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Environment
By
     MUHAMMAD FAHAD ANSARI
                  12 IEEM 14
Why should we study Chemistry?
 Most of the World around us has a chemical basis.
 Consider many ways in which chemistry effects us.

 Our body is a complex aggregate of chemical substances.

 We depends on chemical processes for our life, because
 chemicals provide food, heat, light and the.

 Other essentials such as cloths, building material,
 medicines, dyes, explosives are also made of chemicals.
                                                           3
Chemistry



            4
What is Chemistry?
The science that deals with matter; its
composition; its properties; the changes in
composition that it will undergo; its relationship
to energy; and the laws, principles, theories, and
concepts that describe, interpret, and predict its
behavior and basic nature.




                                                     6
 Organic Chemistry is simply the chemistry of
 the compounds of the element carbon. In other
 words the properties of organic compounds are
 largely a result of the covalent bond.
 Except the carbon-containing compounds such as
 carbon dioxide, the carbonates, bicarbonates, and
 carbides.

 Biochemistry: The chemistry that deals with the
 substances and reaction in living organisms.


                                                     7
 Electrochemistry: the chemistry dealing with the
 effects of electricity on chemical reactions and the
 production of electricity through chemical
 processes.

 Chemical reactions involve an electron exchange
 between the reactants. These reactions are called
 oxidation-reduction reactions or electrochemical
 reactions.
 There are two different classes of electrochemical
 reactions: those that produce electrical energy
 and those that are produced by electrical energy.
                                                        8
 Analytical Chemistry: deals with the analysis of
 compounds and mixtures. Samples are separated
 into their component parts to determine what is
 present (qualitative) and how much (quantitative
 analysis).

 Stoichiometry: refers to measurements and
 relationship involving substances and mixtures of
 chemical interest.

                                                     9
Nuclear Chemistry

The primary functions of atomic nuclei in the phenomena
we have considered in establishing the masses of atoms
and molecules and in furnishing a center of positive
charge to keep electrons in position.




                                                      10
Periodic Table




                 11
 Metals: They are good conductors of electricity;
 they contain only one or two weakly electrons in
 their outer energy levels.

 Non-metals:     They have relatively strong
 attraction for the electrons in their outer energy
 levels.

 Metalloids: The elements whose properties are
 intermediate between those of the metallic and
 non-metallic elements.

                                                  12
 Atomic Number: The number of protons in the
 nucleus of its atoms.

 Atomic Mass: The sum of protons and neutrons
 in an atom.

 Equivalent weight: The molecular weight of a
 substance divided by its combining capacity in the
 reaction.

 Valence: The number of electrons an element
 gains, loses, or shares in forming a compound.   13
Electronegativity




                    14
15
16
17
18
Electro-negativity
 The bonds between two elements can be purely
 ionic, purely covalent, or anywhere in between
 depending on the elements involved.

 The electro-negativity expresses the power of an
 atom in a molecule to attract shared electrons.

 The    electro-negativity values come from
 measurements of the strength of bonds between
 atoms and from measurements of the amount of
 electrical energy required to remove an electron
 from an atom of an element.
                                                   19
 Fluorine (F) which has the strongest attraction for
 electrons of all the reactive elements is assigned
 an electro-negativity value of 4. All other elements
 are compared to fluorine.

 According to Pauling (1901), if the difference
 between the electro-negativity values of the two
 elements is 2.0 or more, the bond is mainly
 ionic. If the electro-negativity difference is less
 than 2.0, the bond is mainly covalent.

                                                    20
Bonding between Elements
 Ionic Bond: The electrostatic attraction that
 exists between positive ions formed when one
 atom loses electrons and negative ions formed by
 the atoms that gain the electrons.

 Covalent Bond (Coordinate Covalent Bond):
 A bond between two atoms in which they are
 overlapping orbitals and sharing a pair of
 electrons, both of which originally belonged to
 only one of the atoms.

                                                21
 Ionic bond with: exchange of electrons to form
 stable octet; bond between a metal and nonmetal;
 example: NaCl, CaF2

 Covalent bond with: sharing of electrons to form
 stable octet; bond between nonmetals; example:
 Cl2, N2

 Polar covalent bond with: unequal sharing of
 electrons to form stable octet; example: H2O, NH3

 Metallic bond with: sea of mobile electrons;
 bond between metals; example: Cu, Ag                22
Polar and Non-Polar Molecules
 Any diatomic molecule that has a non-polar bond
 is non-polar. Example: All diatomic molecules: Cl2,
 N2, O2, etc… Otherwise, it will generally be polar.

 Molecules that consist of 3 or more atoms are
 generally polar unless the following condition is
 met:
 If the central atom has no lone pairs and is
 surrounded by atoms of one element, then the
 molecule will be non-polar, for example, CO2.
                                                   23
Organic and Inorganic Compounds
 The distinction between the compounds found in
 the earth associated with rocks and soil and those
 associated with living organisms.

 The two groups of compounds differ in their
 occurrence and in many of their properties.

 The compounds associated with living organisms
 called organic compounds, and the earthy
 compounds are called inorganic compounds.

                                                  24
Table- Properties of
               Ionic and Covalent Compounds
          Inorganic (Ionic)                        Organic (Covalent)
            Compounds                                 Compounds
1   Solids, often crystalline,      May be solid, liquid, or gas, depending on the size of
    relatively hard and brittle     the molecules and the degree of intermolecular
                                    attraction (polarity and ability to form hydrogen
                                    bonds)
2   Relatively high melting and     Relatively low melting and boiling points, depending
    boiling points                  primarily on the size of the molecules and the
                                    amount of intermolecular attraction
3   Relatively soluble in water and Relatively insoluble in water and soluble in organic
    insoluble in organic (non       liquids; polarity and ability to form hydrogen bonds
    polar) liquids                  greatly increases water solubility
4   Electrolytes-solutions conduct Most are non electrolytes
    electricity
5   Relatively stable to heat       Relatively unstable to heat
                                                                                        25

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Lecture 1 By MUHAMMAD FAHAD ANSARI 12 IEEM 14

  • 1.
  • 2. Environment By MUHAMMAD FAHAD ANSARI 12 IEEM 14
  • 3. Why should we study Chemistry? Most of the World around us has a chemical basis. Consider many ways in which chemistry effects us.  Our body is a complex aggregate of chemical substances.  We depends on chemical processes for our life, because chemicals provide food, heat, light and the.  Other essentials such as cloths, building material, medicines, dyes, explosives are also made of chemicals. 3
  • 5.
  • 6. What is Chemistry? The science that deals with matter; its composition; its properties; the changes in composition that it will undergo; its relationship to energy; and the laws, principles, theories, and concepts that describe, interpret, and predict its behavior and basic nature. 6
  • 7.  Organic Chemistry is simply the chemistry of the compounds of the element carbon. In other words the properties of organic compounds are largely a result of the covalent bond. Except the carbon-containing compounds such as carbon dioxide, the carbonates, bicarbonates, and carbides.  Biochemistry: The chemistry that deals with the substances and reaction in living organisms. 7
  • 8.  Electrochemistry: the chemistry dealing with the effects of electricity on chemical reactions and the production of electricity through chemical processes. Chemical reactions involve an electron exchange between the reactants. These reactions are called oxidation-reduction reactions or electrochemical reactions. There are two different classes of electrochemical reactions: those that produce electrical energy and those that are produced by electrical energy. 8
  • 9.  Analytical Chemistry: deals with the analysis of compounds and mixtures. Samples are separated into their component parts to determine what is present (qualitative) and how much (quantitative analysis).  Stoichiometry: refers to measurements and relationship involving substances and mixtures of chemical interest. 9
  • 10. Nuclear Chemistry The primary functions of atomic nuclei in the phenomena we have considered in establishing the masses of atoms and molecules and in furnishing a center of positive charge to keep electrons in position. 10
  • 12.  Metals: They are good conductors of electricity; they contain only one or two weakly electrons in their outer energy levels.  Non-metals: They have relatively strong attraction for the electrons in their outer energy levels.  Metalloids: The elements whose properties are intermediate between those of the metallic and non-metallic elements. 12
  • 13.  Atomic Number: The number of protons in the nucleus of its atoms.  Atomic Mass: The sum of protons and neutrons in an atom.  Equivalent weight: The molecular weight of a substance divided by its combining capacity in the reaction.  Valence: The number of electrons an element gains, loses, or shares in forming a compound. 13
  • 15. 15
  • 16. 16
  • 17. 17
  • 18. 18
  • 19. Electro-negativity The bonds between two elements can be purely ionic, purely covalent, or anywhere in between depending on the elements involved.  The electro-negativity expresses the power of an atom in a molecule to attract shared electrons.  The electro-negativity values come from measurements of the strength of bonds between atoms and from measurements of the amount of electrical energy required to remove an electron from an atom of an element. 19
  • 20.  Fluorine (F) which has the strongest attraction for electrons of all the reactive elements is assigned an electro-negativity value of 4. All other elements are compared to fluorine.  According to Pauling (1901), if the difference between the electro-negativity values of the two elements is 2.0 or more, the bond is mainly ionic. If the electro-negativity difference is less than 2.0, the bond is mainly covalent. 20
  • 21. Bonding between Elements  Ionic Bond: The electrostatic attraction that exists between positive ions formed when one atom loses electrons and negative ions formed by the atoms that gain the electrons.  Covalent Bond (Coordinate Covalent Bond): A bond between two atoms in which they are overlapping orbitals and sharing a pair of electrons, both of which originally belonged to only one of the atoms. 21
  • 22.  Ionic bond with: exchange of electrons to form stable octet; bond between a metal and nonmetal; example: NaCl, CaF2  Covalent bond with: sharing of electrons to form stable octet; bond between nonmetals; example: Cl2, N2  Polar covalent bond with: unequal sharing of electrons to form stable octet; example: H2O, NH3  Metallic bond with: sea of mobile electrons; bond between metals; example: Cu, Ag 22
  • 23. Polar and Non-Polar Molecules  Any diatomic molecule that has a non-polar bond is non-polar. Example: All diatomic molecules: Cl2, N2, O2, etc… Otherwise, it will generally be polar.  Molecules that consist of 3 or more atoms are generally polar unless the following condition is met: If the central atom has no lone pairs and is surrounded by atoms of one element, then the molecule will be non-polar, for example, CO2. 23
  • 24. Organic and Inorganic Compounds The distinction between the compounds found in the earth associated with rocks and soil and those associated with living organisms.  The two groups of compounds differ in their occurrence and in many of their properties.  The compounds associated with living organisms called organic compounds, and the earthy compounds are called inorganic compounds. 24
  • 25. Table- Properties of Ionic and Covalent Compounds Inorganic (Ionic) Organic (Covalent) Compounds Compounds 1 Solids, often crystalline, May be solid, liquid, or gas, depending on the size of relatively hard and brittle the molecules and the degree of intermolecular attraction (polarity and ability to form hydrogen bonds) 2 Relatively high melting and Relatively low melting and boiling points, depending boiling points primarily on the size of the molecules and the amount of intermolecular attraction 3 Relatively soluble in water and Relatively insoluble in water and soluble in organic insoluble in organic (non liquids; polarity and ability to form hydrogen bonds polar) liquids greatly increases water solubility 4 Electrolytes-solutions conduct Most are non electrolytes electricity 5 Relatively stable to heat Relatively unstable to heat 25