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Inherently Adaptive Structural Systems
Technova Corporation
Adaptive Mechanisms of Bone
Objective
Develop Adaptive Structural Systems with Inherent
Capability to Redistribute Mass for Enhanced Safety
and Efficiency in a Dynamic Service Environment
Outline of the Presentation
Fundamental Principles
System Constituents
System Architectures
Theoretical Modeling
Parametric Studies and Design
Experimental Verification
Fundamental Principles:
Strain Energy Gradient
Defect
Concentration of
Strain energy
Contact
Concentration of
Strain Energy
Concent
r
at
ion
of
St
r
ain
Ener
gy
Eccent
r
ic
Loads
Rupt
ur
ed
Fiber
Local
St
r
ess
Rise
(a) Defect (b) Contact (c) Eccentricity (d) Composite
Self-Healing and Adaptive Mechanisms
Guide: Piezo-Induced Electric Potential
Drive: Piezo-Induced Electric Charge
Mechanism: Electrochemical Mass
Transport in a Solid Electrolyte
System Constituents:
Piezoelectric Materials
+
-
+
- 1 (length)
3 (thickness)
2 (width)
Piezoelectric
Material
d31
(C/m2
)/(N/m2
)
d33
(C/m2
)/(N/m2
)
g31
(V/m)/(N/m2
)
g33
(V/m)/(N/m2
)
k31
%
k33
%
E
GPa
PZT -122x10-12
285x10-12
-10.6x10-3
24.9x10-3
33 70 65
PVDF 23x10-12
-34x10-12
210x10-3
-500x10-3
12 12 2.5
PMNT -370x10-12
1600x10-12
-6.8x10-3
15.8x10-3
42 88 110
Q = d3n
.Xn
.A
V = g3n
.Xn
.t
Solid Electrolytes
Ceramics
Polymers
Composites
System Architectures:
Self-Healing Continuous Fiber Composite
-
-
-
-
+
+
+
+
+
+
+
+
-
-
-
-
+
+
+
+
+
+
+
+
Fiber Stress
Rise
Fiber
Rupture
Core Fiber (conductive or
w/conductive coating)
Piezoelectric
Coating
Ion-Conducting M
atrix
w/Dispersed M
etal Particles
Adaptive Continuous Fiber Composite
Core Fiber (conductive or
w/conductive coating)
Piezoel ectric
Coating
Ion-Conducting M
atrix
w/Dispersed M
etal Particles
+
+
+
+
+
+
+
+
+
-
-
-
-
-
-
-
-
-
-
-
-
-
-
Biomimetic Feature
Self-Healing Discrete Fiber Composite
-
-
-+
+
++
Fl aw
Stress Concentration
at Fl aw
Piezo-Driven
Electrodeposition
M
etal-Filled
Solid Electrolyte
Piezo-Coated
Fiber
Adaptive Cellular Structures
+
+
+
+
-
-
-
-
-
-
Piezo-Coated
Cel lul ar Structure
Piezo-Induced
Potential Gradient
Solid Electrolyte
w/M
etal Fil ler
Electrochem
ical
M
ass T
ransport
Biomimetic Feature
Cancellous Bone Compact Bone
Self-Healing & Adaptive Layered Composites
Self-Heal ing
Adaptive
Piezoelectric Layers Ion-Conducting Layer Conductive Layer
Theoretical Modeling
Mechanical Analysis to Assess Stress Gradient
Piezo-Induced Potential: V = g31.(Smax - Smin) . Tp
Piezo-Induced Charge: Q = d31 . (Smax – Smin) . A
Rate of Mass Transport & Regional Strengthening
-
-
-
-
+
+
+
+
+
+
+
+
-
-
-
-
+
+
+
+
+
+
+
+
Parametric Studies and Design:
Self-Healing Discrete Fiber Composite
-
-
-+
+
++
Rel
ative
Rate
of
M
as
s
T
rans
port
Piezoelectric Coating T
hickness (m
icron)
2 4 6 8 10
20
40
60
80
100
120
140
160
Adaptive Layered Composite
Piezoelectric Layers Ion-Conducting Layer Conductive Layer
Rel
ative
Rate
of
M
as
s
T
rans
port
Piezoelectric Layer T
hickness (m
icron)
2 4 6 8 10
20
40
60
80
100
120
Experimental Verification
Electrostripping and Electrodeposition
Phenomena Within Solid Electrolytes
Piezo-Driven Electrolysis Within Solid
Electrolytes
Electrolysis Within Solid Electrolytes
Constant voltage
DC power supply
Constant voltage
DC power supply
Solid electrolyte
pellet
Electrodes
Alligator clip connecting
to power supply
Solid electrolyte
pellet
Electrodes
Alligator clip connecting
to power supply
+ -
Copper Ion Conducting Polym
er
Copper &Other Electrodes
+ -
Ion Conducting Polym
er
w/Copper Filler
Non-Copper Electrodes
+ -
Verification of Electrolysis
Holes on electrode
Surface due to dissolution
Holes on electrode
Surface due to dissolution
Areas of copper deposition
Areas of copper deposition
Cu Anode
Al Cathode
-50 -40 -30 -20 -10 0 10 20 30 40 50
Voltage, mV
-1.00
-0.75
-0.50
-0.25
0.00
0.25
0.50
0.75
1.00
Current,
mA
Piezo-Driven Electrolysis
+ + + + + + +
- - - - - - - Stainless Steel Mesh
Copper-Ion Conducting Polymer
Copper Layer
Piezoelectric Stack
Applied Stress:
Stress, MPa
Time, sec
30
1
Summary & Conclusions
System Principles & Constituents
Modeling, Parametric Studies & Design
System Architectures
Experimental Verification

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Structural systems

  • 1. Inherently Adaptive Structural Systems Technova Corporation
  • 3. Objective Develop Adaptive Structural Systems with Inherent Capability to Redistribute Mass for Enhanced Safety and Efficiency in a Dynamic Service Environment
  • 4. Outline of the Presentation Fundamental Principles System Constituents System Architectures Theoretical Modeling Parametric Studies and Design Experimental Verification
  • 5. Fundamental Principles: Strain Energy Gradient Defect Concentration of Strain energy Contact Concentration of Strain Energy Concent r at ion of St r ain Ener gy Eccent r ic Loads Rupt ur ed Fiber Local St r ess Rise (a) Defect (b) Contact (c) Eccentricity (d) Composite
  • 6. Self-Healing and Adaptive Mechanisms Guide: Piezo-Induced Electric Potential Drive: Piezo-Induced Electric Charge Mechanism: Electrochemical Mass Transport in a Solid Electrolyte
  • 7. System Constituents: Piezoelectric Materials + - + - 1 (length) 3 (thickness) 2 (width) Piezoelectric Material d31 (C/m2 )/(N/m2 ) d33 (C/m2 )/(N/m2 ) g31 (V/m)/(N/m2 ) g33 (V/m)/(N/m2 ) k31 % k33 % E GPa PZT -122x10-12 285x10-12 -10.6x10-3 24.9x10-3 33 70 65 PVDF 23x10-12 -34x10-12 210x10-3 -500x10-3 12 12 2.5 PMNT -370x10-12 1600x10-12 -6.8x10-3 15.8x10-3 42 88 110 Q = d3n .Xn .A V = g3n .Xn .t
  • 9. System Architectures: Self-Healing Continuous Fiber Composite - - - - + + + + + + + + - - - - + + + + + + + + Fiber Stress Rise Fiber Rupture Core Fiber (conductive or w/conductive coating) Piezoelectric Coating Ion-Conducting M atrix w/Dispersed M etal Particles
  • 10. Adaptive Continuous Fiber Composite Core Fiber (conductive or w/conductive coating) Piezoel ectric Coating Ion-Conducting M atrix w/Dispersed M etal Particles + + + + + + + + + - - - - - - - - - - - - - -
  • 12. Self-Healing Discrete Fiber Composite - - -+ + ++ Fl aw Stress Concentration at Fl aw Piezo-Driven Electrodeposition M etal-Filled Solid Electrolyte Piezo-Coated Fiber
  • 13. Adaptive Cellular Structures + + + + - - - - - - Piezo-Coated Cel lul ar Structure Piezo-Induced Potential Gradient Solid Electrolyte w/M etal Fil ler Electrochem ical M ass T ransport
  • 15. Self-Healing & Adaptive Layered Composites Self-Heal ing Adaptive Piezoelectric Layers Ion-Conducting Layer Conductive Layer
  • 16. Theoretical Modeling Mechanical Analysis to Assess Stress Gradient Piezo-Induced Potential: V = g31.(Smax - Smin) . Tp Piezo-Induced Charge: Q = d31 . (Smax – Smin) . A Rate of Mass Transport & Regional Strengthening - - - - + + + + + + + + - - - - + + + + + + + +
  • 17. Parametric Studies and Design: Self-Healing Discrete Fiber Composite - - -+ + ++ Rel ative Rate of M as s T rans port Piezoelectric Coating T hickness (m icron) 2 4 6 8 10 20 40 60 80 100 120 140 160
  • 18. Adaptive Layered Composite Piezoelectric Layers Ion-Conducting Layer Conductive Layer Rel ative Rate of M as s T rans port Piezoelectric Layer T hickness (m icron) 2 4 6 8 10 20 40 60 80 100 120
  • 19. Experimental Verification Electrostripping and Electrodeposition Phenomena Within Solid Electrolytes Piezo-Driven Electrolysis Within Solid Electrolytes
  • 20. Electrolysis Within Solid Electrolytes Constant voltage DC power supply Constant voltage DC power supply Solid electrolyte pellet Electrodes Alligator clip connecting to power supply Solid electrolyte pellet Electrodes Alligator clip connecting to power supply + - Copper Ion Conducting Polym er Copper &Other Electrodes + - Ion Conducting Polym er w/Copper Filler Non-Copper Electrodes + -
  • 21. Verification of Electrolysis Holes on electrode Surface due to dissolution Holes on electrode Surface due to dissolution Areas of copper deposition Areas of copper deposition Cu Anode Al Cathode -50 -40 -30 -20 -10 0 10 20 30 40 50 Voltage, mV -1.00 -0.75 -0.50 -0.25 0.00 0.25 0.50 0.75 1.00 Current, mA
  • 22. Piezo-Driven Electrolysis + + + + + + + - - - - - - - Stainless Steel Mesh Copper-Ion Conducting Polymer Copper Layer Piezoelectric Stack Applied Stress: Stress, MPa Time, sec 30 1
  • 23. Summary & Conclusions System Principles & Constituents Modeling, Parametric Studies & Design System Architectures Experimental Verification