1. Presented by
Stephen R. Temple
Steen Research LLC
Steenresearch.com
JBS
Presentation
September 17, 2014
STEEN RESEARCH, LLC
Innovations in Chemistry and Engineering
3. o Mechanical Process
o Process
o Maintenance
o Chemistry
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Common SenseCommon Sense
Odor Control
Odor Control
Program Incorporates
6. Cooking Fresh or Decaying ProteinCooking Fresh or Decaying Protein
Generates Odiferous GasesGenerates Odiferous Gases
ProblemProblem
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Common SenseCommon Sense
7. STEEN RESEARCH, LLC
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Odor SourcesOdor Sources
Primary SourcesPrimary Sources Secondary SourcesSecondary Sources
Common SenseCommon Sense
8. STEEN RESEARCH, LLC
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Primary SourcesPrimary Sources
Infall BayInfall Bay
Cooker and Hyrdolyzer (Fugitive Odors)Cooker and Hyrdolyzer (Fugitive Odors)
Non-ConNon-Con
Screw PressScrew Press
CentrifugeCentrifuge
Odor SourcesOdor Sources
Common SenseCommon Sense
9. STEEN RESEARCH, LLC
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Secondary SourcesSecondary Sources
Cooker and Hydrolizer CondensateCooker and Hydrolizer Condensate
Evaporator CondensateEvaporator Condensate
W/W Bio ReactorsW/W Bio Reactors
Aeration Ponds and BasinsAeration Ponds and Basins
Milling RoomMilling Room
Odor SourcesOdor Sources
Common SenseCommon Sense
10. Three Phases of OdorThree Phases of Odor
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Common SenseCommon Sense
11. Nature of OdorNature of Odor
Gas-Phase VOCsGas-Phase VOCs
Aerosol Fats & OilsAerosol Fats & Oils
Water VaporWater Vapor
Solid ParticulatesSolid Particulates
SmokeSmoke
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Odor SourcesOdor Sources
Common SenseCommon Sense
44. Water SolubilityWater Solubility
Compounds Affinity For WaterCompounds Affinity For Water
VolatilityVolatility
Compounds Affinity For AirCompounds Affinity For Air
AdsorptionAdsorption
Compounds Affinity For SolidsCompounds Affinity For Solids
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ScienceScience
Physical Properties
Gases
45. STEEN RESEARCH, LLC
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Gases
ScienceScience
Water Solubility
Temperature Sensitive
Low Temp = High Solubility
Volatility
pH Sensitive
Alkaline pH Sulfur Compounds
Acidic pH Nitrogen Compounds
Neutral pH Oxygenated Compounds
46. STEEN RESEARCH, LLC
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Gases
ScienceScience
AdsorptionAdsorption
Aerosolized Fats Oils Greases,
Solid Particulates and Smoke
Contain:
56. STEEN RESEARCH, LLC
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Engineering
Engineering is theEngineering is the
Application ofApplication of
ScienceScience
to Solve ato Solve a
Real-World ProblemReal-World Problem
62. Masking Agents, Enzymes and ScavengersMasking Agents, Enzymes and Scavengers
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63. Masking AgentsMasking Agents
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Adds VOC’sAdds VOC’s
EnvironmentalEnvironmental
SensitivitySensitivity
No Feedback ControlNo Feedback Control
Based on LoadingBased on Loading
High Water UseHigh Water Use
Bio-FoulingBio-Fouling
Engineering
64. EnzymeEnzyme
withwith
Masking AgentMasking Agent
Patent TextPatent Text
http://www.google.com/patents/US20120219480http://www.google.com/patents/US20120219480
Minimal Reduction of H2S and NH3 compared to straight water w/o pHMinimal Reduction of H2S and NH3 compared to straight water w/o pH
modificationmodification
Enzymes - Slow Reaction TimeEnzymes - Slow Reaction Time
Masking AgentMasking Agent
VOC GenerationVOC Generation
FoamingFoaming
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65. TriazineTriazine
Old Oil Field TechnologyOld Oil Field Technology
Nitrogen Loading to WWTNitrogen Loading to WWT
No Loading Feedback ControlNo Loading Feedback Control
High Water UseHigh Water Use
Triazine → Thiadiazine, → DithiazineTriazine → Thiadiazine, → Dithiazine
BioFoulingBioFouling
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67. OHOH the Hydroxyl Radical and the 2the Hydroxyl Radical and the 2ndnd
strongest oxidizer known to man.strongest oxidizer known to man.
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Relative Oxidation Of Reactive Species
Oxidizers
68. Bleach and Chlorine DioxideBleach and Chlorine Dioxide
ClOClO22 Weak OxidizerWeak Oxidizer
Volatile at low temperatures (Like Bleach which flashes at a lowVolatile at low temperatures (Like Bleach which flashes at a low
temperature, 100 Degrees F, Chlorine dioxide flashes at 110 Degrees F)temperature, 100 Degrees F, Chlorine dioxide flashes at 110 Degrees F)
When free chlorine interacts with proteins environmentally detrimentalWhen free chlorine interacts with proteins environmentally detrimental
compounds are such ascompounds are such as haloamines, and trihalomethaneshaloamines, and trihalomethanes, THM’s are, THM’s are
produced.produced. (THM’s are toxic and known carcinogens)(THM’s are toxic and known carcinogens)
Addition of salts to the water systemAddition of salts to the water system
Has a negative effect on waste waterHas a negative effect on waste water
biological systembiological system
ClO2 Engineering
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69. Bleach and Chlorine DioxideBleach and Chlorine Dioxide
ClOClO22
Microbial and Disinfection Byproduct Rules Simultaneous ComplianceMicrobial and Disinfection Byproduct Rules Simultaneous Compliance
Guidance Manual (Guidance Manual (http://www.epa.gov/ogwdw/mdbp/simult.pdfhttp://www.epa.gov/ogwdw/mdbp/simult.pdf))
Volatile at low temperatures (Like Bleach which flashes at a lowVolatile at low temperatures (Like Bleach which flashes at a low
temperature, 100 Degrees F, Chlorine dioxide flashes at 110 Degrees F)temperature, 100 Degrees F, Chlorine dioxide flashes at 110 Degrees F)
When free chlorine interacts with proteins environmentally detrimentalWhen free chlorine interacts with proteins environmentally detrimental
compounds are such ascompounds are such as haloamines, and trihalomethaneshaloamines, and trihalomethanes, THM’s are, THM’s are
produced.produced. (THM’s are toxic and known carcinogens)(THM’s are toxic and known carcinogens)
Addition of salts to the water systemAddition of salts to the water system
Has a negative effect on waste waterHas a negative effect on waste water
biological systembiological system ClO2 Engineering
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70. Purate 2 Part ClO2Purate 2 Part ClO2
Low pHLow pH
Insoluble about 110 FInsoluble about 110 F
Acid Scrubbing onlyAcid Scrubbing only
Toxic blow down to bio pondsToxic blow down to bio ponds
Produces CarcinogenicProduces Carcinogenic
CompoundsCompounds THM’sTHM’s
Extreme Fire HazardExtreme Fire Hazard
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3 Part ClO23 Part ClO2
Better pH rangeBetter pH range
Insoluble about 110 FInsoluble about 110 F
Toxic blow-down to bio pondsToxic blow-down to bio ponds
Adds Lots of SaltsAdds Lots of Salts
Produces CarcinogenicProduces Carcinogenic
CompoundsCompounds THM’sTHM’s
Extreme Fire HazardExtreme Fire Hazard
71. STEEN RESEARCH, LLC
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Ozone OOzone O33
Triatomic OxygenTriatomic Oxygen
Low Solubility in WaterLow Solubility in Water
Solubility Decreases with IncreasingSolubility Decreases with Increasing
TemperatureTemperature
Solubility Decreases with IncreasingSolubility Decreases with Increasing
pHpH
Increases VOC’s in air scrubberIncreases VOC’s in air scrubber
Gold Kist Ball Ground, GA Case studyGold Kist Ball Ground, GA Case study
O3
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Ozone Solubility vs. TempOzone Solubility vs. Temp
The chart above shows ozone solubility vs. temperature for different ozone
concentrations. The water pressure is at atmospheric (0 PSIG).
(35 Degrees C = 95 Degrees F) Engineering
73. STEEN RESEARCH, LLC
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Engineering
Ozone Solubility vs. pHOzone Solubility vs. pH
Engineering
75. OZONE
Toxicity, CDC, OSA (Toxicity, CDC, OSA (Known CarcinogenKnown Carcinogen))
Does Ozone Cause Precancerous Changes in Cells?Does Ozone Cause Precancerous Changes in Cells?
http://cfpub.epa.gov/ncer_abstracts/index.cfm/fuseaction/display.abstractDetail/abstract/2314http://cfpub.epa.gov/ncer_abstracts/index.cfm/fuseaction/display.abstractDetail/abstract/2314
OzoneOzone
https://www.osha.gov/dts/chemicalsampling/data/CH_259300.htmlhttps://www.osha.gov/dts/chemicalsampling/data/CH_259300.html
Health EffectsHealth Effects
http://www.epa.gov/glo/health.htmlhttp://www.epa.gov/glo/health.html
Destroys Packing And PlasticsDestroys Packing And Plastics
Low SolubilityLow Solubility
Low pH Soluble OnlyLow pH Soluble Only
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76. Fenton Radox ReactionFenton Radox Reaction
Hydroxyl Radical the second strongest oxidizer know to man.
Secondary Fenton chemistry reaction is the generation of peroxide free radical.
FeFe2+2+
+ H+ H22OO22 → Fe→ Fe3+3+
+ OH+ OH −−
++ OHOH
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Fe3+
+ H2O2 => Fe2+
+ H+
+ HOO0
The peroxide molecule formed in this reaction (HO2
0
) is a powerful
peroxide free radical which can also oxidize organic compounds.
Engineering
77. Characteristic Radox ReactionCharacteristic Radox Reaction
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Highly ReactiveHighly Reactive
Destroys All Odor Compounds, VOC’sDestroys All Odor Compounds, VOC’s
Effective At Any pHEffective At Any pH
Very High Solubility in Scrubber WaterVery High Solubility in Scrubber Water
Not Toxic or CarcinogenicNot Toxic or Carcinogenic
Effective at All TemperaturesEffective at All Temperatures
No BioFouling, Keeps The Scrubber CleanNo BioFouling, Keeps The Scrubber Clean
No Fire RiskNo Fire RiskEngineering
78. Radox Full Scale TestRadox Full Scale Test
Case Study 1:Case Study 1:
High Intensity ScrubberHigh Intensity Scrubber
Scrubber pulled from the
cooker and presses.
Non-Methane Organic
Carbon (NMOC)
ermined using
US EPA Method 25A
Scrubber efficiency needed
to be better then 80 percent
removal.
Three continuous samples,
each 45 minutes in duration.
RUN 1 RUN 2 RUN 3 Average
Inlet
Flow Rate,
dsfm 523 519 520 521
acfm 565 559 560 561
Total Non-Methane Hydrocarbon,
ppm, as C1 1131 1035 1126 1097
lb/hr, as CH4 1.474 1.338 1.454 1.422
Outlet
Flow Rate,
dsfm 845 845 845 845
acfm 906 905 906 906
Total Non-Methane Hydrocarbon,
ppm, as C1 39.5 41.4 36.6 39.1
lb/hr, as CH4 0.0832 0.0872 0.0771 0.0825
DESTRUCTION EFFICIENCY, % 94.4 93.5 94.7 94.2
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79. Radox USDA STUDYRadox USDA STUDY
Case Study 2:Case Study 2:
Feather Dryer AirFeather Dryer Air
ScrubberScrubber
100 K SCFM Packed Bed Air
Scrubber
USDA Compared ClO2 to RADOX-
23 Fenton Treatment System
Gas chromatography ("GC") and
mass spectrometry ("MS") was
used to determine destruction
efficiency
Results From USDA Study:Results From USDA Study:
“Samples from Radox-treated air streams had (1) 42 % higher
concentration of carbon dioxide (CO2); (2) 69 % lower
concentrations of the highly aldehyde compounds, and (3) 52 %
lower total VOC when compared to untreated, or ClO2-treated
samples.”
“The RADOX treatment reduced the total perceived odor intensity
by 74 while the ClO2 treatment did not significantly alter the odor
intensity.“
"The RADOX catalyst was shown to be significantly more
effective than chlorine dioxide (ClO2) for reducing the
concentration of malodorous VOC and total VOC emitted from
poultry rendering.
“The concentration of highly malodorous aldehyde compounds,
which were responsible for a majority of the poultry rendering
odor, were not changed by the ClO2 treatment.”
“Additionally, there was a 5-fold higher concentration of indole in
the ClO2 samples when compared to RADOX-treated samples.”
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80. Sulfuric acid
tank
Acid Pump
Precursor “B”
Tote
Make-Down
System
Soap
Pump
To Each
Scrubber
pH probe
Application of Radox-23 Fenton System
Red Control ValveRed Control Valve
To Scrubber Pump
suction
Pre “B” pump
Red Control ValveRed Control Valve
SC-
211
Drum
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Acid Pre-B and Soap
Make-Down
81. Radox-23 Fenton System AppliedRadox-23 Fenton System Applied
Multiple ScrubbersMultiple Scrubbers
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Acid, Pre-B & Soap
Applied
82. Radox-23 Fenton System AppliedRadox-23 Fenton System Applied
Multiple ScrubbersMultiple Scrubbers
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Pre-A
Make-Down
84. STEEN RESEARCH, LLC
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Helpful
Tools
Detection Tubes
GasTec/Drager/Rae
Multi Gas Meter
85. Question and AnswersQuestion and Answers
“Yes …I believe there’s a question there in the back.”
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Editor's Notes
Spray Venturis are not designed to remove Smoke and Micro particulate and Micro Aerosols
Micro Particulate are known carcinogens
PM 10 EPA PM 2.5