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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072
`
© 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 623
Effect of steel fiber and poly propylene fiber on the strength properties
of fly ash based Geopolymer concrete
Gururaj M H 1, Naresh Kumar B G 2
1 Assistant Professor, Department of Civil Engineering, Maharaja Institute of Technology Mysore,
Mandya, Karnataka, India.
2 Professor, Department of Civil Engineering, Maharaja Institute of Technology Mysore,
Mandya, Karnataka, India.
---------------------------------------------------------------------***---------------------------------------------------------------------
Abstract – In order to improve the tensile strength and
durability properties of Geopolymer concrete addition offibre
particles play a vital role in the field of modern concrete
technology. In this research, combined effectsofsteelfibre and
polypropylene fibre were studied with different aspect ratios.
The crimped steel fiber with aspect ratio 60 and polymeric
synthetic fibers of aspect ratio 240 were used. Alkaline liquids
(Sodium Hydroxide and Sodium, Silicate solution) together
mixed with proper ratio (Ratio of Na2SiO3 to NaOH is 2.50).
Sodium hydroxide solution was madeby dissolvingNaOH solid
in water. Sodium hydroxide solutions were prepared for 12
molar mass of solid depends on the concentration of solution.
For 12 molar solution 480gm of NaOH pellet were mixed in
1000 ml of water.
Key Words: Steel fiber, poly propylene fiber, geopolymer
concrete, fly ash, alkaline liquid.
1. INTRODUCTION
Concrete is the second highest consumable material in the
world next to water. As construction increases demand of
concrete increases so the demand of Portland cement also
increases. Around 65% of global warming is contributed by
carbon dioxide among all greenhouse gasses due to the
production of cement. The cement industries is also one of
the responsible for the emission ofcarbondioxidethatisone
tone of carbon dioxide is emitted in production of one tone
Portland cement to the atmosphere The utilization of the
other cementing materials such as fly ash, silica fume,
granulated blast furnace slag, rice husk etc. are developedas
the alternative binders to the Portland cement. In the
meantime the Geopolymer technology was introduced.
These new binders which are alternative materials to
blended cement and concrete are obtained by the alkaline
activation or geopolymerization of different industrial
products. To improve the mechanical performance of
Geopolymer concrete theefficientmethodistoaddthefibers
in concrete. Adding of these fibers will arrest the crack, also
it is well known for the increase in facture toughness
provided by fiber bridging on the main crack plane prior to
crack extension. The steel fiber and polypropylenefibers are
used in this experiment and study themechanical properties
and behavior of Geopolymer concrete.
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end of the paper.
1.1 Scope of the work
 The experimental work was conducted to obtain the
strength of fly ash based GPC at temperature of 60ºC.
 In this experimental work only one source of dry low
calcium fly ash (class F) from the Raichur Thermal Power
Station (RTPS) was used.
 Sodium silicate solution and Sodium hydroxide pellets
were procured commercially from local vender.
 Fiber admixture like steel fiber and polypropylene fiber
are introduced in the concrete.
 To prepare the concrete that exhibits environmental
friendly and minimize the global warming.
 Manufacture and test of compressive strength, split
tensile strength and flexural strength of geopolymer
concrete beams with fiber reinforced and without fiber
reinforced by changing the volume fraction of the fiber.
2. MATERIALS & METHODS
2.1 Fly ash
Fly ash used in this study was low calcium (class F) dry fly
ash from Raichur Termal Power Station, Shakthinagar,
Karntaka. Fly ash is the alumino silicatesource materialused
for the synthesis of geo polymeric binder.
 Specific gravity : 2.36
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072
`
© 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 624
 Fineness (air permeabilityapparatus):426.038cm2/gm
Fig -1: Low calcium fly ash
2.2 Aggregates
Locally available aggregates were used comprising of
20mm, 12mm and 6mm and fine aggregate passing through
4.75 mm all aggregates were in saturated surface dry
condition. The course aggregates were crushed granite type
and the fine aggregate used in this study was manufactured
sand.
Table -1: Physical characteristics of course aggregate
Sl.
No.
Specific
gravity
Fineness
modulus
Flakiness
index
Density kg/m3
loose Rodded
1 2.63 7.04 28.4% 1228 1504
Fig -2: Coarse aggregate
Fig -3: Fine aggregate
Table -2: Physical characteristics of fine aggregate
Sl.
No.
Specific
gravity
Fineness
modulus
Density kg/m3
loose Rodded
1 2.56 2.506 1350 1617
2.3 Alkali Activator
In the alkaline activator substances of Silica are dissolved in
strong alkaline conditions with high PH. During the
dissolution of the silicaand aluminum the alkalinesolutionis
active and plays a main role in the condensation process
(Lindgård et al. 2012). Sodium hydroxide, potassium
hydroxide, sodium silicate and potassium silicate are the
common activators used forgeopolymer. Alkaline liquidwas
framed by mixing sodium hydroxide (NaOH) solution and
sodium silicate (Na2SiO3) solution. Sodium hydroxide
solution was madebydissolvingNaOHsolidinwater.Sodium
hydroxidesolutionswerepreparedfor12molarmassofsolid
depends on the concentration of solution. For 12 molar
solution 480gm of NaOH pellet were mixed in 1000 ml of
water. Where 1M = 40gm of solid in 1000 ml water, during
the process of mixing lotofheatgetliberatedwhendissolving
NaOH pellet in water. Therefore solution is kept for cool for
24 hour; this duration is required forpolymerizationprocess
of alkaline liquids.
2.3.1 Sodium Hydroxide (NaOH)
Caustic soda is the other name to Sodium hydroxide,
which is manufactured by theelectrolysis of sodiumchloride
brine in a membrane or diaphragm electrolytic cell
(Occidental Chemical Corporation 2000). Paperindustryand
manufacturers that need an alkaline based material are the
largest users and buyers of caustic soda. Sodium hydroxide
(NaOH) is accessible in four varieties: beads, flakes,
compounders andsolid castings. All the forms have thesame
chemical composition.
Fig.4. Sodium Hydroxide flakes
2.3.2 Sodium Silicate Solution (Na2SiO3)
Alkali silicates Solutions are also termed as “water
glass”. Na2SiO3Solution can be produced in two ways one by
dissolving alkali silicate pellets in hot water or second way is
hydrothermally dissolving a reactive silica source, mainly
silica sand, into the respective alkali hydroxide solution (PQ
Europe 2004).
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072
`
© 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 625
Fig.5. Sodium Silicate Solution
2.4 Super plasticizer
To improve the workability of fresh concrete super
plasticizer are added which are high range water reducing
naphthalene based super plasticizer Conplast SP 430.
 Conplast SP-430 is based on sulphonated naphthalene
polymer.
 It is brown in color and instantly disperses in water.
 Conplast SP-430 has a minimum 12 month of durability
when stored in normal temperature.
Fig.6. Conplast SP-430
2.5 Steel fibers
Steel fibers were used to increase the tensile strength of the
Geopolymer concrete. It also act has a crack arresting
material in concrete. Thecrimpedsteelfiberwithaspectratio
60 is used.
 Effective diameter : 0.5 mm
 Length: 30 mm
 Specific gravity more than: 7.86
 Melting point : 11210 C
 Aspect ratio : 60
 Density of steel fiber : 7850 Kg/m3
Fig.7. Steel fibers
2.6 Poly propylene fiber
The fibers are polymeric synthetic fibers used toincreasethe
tensile strength and to arrest the crack.
 Effective diameter : 0.05 mm
 Length: 12 mm
 Specific gravity more than: 1.0
 Melting point : 160o C
 Aspect ratio : 240
 Density of polypropylene fiber : 900 to 920 Kg/m3
Fig.8. Polypropylene fiber
2.7 Ratio of Steel fiber to polypropylene fiber
As the density of steel fiber is higher than the density of poly
propylene fiber, (i.e. 1 part of polypropylene fiber equal to
8.72 times of steel fiber). The amount addition of fiber in this
study is combination of steel and polypropylene fiber of
0.3%, 0.6% and 0.90%. So add 88.50% of steel fiber and
11.5% of poly propylene fiber to the amount of cementitious
material (Fly ash). Following Table.3 gives the details of
amount of fiber (steel fiber and poly propylene fiber
separately) to be added to the geopolymer concrete at the
time of preparation.
Table -3: Quantity of fiber required to the GPC mix
Material
Mass, kg/m3
0.3% 0.6% 0.9%
Steel fiber
(88.50%)
1.046 2.092 3.138
Poly propylene
fiber (11.50%)
0.135 0.270 0.405
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072
`
© 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 626
3. GEOPOLYMER CONCRETE MIX PROPORTION
3.1 Mixing
Fly ash and aggregates were first mixed together dry in 80
liters capacity pan mixer for around 2 to 3 minutes.
Aggregates used in this mix are saturated surface dry
condition. Get ready with alkaline liquid and super
plasticizer, and the extra water if required to be added
depends upon the workability or ease of the concrete. The
liquid componentalkalineliquidslowlyaddedtothepanwith
continuous mix with the dry material, this mixing should be
again continued up to 2 minutes. Then the steel fibers and
poly propylene fibers were added after the addition of liquid
in the pan mixer and mixed for 1 to 2 more minutes the same
procedure were repeated for different volume fraction of
fibers 0.3%, 0.6% and 0.9%. Then the prepared fresh
concrete is poured in the workability mould and check the
consistency of the concrete. If the Geopolymer concrete
doesn’t achieve required slump (80 to 100), discard the
sample and prepare the freshmixonceagainbyrepeatingthe
same procedure with different mix proportions, then pour
the concrete to the moulds prepared which are already oiled
or greased and tamped as same as the conventionalconcrete.
Table -4: Quantity of materials as per the Mix design
Materials Mass, kg/m3
Coarse aggregate
15% 20mm 277
20% 12mm 370
35% 6mm 647
Fine aggregate
(30%)
554
Fly ash 394.28
Na2Sio3 112.66
NaOH 45.06
Super plasticizer 2.0 %
Extra water 5 %
Fig.9. Fresh Geopolymer Concrete mix
3.2 Curing of geopolymer concrete
After the preparation of freshconcretetheconcreteisfilledin
the moulds and leave them24hoursintheroomtemperature
and then it is demoulded and kept in oven for curing at the
temperature of 600 C for 24 hours. The curing temperature
will also influence the strength of concrete. The chemical
reaction occurs in the geopolymer concrete and the
polymerization process takes place in the curing processes.
The specimens were then allowed to ambient curing. Some
researches noticed that even curing these specimens in oven
for extended duration with constant temperature may
increase the strength properties of the geopolymer concrete.
Fig.10. Oven curing of Geopolymer Concrete specimens
4. TEST RESULTS AND DISCUSSIONS
4.1 Compressive Strength on GPC
Concrete is used mostly for structural purposes such as
foundations, columns, beams and floors and therefore must
be capable in taking the loads that will be applied. One of the
methods of checking its fit for purpose is to carry out a
concrete cube test which measures the compressible cube
strength of the concrete and relates directly to the required
design strength specified. Compressive strength is in turn
related with durability, higher compressivestrengthbetteris
the durability.
Relevant Indian Standards: As per IS: 516-1959
Compressive strength = [P/A] N/mm2
Cross sectional area of cube = 0.0225m2 ,
Pace ratio = 5.2
Table -5: Compressive strength test results
Compressive strength (MPa)
% of
fibre
7 Days 28 Days
Steel
Fibre
Poly-
propylene
Steel
Fibre
Poly-
propylene
0 54.45 54.45 57.30 57.30
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072
`
© 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 627
0.3 60.01 56.80 60.85 60.96
0.6 54.75 52.90 56.05 56.86
0.9 52.85 50.85 53.50 54.15
Chart -1: Compressive strength v/s % of fiber @ 7 days
Chart -2: Compressive strength v/s % of fiber @ 28 days
4.2 Split Tensile Strength on GPC
Tensile strength is one of the basic and important properties
of concrete. The concrete is not usually expected to resist the
direct tension because of its low tensile strength and brittle
nature. However determination of tensile strength of
concrete is necessary to determine the load at which the
concrete may crack. The crack is a form of tension or flexure
failure.
cross sectional area of cylinder = [(2xP) / (πxdxL)] N/mm2
Pace ratio = 4.8
Table -6: Split Tensile strength test results
Split Tensile strength (MPa)
% of
fibre
7 Days 28 Days
Steel
Fibre
Poly
propylene
Steel
Fibre
Poly
propylene
0 2.61 2.61 3 3.00
0.3 3.72 3.28 3.82 3.52
0.6 4.39 3.25 5.33 3.34
0.9 3.52 2.76 3.69 2.81
Chart -3: Split tensile strength v/s % of fiber @ 7 days
Chart -4: Split tensile strength v/s % of fiber @ 28 days
4.3 Flexural Strength on GPC
The flexural strength is expressed as “Modulus of Rupture”
(MR). Flexural MR is about 12% to 20% of compressive
strength. However, the best correlation forspecificmaterials
is obtained by laboratory tests. Flexural tests are extremely
sensitive to specimen preparation, handling, and curing
procedure. A short period ofdryingcanproduceasharpdrop
in flexural strength. The beam is of a rectangular cross
section of 100 mm x 100 mm and length of 500 mm. The size
of test specimen was selected to suit the capacity of the
testing machine in the laboratory. All beams were simply
supported over a span of 500 mm. Fig. 4.19, 4.20 and 4.21
show the loading configuration and a typical test set-up for
each test specimen. Flexural strength is the ability of a beam
or slab to resist failure in bending.
Flexural strength= [(PxL) / (BxD2)] N/mm2
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072
`
© 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 628
Where,
P: Failure load ; L: Length of the beam
B: Breadth of the beam ; D: Depth of the beam
Table -7: Flexural strength test results
Flexural strength (MPa)
% of
fibre
7 Days 28 Days
Steel
Fibre
Poly
propylene
Steel
Fibre
Poly
propylene
0 6.62 6.62 6.87 6.88
0.3 9.75 9.88 10.375 10.125
0.6 10.75 7.62 11.25 7.75
0.9 10.37 6 10.625 6.25
Chart -5: Flexural strength v/s % of fiber @ 7 days
Chart -6: Flexural strength v/s % of fiber @ 28 days
5.0 CONCLUSION
 The geopolymer concrete is having good compressive
strength as the % of steel fibres and polypropolyne fibre
increased up to volume fraction of 0.3% and the strength
decreases hence the optimum dosage of fibre is 0.3%.
 The geopolymer concrete with steel fibre increase the
split tensile strength up to 0.6% of volume fraction and
decreases as the fibre increased from 0.6% to 0.9%
therefore the optimum dosage of steel fibre admixture
was 0.6%.
 The geopolymer concrete with steel fibre increase the
flexural strength up to 0.6% of volume fraction and
decreases as the fibre increased from 0.6% to 0.9%
therefore the optimum dosage of steel fibre admixture
was 0.6%.
 The geopolymer concrete with polypropylene fibres
increase the split tensile strength up to 0.3% of volume
fraction and decreases as the fibreincreasedfrom0.3%to
0.9% therefore the optimum dosage of steel fibre
admixture was 0.3%.
 The geopolymer concrete with polypropylene fibre
increase the flexural strength up to 0.3% of volume
fraction and decreases as the fibreincreasedfrom0.3%to
0.9% therefore the optimum dosage of steel fibre
admixture was 0.3%.
REFERENCES
[1] Davidovits, J.Supriya, “Experimental Study on Bagasse
Ash in Concrete by Partially Replacement withCement”,
International Journal of Computer Engineering In
Research Trends, Volume 2, Issue 12, December-1994,
PP. 995-1001.
[2] D. Hardjito, B. V. Rangan, “Development and properties
of Low-calcium fly ash based geopolymer concret”,
Austria, 2005, pp. 1-94,
https://hdl.handle.net/20.500.11937/5594.
[3] M I Abdul Aleem, P D Arumairaij, “Optimum mix for the
geopolymer concrete”, Indian Journal of Science and
Technology, Vol.5, pp.2299-2301, 2012.
[4] Nabil M. and Al-Akhras, „Durability of metakaolin
concrete to sulphate attack‟, Cement and Concrete
Research, Vol. 36, Issue. 9, 2006.
[5] Abhishek C. Ayachit, Pranav B. Nikam, SiddharthN.Pise,
Akash D. Shah , Vinayak, H. Pawar “Mix Design of Fly-
Ash Based Geopolymer Concrete”, International Journal
of Scientific and Research Publications,Vol 6,Issue2,pp.
381- 385, 2016.
[6] Ali A. Aliabdo, Abd Elmoaty M. Abd Elmoaty, Hazem A.
Salem, “Effect of CementAddition,SolutionResting Time
and Curing CharacteristicsonFlyAshBasedGeopolymer
Concrete Performance”, Construction and building
materials, Vol.23, pp. 581-593, 2016.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072
`
© 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 629
[7] Amin N, “Use of bagasse ash in concrete and its impact
on the strength and chloride resistivity”, Journal of
Materials in civil engineering (ASCE)23(5),pp.717-720,
2011.
[8] Lavanya M R, Sugumaran B, Pradeep T, “An
experimental study on the compressive strength of
concrete by partial replacement of cement with
sugarcane bagasse ash”, International Journal of
Engineering Innovations, 1, pp.01-04, 2012.
[9] Bahurudeen A, Kanraj D, Dev V G, Santhanam M,
“Performance evaluation of sugarcane bagasse ash
blended cement in concrete”, Cement and concrete
Composites, 2015.
[10] Castaldelli V N, Akasaki J L, Melges J T, Tashima M M,
Soriano L, Borrachero M V, Monzo J, Paya J, “Use of slag
/sugarcane bagasse ash blends in thr production of
alkali – activated materials”, Materials, 6(8), p.p.3108-
3127, 2013.
[11] Akram T, Memon S A, Obaid H, “Production of low cost
self compacting concrete using bagasse ash”,
Construction and building Materials, 23(2),pp.703-712,
2009.

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Effect of steel fiber and poly propylene fiber on the strength properties of fly ash based Geopolymer concrete

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072 ` © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 623 Effect of steel fiber and poly propylene fiber on the strength properties of fly ash based Geopolymer concrete Gururaj M H 1, Naresh Kumar B G 2 1 Assistant Professor, Department of Civil Engineering, Maharaja Institute of Technology Mysore, Mandya, Karnataka, India. 2 Professor, Department of Civil Engineering, Maharaja Institute of Technology Mysore, Mandya, Karnataka, India. ---------------------------------------------------------------------***--------------------------------------------------------------------- Abstract – In order to improve the tensile strength and durability properties of Geopolymer concrete addition offibre particles play a vital role in the field of modern concrete technology. In this research, combined effectsofsteelfibre and polypropylene fibre were studied with different aspect ratios. The crimped steel fiber with aspect ratio 60 and polymeric synthetic fibers of aspect ratio 240 were used. Alkaline liquids (Sodium Hydroxide and Sodium, Silicate solution) together mixed with proper ratio (Ratio of Na2SiO3 to NaOH is 2.50). Sodium hydroxide solution was madeby dissolvingNaOH solid in water. Sodium hydroxide solutions were prepared for 12 molar mass of solid depends on the concentration of solution. For 12 molar solution 480gm of NaOH pellet were mixed in 1000 ml of water. Key Words: Steel fiber, poly propylene fiber, geopolymer concrete, fly ash, alkaline liquid. 1. INTRODUCTION Concrete is the second highest consumable material in the world next to water. As construction increases demand of concrete increases so the demand of Portland cement also increases. Around 65% of global warming is contributed by carbon dioxide among all greenhouse gasses due to the production of cement. The cement industries is also one of the responsible for the emission ofcarbondioxidethatisone tone of carbon dioxide is emitted in production of one tone Portland cement to the atmosphere The utilization of the other cementing materials such as fly ash, silica fume, granulated blast furnace slag, rice husk etc. are developedas the alternative binders to the Portland cement. In the meantime the Geopolymer technology was introduced. These new binders which are alternative materials to blended cement and concrete are obtained by the alkaline activation or geopolymerization of different industrial products. To improve the mechanical performance of Geopolymer concrete theefficientmethodistoaddthefibers in concrete. Adding of these fibers will arrest the crack, also it is well known for the increase in facture toughness provided by fiber bridging on the main crack plane prior to crack extension. The steel fiber and polypropylenefibers are used in this experiment and study themechanical properties and behavior of Geopolymer concrete. This document is template. We ask that authors followsome simple guidelines. In essence,weask youtomakeyourpaper look exactly like this document. The easiest way to do this is simply to download the template, and replace(copy-paste) the content with your own material. Number the reference items consecutively in square brackets (e.g. [1]). However the authors name can be used along with the reference number in the running text. The order of reference in the running text should match with the list of references at the end of the paper. 1.1 Scope of the work  The experimental work was conducted to obtain the strength of fly ash based GPC at temperature of 60ºC.  In this experimental work only one source of dry low calcium fly ash (class F) from the Raichur Thermal Power Station (RTPS) was used.  Sodium silicate solution and Sodium hydroxide pellets were procured commercially from local vender.  Fiber admixture like steel fiber and polypropylene fiber are introduced in the concrete.  To prepare the concrete that exhibits environmental friendly and minimize the global warming.  Manufacture and test of compressive strength, split tensile strength and flexural strength of geopolymer concrete beams with fiber reinforced and without fiber reinforced by changing the volume fraction of the fiber. 2. MATERIALS & METHODS 2.1 Fly ash Fly ash used in this study was low calcium (class F) dry fly ash from Raichur Termal Power Station, Shakthinagar, Karntaka. Fly ash is the alumino silicatesource materialused for the synthesis of geo polymeric binder.  Specific gravity : 2.36
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072 ` © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 624  Fineness (air permeabilityapparatus):426.038cm2/gm Fig -1: Low calcium fly ash 2.2 Aggregates Locally available aggregates were used comprising of 20mm, 12mm and 6mm and fine aggregate passing through 4.75 mm all aggregates were in saturated surface dry condition. The course aggregates were crushed granite type and the fine aggregate used in this study was manufactured sand. Table -1: Physical characteristics of course aggregate Sl. No. Specific gravity Fineness modulus Flakiness index Density kg/m3 loose Rodded 1 2.63 7.04 28.4% 1228 1504 Fig -2: Coarse aggregate Fig -3: Fine aggregate Table -2: Physical characteristics of fine aggregate Sl. No. Specific gravity Fineness modulus Density kg/m3 loose Rodded 1 2.56 2.506 1350 1617 2.3 Alkali Activator In the alkaline activator substances of Silica are dissolved in strong alkaline conditions with high PH. During the dissolution of the silicaand aluminum the alkalinesolutionis active and plays a main role in the condensation process (Lindgård et al. 2012). Sodium hydroxide, potassium hydroxide, sodium silicate and potassium silicate are the common activators used forgeopolymer. Alkaline liquidwas framed by mixing sodium hydroxide (NaOH) solution and sodium silicate (Na2SiO3) solution. Sodium hydroxide solution was madebydissolvingNaOHsolidinwater.Sodium hydroxidesolutionswerepreparedfor12molarmassofsolid depends on the concentration of solution. For 12 molar solution 480gm of NaOH pellet were mixed in 1000 ml of water. Where 1M = 40gm of solid in 1000 ml water, during the process of mixing lotofheatgetliberatedwhendissolving NaOH pellet in water. Therefore solution is kept for cool for 24 hour; this duration is required forpolymerizationprocess of alkaline liquids. 2.3.1 Sodium Hydroxide (NaOH) Caustic soda is the other name to Sodium hydroxide, which is manufactured by theelectrolysis of sodiumchloride brine in a membrane or diaphragm electrolytic cell (Occidental Chemical Corporation 2000). Paperindustryand manufacturers that need an alkaline based material are the largest users and buyers of caustic soda. Sodium hydroxide (NaOH) is accessible in four varieties: beads, flakes, compounders andsolid castings. All the forms have thesame chemical composition. Fig.4. Sodium Hydroxide flakes 2.3.2 Sodium Silicate Solution (Na2SiO3) Alkali silicates Solutions are also termed as “water glass”. Na2SiO3Solution can be produced in two ways one by dissolving alkali silicate pellets in hot water or second way is hydrothermally dissolving a reactive silica source, mainly silica sand, into the respective alkali hydroxide solution (PQ Europe 2004).
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072 ` © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 625 Fig.5. Sodium Silicate Solution 2.4 Super plasticizer To improve the workability of fresh concrete super plasticizer are added which are high range water reducing naphthalene based super plasticizer Conplast SP 430.  Conplast SP-430 is based on sulphonated naphthalene polymer.  It is brown in color and instantly disperses in water.  Conplast SP-430 has a minimum 12 month of durability when stored in normal temperature. Fig.6. Conplast SP-430 2.5 Steel fibers Steel fibers were used to increase the tensile strength of the Geopolymer concrete. It also act has a crack arresting material in concrete. Thecrimpedsteelfiberwithaspectratio 60 is used.  Effective diameter : 0.5 mm  Length: 30 mm  Specific gravity more than: 7.86  Melting point : 11210 C  Aspect ratio : 60  Density of steel fiber : 7850 Kg/m3 Fig.7. Steel fibers 2.6 Poly propylene fiber The fibers are polymeric synthetic fibers used toincreasethe tensile strength and to arrest the crack.  Effective diameter : 0.05 mm  Length: 12 mm  Specific gravity more than: 1.0  Melting point : 160o C  Aspect ratio : 240  Density of polypropylene fiber : 900 to 920 Kg/m3 Fig.8. Polypropylene fiber 2.7 Ratio of Steel fiber to polypropylene fiber As the density of steel fiber is higher than the density of poly propylene fiber, (i.e. 1 part of polypropylene fiber equal to 8.72 times of steel fiber). The amount addition of fiber in this study is combination of steel and polypropylene fiber of 0.3%, 0.6% and 0.90%. So add 88.50% of steel fiber and 11.5% of poly propylene fiber to the amount of cementitious material (Fly ash). Following Table.3 gives the details of amount of fiber (steel fiber and poly propylene fiber separately) to be added to the geopolymer concrete at the time of preparation. Table -3: Quantity of fiber required to the GPC mix Material Mass, kg/m3 0.3% 0.6% 0.9% Steel fiber (88.50%) 1.046 2.092 3.138 Poly propylene fiber (11.50%) 0.135 0.270 0.405
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072 ` © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 626 3. GEOPOLYMER CONCRETE MIX PROPORTION 3.1 Mixing Fly ash and aggregates were first mixed together dry in 80 liters capacity pan mixer for around 2 to 3 minutes. Aggregates used in this mix are saturated surface dry condition. Get ready with alkaline liquid and super plasticizer, and the extra water if required to be added depends upon the workability or ease of the concrete. The liquid componentalkalineliquidslowlyaddedtothepanwith continuous mix with the dry material, this mixing should be again continued up to 2 minutes. Then the steel fibers and poly propylene fibers were added after the addition of liquid in the pan mixer and mixed for 1 to 2 more minutes the same procedure were repeated for different volume fraction of fibers 0.3%, 0.6% and 0.9%. Then the prepared fresh concrete is poured in the workability mould and check the consistency of the concrete. If the Geopolymer concrete doesn’t achieve required slump (80 to 100), discard the sample and prepare the freshmixonceagainbyrepeatingthe same procedure with different mix proportions, then pour the concrete to the moulds prepared which are already oiled or greased and tamped as same as the conventionalconcrete. Table -4: Quantity of materials as per the Mix design Materials Mass, kg/m3 Coarse aggregate 15% 20mm 277 20% 12mm 370 35% 6mm 647 Fine aggregate (30%) 554 Fly ash 394.28 Na2Sio3 112.66 NaOH 45.06 Super plasticizer 2.0 % Extra water 5 % Fig.9. Fresh Geopolymer Concrete mix 3.2 Curing of geopolymer concrete After the preparation of freshconcretetheconcreteisfilledin the moulds and leave them24hoursintheroomtemperature and then it is demoulded and kept in oven for curing at the temperature of 600 C for 24 hours. The curing temperature will also influence the strength of concrete. The chemical reaction occurs in the geopolymer concrete and the polymerization process takes place in the curing processes. The specimens were then allowed to ambient curing. Some researches noticed that even curing these specimens in oven for extended duration with constant temperature may increase the strength properties of the geopolymer concrete. Fig.10. Oven curing of Geopolymer Concrete specimens 4. TEST RESULTS AND DISCUSSIONS 4.1 Compressive Strength on GPC Concrete is used mostly for structural purposes such as foundations, columns, beams and floors and therefore must be capable in taking the loads that will be applied. One of the methods of checking its fit for purpose is to carry out a concrete cube test which measures the compressible cube strength of the concrete and relates directly to the required design strength specified. Compressive strength is in turn related with durability, higher compressivestrengthbetteris the durability. Relevant Indian Standards: As per IS: 516-1959 Compressive strength = [P/A] N/mm2 Cross sectional area of cube = 0.0225m2 , Pace ratio = 5.2 Table -5: Compressive strength test results Compressive strength (MPa) % of fibre 7 Days 28 Days Steel Fibre Poly- propylene Steel Fibre Poly- propylene 0 54.45 54.45 57.30 57.30
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072 ` © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 627 0.3 60.01 56.80 60.85 60.96 0.6 54.75 52.90 56.05 56.86 0.9 52.85 50.85 53.50 54.15 Chart -1: Compressive strength v/s % of fiber @ 7 days Chart -2: Compressive strength v/s % of fiber @ 28 days 4.2 Split Tensile Strength on GPC Tensile strength is one of the basic and important properties of concrete. The concrete is not usually expected to resist the direct tension because of its low tensile strength and brittle nature. However determination of tensile strength of concrete is necessary to determine the load at which the concrete may crack. The crack is a form of tension or flexure failure. cross sectional area of cylinder = [(2xP) / (πxdxL)] N/mm2 Pace ratio = 4.8 Table -6: Split Tensile strength test results Split Tensile strength (MPa) % of fibre 7 Days 28 Days Steel Fibre Poly propylene Steel Fibre Poly propylene 0 2.61 2.61 3 3.00 0.3 3.72 3.28 3.82 3.52 0.6 4.39 3.25 5.33 3.34 0.9 3.52 2.76 3.69 2.81 Chart -3: Split tensile strength v/s % of fiber @ 7 days Chart -4: Split tensile strength v/s % of fiber @ 28 days 4.3 Flexural Strength on GPC The flexural strength is expressed as “Modulus of Rupture” (MR). Flexural MR is about 12% to 20% of compressive strength. However, the best correlation forspecificmaterials is obtained by laboratory tests. Flexural tests are extremely sensitive to specimen preparation, handling, and curing procedure. A short period ofdryingcanproduceasharpdrop in flexural strength. The beam is of a rectangular cross section of 100 mm x 100 mm and length of 500 mm. The size of test specimen was selected to suit the capacity of the testing machine in the laboratory. All beams were simply supported over a span of 500 mm. Fig. 4.19, 4.20 and 4.21 show the loading configuration and a typical test set-up for each test specimen. Flexural strength is the ability of a beam or slab to resist failure in bending. Flexural strength= [(PxL) / (BxD2)] N/mm2
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 02 | Feb 2023 www.irjet.net p-ISSN: 2395-0072 ` © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page 628 Where, P: Failure load ; L: Length of the beam B: Breadth of the beam ; D: Depth of the beam Table -7: Flexural strength test results Flexural strength (MPa) % of fibre 7 Days 28 Days Steel Fibre Poly propylene Steel Fibre Poly propylene 0 6.62 6.62 6.87 6.88 0.3 9.75 9.88 10.375 10.125 0.6 10.75 7.62 11.25 7.75 0.9 10.37 6 10.625 6.25 Chart -5: Flexural strength v/s % of fiber @ 7 days Chart -6: Flexural strength v/s % of fiber @ 28 days 5.0 CONCLUSION  The geopolymer concrete is having good compressive strength as the % of steel fibres and polypropolyne fibre increased up to volume fraction of 0.3% and the strength decreases hence the optimum dosage of fibre is 0.3%.  The geopolymer concrete with steel fibre increase the split tensile strength up to 0.6% of volume fraction and decreases as the fibre increased from 0.6% to 0.9% therefore the optimum dosage of steel fibre admixture was 0.6%.  The geopolymer concrete with steel fibre increase the flexural strength up to 0.6% of volume fraction and decreases as the fibre increased from 0.6% to 0.9% therefore the optimum dosage of steel fibre admixture was 0.6%.  The geopolymer concrete with polypropylene fibres increase the split tensile strength up to 0.3% of volume fraction and decreases as the fibreincreasedfrom0.3%to 0.9% therefore the optimum dosage of steel fibre admixture was 0.3%.  The geopolymer concrete with polypropylene fibre increase the flexural strength up to 0.3% of volume fraction and decreases as the fibreincreasedfrom0.3%to 0.9% therefore the optimum dosage of steel fibre admixture was 0.3%. REFERENCES [1] Davidovits, J.Supriya, “Experimental Study on Bagasse Ash in Concrete by Partially Replacement withCement”, International Journal of Computer Engineering In Research Trends, Volume 2, Issue 12, December-1994, PP. 995-1001. [2] D. Hardjito, B. V. Rangan, “Development and properties of Low-calcium fly ash based geopolymer concret”, Austria, 2005, pp. 1-94, https://hdl.handle.net/20.500.11937/5594. [3] M I Abdul Aleem, P D Arumairaij, “Optimum mix for the geopolymer concrete”, Indian Journal of Science and Technology, Vol.5, pp.2299-2301, 2012. [4] Nabil M. and Al-Akhras, „Durability of metakaolin concrete to sulphate attack‟, Cement and Concrete Research, Vol. 36, Issue. 9, 2006. [5] Abhishek C. Ayachit, Pranav B. Nikam, SiddharthN.Pise, Akash D. Shah , Vinayak, H. Pawar “Mix Design of Fly- Ash Based Geopolymer Concrete”, International Journal of Scientific and Research Publications,Vol 6,Issue2,pp. 381- 385, 2016. [6] Ali A. Aliabdo, Abd Elmoaty M. Abd Elmoaty, Hazem A. Salem, “Effect of CementAddition,SolutionResting Time and Curing CharacteristicsonFlyAshBasedGeopolymer Concrete Performance”, Construction and building materials, Vol.23, pp. 581-593, 2016.
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