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Today’s objectives-Mechanical Properties ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Abrasives ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],http://www.abrasiveengineering.com/eurostus.pdf Almost 3000 tons a day! 700 Sand 550 Glass 600 Steel 80 Nickel 2500 Silicon carbide (SiC) 2100 Alumina (AL2O3) 2100 Tungsten carbide (WC) 800 Quartz (SiO2) 1 Graphite 7000 Diamond (C) Knoop Hardness (100g load) Material 60 1150 550 Super (no gems) 850k 310 580 Loose 70k 850 1600 Coatings 65k 860 450 Bonded tons Europe $ US $ Abrasive use, 2002 http://www.chm.bris.ac.uk/pt/diamond
Stress vs. Strain ,[object Object],[object Object],[object Object],[object Object],Brass Brass strains to 35% = Fracture  Strength (stress at failure) Ceramics strain to 0.1%
Fracture strength Callister, Appendix B Note that the fracture strength for ceramics is about 10* better in compression than in tension.  Body armor 69 Soda lime glass 13.8-69 Graphite 230-825 SiC (sintered) 1050 Diamond (natural) 800-1400 Diamond (synthetic) 37.3-41.3 Concrete 130 Si [100] cleaved 282-551 Al 2 O 3  (99.9% pure) Strength (MPa) Ceramic
Failure Mechanisms-single xtals ,[object Object],[object Object],[object Object],[object Object],http://www.theimage.com/crystalinfo/crystal_page2.htm
Failure Mechanisms-polycrystals ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Typical mechanical property measurements ,[object Object],[object Object],[object Object],[object Object]
Measuring ceramic mechanical properties ,[object Object],Solution: bend test. Most appropriate for bars, rods, plates, and wafers. Where will cracks form?  Which part is under tension and which is under compression?
MEASURING FRACTURE STRENGTH •  3-point bend test to measure room T strength. Adapted from Fig. 12.29,  Callister 6e. •  Flexural strength: Flexural fracture strength is higher than the tensile fracture strength. Why? Test specimens undergo compressive and tensile loads instead of pure tension. Si carbide Al oxide glass (soda) 550-860 275-550 69 Data from Table 12.5,  Callister 6e. circ.
MEASURING ELASTIC MODULUS •  Room T behavior is usually elastic, with brittle failure. •  Determine elastic (Young’s) modulus according to slope: Adapted from Fig. 12.29,  Callister 6e. Si carbide Al oxide glass (soda) 430 390 69 Data from Table 12.5,  Callister 6e.
Measured Fracture Strengths ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Fracture Toughness ,[object Object],[object Object],Mode I a 2.7-5 Aluminum Oxide usually greater metals 0.7-1.1 Soda-lime glass 0.2-1.4 Concrete K Ic  (MPa*m ½ ) Ceramic
[object Object],[object Object],[object Object],[object Object],[object Object],Fracture Toughness-stress concentration Note: no such stress concentration occurs for compression.
Journal of Irreproducible Results? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Weibull statistics ,[object Object],[object Object],130 MPa Si [100] cleaved 81.8 MPa Si [100] laser scribed
Minimizing Failures ,[object Object],[object Object],[object Object],rated load
Guaranteeing No Failures ,[object Object],[object Object],[object Object],[object Object],rated load
Where failures matter ,[object Object],[object Object],[object Object],[object Object]
Caveat for brittle materials: delayed fracture ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Ceramics at higher temperatures ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Ionic Bonding Slip is impossible:  Too much electrostatic repulsion + - + - + - + - + - + -
Improvements for mechanical applications ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
SUMMARY Reading for next class Phase diagrams Chapter sections 12.6, 12.7 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]

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Lecture 04

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  • 4. Fracture strength Callister, Appendix B Note that the fracture strength for ceramics is about 10* better in compression than in tension. Body armor 69 Soda lime glass 13.8-69 Graphite 230-825 SiC (sintered) 1050 Diamond (natural) 800-1400 Diamond (synthetic) 37.3-41.3 Concrete 130 Si [100] cleaved 282-551 Al 2 O 3 (99.9% pure) Strength (MPa) Ceramic
  • 5.
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  • 9. MEASURING FRACTURE STRENGTH • 3-point bend test to measure room T strength. Adapted from Fig. 12.29, Callister 6e. • Flexural strength: Flexural fracture strength is higher than the tensile fracture strength. Why? Test specimens undergo compressive and tensile loads instead of pure tension. Si carbide Al oxide glass (soda) 550-860 275-550 69 Data from Table 12.5, Callister 6e. circ.
  • 10. MEASURING ELASTIC MODULUS • Room T behavior is usually elastic, with brittle failure. • Determine elastic (Young’s) modulus according to slope: Adapted from Fig. 12.29, Callister 6e. Si carbide Al oxide glass (soda) 430 390 69 Data from Table 12.5, Callister 6e.
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