Thermal engineering concepts including pure substances, systems, properties, and processes are introduced. A pure substance remains homogeneous and does not change chemically during phase changes. Systems are defined as regions with focused energy transfers, surrounded by boundaries separating them from their surroundings. Properties include extensive properties directly proportional to mass like volume and entropy, and intensive properties independent of mass like temperature and density. Processes are classified as closed systems allowing only energy transfer, open systems permitting both energy and mass transfer, and isolated systems with no transfers. Specific concepts like specific volume, density, temperature, and pressure types including gauge, absolute, vacuum and atmospheric pressures are also defined.