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Thickening Agents In
Cosmetics
              By
      Anay.Nilesh.Kacharia
Role
   Of
     Thickening
            Agent
                in
                 Cosmetic
Principles involved in Thickening


• Stokes's law - is the basis of the falling-sphere
viscometer, in which the fluid is stationary in a vertical
glass tube. A sphere descends through the liquid. it
reaches terminal velocity, which can be measured by the
time it takes to pass two marks on the tube.

• Thixiotropy - It is a property of certain gels which tend
to flow on the account of stress applied on it.
Classification Of Thickening Agents

• Lipid Thickeners- (Beeswax, Cetyl alcohol,
Steryl alcohol )

• Naturally Derived thickeners- (Modified Cellulose,
Guar gum, Xanthan Gum, Gelatin )

•Synthetic Thickeners- (Carbomers, Polyethylene
Glycol)

• Ionic Thickeners- (Salt)
Carbomer’s
• A family of Cross-Linked Acid Polymers

• They are essential ingredients in Cosmetics and
  Pharmaceuticals
• They are Excellent Rheology Modifiers
Carbopol Polymers
• They are High Mol.Wt Polyacrylic acids,
  Cross-Linked with polyalkenylether

• They provide Thickening with a wide range of flow
  properties
Thickening

Mechanism
Hair Styling Gel
           Formulation
Ingredient           Weight %   Function
Deionized Water      61.2       Diluent

PVP                  2.5        Hair Settling Resin

Aminomethyl Propanol 0.30       Neutralizing Agent



CARBOPOL             0.5        Rheology Modifier

Wheat Protein        0.5        Conditioner

Methyl Paraben       0.5        Preservative

Ethanol              34.5       Solvent
Hydroxy Ethyl Cellulose
• It is derived from cellulose

• It is a non-ionic water soluble Polymer

• It can –
   1) Thicken
   2) Bind
   3) Emulsify
   4) Form Films
   5) Retains Water
Salient Features Of
        H.E.C
• Provides a smooth and silky feel to product

• It has high ionic tolerance

• It gives an extremely high clarity in gels

• It offers good compatibility with surfactants

• Wide range of viscosities can be achived with
HEC
• A purified cellulose is treated with NaOH to form a
swollen alkali cellulose

• This swollen alkali cellulose is treated with
ethylene oxide to get a long chains of hydroxy ethyl
cellulose
Physical Properties
Problems with HEC

• CLOUDINESS tends to appear in clear solution in
a short span of time

• It gives a sticky feeling on the hand over a period
of time.

• It consists of 5% of volitile matter which is not
accepted worldwide.
Toothpaste Formulation
         With HEC

Ingredienta                   % weight

Gelling agent (HEC)           1

Humectant(Glycerine)          10-30

Abrasive(CaCO3)               15-40

Sweetner(Saccharin)           0.1-0.2

Flavour                       1-1.5

Surface active agent          1-2

Presevative ,colour & Water   qs
References-
• Harrys cosmeticology

• Noveon website

• ISP Product handbook

• Lubrizol website
Thank you

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Thickening Agents In Cosmetics

  • 1. Thickening Agents In Cosmetics By Anay.Nilesh.Kacharia
  • 2.
  • 3. Role Of Thickening Agent in Cosmetic
  • 4. Principles involved in Thickening • Stokes's law - is the basis of the falling-sphere viscometer, in which the fluid is stationary in a vertical glass tube. A sphere descends through the liquid. it reaches terminal velocity, which can be measured by the time it takes to pass two marks on the tube. • Thixiotropy - It is a property of certain gels which tend to flow on the account of stress applied on it.
  • 5. Classification Of Thickening Agents • Lipid Thickeners- (Beeswax, Cetyl alcohol, Steryl alcohol ) • Naturally Derived thickeners- (Modified Cellulose, Guar gum, Xanthan Gum, Gelatin ) •Synthetic Thickeners- (Carbomers, Polyethylene Glycol) • Ionic Thickeners- (Salt)
  • 6. Carbomer’s • A family of Cross-Linked Acid Polymers • They are essential ingredients in Cosmetics and Pharmaceuticals • They are Excellent Rheology Modifiers
  • 7. Carbopol Polymers • They are High Mol.Wt Polyacrylic acids, Cross-Linked with polyalkenylether • They provide Thickening with a wide range of flow properties
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  • 19. Hair Styling Gel Formulation Ingredient Weight % Function Deionized Water 61.2 Diluent PVP 2.5 Hair Settling Resin Aminomethyl Propanol 0.30 Neutralizing Agent CARBOPOL 0.5 Rheology Modifier Wheat Protein 0.5 Conditioner Methyl Paraben 0.5 Preservative Ethanol 34.5 Solvent
  • 20. Hydroxy Ethyl Cellulose • It is derived from cellulose • It is a non-ionic water soluble Polymer • It can – 1) Thicken 2) Bind 3) Emulsify 4) Form Films 5) Retains Water
  • 21. Salient Features Of H.E.C • Provides a smooth and silky feel to product • It has high ionic tolerance • It gives an extremely high clarity in gels • It offers good compatibility with surfactants • Wide range of viscosities can be achived with HEC
  • 22. • A purified cellulose is treated with NaOH to form a swollen alkali cellulose • This swollen alkali cellulose is treated with ethylene oxide to get a long chains of hydroxy ethyl cellulose
  • 24. Problems with HEC • CLOUDINESS tends to appear in clear solution in a short span of time • It gives a sticky feeling on the hand over a period of time. • It consists of 5% of volitile matter which is not accepted worldwide.
  • 25. Toothpaste Formulation With HEC Ingredienta % weight Gelling agent (HEC) 1 Humectant(Glycerine) 10-30 Abrasive(CaCO3) 15-40 Sweetner(Saccharin) 0.1-0.2 Flavour 1-1.5 Surface active agent 1-2 Presevative ,colour & Water qs
  • 26. References- • Harrys cosmeticology • Noveon website • ISP Product handbook • Lubrizol website