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Schedule Q
Drugs & Cosmetic Act 1940
Presented by:
Mahewash Sana A. Pathan
INTRODUCTION:
• Schedule Q is one of the schedules under Drugs and Cosmetics rules which
describes the list of dyes, colors and pigments permitted to be used in cosmetics
and soaps.
• Schedule Q further consists of two parts:
• Part I: It consists of the list of dyes, colours and pigments permitted to be used in
cosmetics and soaps as per amended by the BIS from time to time
• Part II: It consists of the list of colours permitted to be used in Soap.
• As per Schedule Q synthetic Organic Colours and Natural Organic Colours used in
the Cosmetics that are permitted for use shall not contain more than:
• 2 parts per million of Arsenic calculated as Arsenic Trioxide.
• 20 parts per million of lead calculated as lead.
• 100 parts per million of Heavy Metals other than lead calculated as the total of
the respective metals.
The list of approved colours and dyes as per
Schedule Q Part I
1. Guinea Green B 2. Toluidine Red
3. Light Green SF Yellowish 4. Flaming Red
5. Tartrazine 6. Deep Red (Maroon)
7. Sunset yellow FCF 8. Alba Red
9. Ponceau 3R 10. Orange G
11. Amarnath 12. Orange II
13. Erythrosine 14. Dichlorofluorescein
15. Ponceau SX 16. Dichlorofluorescein. NA
17. Brilliant Blue FCF 18. Diiodofluorescein
19. Indigo carmine 20. Erythrosine Yellowish NA
21. Wool Violet 5 BN (Acid- violet 6B) 22. Erythrosine Yellowish K
23. Light Green SF Yellowish 24. Erythrosine Yellowish NH
25. Alizarin Cyanine Green F 26. Orange TR
27. Quinizarine Green SS 28. Alizarin
29. Fast Green FCF 30. Dibromodiiodofluorescein
31. Acid Fast Green 32. Resorcin Brown
33. Pyranine Concentrated 34. Alphazurine FG
35. Quinoline Yellow WS 36. Allarin Astrol B
37. Quinoline Yellow SS 38. Indigo
39. Ponceau 2 R 40. Patent Blue NA
41. Lithol Rubin B. 42. Patent Blue CA
42. Lithol Rubin BCA 43. Curbrantherene Blue
44. Lake Red D. 45. Napthol Blue Black
46. Lake Red DBA 47. Alizurol purple SS
48. Lake Red DCA 49. Acid Red 89
50. Toney Red 51. Acid Red 97
52. Oil Red OS 53. Acid Blue 1
54. Tetrabromofluorescein 55. Food Blue 3
56. Eosin TS 57. Natural Orange
58. Eosin YSK 59. Solvent Blues 4
60. Tetrachlorofluorescein NA 61. Solvent Yellow 18
62. Tetrachlorofluorescein K 63. Food Yellow 18
64. Tetrachloro Tetrabromofluorescein 65. Solvent Red 1
66. Phloxine B 67. Solvent Yellow 32
68. Bluish Orange T.R. 69. Fanchon Yellow
71. Helindone Pink CN. 72. (Hansa Yellow G)
73. Deep Maroon (Fanchon Maroon)
Part II – List of Colours permitted to be used in Soaps
1. Phthalocyanine Blue
2. Irgalite Red CVPB Paste or Pigment Orange 5
3. Citrus Red No.2
4. Rhodamine B 500
5. Aqueous Green Paste
6. Pigment Yellow 3
7. Irgalite Carmine F-P Powder or Pigments Red 5.
8. Monolite Red 4R HV Paste or Pigment Red 7
9. Oil Red No.1 or Solvent Red 24 or Oil Red 3R
Common name Color index
number
Chemical name of color
Guinea Green B 42085 Monosodium salt of 4-(N-ethyl-p-sulfobenzylamino)
diphenylmethylone-(1-(N-ethyl-N-p-sulfoniumbenzyl) 2,5-
cyclohexadienimine).
Light Green SF
Yellowish
42095 Disodium salt of 4-[4-(N-ethyl-p-sulfobenzylamine)-phenyl)-
4sulphoniumphenyl) methylene]-2(-(N-ethyl-N-sulfobenzyl) 2,5-
Cyclohexadienimine.
Tartrazine 19140 Trisodium salt of 3-carboxy-5-hydroxy-1-p-sulfophenyl-4-p-
sulfophenylazo-pyrazole.
Sunset yellow FCF 15985 Disodium salt of 1-p-sulfophenylazo-2- naphthol-6-sulfonic acid.
Ponceau 3R 16155 Disodium salts of a mixture of 1-alkyl- phenylazo-2-napthol 3, 6-
disulfonic acids.
Amarnath. 16185 Trisodium salt of 1-(4-sulfo-1- napthylazo) 2-naphthol 3, 6-
disulfonic acid.
Erythrosine. 45430 Disodium salt of 9-0-carboxyphenyl-6- hydroxy 2,4,5, 7-
tetraiodo-3- isoxanthone.
Ponceau SX 14700 Disodium salt of 2-(5 sulfo-2, 4-xylyl- azo)-1-naphthol-4- sulfonic
acid.
Brilliant Blue FCF 42090 Disodium salt of 4-(9-4-(N-ethyl-p-sulfobenzylamino)-phenyl)- 2-
sulfonium phenyl)- methylene)-(1-(N-ethyl-N-p-sulfobenzyl) 2, 5-
cyclohexadienimine).
Indigocarmine. 73015 Disodium salt of 5, -indigotindisulfonic acid.
Wool Violet 5 BN
(Acid- violet 6B)
42640 Monosodium salt of 4-(N-ethyl-p-sulfobenzylamino)-phenyl)-(4- (N-
ethyl-p-(sulfonium-benzylamine)-phenyl) methylene)-(N, N-
dimethyl- 2,5-cyclohexadienimine)
Light Green SF
Yellowish
42095 Calcium salt of 4-(4-(N-ethyl-p-sulfobenzyl) (minophenyl) (4-
sulfonium-phenyl)methylene), (1-(N-ethyl-N-p-sulfobenzyl)- 2,5-
cyclohexadienimine).
Alizarin Cyanine Green
F
61570 Disodium salt of 1,4-bis (O-sulfo-p-toluino) anthraquinone
Quinazarine Green SS 61565 1,4-bis-(p-Toluino)-anthraquinone
Fast Green FCF 42053 Disodium salt of 4-(4-(ethyl-p-sulfobenzylamino)-phenyl) (4-
hydroxy-2 sulphoniumphenyl) methylene)-(1-N-ethyl-N-p-
sulfobenzyl) 2, 5, cyclohexadienimine).
Acid Fast Green 42100 Monosodium salt of 4-(4-N-ethyl-p-sulfobenzylomino) phenyl)- (o-
chlorophenyl)-methylene)- 1-(N-ethyl-N- p-sulfonium- benzyl-
2,5, cyclohexadienimine).
Pyranine Concentrated 59040 Trisodium salt of acid.
Quinoline Yellow WS 47005 Disodium salt of disulfonic acid of 2-(2-Quinolyl)-1, 3indandione.
Quinoline Yellow SS 47000 2-(2-quinolyl)-1, 3 indandiene
Poneceau 2 R 16150 Disodium salt of 1-xylylazo-2-naphthol-3, 6-disulfonic acid
Lithol Rubin B 15850 Monosodium salt of 4-(o-sulfo-p-tolylazo)3 hydroxy-2-naphthoic acid
Lithol Rubin BCA 15850 Calcium salt of 4-(o-sulfo-p-tolylazo)-3-hydroxy-2-naphthoic acid
Lake Red D. 15500 Monosodium salt of 1-0-carboxyphenylazo-2-naphthol.
Lake Red DBA 15500 Barium salt of 1-o-carboxyphenylazo-2-naphthol
Lake Red DCA 15500 Calcium salt of 1-o-carboxyphenylazo-2-naphthol
Toney Red 26100 I-p-phenylazophenylazo-2-naphthol.
Oil Red OS. 26125 I-Xylylazoxylylazo-2-napththol
Tetrabromofluorescein 45380 2,4,5,7-Tetrabromo-3, 6-flurandiol
Eosin TS Disodium salt of 2,4,5,7-tetrabromo-9-0 carboxyphenyl-6- hyroxy-3-
isoxanthone.
Eosin YSK Dipotassium salt of 2,4,5,7-tetrabromo-9-0 carboxyphenyl- 6-hyroxy-
3-isoxanthon
Tetrachlorofluorescein
NA
45366 2,4,5,7- tetrachloro-S, 6-Fluorandiol
Tetrachlorofluorescein
K.
45366 Disodium salt of 9-0-carboxyphenyl-2,4,5,7-tetrachloro-6- hydroxy-3-
isoxanthone
Tetrachloro
Tetrabromo fluorescei
45410 2,4,5,7-Tetrabromo-12,13,14,15-tetrachloro-3, 6-fluorandiol.
Phloxine B 45410 Disodium salt of 2,4,5,7-tetrabromo-9 (3,4,5,6-tetra chloro- o-
carboxyphenyl)-6-hydroxy-3-isoxanthone
Bluish Orange T.R 45457 1,4,5,8, 15-Pentabromo-2, 7-dicarboxy-3, 6-fluoran diol.
Helindone Pink CN. 73360 5, 5-Dichloro-3, 3 dimethyl-thioindigo
Deep Maroon
(Fanchon Maroon)
15880 Calcium salt of 4-(I-sulfo-2-naphthylazo 3- hydroxy-2- naphthoic
acid.
Toluidine Red. 12120 1-(o-Nitro-p-tolylazo)-2-naphthol
Flaming Red. 12085 I- (o-Chloro-p-nitrophenylazo)-2-naphthol
Deep Red (Maroon). 12350 3-Hydroxy-N-(m-nitrophenyl)-4-(o-nitro-p-tolylazo)-2naphthamide
Alba Red. 13058 o- -Dihydroxy-diethylamino)-phenylazo)-benzoic acid.
Orange G 16023 Disodium salt of 1-phenylazo-2-naphthol-6-8-disulfonic acid
Orange II 15510 Monosodium salt of 1-p-sulfophenylazo-2-naphthol.
Dichlorofluorescein 45365 4,5-Dichloro-3, 6-fluorandiol.
Dichlorofluorescein.
NA
45365 Disodium salt of 9-o-carboxyphenyl-1-4,5- dichloro-6- hydroxy-3-
isoxanthone
Diiodofluorescein 45425 4,5 Diiodo-3, 6-fluorandiol
Erythrosine Yellowish
NA
45425 Disodium salt of 9-o-carboxyphenyl-6- hydroxy-4, 5- diiodo-3-
isoxanthone.
Erythrosine Yellowish
K.
45425 Dipotassium salt of 9-o-carboxyphenyl-6-hydroxy-4, 5- diiodo-3-
isoxanthone.
Erythrosine Yellowish
NH
45425 Dipotassium salt of 9-o-carboxyphenyl-6-hydroxy-4, 5- diiodo-3-
isoxanthone
Orange TR 45456 4,5, 15-Tribromo 2, 7-dicarboxy-3, 6- fluorandiol.
Alizarin. 58000 1,2- Anthraquinonediol
Dibromodiiodofluo
rescein.
45371 4 ,5- Dibromo-2, 7-diiodo-3, 6-fluorandiol.
Alphazurine FG 42090 Diammonium salt of 4-(N-ethyl-p- sulfobenzyl amino)- phenyl)-(2-
sulfoniumphenyl)-Methytlene)-(-(1 (N-ethyl-N- p-sulfobenzyl) 2 ,5-
cyclohexadienimine)
Allarin Astrol B. 61530 Monosodium salt of 1-methylamino-4-(o-sulfo-p-toluino)-
anthroquinone
Indigo. 73000 Indigotin.
Patent Blue NA 42052 Monosodium salt of 4-(4- (N-ethyl- benzyl-amino)-phenyl (5-hydroxy-
4-sulfo-2-sulfoniumphenyl-methylene)(N-ethyl- Benzyl- 2, 5-
cyclohexadienimine)
Patent Blue CA. 42052 Calcium salt of 4-(4- (N-ethyl- benzyl-amino)-phenyl)-(5 hydroxy-4-
sulfo-2-sulfoniumphenyl, methylene)- (N-ethyl- N-benzyl- 2- 5-
cyclohexadienimine).
Carbrantherene
Blue
69825 3, 3- Dichloroindanthrene.
Napthol Blue Black 20470 Disodium salt of 8-amino-7-p- nitrophenylazo 3phenylazo-1-
naphthol-3, 6-disulfonic acid
Alizurol purple SS 60725 I-hydroxy-4-p-toluino-anthraquinone
THANKYOU

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Shedule Q (List of colors, dyes or pigments approved for use in cosmetics under D & C Act) .pptx

  • 1. Schedule Q Drugs & Cosmetic Act 1940 Presented by: Mahewash Sana A. Pathan
  • 2. INTRODUCTION: • Schedule Q is one of the schedules under Drugs and Cosmetics rules which describes the list of dyes, colors and pigments permitted to be used in cosmetics and soaps. • Schedule Q further consists of two parts: • Part I: It consists of the list of dyes, colours and pigments permitted to be used in cosmetics and soaps as per amended by the BIS from time to time • Part II: It consists of the list of colours permitted to be used in Soap. • As per Schedule Q synthetic Organic Colours and Natural Organic Colours used in the Cosmetics that are permitted for use shall not contain more than: • 2 parts per million of Arsenic calculated as Arsenic Trioxide. • 20 parts per million of lead calculated as lead. • 100 parts per million of Heavy Metals other than lead calculated as the total of the respective metals.
  • 3. The list of approved colours and dyes as per Schedule Q Part I 1. Guinea Green B 2. Toluidine Red 3. Light Green SF Yellowish 4. Flaming Red 5. Tartrazine 6. Deep Red (Maroon) 7. Sunset yellow FCF 8. Alba Red 9. Ponceau 3R 10. Orange G 11. Amarnath 12. Orange II 13. Erythrosine 14. Dichlorofluorescein 15. Ponceau SX 16. Dichlorofluorescein. NA 17. Brilliant Blue FCF 18. Diiodofluorescein 19. Indigo carmine 20. Erythrosine Yellowish NA
  • 4. 21. Wool Violet 5 BN (Acid- violet 6B) 22. Erythrosine Yellowish K 23. Light Green SF Yellowish 24. Erythrosine Yellowish NH 25. Alizarin Cyanine Green F 26. Orange TR 27. Quinizarine Green SS 28. Alizarin 29. Fast Green FCF 30. Dibromodiiodofluorescein 31. Acid Fast Green 32. Resorcin Brown 33. Pyranine Concentrated 34. Alphazurine FG 35. Quinoline Yellow WS 36. Allarin Astrol B 37. Quinoline Yellow SS 38. Indigo 39. Ponceau 2 R 40. Patent Blue NA
  • 5. 41. Lithol Rubin B. 42. Patent Blue CA 42. Lithol Rubin BCA 43. Curbrantherene Blue 44. Lake Red D. 45. Napthol Blue Black 46. Lake Red DBA 47. Alizurol purple SS 48. Lake Red DCA 49. Acid Red 89 50. Toney Red 51. Acid Red 97 52. Oil Red OS 53. Acid Blue 1 54. Tetrabromofluorescein 55. Food Blue 3 56. Eosin TS 57. Natural Orange 58. Eosin YSK 59. Solvent Blues 4 60. Tetrachlorofluorescein NA 61. Solvent Yellow 18 62. Tetrachlorofluorescein K 63. Food Yellow 18 64. Tetrachloro Tetrabromofluorescein 65. Solvent Red 1 66. Phloxine B 67. Solvent Yellow 32 68. Bluish Orange T.R. 69. Fanchon Yellow 71. Helindone Pink CN. 72. (Hansa Yellow G) 73. Deep Maroon (Fanchon Maroon)
  • 6. Part II – List of Colours permitted to be used in Soaps 1. Phthalocyanine Blue 2. Irgalite Red CVPB Paste or Pigment Orange 5 3. Citrus Red No.2 4. Rhodamine B 500 5. Aqueous Green Paste 6. Pigment Yellow 3 7. Irgalite Carmine F-P Powder or Pigments Red 5. 8. Monolite Red 4R HV Paste or Pigment Red 7 9. Oil Red No.1 or Solvent Red 24 or Oil Red 3R
  • 7. Common name Color index number Chemical name of color Guinea Green B 42085 Monosodium salt of 4-(N-ethyl-p-sulfobenzylamino) diphenylmethylone-(1-(N-ethyl-N-p-sulfoniumbenzyl) 2,5- cyclohexadienimine). Light Green SF Yellowish 42095 Disodium salt of 4-[4-(N-ethyl-p-sulfobenzylamine)-phenyl)- 4sulphoniumphenyl) methylene]-2(-(N-ethyl-N-sulfobenzyl) 2,5- Cyclohexadienimine. Tartrazine 19140 Trisodium salt of 3-carboxy-5-hydroxy-1-p-sulfophenyl-4-p- sulfophenylazo-pyrazole. Sunset yellow FCF 15985 Disodium salt of 1-p-sulfophenylazo-2- naphthol-6-sulfonic acid. Ponceau 3R 16155 Disodium salts of a mixture of 1-alkyl- phenylazo-2-napthol 3, 6- disulfonic acids. Amarnath. 16185 Trisodium salt of 1-(4-sulfo-1- napthylazo) 2-naphthol 3, 6- disulfonic acid. Erythrosine. 45430 Disodium salt of 9-0-carboxyphenyl-6- hydroxy 2,4,5, 7- tetraiodo-3- isoxanthone. Ponceau SX 14700 Disodium salt of 2-(5 sulfo-2, 4-xylyl- azo)-1-naphthol-4- sulfonic acid.
  • 8. Brilliant Blue FCF 42090 Disodium salt of 4-(9-4-(N-ethyl-p-sulfobenzylamino)-phenyl)- 2- sulfonium phenyl)- methylene)-(1-(N-ethyl-N-p-sulfobenzyl) 2, 5- cyclohexadienimine). Indigocarmine. 73015 Disodium salt of 5, -indigotindisulfonic acid. Wool Violet 5 BN (Acid- violet 6B) 42640 Monosodium salt of 4-(N-ethyl-p-sulfobenzylamino)-phenyl)-(4- (N- ethyl-p-(sulfonium-benzylamine)-phenyl) methylene)-(N, N- dimethyl- 2,5-cyclohexadienimine) Light Green SF Yellowish 42095 Calcium salt of 4-(4-(N-ethyl-p-sulfobenzyl) (minophenyl) (4- sulfonium-phenyl)methylene), (1-(N-ethyl-N-p-sulfobenzyl)- 2,5- cyclohexadienimine). Alizarin Cyanine Green F 61570 Disodium salt of 1,4-bis (O-sulfo-p-toluino) anthraquinone Quinazarine Green SS 61565 1,4-bis-(p-Toluino)-anthraquinone Fast Green FCF 42053 Disodium salt of 4-(4-(ethyl-p-sulfobenzylamino)-phenyl) (4- hydroxy-2 sulphoniumphenyl) methylene)-(1-N-ethyl-N-p- sulfobenzyl) 2, 5, cyclohexadienimine). Acid Fast Green 42100 Monosodium salt of 4-(4-N-ethyl-p-sulfobenzylomino) phenyl)- (o- chlorophenyl)-methylene)- 1-(N-ethyl-N- p-sulfonium- benzyl- 2,5, cyclohexadienimine).
  • 9. Pyranine Concentrated 59040 Trisodium salt of acid. Quinoline Yellow WS 47005 Disodium salt of disulfonic acid of 2-(2-Quinolyl)-1, 3indandione. Quinoline Yellow SS 47000 2-(2-quinolyl)-1, 3 indandiene Poneceau 2 R 16150 Disodium salt of 1-xylylazo-2-naphthol-3, 6-disulfonic acid Lithol Rubin B 15850 Monosodium salt of 4-(o-sulfo-p-tolylazo)3 hydroxy-2-naphthoic acid Lithol Rubin BCA 15850 Calcium salt of 4-(o-sulfo-p-tolylazo)-3-hydroxy-2-naphthoic acid Lake Red D. 15500 Monosodium salt of 1-0-carboxyphenylazo-2-naphthol. Lake Red DBA 15500 Barium salt of 1-o-carboxyphenylazo-2-naphthol Lake Red DCA 15500 Calcium salt of 1-o-carboxyphenylazo-2-naphthol Toney Red 26100 I-p-phenylazophenylazo-2-naphthol. Oil Red OS. 26125 I-Xylylazoxylylazo-2-napththol Tetrabromofluorescein 45380 2,4,5,7-Tetrabromo-3, 6-flurandiol Eosin TS Disodium salt of 2,4,5,7-tetrabromo-9-0 carboxyphenyl-6- hyroxy-3- isoxanthone. Eosin YSK Dipotassium salt of 2,4,5,7-tetrabromo-9-0 carboxyphenyl- 6-hyroxy- 3-isoxanthon Tetrachlorofluorescein NA 45366 2,4,5,7- tetrachloro-S, 6-Fluorandiol
  • 10. Tetrachlorofluorescein K. 45366 Disodium salt of 9-0-carboxyphenyl-2,4,5,7-tetrachloro-6- hydroxy-3- isoxanthone Tetrachloro Tetrabromo fluorescei 45410 2,4,5,7-Tetrabromo-12,13,14,15-tetrachloro-3, 6-fluorandiol. Phloxine B 45410 Disodium salt of 2,4,5,7-tetrabromo-9 (3,4,5,6-tetra chloro- o- carboxyphenyl)-6-hydroxy-3-isoxanthone Bluish Orange T.R 45457 1,4,5,8, 15-Pentabromo-2, 7-dicarboxy-3, 6-fluoran diol. Helindone Pink CN. 73360 5, 5-Dichloro-3, 3 dimethyl-thioindigo Deep Maroon (Fanchon Maroon) 15880 Calcium salt of 4-(I-sulfo-2-naphthylazo 3- hydroxy-2- naphthoic acid. Toluidine Red. 12120 1-(o-Nitro-p-tolylazo)-2-naphthol Flaming Red. 12085 I- (o-Chloro-p-nitrophenylazo)-2-naphthol Deep Red (Maroon). 12350 3-Hydroxy-N-(m-nitrophenyl)-4-(o-nitro-p-tolylazo)-2naphthamide Alba Red. 13058 o- -Dihydroxy-diethylamino)-phenylazo)-benzoic acid.
  • 11. Orange G 16023 Disodium salt of 1-phenylazo-2-naphthol-6-8-disulfonic acid Orange II 15510 Monosodium salt of 1-p-sulfophenylazo-2-naphthol. Dichlorofluorescein 45365 4,5-Dichloro-3, 6-fluorandiol. Dichlorofluorescein. NA 45365 Disodium salt of 9-o-carboxyphenyl-1-4,5- dichloro-6- hydroxy-3- isoxanthone Diiodofluorescein 45425 4,5 Diiodo-3, 6-fluorandiol Erythrosine Yellowish NA 45425 Disodium salt of 9-o-carboxyphenyl-6- hydroxy-4, 5- diiodo-3- isoxanthone. Erythrosine Yellowish K. 45425 Dipotassium salt of 9-o-carboxyphenyl-6-hydroxy-4, 5- diiodo-3- isoxanthone. Erythrosine Yellowish NH 45425 Dipotassium salt of 9-o-carboxyphenyl-6-hydroxy-4, 5- diiodo-3- isoxanthone Orange TR 45456 4,5, 15-Tribromo 2, 7-dicarboxy-3, 6- fluorandiol. Alizarin. 58000 1,2- Anthraquinonediol
  • 12. Dibromodiiodofluo rescein. 45371 4 ,5- Dibromo-2, 7-diiodo-3, 6-fluorandiol. Alphazurine FG 42090 Diammonium salt of 4-(N-ethyl-p- sulfobenzyl amino)- phenyl)-(2- sulfoniumphenyl)-Methytlene)-(-(1 (N-ethyl-N- p-sulfobenzyl) 2 ,5- cyclohexadienimine) Allarin Astrol B. 61530 Monosodium salt of 1-methylamino-4-(o-sulfo-p-toluino)- anthroquinone Indigo. 73000 Indigotin. Patent Blue NA 42052 Monosodium salt of 4-(4- (N-ethyl- benzyl-amino)-phenyl (5-hydroxy- 4-sulfo-2-sulfoniumphenyl-methylene)(N-ethyl- Benzyl- 2, 5- cyclohexadienimine) Patent Blue CA. 42052 Calcium salt of 4-(4- (N-ethyl- benzyl-amino)-phenyl)-(5 hydroxy-4- sulfo-2-sulfoniumphenyl, methylene)- (N-ethyl- N-benzyl- 2- 5- cyclohexadienimine). Carbrantherene Blue 69825 3, 3- Dichloroindanthrene. Napthol Blue Black 20470 Disodium salt of 8-amino-7-p- nitrophenylazo 3phenylazo-1- naphthol-3, 6-disulfonic acid Alizurol purple SS 60725 I-hydroxy-4-p-toluino-anthraquinone