bioenergetics with respect to Biochemistry What is Thermodynamics? It is that field of physical science which describes the relationship between heat and other forms of mechanical, chemical and electrical energy. It basically deals with the basics of heat to the kinetic theories to the laws of thermodynamics. Thermodynamics is widely used by biochemists to understand chemical reactions and processes taking place in an organism. Thermodynamics is based to three laws, out of which the first two are of importance for the biochemists. First Law Of Thermodynamics The first law is also known as the the law of conservation of energy. The law states that the energy can neither be created nor destroyed but it can be changed from one form to another. Meaning energy in the universe remains constant but can be changed from one form to another. The transfer of energy from one form to another is an inefficient process. Energy is lost in many ways when work is done ... Show more content on Helpwriting.net ... Entropy is basically the measure of energy which is not available in a closed system for mechanical work or in easier words the degree of randomness in a system. An good biochemical example is that of proteins. A polypeptide that is folded into a protein is more confined in orientation that that of unfolded protein chain, which can be freely undergo into any conformation. The polypeptide chain that is folded has a negative entropy change and the polypeptide that is unfolded, the entropy increases and the change is positive. Entropy is can only be measured in a closed system. As the organism is not a closed system, there are a number of difficulties in measuring entropy changes for biological processes. The Gibbs Free Energy (G) is a better indicator of spontaneous change, as it takes the enthalpy change into consideration as ... Get more on HelpWriting.net ...
  • 40.
  • 41. Evaluation Of Single Cylinder Direct Injection Essay This paper presents exergetic evaluation of single cylinder direct injection, water cooled diesel engine at varying operating conditions. Normally, first law of thermodynamics has been used to analyze the engine cycle process. However recent research indicates that the first law of thermodynamics is inadequate to study the diesel engine performance. Exergy analysis is used to determine in detail the amounts of losses in a system and locations where they occur, and the processes that cause them so the application of exergy analysis for diesel engine allows determining the sources of irreversibilities and obtaining more accurate information about engine efficiency. An Exergy–based performance analysis is based on the second law of thermodynamics that overcomes the limitation of an energy–based analysis. Consider the advantages of second law of thermodynamics over first law, this study includes exergy analysis of single cylinder, 4–stroke, water cooled, on a single cylinder 8.1 kW direct injection, diesel engine. In this study first and second laws of thermodynamics ae applied to analyze the quantity and quality of energy in diesel engine cycle. The experimental data were collected using steady state test condition which enables the accurate measurements of air, fuel, and cling water flow rates, engine load, and all relevant temperatures. Each experiment was performed at five different speeds between 1300 rev/min and 2400 rev/min at intervals of 300 rev/min for five different ... Get more on HelpWriting.net ...
  • 42.
  • 43. Energy Is An Important Part Of Human Evolution Energy has been an important part of human evolution. Ever since human began development, energy was a major factor. We need energy for everything we do. Heat is one of many types of energy, and it is a very important type of energy. We use heat to warm our shelter, drive cars. Heat transfer is one of the most obvious processes in the nature. It occurs at all the places such as machine, biological creatures, etc... In engineering this heat transfer is a key part of understanding heat energy. The study of heat behaviour and harnessing heat energy is called thermodynamics. Thermodynamics is used for many areas such as nuclear power plant, car engines, etc... This essay will cover topics such as, what is energy, and what makes it useful? , what is thermodynamics, success rate for harnessing and manipulating energy and how energy is vital to us all and how we use it. Firstly, energy is a power produced from physical or chemical resources, such as heat provided to work the machines. It defines the capacity for doing the work, generating heat, etc... There are many types of energies such as mechanical, electrical, thermal, nuclear, etc... This essay will cover thermal energy. Thermal energy is the random motion of particles in the substance. An example of this situation would be warming a cup of water, where water particles gets in random motion when heated. The uses of thermal energy are very broad. Thermal energy is used in simple tasks such as a coffee maker, to a solar plant. It is ... Get more on HelpWriting.net ...
  • 44.
  • 45. Thermodynamics Of Mixing Of Poly Essay Thermodynamics Paper: Thermodynamics of mixing of poly(vinyl chloride) and poly(ethylene–co– vinyl acetate) Introduction The mixing of poly(vinyl chloride) (PVC) and poly(ethylene–co–vinyl acetate) (EVA) is investigated for its thermodynamic properties such as enthalpy of mixing and glass transition temperature. Both the two pure polymers and the mixtures are investigated in terms of specific heat as well. The mixing of PVC and EVA are investigated because of the possible use of EVA as a plasticizer for PVC. The benefit of an EVA plasticizer would not having the need to introduce low molecular plasticizers [1]. This paper will explore the enthalpy of mixing found throughout the various mixtures and the indications of these values as well as the excess specific heats. Some applications of EVA as a plasticizer is also explored. Theory and Background The miscibility of PVC and EVA is an example of a miscible blend of homopolymer–copolymer. This blend is made despite the immiscible behavior of the homopolymers. It as at certain ranges of copolymer composition that PVC is able to mix with EVA, while being not doing so with polyethylene and poly (vinyl acetate). It is possible that the two copolymer units' repulsion forces influence the miscibility based on copolymer composition [1]. Studies show that EVA is able to mix with PVC with a vinyl acetate content range of 45 to 85 wt%. Differences in results for the range are considered to be due to when the phase separation ... Get more on HelpWriting.net ...
  • 46.
  • 47. Fine Tuning Research Paper Science is defined as knowledge covering general truths of the operation of general laws as obtained and tested through scientific method and concerned with the physical world. The steps of the scientific method are defining a problem, forming a hypothesis, collecting research and data, conducting the experiment, and defining the conclusion. Fine tuning is the precision of the physical constants of nature, as the beginning of the universe requires extremely precise values. These constants serve to explain the nature of the universe, theories that potentially point to a divine creator. Evidenced through the initial conditions of the universe, such as the expansion energy and rate of the Big Bang, the creation of the universe requires such fine–tuned ... Show more content on Helpwriting.net ... The likelihood of being able to observe another universe is slim because information probably could not transfer between universes. Besides these reasons, a universe generator itself, or whatever universe production process would require many constraints and parameters, fine–tuning(!) as well. According to probability, small patches of order are far more likely that large ones, so the most probable observable universe would be a small one inhabited by a single simple observer. Surprisingly, what is actually observed is a vast and fine–tuned universe inhabited by billions of observers. The laws of nature are definitely hospitable to life, because humans exist. Otherwise, humans would not exist to notice this. If both necessity and chance are not indicative of the existence of the universe, finally, design seems to be the most probable option. As said by Fred Hoyle, "A common sense interpretation of the facts suggests that a super–intellect has monkeyed with physics... and that there are no blind forces worth speaking about in nature. The numbers one calculates from the facts seem to me so overwhelming as to put this conclusion almost beyond ... Get more on HelpWriting.net ...
  • 48.
  • 49. Entropy SAFETY HANDBOOK Student's name Course title Date Safety Handbook Introduction Safety is the state of serenity being devoid of harm or any form of event that may be considered non–desirable. In any type of institution, be it, a business, school, industry, laboratory or even the common workplace, safety plays a major role in ensuring activities run smoothly and no–one gets hurt while doing their job. Safety encompasses protection from a wide host of potential hazards which could be physical, financial, emotional or biological. In the common workplace health is a major concern and infection control is the main aim of a safety handbook. Biosafety in the work setup starts by assuming every individual is a potential source of infection. ... Show more content on Helpwriting.net ... Use different or fresh pair of gloves for each procedure or client handled where necessary.3. Personal items should not be shared e.g. razors, toothbrushes, towels or clothing. B. Cleanliness: The workplace should be kept clean by carrying out scheduled cleaning procedures on a regular basis. Spot cleaning should also be done when necessary. Disinfectants should be utilized when cleaning up bodily fluids e.g. blood. Wash floors and surfaces with a mixture of warm water and detergent regularly while walls and ceilings should be cleaned periodically. Special procedures involving isolation of area, wearing protective attire, disinfecting using chlorine for 10mins,irrigation with water, washing with hot water and detergent followed by drying should be followed when dealing with bodily fluid spillage. C. Disposal of Waste: During disposal of possible contaminated infectious waste wear appropriate protective attire including heavy duty gloves. Place the waste in clearly labeled containers and dispose according to EPA regulations. D. Handling sharps: Contaminated sharp objects should be handled with care e.g. needles should be handled by their barrel and you should never attempt to bend or re–cap used ones. They should then be placed in yellow clearly–labeled containers marked with a biohazard symbol. E. Occupational exposure: In–case of accidental ... Get more on HelpWriting.net ...
  • 50.
  • 51. Lab Report On Calorimetry Calorimetry Lab Calorimetry is the science of measuring the change in heat absorbed or released during a chemical reaction. The change in heat can tell us if the reaction is either exothermic – it released or heat into surroundings, or endothermic – it absorbed heat from surroundings. The device used to measure calorimetry is a calorimeter. A calorimeter can range from very expensive lab ones to coffee styrofoam cups but they are all tightly sealed in order to prevent heat from escaping. In order to measure the heats of reactions, add the reactants into the calorimeter and measure the difference between the initial and final temperature. The temperature difference helps us calculate the heat released or absorbed by the reaction. The equation for calorimetry is q=mc(ΔT). ΔT is the temperature change, m is the mass, c is the specific heat capacity of the solution, and q is the heat transfer. Given that the experiment is operated under constant pressure in the lab, the temperature change is due to the enthalpy of the reaction, therefore the heat of the reaction can be calculated. In this lab, there are two days. In the first day, there are is part A and part B. Part A is further divided into three experiments. In experiment one, we were to figure out the heat capacity of the calorimeter that we made. The next two experiment's goal was to calculate the enthalpy of 2 reactions and using hess's law, figure out the heat of formation of magnesium oxide. In a reaction, there are ... Get more on HelpWriting.net ...
  • 52.
  • 53. The Mathematical Theory Of Communication In Thomas... According to the Merriam Webster dictionary, entropy can be defined as "the degree of disorder or uncertainty in a system." In his novel, The Crying of Lot 49, Thomas Pynchon manipulates the definition of the scientific term "entropy" to manifest the innate chaos and disorder in both a closed thermodynamic system and in the life of the protagonist: Oedipa Maas. In the novel, Oedipa Maas explores entropy with respect to the thermodynamic sorting of molecules in Maxwell's Demon, and the communication information regarding the "Tristero". According to Warren Weaver's, Recent Contributions to The Mathematical Theory of Communication, there are technical, semantic, and effectiveness problems that may distort the accuracy of communication, ... Show more content on Helpwriting.net ... Since entropy prospers in closed environments much like Oedipa's life at the beginning of the novel, Pynchon develops the idea that the chaos in Oedipa's life is subject to increase with the discovery of more information pointing to the existence of Tristero. This overload of information Oedipa experiences serves as a roadblock to her understanding of the true meaning behind the Tristero. According to Warren Weaver, "the entropy in the channel is determined both by what one attempts to feed into the channel and by the capabilities of the channel to handle different signal situations" (Weaver, 10). Thus, when Oedipa is fed copious amounts of symbols, words, and theories, she finds it hard to handle sorting what is real and unreal. This confusion that Oedipa endures is a direct consequence of the "noise" created by different people, symbols, and word that disrupt Oedipa's deciphering of the Tristero. Warren Weaver comments on this "noise" seen in Claude Shannon's communication transmission model, stating that, "If noise is introduced, then the received message contains certain distortions...that would certainly lead one to say that the received message exhibits, because of the effects of the noise, an increased uncertainty... If the information source has any residual uncertainty...then this must be undesirable uncertainty due to noise" (Weaver, 11). This "undesirable uncertainty due to noise" leads ... Get more on HelpWriting.net ...
  • 54.
  • 55. The Between Heat And Energy The term thermodynamics is known as the branch of physics that covers the relationship between heat or temperature and all the forms of energy, including mechanical, electrical, or chemical. Thermodynamics is a combination of four laws, which are known as zeroth law of thermodynamics, first law of thermodynamics, second law of thermodynamics, and third law of thermodynamics. According to Wolfram, "The relation between heat and energy was important for the development of steam engines, and in 1824 Sadi Carnot had captured some of the ideas of thermodynamics in his discussion of the efficiency of an idealized engine" (1019). After this statement was made, scientist developed its laws. The term thermal equilibrium is when two bodies are at the same temperature. Therefore, the zeroth law of thermodynamics states that if two bodies are in thermal equilibrium with a third body, they are all in thermal equilibrium. In other words, they are all have the same temperature. Joseph Black was one of the first scientist and physic known as founder of the zeroth law of thermodynamics in the late 18th century. The first law of thermodynamics states that heat energy can not be created or destroyed. It can be just transformed into other forms or transferred into another location. Rudolf Clausius and William Rankine were the first physics that made a full statement of the first law of thermodynamics in 1850. It is also known as "another version of the law of conservation of energy." The ... Get more on HelpWriting.net ...
  • 56.
  • 57. The Behavior Of Binary Alloys Abstract The behavior of binary alloys was investigated by the Metropolis Monte Carlo Simulations in Matlab. Temperatures, alloy concentrations and interaction parameters are variables being varied in this simulation. Increases in temperature led to an increase in entropy as well as a decrease in relative correlation of orders. The entropy and enthalpy of mixing both were affected by the alloy concentration, with a maximum of 50%. Lastly, the interaction parameter defined the type of bonds that were energetically favorable: for negative bond energies, the alloy consisted of intermetallic compounds whereas for positive bond energies, the two types of atoms had a tendency to cluster and thus phase separation occurred. When the bonding energy ... Show more content on Helpwriting.net ... Although the substitution occurs randomly, an ordered structure can be obtained under certain conditions. For a binary alloy of A and B metals, there are two types of order: long range and short range. The first one measures the fraction of metal A atoms positioned on α sites and the second one is an indicator of the average number of B atoms surrounding an A atom. Depending on the energy of the bonds between the two metal atoms with each other and themselves, an alloy's ordered state will vary. The extent to which an alloy becomes ordered under certain conditions depends on which arrangement is more energetically favored, given by the state's Gibbs energy. For low temperatures, the Gibbs energy is proportional to the relative concentrations of the two metals and the bond strengths. Above a critical temperature, the entropy of the solution is dominant and long range order disappears while the short range order is present to a certain extent. [2] This temperature dependence has a significant impact on the applications of a certain material. The two main methods of studying the order and configuration of alloys are X–rays diffuse scattering and Monte Carlo simulations. The former can be used to study individual "sections" (i.e. short range order) but is extensive as individual experiments on single crystals are needed. In order to study the ... Get more on HelpWriting.net ...
  • 58.
  • 59. BITS F111 2011 12 BIRLA INSTITUTE OF TECHNOLOGY AND SCIENCE, PILANI INSTRUCTION DIVISION FIRST SEMESTER 2011‐2012 Course Handout (Part – II) Date: 02/08/2011 In addition to Part I (General handout for all course appended to timetable), this portion gives further specific details regarding the course. Course No. : Course Title : Instructor‐in‐Charge : Team of Instructors : 1. 2. 3. 4. BITS F111 Thermodynamics M S Soni Sachin U Belgamwar, Dileep Kumar Gupta, Gudla Prashanth, Priya C Sande, R J Bhargavi, Varinder Kumar, Navin Singh, P Srinivasan, Rajeev Sharma, Satish K Dubey, Utkarsh Maheshwari, Course Description Concepts and laws ... Show more content on Helpwriting.net ...
  • 60. tances 8 Work and heat Definition of work and its identification, work done at the moving boundary 9‐10 Work and heat Concept of heat, comparison of heat and work, Engineering Applications 11‐12 First law for control First law for a cycle as well as for a change of state; mass internal energy & enthalpy 13‐14 First law for control Specific heats; internal energy, enthalpy & specific heat Text book Chap/Sec # 2 3.1‐3.3,3.6, 3.7 3.4 4.1, 4.2, 4.3,4.5 4.6, 4.8, 4.9 5.1‐5.5 5.6‐5.8, 5.10 mass 15‐17 18 19‐23 First law for control volume First law for control volume Second Law of Thermodynamics 24‐29 Entropy 30‐31 Second law for control volume Second law for control volume 32‐34
  • 61. 35‐39 Irreversibility and availability 40‐41 Thermodynamic relations of ideal gases; first law as a rate equation; problem analysis & solution technique, Engineering Applications Conservation of mass in control volume; first law for control volume; SS process; examples of SS processes Transient processes; examples, Engineering Applications Limitations of first law & need for the second law; Reversible process; heat engine, heat pump, refrigerator; Carnot cycle; Two prepositions regarding efficiency of Carnot cycle; energy‐conversion efficiency and COP, Kelvin‐Planck & Clausius statements, The ideal gas Carnot Cycle, Engineering Applications Concept ... Get more on HelpWriting.net ...
  • 62.
  • 63. A World Of Books By Borges Disorder In A World of Books In Borges's Ficciones, it is evident that Borges knew a lot about science and scientific writing and writers. How we as readers know that, is by way of his writing. In his writing he demonstrates that scientific knowledge by incorporating some aspects in his stories. One of the biggest scientific ideas that are seen throughout his stories is the idea of entropy. Entropy, in its simplest definition is defined as, disorder whether it is in society or anywhere else in the universe. This concept of entropy plays a huge role in many of the stories; it is a critical concept, without it many of those stories would no longer have their intended meaning. So in this essay we are going to go in more depth and find out what entropy it really is, as well as look at how it is used as a basis for some of the stories by Borges. As expressed before, Borges makes this vast knowledge of scientific knowledge known in his writing. In his stories Borges also demonstrates his understanding of the laws of thermodynamics. Thermodynamics is the branch of physical science that deals with the relationship between heat and other forms of energy such as mechanical, electrical, or chemical energy. In physics, according to the second law of thermodynamics, the total amount of entropy system will never decrease because the system will try to strike a balance of Thermal equilibrium or in other words, it will always find a way to go back to order/peace. The systems that ... Get more on HelpWriting.net ...
  • 64.
  • 65. The Three Laws Of Thermodynamics Thermodynamics... Thermodynamics is a branch in physics that deal with heat and temperature and how they are related with energy and work. There are 3 laws of thermodynamics which are used almost every day and some of them are present in our body. Thermoregulation: Thermoregulation is process by which our body keeps our internal body temperature constant. Our optimum body temperature is 37°C to 40°C. Whenever our body temperature increases or decreases our internal system brings our temperature back to normal. As the second law of thermodynamics states, "the energy will spread from a high concentration to low concentration or heat moves from high temperature to low temperature", similarly when our body temperature increases our internal system tries to ... Show more content on Helpwriting.net ... Higher the entropy the more disordered is the system. As the second law of thermodynamics states, "the entropy of a system will either increase or remain the same." Entropy can be used in monitoring a patient's EEG. EEG is Electroencephalography which is a method used to record a patient's electric activity of the brain. It measure the voltage fluctuation of ionic current within the neurons of the brain. Mainly there are two entropy parameters, the fast–reacting Response Entropy (RE) and the more steady and robust State Entropy (ST). State entropy consists of the entropy of the EEG signals 32 Hz. Response Entropy includes high frequencies up to 47 Hz. Advantages: 1. Depth of anesthesia used 2. Possibility for the reduction of anesthetic related side effects. Disadvantages: 1. It is necessary to understand the theoretical foundations that are associated with the design– which includes basic understanding the relation between GA and consciousness. Heat: Heat is the energy that is transferred to and from its surroundings. In medicine heat is used in treating cancer in two ways hyperthermia and gold nanoparticles. ... Get more on HelpWriting.net ...
  • 66.
  • 67. Ap Assignment Focus On Concepts Section 15.3 The First Law of Thermodynamics 1. The first law of thermodynamics states that the change U in the internal energy of a system is given by U = Q – W, where Q is the heat and W is the work. Both Q and W can be positive or negative numbers. Q is a positive number if ________, and W is a positive number if ________. (a) the system loses heat; work is done by the system (b) the system loses heat; work is done on the system (c) the system gains heat; work is done by the system (d) the system gains heat; work is done on the system Section 15.4 Thermal Processes 4. The drawing shows the expansion of three ideal gases. Rank the gases according to the work they do, largest to smallest. (a) A, B, C (b) A and B ... Show more content on Helpwriting.net ... * 18. When a system changes from A to B along the path shown on the pressure–versus–volume graph, it gains 2700 J of heat. What is the change in the internal energy of the system? Section 15.5 Thermal Processes Using an Ideal Gas * 28. An ideal gas is taken through the three processes shown in the drawing. In general, for each process the internal energy U of the gas can change because heat Q can be added to or removed from the gas and work W can be done by the gas or on the gas. For the three processes shown in the drawing, fill in the five missing entries in the following table. * 29. ssm The drawing refers to one mole of a monatomic ideal gas and shows a process that has four steps, two isobaric (A to B, C to D) and two isochoric (B to C, D to A). Complete the following table by calculating DU, W, and Q (including the algebraic signs) for each of the four steps. ––––––––––––––––––––––––––––––––––––––––––––––––– W Q A to B B to C C to D ––––––––––––––––––––––––––––––––––––––––––––––––– D to A * 31. The pressure and volume of an ideal monatomic gas change from A to B to C, as the drawing shows. The curved line between A and C is an isotherm. (a) Determine the total heat for the process and (b) state whether the flow of heat is into or out of the gas. Section 15.8 Heat Engines * 48. A 52–kg mountain climber, starting from rest, climbs a ... Get more on HelpWriting.net ...
  • 68.
  • 69. A Brief Introduction to the Pinch Analysis The economics of industrial production, limitation of global energy supply, and the realities of environmental conservation are an enduring concern for all industries. Wherever you turn, there's another entreaty to save energy, reduce carbon emissions and protect the environment for posterity. Pinch analysis is a tools used to design a heat exchanger networks (HEN) that reduce the energy usage. This paper will be about brief introduction for the pinch analysis, application of the second law of thermodynamics in design heat exchanger network Pinch Analysis: Pinch technology is the technology that provides a systematic methodology for energy saving in processes and total sites. The methodology is based upon first low and second low of ... Show more content on Helpwriting.net ... Minimizing the total entropy produced by heat exchanger network lead to minimizing the use of high energy quality. The entropy can define for single heat exchanger i.e. exchange heat of one hot stream with one cold stream as S=∮▒dS=∫▒dq/T S=∫_(T_Hi)^(T_Ho)▒(C_H dT_H)/T_H –∫_(T_Ci)^(T_Co)▒(C_C dT_C)/T_C 〖S=C〗_C ln⁡ 〖(T_Co/T_Ci 〗)–C_H ln⁡ 〖(T_Hi/T_Hi 〗) Sets of heat exchanger network will have constant total entropy when they use same type and amount of utilities. On the other hand, the entropy will vary for networks having different types and amount of utilities. The networks' entropy that is used high energy qualities is higher than the one that used low energy qualities. The changes come from using high energy qualities, and this lead to have higher temperature different in some heat exchangers, hence high entropy. Due to that, the total area of the networks also will vary with the use of different utilities since total area is in related with temperature different in heat exchanger. As the temperature different increase the area will decrease. Furthermore, total entropy can be used as objected furcation in mathematical programing. Total entropy can help to find total energy required with from each energy levels in small code. Case study: The objective of this case study is show the change of total entropy when different types of utility used i.e. LP steam, MP steam and HP steam. The case study has three hot streams and three ... Get more on HelpWriting.net ...
  • 70.
  • 71. Oedipa's Search For Truth In The Crying Of Lot 49 Oedipa's search for truth is caught in a paradox: On one hand, she is (or at least believes she is) in search of "absolute" meaning; on the other hand, that meaning is concentrated around herself and is shutting her off from the world around her in a subjective circle of signification where the communicational void she wishes to escape is filled with illusions of meaning. Oedipa's search is fueled by a belief that it will bring to an "end her encapsulation in her tower (Pynchon 31)." The complication to her journey is that all language (truth, communication, meaning, etc....) is founded in entropy, on a waste of force that alone makes possible the fictional constitution of abstract truth. In The Crying of Lot 49, Pynchon uses the ideas of entropy in thermodynamics and information theory (through Maxwell's Demon) to more fully delve into Oedipa's paradoxical search for meaning in a world that has created, forgotten, and rediscovered it's own truth. Thermodynamics is the study of the relationship between heat and other energies. It deals with the changes within a system if the energy distribution in that system is unbalanced. Thermodynamic entropy is the measure of this chaos in the universe. In beginning of The Crying of Lot 49, Oedipa Maas realizes that she exists within "the confinement of [a] tower, (11)" that is similar to a closed system. Entropy thrives in closed systems; therefore, if she does not open her system she is doomed to slow degradation, till she is nothing ... Get more on HelpWriting.net ...
  • 72.
  • 73. The Problem Of Arson Investigation Arson investigation began sometime in the mid 1970's, and has been a process changed and evolved ever since. The act of arson consists of purposely setting or starting a fire on someone's property, and can be for a number of reasons anywhere from vandalism, excitement or serial arson, to revenge, extremism or crime concealment (Newton, M., 15). Some previously "proven" indicators pointing as to whether or not a fire is an act of arson has been questioned, further researched and tested. Many of these theories have stated that certain markings, post–fire, could only appear due an accelerant being used to help engage the fire or intensify it, though recently many of these theories have been debunked. The truth behind some of these markings ... Show more content on Helpwriting.net ... One of the most misleading processes that can lead to a wrongful conviction is a term called flashover. Flashover is what seemingly happens when an entire room is engulfed in fire, and flames protrude from openings within the building. The process occurs in an enclosed space when particles and combustible gases begin to cluster close to the ceiling, and then slowly fall towards the floor. At this point, it is likely that an accumulation of air would rush into the room through windows, doors or other cavities, and ignite the muddle of particles and gases (Starr, 2011). As this process was not realized until later when arson investigation became more developed, many explanations as to whether an accelerant was used to start a fire have been recently proven to be more than likely due to the effects of a flashover. Some of these beliefs were that melted metals, especially those in or near doorways, burn marks under pieces of furniture, or on the floor were a sure sign that a liquid accelerant was used to start the fire. Detectives believed melted metals were a sign of a liquid accelerant because they thought that temperatures high enough to melt these types of metals were unattainable without an accelerant. In reality, wood fires commonly reach and exceed the melting point of metals, especially once they hit ... Get more on HelpWriting.net ...
  • 74.
  • 75. The Mathematical Theory Of Communication In Thomas... According to the Merriam Webster dictionary, entropy can be defined as "the degree of disorder or uncertainty in a system." In his novel, The Crying of Lot 49, Thomas Pynchon manipulates the definition of the scientific term "entropy" to manifest the innate chaos and disorder in both a closed thermodynamic system and in the life of the protagonist: Oedipa Maas. In the novel, Oedipa Maas explores entropy with respect to the thermodynamic sorting of molecules in Maxwell's Demon, and the communication information regarding the "Tristero". According to Warren Weaver's, Recent Contributions to The Mathematical Theory of Communication, there are technical, semantic, and effectiveness problems that may distort the accuracy of communication, ... Show more content on Helpwriting.net ... Since entropy prospers in closed environments much like Oedipa's life at the beginning of the novel, Pynchon develops the idea that the chaos in Oedipa's life is subject to increase with the discovery of more information pointing to the existence of Tristero. This overload of information Oedipa experiences serves as a roadblock to her understanding of the true meaning behind the Tristero. According to Warren Weaver, "the entropy in the channel is determined both by what one attempts to feed into the channel and by the capabilities of the channel to handle different signal situations" (Weaver, 10). Thus, when Oedipa is fed copious amounts of symbols, words, and theories, she finds it hard to handle sorting what is real and unreal. This confusion that Oedipa endures is a direct consequence of the "noise" created by different people, symbols, and word that disrupt Oedipa's deciphering of the Tristero. Warren Weaver comments on this "noise" seen in Claude Shannon's communication transmission model, stating that, "If noise is introduced, then the received message contains certain distortions...that would certainly lead one to say that the received message exhibits, because of the effects of the noise, an increased uncertainty... If the information source has any residual uncertainty...then this must be undesirable uncertainty due to noise" (Weaver, 11). This "undesirable uncertainty due to noise" leads ... Get more on HelpWriting.net ...
  • 76.
  • 77. The First Law Of Thermodynamics Thermodynamics is the study of heat and energy transfer, more specifically how heat transfer relates to energy changes within a system. The laws of thermodynamics were developed to predict and outline behaviors of thermodynamic processes (5). The First Law of Thermodynamics states that "the change in a system 's internal energy is equal to the difference between heat added to the system from its surroundings and work done by the system on its surroundings" (5). The idea behind this is conservation of energy, meaning all energy in and out of a system must be accounted for. If energy is added to a system in the form of heat, it must be used. If heat is added to a system, the system either performs work (an exothermic process) or changes internal energy (an endothermic process) (4). Enthalpy, a thermodynamic potential, is the measure of the energy within this system. The change in enthalpy, H, must be measured in order to find out how energy is transferred throughout a system. If H has a positive value, the system is endothermic and it will keep the added heat, increasing its internal energy. If H has a negative value, it means the system lost heat or "did work" when energy was put into the system, so the system is exothermic (3). Gibbs Free Energy, G, is the maximum amount of energy or enthalpy available to do work. The decrease in Gibbs Free Energy is equivalent to the work done by a system to its surroundings, excluding pressure work (5). A negative G is required for a ... Get more on HelpWriting.net ...
  • 78.
  • 79. The Theory Of Classical And Quantum Mechanics If one thought that time and its direction reduce to some reductive base in fundamental physical science one would encounter a perceived barrier viz., the fact that the underlying dynamical laws of fundamental physical theory do not privilege the past or the future. If those laws permit certain physical processes to be future directed or oriented, then they also allow for those self–same processes to be past directed or oriented. The dynamical laws are time–reversal invariant. As Roger Penrose stated, ...the dynamical equations of classical and quantum mechanics are symmetrical under a reversal of the direction of time! As far as mathematics is concerned, one can just as well specify final conditions, at some remote future time, and evolve ... Show more content on Helpwriting.net ... Moreover, we have experimentally confirmed a violation of time reversal invariance in B0 meson systems. Weakly interacting systems are anomalous for this reason. I will have more to say about how to understand such systems in the context of discussing the arrow of time. For now, let's unashamedly affirm that the fundamental dynamical laws are time–reversal invariant, deliberately suppressing worries about weakly interacting systems for the purposes of deliberation. Even though the dynamical laws of our fundamental physical theories are time–reversal invariant, there appear to be macroscopic energetically isolated processes that are temporally irreversible. So the microphysics is such that it suggests temporal symmetry, though macroscopic goings–on suggest temporal asymmetry. To make things worse, given an appropriately robust reductionist story in the background, macroscopic phenomena depend in some strong sense on underlying microphysical phenomena. We should now ask: "what could be the source of...[the]...widespread temporal bias in the" macroscopic "world, if the underlying" microphysical "laws are so even–handed?" This is the puzzle of the arrow of time. Why isn't the temporal handedness accounted for by the phenomenon of weakly interacting systems previously discussed? Answer: That phenomenon does not occur frequently enough to serve as ... Get more on HelpWriting.net ...
  • 80.
  • 81. Time's Arrow by Martin Amis Time's Arrow by Martin Amis The human being is an analytical creature. From scientists to philosophers to star–crossed teenaged lovers, the human is internally motivated to understand the world around him. That world provides countless puzzles for the human to solve, whether these puzzles lie in the forests of the heart, the laws of mathematics or the annals of history. However, some of the most unfathomable aspects of this world have been entirely created by humans. The Holocaust is one of the most unfathomable events in human history. Countless documentaries, pieces of literature, psychological analyses and films have explored the topic in an attempt to understand exactly how humans could commit such terrible atrocities against ... Show more content on Helpwriting.net ... S. Eddington awarded the second law of thermodynamics "the supreme position among the laws of Nature" since it alone was responsible for what he was the first to call "time's arrow"... The directionality of time that results from entropy's increase, Eddington points out, is intimately installed in our awareness of ourselves in the world, confirmed by human reason, and dependent upon the fact that there are multiple parts to be organized or disordered (Menke, 970). Therefore, Eddington claims that the directionality of time is inherently within the human awareness. Human beings are essentially rational creatures who have an inborn need to make sense of the ever–increasing disorder in the world around them. We use the constant forward linear march of time to establish order in a disordered universe in which entropy continually increases. The Holocaust threatens our attempts to maintain this illusion of order. The extermination at Nazi camps like Auschwitz was at the same time the most entropic and ordered event in all of human history. Never before had death, destruction, and the process of dehumanization (all ... Get more on HelpWriting.net ...