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LINEAR COMBINATION OF
ATOMIC ORBITALS (L.C.A.O).
COURSE: REVIEW OF QUANTUM MECHANICS AND E.M.T
CODE: 612
COURSE INSTRUCTOR: ASSISTANT PROFESSOR DR. P. THANGADURAI.
PRESENTED BY :
ROOPAVATH UDAY KIRAN
M.Tech 1st YEAR , sem -1.
Introduction
• If an electron can be found in an atomic orbital
belonging to atom A and also in an atomic orbital
belonging to atom B, then the over all wave
function is a superposition of the two orbitals.
• The technical term for superposition in the above
equation is a linear combination of atomic
orbitals.
• The approximate molecular orbital formed from a
linear combination of atomic orbitals is called a
LCAO-MO.
• The lower-energy orbital, which has the form
is called a bonding orbital.
• The higher energy orbital, which has the form
• is called Anti bonding orbital
• An anti bonding orbital is more anti bonding
than a bonding orbital is bonding.
Linear combination of tomic orbitals
Linear combination of tomic orbitals
Linear combination of tomic orbitals
Linear combination of tomic orbitals
Linear combination of tomic orbitals
Linear combination of tomic orbitals
Linear combination of tomic orbitals
Linear combination of tomic orbitals

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Linear combination of tomic orbitals

  • 1. LINEAR COMBINATION OF ATOMIC ORBITALS (L.C.A.O). COURSE: REVIEW OF QUANTUM MECHANICS AND E.M.T CODE: 612 COURSE INSTRUCTOR: ASSISTANT PROFESSOR DR. P. THANGADURAI. PRESENTED BY : ROOPAVATH UDAY KIRAN M.Tech 1st YEAR , sem -1.
  • 2. Introduction • If an electron can be found in an atomic orbital belonging to atom A and also in an atomic orbital belonging to atom B, then the over all wave function is a superposition of the two orbitals. • The technical term for superposition in the above equation is a linear combination of atomic orbitals. • The approximate molecular orbital formed from a linear combination of atomic orbitals is called a LCAO-MO.
  • 3.
  • 4. • The lower-energy orbital, which has the form is called a bonding orbital. • The higher energy orbital, which has the form • is called Anti bonding orbital • An anti bonding orbital is more anti bonding than a bonding orbital is bonding.