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PHOTOCHEMICAL CELL
PRESENTED BY,
YUVARAJA .MM
2ND SEM, M.TECH
RENEWABLE ENERGY
Disadvantages of Conventional solar cells
 Low efficiency
 Costly equipment
 High initial cost
 Requires experts to manufacture
INTRODUCTION
 Photochemical solar cells converts visible light into electricity.
 A photochemical solar cell that is based on the dye-
sensitization of thin nanocrystalline films of TiO2
nanoparticles.
What is DSSC?
 A dye‐sensitized solar cell(DSSC) is a low‐cost solar cell
belonging to the group of thin film solar cells.
 First version of a dye solar cell, also known as the Gratzel
cell, was invented by Michael Gratzel.
Components of DSSC
 Transparent conducting and counter conducting
electrodes
 The nanostructured wide band gap semiconducting
layer
 The dye molecules
 The electrolyte
How to make a DSSC?
 The anode is transparent like glass.
 Between the anode and the cathode is a mesh of Titanium
Dioxide nanoparticles.
 The TiO2 nanoparticles are coated with a light absorbing dye
that converts photons into electrons.
 An Electrolyte (Iodide) fills the spaces between the TiO2
nanoparticles.
 Put all these pieces together to have DYE SENSITIZED
SOLAR CELL.
Mechanism of DSSC
 When a photon strikes a dye molecule, the energy from the
photon is absorbed into the dye molecule. The dye molecule
enters an excited state and emits an electron.
 The emitted electron travels through the TiO2 nanoparticles
until it reaches the anode.
 The dye molecule just emitted one of its own electron, it will
start to decompose unless it receives another electron to
replace the one it lost.
 The dye coated TiO2 nanoparticles are immersed in the
solution of iodide. The iodide is able to replace the electrons
lost by the dye molecules.
 The iodide molecules are oxidized into tri-iodide which will
float around until it comes in contact with the cathode.
 The tri-iodide recovers the missing electron from the cathode
which reduces tri-iodide back to three iodide molecules.
 The electron emitted from the dye flows from the anode to
whatever is powered by DSSC and then flow back into the cell
through the cathode.
 The electrons from the cathode restores the electron needed by
the iodide which restores the electron needed by the dye
molecules and the whole process starts over again.
Comparison
Advantages
 Dye sensitized solar cells are the most efficient third-
generation solar technology available & is greatly used in
applications like rooftop solar collectors.
 DSSCs work even in low-light conditions. Hence they are
very popular under cloudy weather conditions and non-direct
sunlight.
 DSSCs are built up with only a thin layer of conductive
plastic on the front side to allow radiation of heat much easily.
 DSSCs are light weight and flexible.
 DSSCs are economical and easy to manufacture.
Disadvantages
 DSSCs are not considered as an option, for large-scale
developments.
 the liquid electrolyte, which is not very stable at varying
temperatures. The electrolyte can freeze at low temperatures
cutting power production and causing physical damage.
 Another major drawback is the electrolyte solution, which
contains volatile organic solvents and must be carefully
sealed.
Applications

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Photochemical cell

  • 1. PHOTOCHEMICAL CELL PRESENTED BY, YUVARAJA .MM 2ND SEM, M.TECH RENEWABLE ENERGY
  • 2. Disadvantages of Conventional solar cells  Low efficiency  Costly equipment  High initial cost  Requires experts to manufacture
  • 3. INTRODUCTION  Photochemical solar cells converts visible light into electricity.  A photochemical solar cell that is based on the dye- sensitization of thin nanocrystalline films of TiO2 nanoparticles.
  • 4. What is DSSC?  A dye‐sensitized solar cell(DSSC) is a low‐cost solar cell belonging to the group of thin film solar cells.  First version of a dye solar cell, also known as the Gratzel cell, was invented by Michael Gratzel.
  • 5. Components of DSSC  Transparent conducting and counter conducting electrodes  The nanostructured wide band gap semiconducting layer  The dye molecules  The electrolyte
  • 6. How to make a DSSC?  The anode is transparent like glass.  Between the anode and the cathode is a mesh of Titanium Dioxide nanoparticles.  The TiO2 nanoparticles are coated with a light absorbing dye that converts photons into electrons.  An Electrolyte (Iodide) fills the spaces between the TiO2 nanoparticles.  Put all these pieces together to have DYE SENSITIZED SOLAR CELL.
  • 8.  When a photon strikes a dye molecule, the energy from the photon is absorbed into the dye molecule. The dye molecule enters an excited state and emits an electron.  The emitted electron travels through the TiO2 nanoparticles until it reaches the anode.  The dye molecule just emitted one of its own electron, it will start to decompose unless it receives another electron to replace the one it lost.  The dye coated TiO2 nanoparticles are immersed in the solution of iodide. The iodide is able to replace the electrons lost by the dye molecules.  The iodide molecules are oxidized into tri-iodide which will float around until it comes in contact with the cathode.
  • 9.  The tri-iodide recovers the missing electron from the cathode which reduces tri-iodide back to three iodide molecules.  The electron emitted from the dye flows from the anode to whatever is powered by DSSC and then flow back into the cell through the cathode.  The electrons from the cathode restores the electron needed by the iodide which restores the electron needed by the dye molecules and the whole process starts over again.
  • 11. Advantages  Dye sensitized solar cells are the most efficient third- generation solar technology available & is greatly used in applications like rooftop solar collectors.  DSSCs work even in low-light conditions. Hence they are very popular under cloudy weather conditions and non-direct sunlight.  DSSCs are built up with only a thin layer of conductive plastic on the front side to allow radiation of heat much easily.  DSSCs are light weight and flexible.  DSSCs are economical and easy to manufacture.
  • 12. Disadvantages  DSSCs are not considered as an option, for large-scale developments.  the liquid electrolyte, which is not very stable at varying temperatures. The electrolyte can freeze at low temperatures cutting power production and causing physical damage.  Another major drawback is the electrolyte solution, which contains volatile organic solvents and must be carefully sealed.