This slide completely describes you about the stuff include in it and also everything about chemical engineering. Fluid Mechanics. Thermodynamics. Mass Transfer Chemical Engineering. Energy Engineering, Mass Transfer 2, Heat Transfer,
2. Chemical reaction engineering is at the heart of virtually every
chemical process. It separates the chemical engineer from other
engineers.
Chemical Reaction Engineering (CRE) is the field that studies
the rates and mechanisms of chemical reactions and the design
of the reactors in which they take place.
3. In Majority of cases, reactor do three things, it provides
I. Residence Time
II. Transfer Heat
III. Agitates or mix phases
Principle Factors Involved in the design of Reactor:
The principle factors which must be considered in the design
of the reactor are:
The Phase involved
Temperature Range
Operating Pressure
Residence Time or Space Velocity
4. Corrosiveness
Heat Transfer
Temperature Control
Agitation for uniformity or temperature control
Batch or Continuous operation
Production rate
5. 4 Types of Reactors
1.. Batch Reactors
2..Continuous Stirred Tank Reactors (CSTR)
3..Tubular Reactors (PFR)
4..Packed Bed Reactors (PBR)
6. A batch reactor has neither inflow nor outflow of reactants or
products while the reaction is being carried out.
In such extend of reaction and properties of reaction mixture
very with time.
Thus composition changes with time.
For gas phases batch reactor may be constant volume or constant
pressure.
7.
8. The reactants are continuously fed and product are also
continuously removed from the reactor.
In such reactor the extend of reaction may vary with position in
reactor not with time.
Thus composition at any point is not changed with time(They
may be continuous-stirred tank or Tubular Reactor)
9.
10. Tubular reactor is one in which there is no mixing in the
direction of flow in the reactor. The reactants are continuously
consumed as they flow in the axial (Down THE LENGTH OF
REACTOR) direction. Thus the concentration varies along the
axial direction. They also called plug flow reactor(PFR), Slug
Flow Reactor, Piston Flow Reactor or un-mixed flow reactor.
11.
12.
13. The starting point of all designs is the material balanced
expressed for any reactant/product. A material Balance on a
reactant species of interest for an element of volume say ΔV can
be written as:
In short,
INPUT – OUTPUT – LOSS OF REACTION = ACCUMULATION
14.
15. When the composition within the reactor is uniform (Independent of
position), we will consider the whole reactor of material balance.
On the other hand when the composition within the reactor is not uniform,
it must be made over a differential element of volume and then integrated
across the whole reactor for the appropriate flow and concentration
condition (For Tubular Flow Reactor).
For the batch reactor the first two terms are zero.
For continuous flow reactors operating at steady –state, the accumulation
terms is omitted.
Where for unsteady state condition are involved, it will be necessary to
integrate over time as well as over volume in order to determine the
performance characteristics of the reactor.
16. Since rate of chemical reactions is normally strongly temperature
dependent, it’s essential to know the temperature at each point in the
reactor in order to be able to utilize the material balance properly.
When there are temperature gradients with in the reactor, it is necessary
to utilize an energy balance in conjunction with the material balance in
order to determine the temperature and composition at each point in the
reactor at a particular time.
The general Energy balance for an element of volume ΔV over a time Δt
can be written as:
17. For completeness, the term corresponding to the entry (In) of
material to the volume element and out, therefore must
contain in addition to the ordinary enthalpy of the material,
its kinetic and potential energy.
However in chemical reactors, only the enthalpy term is
significant.
Although the heat effects in chemical reactors are significant,
shaft work effects are usually negligible.
18. The first, second and fourth terms reflect differences in
temperature and or in composition of the entering and
leaving streams.
The energy effects associated with composition changes are a
direct reflection of enthalpy change associated with the
reaction (i.e heat of reaction)
From the summary we can write in short:
Heat In – Heat Out – Disappearance by reaction = accumulation
19. For the stirred tank reactor contents are uniform in
temperature and composition throughout and it is possible to
write the energy balance over the entire reactor.
In the case of batch reactor, first and second terms are not
there.
For continuous flow systems operating at steady state, the
accumulation term disappears.
For adiabatic operation in the absence of shaft work effects
the energy transfer/disappear term will be omitted/zero.
20. For Tubular Flow Reactors, neither the composition nor the
temperature need to be independent of position and the
energy balance must be written on a differential element of
reactor volume.
The resultant differential equation then must be solved in
conjunction with the differential equation describing the
material balance on the differential element.
The Purpose of the energy balance is to describe the
temperature at each point in the reactor ( or at each time for
Batch Reactor) so that the proper rate may be assigned to that
point.
24. This includes most liquid reactions and also those gas
reactions run at constant temperature and density. Here CA &
XA are related as follows:
Fractional change in volume of the system b/w
no conversion and complete conversion of
reactant A, Thus
Editor's Notes
Π = Total Pressure
PA = Partial Pressure
NA = No. of moles “A”