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Find the second virial coefficient for the Dieterici equation of state
p = RT/V-b exp (-a/RTV)
Solution
where a is associated with the interaction between molecules and b takes into account the finite
size of the molecules, similarly to the Van der Waals equation.
the viral coefficient are
Tc= a/(4Rb)
Pc= a/(4c2b2)
Vc=2b

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Find the second virial coefficient for the Dieterici equation of sta.pdf

  • 1. Find the second virial coefficient for the Dieterici equation of state p = RT/V-b exp (-a/RTV) Solution where a is associated with the interaction between molecules and b takes into account the finite size of the molecules, similarly to the Van der Waals equation. the viral coefficient are Tc= a/(4Rb) Pc= a/(4c2b2) Vc=2b