3. Learning Objectives
At the end of the lesson students will be able to:
WRITE THE TYPICAL
REACTIONS OF CARBOXYLIC
ACIDS
EXPLAIN HOW THE
REACTIONS HAPPEN
DISCUSS THE APPLICATION
OF CARBOXYLIC ACIDS
4. Whether soluble in
water or not,
carboxylic acids
react with aqueous
solutions of sodium
hydroxide (NaOH),
sodium carbonate
(Na2CO3), and
sodium bicarbonate
(NaHCO3) to form
salts:
RCOOH + NaOH(aq) →
RCOO−Na+(aq) + H2O
2RCOOH + Na2CO3(aq) →
2RCOO−Na+(aq) + H2O + CO2(g)
RCOOH + NaHCO3(aq) →
RCOO−Na+(aq) + H2O + CO2(g)
Here the carboxylic acids
act like inorganic acids: they
neutralize basic
compounds.
7. Naming Carboxylic Acid Salts
We name them in the same manner as inorganic
salts: the name of the cation is followed by the
name of the organic anion. The name of the anion
is obtained by dropping the -ic ending of the acid
name and replacing it with the suffix -ate. This rule
applies whether we are using common names
or IUPAC names:
8. Carboxylic Acids react with more reactive
Metals
In the reaction they produce a salt and hydrogen
Examples:
CH3COOH + Zn →
HCOOH + K →
C2H5COOH + Mg →
9. Neutralisation
As other acids, carboxylic acids react with base oxide or
alkali to produce salt and water
Examples:
HCOOH + CaO →
CH3COOH + NaOH →
11. Esterification
Carboxylic acids react with alcohol with the presence of
concentrated sulphuric acid (________) as catalyst to produce ester
and water
Example:
CH3COOH + C2H5OH → CH3COOC2H5 + H2O
CH3COOH + CH3OH →