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Arid Zone Journal of Engineering, Technology and Environment. August, 2016; Vol. 12:103-109
Copyright © Faculty of Engineering, University of Maiduguri, Nigeria.
Print ISSN: 1596-2490, Electronic ISSN: 2545-5818
www.azojete.com.ng
STATISTICAL MODELLING OF THE ENERGY CONTENT OF MUNICIPAL SOLID
WASTES IN NORTHERN NIGERIA
M. Ben Oumarou1*
, Sulaimon Shodiya1
, Garba M. Ngala1
and Ndubisi A. Aviara2
(1
Department of Mechanical Engineering, University of Maiduguri, PMB 1069, Maiduguri,
Borno State, NIGERIA
2
Department of Agricultural and Environmental Resources Engineering, University of Maiduguri,
PMB 1069, Maiduguri, Borno State, NIGERIA)
*Corresponding author’s e-mail: mmbenomar@yahoo.com
Abstract
The ability to predict the quantity of energy to be produced is of paramount importance in every country. It would assist
in setting up a waste management plan which will lead to a sustainable energy policy. This paper presents the
development of a statistical linear regression mathematical model to predict the amount of energy contained in municipal
solid wastes from the knowledge of such characteristics of the wastes as physical composition and/or moisture content.
Major cities of Kano, Katsina, Dutse, Damaturu, Maiduguri, Bauchi, Birnin Kebbi, Gusau and Sokoto in Northern
Nigeria, with high population densities and intense industrial activities constituted the area of study. Ten kilogram each,
of the municipal solid waste was collected from the government designated refuse dumping sites in both highly dense
populated low income areas and government residential areas, during the hottest months of February, March and April
and during the rainy season in the month of August for three years. The waste material was prepared for the
determination of its physical characteristics by sifting through. Proximate, ultimate analyses and calorific values were
determined using ASTM analytical techniques and formulas from the literature. An empirical linear regression based
mathematical model was developed using statistical methods and experimental data. Comparison between experimental
and predicted values of the calorific values showed an agreement of about 70% with an average deviation of 5.03%
while the standard deviation was found to be 5.29%.
Keywords: Mathematical model, municipal solid waste, energy policy, calorific value, moisture
content.
1. Introduction
Energy problems and solutions should always be guided by local economic, environmental and
social considerations. Energy policy formulation should bring together national energy development
policies with the locally perceived priorities. There needs to be increased emphasis on non-fossil fuel
alternatives to the provision of energy services in developing countries (FAO, 2016).These
alternatives range from the modern renewable energy sources, such as improved biomass conversion
(including liquid biofuels, biogas, gasification, incineration), solar energy (PV), wind and
geothermal energy and small-scale hydropower, to lower energy intensity industries, material and
energy recycling and better means of utilizing traditional energy sources, such as improved cooking
stoves. Developing countries in general produce more wet waste with lower calorific value but if
dried it can easily reach high calorific values. The improvement of waste collection and treatment in
those countries is slow and mostly not integrated (Filip and Niko, 2013).
One of the most difficult tasks in waste management remain the prediction of the nature and
composition of the waste, its moisture content as well as the energy content when waste-to-energy
schemes are to be considered. Beigl et al. (2003) opined that an understanding of the relationships
between the quantity and quality of environmentally relevant outputs from human processes and
regional characteristics is a prerequisite for planning and implementing ecologically sustainable
strategies. Apart from process-related parameters, continuous and discontinuous socio-economic
Oumarou et al.: Statistical Modelling of the Energy Content of Municipal Solid Wastes in Northern Nigeria.
AZOJETE, 12:103-109. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng
104
long-term trends often play a key role in the assessment of environmental impacts. Karajgi et al.
(2012) modelled the generation of electrical energy from municipal solid wastes (MSW). They
emphasized that it is a complex process since the waste has to undergo various unit operations before
it is put in to the process of energy production. The modelling of power generation from MSW
therefore has to include all these unit operations, waste flow paths etc. The modelling must also be
capable of providing information on important issues like economic, environmental, among many
others.
All difficulties lie in the heterogeneous nature of the MSW which makes it even difficult to design
and develop a thermal treatment plant. These difficulties thus make the development of a
mathematical model a necessity. This paper presents the development of a statistical mathematical
model to predict the amount of energy contained in MSW from the knowledge of such
characteristics of the wastes as physical composition and/or moisture content. Source separation and
collection centres separation are only suitable for places where the waste management authority is
well structured and equipped, and places where poverty, homelessness, roads, and other
infrastructures are no longer a problem.
2. Materials and Methods
2.1 Study Area
Major cities of Northern Nigeria, with high population densities (National Bureau for Statistics,
2006) and intense industrial activities constitute the area of study. These cities are Kano, Katsina,
Dutse, Damaturu, Maiduguri, Bauchi, Birnin-Kebbi, Gusau and Sokoto in Kano state, Katsina state,
Jigawa state, Yobe state, Borno state, Bauchi state, Kebbi state, Zamfara state and Sokoto state,
respectively.
2.2 Data Collection
Ten kilogram of the municipal solid waste (MSW) was collected from the government designed
refuse dumping sites in both, high densely populated low income areas and government residential
areas, during the dry season corresponding to hottest months of the year (February, March and April)
and during the raining season in the month of August for three years (2012-2015). The samples were
collected twice a month. Collection was done in a random manner and carried out across the waste
dump using shovels. First collection was carried out midway in the month and the second collection
during the last week of the month. This was done so, as to account for fluctuations in patterns due to
the salary payment period and other spending patterns. The waste material was prepared for the
determination of the refuse characteristics by sifting through and separated into paper, glass, plastics,
metal, wood chips, etc. An initial sieving was carried out using sieves to remove sand. This was
followed by hand picking at first to remove small stones which could not pass through the sieves and
then crushing inside the mortar to a fine powder.
2.3 Experimental
A METTLER TOLEDO AB 54 electronic digital weighting machine with limitations of 10 mg
minimum and a maximum of 51 grams was used to weight the refuse samples powder. Glass ware
equipment including 16 pieces of PYREX conical flasks, pipettes, burettes, beaker, volumetric flask,
plastic bottles and filter papers for the titration of the samples; a digital Spectrometer
SPECTRUMLAB 22 PC as well as a Gerhardt - Kjeldatherm machine were used to evaluate the
organic components of the refuse.
Arid Zone Journal of Engineering, Technology and Environment, August, 2016; Vol. 12: 103-109.
ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng
105
The reagents used are Sulphuric acid (H2SO4), Orthophosphoric acid (H3PO4), Ferrous sulphate
(FeSO4), Sodium Fluoride(NaF), Potassium dichromate (K2Cr2O7), Diphenylamine indicator, Kjel
tabs, Boric acid, Absolute ethanol, Bromolysol green methyl red, Sodium hydroxide. Nitric acid,
acetic acid, magnesium sulphate, gum Arabic, barium chloride. Others are Potassium chloride (KCl),
Sodium hydroxide (NaOH), Hydrochloric acid (HCl) and Phenolphthalein indicator. These were
used in the chemical analyses to determine the elemental components of the wastes as C (carbon), H
(hydrogen), N (nitrogen), S (sulphur)and O (oxygen) using ASTM D 874, ASTM D 4530, ASTM D
5453 and ASTM D 1160 respectively (Behling et al., 2012).
2.4 Analytical Techniques
Proximate analysis of the MSW was carried out using the method suggested by Elmer (1966) to
determine the moisture content M’o (in weight percent (w/o) by driving off the free moisture at ~
107o
C for approximately 1 hour. The volatile matter content (V’, w/o) was determined by driving
off volatile hydrocarbons CO, CO2 and combine H2O at ~ 950o
C. The refuse was then burned and
the inorganic residue was the ash content (A’, w/o). The fixed carbon ( ) was calculated by
difference as shown by Equation (1) (Weisman and Eckart 1985).
        owsowowowf AVMC //// 100 
(1)
2.4.1 Ultimate Analysis
This is an elemental quantitative evaluation of the total carbon (C’, w/o), hydrogen (H’, w/o),
nitrogen (N’, w/o), sulphur (S’, w/o), oxygen (O’, w/o) percentages after removal of the moisture
and ash (Tabatabai, 1974). This analysis was performed using classic oxidation, decomposition,
and/or reduction technique (Golightly and Simon, 1989) to determine, C (carbon content, w/o), H
(hydrogen, w/o), N (nitrogen, w/o) and S (sulphur, w/o). Oxygen O’ (w/o) was calculated by
difference using Equation (2) (Weisman and Eckart 1985; Lee and Hauffman, 2001):
              owsowoowowowowow AMSNHCO /////// 100  (2)
2.4.1 Heating or Calorific Value
Since the elemental composition has been known during the ultimate analysis, the ash free, dry
heating value was calculated to within 2% accuracy using the empirical Dulong- Berthelot
relationship (Weisman and Eckart 1985):
  S
NO
HCQd 2.22
8
1
34537.81 




 
 (3)
All calculations, data interpretation and mathematical modelling were carried out using basic
Statistics while graphs were generated using Microsoft Excel, 2010. The average or mean deviation
(M.D) and standard deviation (S. D) were obtained using the statistical formulas in Equations (4)
and (5) respectively.
( ) ∑ ( ) (4)
Oumarou et al.: Statistical Modelling of the Energy Content of Municipal Solid Wastes in Northern Nigeria.
AZOJETE, 12:103-109. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng
106
( ) √ ∑ ( ) (5)
3. Results and Discussion
Physical characterization of the MSW showed that wood, grass, metal, plastic, food remnants,
leaves, glass and paper were present in varying proportions in all waste samples in the study area.
Table 1 shows the source of secondary data for the model to be generated.
Table 1: Physical Composition of the Waste in the Study Area
Locality Components (%)
Wood Grass Paper Leaves Food
remnants
Plastic Metal Glass
Kano 28.46 6.57 9.66 8.92 6.79 18.99 12.58 8.00
Damaturu 16.62 11.48 3.58 16.24 6.03 38.20 3.64 4.21
Maiduguri 27.28 5.59 6.69 13.17 6.17 32.56 2.94 5.599
Dutse 19.04 5.73 11.34 19.14 5.94 23.93 6.46 8.39
Bauchi 22.28 6.29 14.86 13.83 5.12 24.93 7.80 4.87
Katsina 24.75 6.05 10.52 15.57 4.35 20.46 9.76 8.54
Sokoto 20.07 5.02 8.82 8.54 6.88 17.63 15.85 7.35
Gusau 17.99 17.11 8.18 14.99 8.03 16.27 10.73 6.70
BirninKebbi 19.78 5.35 9.82 5.48 5.98 34.58 12.96 6.04
(Source: Oumarou et al., 2012a and b)
MSW characteristics form each city of the study area such as the basic constituents of the waste are
considered. Of prime importance are the moisture content, ash content and volatile matter. These
form the basis of the model, which is empirical in nature. Thus a linear regression mathematical
model developed using the knowledge of the physical component of the MSW in the study area is as
shown in equation below:
dQ =1.0325 – 0.0011a +0.2254b – 0.0046c – 0.0068d + 0.3184e – 0.0119f – 0.0053g + 0.1099h.
(6)
where: dQ is the calorific value of the MSW and represents the independent variable of the model.
Variables a, b, c, d e, f, g and h represent the percentage composition, after drying, of Wood, Grass,
Paper, Leaves, Food remnants, Plastic, Metal and Glass respectively.
Table 2: Average Actual and Predicted Generated Values of Calorific Values of MSW in the Study
Area.
Arid Zone Journal of Engineering, Technology and Environment, August, 2016; Vol. 12: 103-109.
ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng
107
Locality Actual Calorific value (MJ/kg) Predicted Calorific Value (MJ/kg)
Kano 5.667 5.1255
Katsina 5.345 5.3837
Maiduguri 5.078 4.3191
Damaturu 5.277 4.6152
Dutse 5.379 4.0908
Bauchi 5.476 4.2431
Gusau 5.362 4.7479
Sokoto 5.164 7.7724
BirninKebbi 5.494 7.9444
Average Deviation (A.D) = 5.03%, Standard Deviation (S. D) = 5.29%
A comparative analysis of the results in Table 2 show an agreement of 69.6% say 70% between the
actual experimental values of the calorific values and those values predicted by the statistical model.
This model takes into consideration all the components of the MSW even though some components
such as glass, metal and some plastics could easily find their ways back to the usefulness stream.
These organic and biodegradable components of the refuse (Table 1), which account for an average
of 57% of the total refuse, would need to be separated at first, then recycled, composted or re-used.
Other components such as wood, leaves, paper, certain category of plastic from which very little or
no other future benefits could be derived, and grass would be left over.
Energy policies either local or national are directed by the three main objectives, namely the security
of supply, the competitiveness of the energy market, and the environmental protection (Doukas et
al., 2008). Even though this research is not directly focused towards the development of an energy
policy, it would assist in achieving some the keys objectives; namely the security of supply and the
environmental protection. The fact that energy policy is developed through a number of social and
economic challenges makes this model suitable to the local waste management schemes which are
largely based on the informal sector, made of scavengers and town/ city cleaners often grouped now
into associations, groups. Waste management is not only about removing waste from the
environment and returning it as new products or raw material. It is also a tool of social integration
and economic well-being. A collection scenario focused on material recovery and recycling from
municipal solid wastes in a selected metropolis of the Sub-Saharan region of Nigeria and Niger
republic was designed. The scenario involved 2000 respondents/participants operating at open dump
areas. Data obtained were analyzed using simple statistical methods and their findings revealed an
annual estimate of the recovery as 16.8 tons of bottles/glasses, 158.4 tons of plastics/rubber, and 264
tons of metal. It also indicated that considerable amount of money could be made from material
Oumarou et al.: Statistical Modelling of the Energy Content of Municipal Solid Wastes in Northern Nigeria.
AZOJETE, 12:103-109. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng
108
recovery and recycling. These recoverables have paved great means of livelihood to many people
involved in this activity. In addition to this, governments must pose suitable environmental and
economic policies and the free market imposes the necessary energy changes.
4. Conclusion
At present there are no environmental models in the study area that take care of energy potentials of
municipal solid wastes. The present approach integrates the impacts of regional socio-demographic
and economic dynamics on the municipal solid waste generation. A qualitative approach was
combined with the econometric methodology in order to assess these relationships for nine
heterogeneous cities representing the northern Nigeria.
The results showed that the model, with about 70% agreement, can be implemented as a helpful
decision support tool for energy policy set-up. In future work, this model will be statistically refined
by eliminating all components of the municipal solid waste from which a secondary or additional
value could be derived (especially glass, metal, plastics, organic components).
Nomenclature
dQ - dry heating value, MJ/kg.
M’o(w/o) – moisture content in weight percent
V’ (w/o) - volatile matter content in weight percent
A’ (w/o) - ash content in weight percent
( ) -fixed carbon content in weight percent
(C’, w/o) - total carbon in weight percent
(H’, w/o)– total hydrogen in weight percent
(N’, w/o) – total nitrogen in weight percent
(S’, w/o) – total sulphur in weight percent
(O’, w/o) – total oxygen in weight percent
C (w/o) - carbon content in weight percent
H (w/o)- hydrogen content in weight percent
N (w/o) – nitrogen content in weight percent
S (w/o)- sulphur content in weight percent
O’ (w/o) - Oxygen content in weight percent
References
Behling, J., Krüger, B., Danz, P., Marzi, T. and Wirtz, S. 2012. New methods for the
characterization of refuse derived fuels and wastes. Waste Management, pp. 479- 490, downloaded
from www.vivis.de/phocadownload/2012_wm/2012_WM_479_490_Behling.pdf.
Beigl, P., Wassermann, G., Schneider, F. and Salhofer, S. 2003. Forecasting Municipal Solid Waste
Generation in Major European Cities. Institute of Waste Management, BOKU – University of
Natural Resources and Applied Life Sciences, Vienna, Austria.
Arid Zone Journal of Engineering, Technology and Environment, August, 2016; Vol. 12: 103-109.
ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng
109
Doukas, H., Patlitzianas, KD., Kagiannas, AG. and Psarras, J. 2008. Energy Policy Making: An Old
Concept or a Modern Challenge; Energy Sources, Part B, 3:362–371.
Elmer, RK. 1966. Chemical Analyses of Refuse Components. National Incineration Conference
(ASME) New York, pp. 84-88.
FAO. 2016. Environment and Natural Resources Working Paper- Energy for Agriculture. Natural
Resources Management and Environment Department, Food and Agricultural Organization of the
United Nations, Rome: Available at: http://www.fao.org/nr/index_en.htm, Accessed on January 26,
2016.
Filip, K. and Niko, S. 2013. Combustion of Municipal Solid Waste for Power Production. In
Advances in Internal Combustion Engines and Fuel Technologies, Licensee InTech. Available at:
(http://creativecommons.org/licenses/by/3.0, Accessed on February 26, 2016.
Golightly, DW. and Simon, FO. 1989. Methods for Sampling and Inorganic Analysis of Coal. US.
Geological Survey bulletin, United States Government Printing Office.
Karajgi, SB., Udaykumar, RY. and Kamalapur, GD. 2012. Modelling of Power Generation using
Municipal Solid Waste in India. International Journal of Electrical and Computer Engineering
(IJECE), 2(2): 197-202.
Lee, CC. and Huffman, GL. 2001. Solid Waste Calculations. Thermodynamics used in
Environmental Engineering, part 2. U.S. Environmental Protection Agency, Cincinnati, Ohio, pp:
2.47.
National Bureau for Statistics 2006. The National Population Census. Annual report, Nigeria, 2006,
01-07.
Oumarou, MB., Dauda, M., Suleiman, AT. and Babagana, MT. 2012a. Characterization and
Generation of Municipal Solid Wastes in North Eastern Nigeria. Continental Journal of Renewable
Energy, 3(1): 1 – 7, http://www.wiloludjournal.com.
Oumarou, MB., Dauda, M., Abdulrahim, AT. and Abubakar, AB. 2012b. Characterization and
Generation of Municipal Solid Waste in North Central Nigeria. International Journal of Modern
Engineering Research, 2(5): 3669-3672.
Tabatabai, MA. 1974. Determination of Sulphates in Water Samples. Sulphur Institute Journal, 10:
11-13.
Weisman, J. and Eckart, R. 1985. Modern Power Plant Engineering, 2nd edition, Prentice Hall
International, New Delhi.

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Statistical Modelling of the Energy Content of Municipal Solid Wastes in Northern Nigeria

  • 1. Arid Zone Journal of Engineering, Technology and Environment. August, 2016; Vol. 12:103-109 Copyright © Faculty of Engineering, University of Maiduguri, Nigeria. Print ISSN: 1596-2490, Electronic ISSN: 2545-5818 www.azojete.com.ng STATISTICAL MODELLING OF THE ENERGY CONTENT OF MUNICIPAL SOLID WASTES IN NORTHERN NIGERIA M. Ben Oumarou1* , Sulaimon Shodiya1 , Garba M. Ngala1 and Ndubisi A. Aviara2 (1 Department of Mechanical Engineering, University of Maiduguri, PMB 1069, Maiduguri, Borno State, NIGERIA 2 Department of Agricultural and Environmental Resources Engineering, University of Maiduguri, PMB 1069, Maiduguri, Borno State, NIGERIA) *Corresponding author’s e-mail: mmbenomar@yahoo.com Abstract The ability to predict the quantity of energy to be produced is of paramount importance in every country. It would assist in setting up a waste management plan which will lead to a sustainable energy policy. This paper presents the development of a statistical linear regression mathematical model to predict the amount of energy contained in municipal solid wastes from the knowledge of such characteristics of the wastes as physical composition and/or moisture content. Major cities of Kano, Katsina, Dutse, Damaturu, Maiduguri, Bauchi, Birnin Kebbi, Gusau and Sokoto in Northern Nigeria, with high population densities and intense industrial activities constituted the area of study. Ten kilogram each, of the municipal solid waste was collected from the government designated refuse dumping sites in both highly dense populated low income areas and government residential areas, during the hottest months of February, March and April and during the rainy season in the month of August for three years. The waste material was prepared for the determination of its physical characteristics by sifting through. Proximate, ultimate analyses and calorific values were determined using ASTM analytical techniques and formulas from the literature. An empirical linear regression based mathematical model was developed using statistical methods and experimental data. Comparison between experimental and predicted values of the calorific values showed an agreement of about 70% with an average deviation of 5.03% while the standard deviation was found to be 5.29%. Keywords: Mathematical model, municipal solid waste, energy policy, calorific value, moisture content. 1. Introduction Energy problems and solutions should always be guided by local economic, environmental and social considerations. Energy policy formulation should bring together national energy development policies with the locally perceived priorities. There needs to be increased emphasis on non-fossil fuel alternatives to the provision of energy services in developing countries (FAO, 2016).These alternatives range from the modern renewable energy sources, such as improved biomass conversion (including liquid biofuels, biogas, gasification, incineration), solar energy (PV), wind and geothermal energy and small-scale hydropower, to lower energy intensity industries, material and energy recycling and better means of utilizing traditional energy sources, such as improved cooking stoves. Developing countries in general produce more wet waste with lower calorific value but if dried it can easily reach high calorific values. The improvement of waste collection and treatment in those countries is slow and mostly not integrated (Filip and Niko, 2013). One of the most difficult tasks in waste management remain the prediction of the nature and composition of the waste, its moisture content as well as the energy content when waste-to-energy schemes are to be considered. Beigl et al. (2003) opined that an understanding of the relationships between the quantity and quality of environmentally relevant outputs from human processes and regional characteristics is a prerequisite for planning and implementing ecologically sustainable strategies. Apart from process-related parameters, continuous and discontinuous socio-economic
  • 2. Oumarou et al.: Statistical Modelling of the Energy Content of Municipal Solid Wastes in Northern Nigeria. AZOJETE, 12:103-109. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng 104 long-term trends often play a key role in the assessment of environmental impacts. Karajgi et al. (2012) modelled the generation of electrical energy from municipal solid wastes (MSW). They emphasized that it is a complex process since the waste has to undergo various unit operations before it is put in to the process of energy production. The modelling of power generation from MSW therefore has to include all these unit operations, waste flow paths etc. The modelling must also be capable of providing information on important issues like economic, environmental, among many others. All difficulties lie in the heterogeneous nature of the MSW which makes it even difficult to design and develop a thermal treatment plant. These difficulties thus make the development of a mathematical model a necessity. This paper presents the development of a statistical mathematical model to predict the amount of energy contained in MSW from the knowledge of such characteristics of the wastes as physical composition and/or moisture content. Source separation and collection centres separation are only suitable for places where the waste management authority is well structured and equipped, and places where poverty, homelessness, roads, and other infrastructures are no longer a problem. 2. Materials and Methods 2.1 Study Area Major cities of Northern Nigeria, with high population densities (National Bureau for Statistics, 2006) and intense industrial activities constitute the area of study. These cities are Kano, Katsina, Dutse, Damaturu, Maiduguri, Bauchi, Birnin-Kebbi, Gusau and Sokoto in Kano state, Katsina state, Jigawa state, Yobe state, Borno state, Bauchi state, Kebbi state, Zamfara state and Sokoto state, respectively. 2.2 Data Collection Ten kilogram of the municipal solid waste (MSW) was collected from the government designed refuse dumping sites in both, high densely populated low income areas and government residential areas, during the dry season corresponding to hottest months of the year (February, March and April) and during the raining season in the month of August for three years (2012-2015). The samples were collected twice a month. Collection was done in a random manner and carried out across the waste dump using shovels. First collection was carried out midway in the month and the second collection during the last week of the month. This was done so, as to account for fluctuations in patterns due to the salary payment period and other spending patterns. The waste material was prepared for the determination of the refuse characteristics by sifting through and separated into paper, glass, plastics, metal, wood chips, etc. An initial sieving was carried out using sieves to remove sand. This was followed by hand picking at first to remove small stones which could not pass through the sieves and then crushing inside the mortar to a fine powder. 2.3 Experimental A METTLER TOLEDO AB 54 electronic digital weighting machine with limitations of 10 mg minimum and a maximum of 51 grams was used to weight the refuse samples powder. Glass ware equipment including 16 pieces of PYREX conical flasks, pipettes, burettes, beaker, volumetric flask, plastic bottles and filter papers for the titration of the samples; a digital Spectrometer SPECTRUMLAB 22 PC as well as a Gerhardt - Kjeldatherm machine were used to evaluate the organic components of the refuse.
  • 3. Arid Zone Journal of Engineering, Technology and Environment, August, 2016; Vol. 12: 103-109. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng 105 The reagents used are Sulphuric acid (H2SO4), Orthophosphoric acid (H3PO4), Ferrous sulphate (FeSO4), Sodium Fluoride(NaF), Potassium dichromate (K2Cr2O7), Diphenylamine indicator, Kjel tabs, Boric acid, Absolute ethanol, Bromolysol green methyl red, Sodium hydroxide. Nitric acid, acetic acid, magnesium sulphate, gum Arabic, barium chloride. Others are Potassium chloride (KCl), Sodium hydroxide (NaOH), Hydrochloric acid (HCl) and Phenolphthalein indicator. These were used in the chemical analyses to determine the elemental components of the wastes as C (carbon), H (hydrogen), N (nitrogen), S (sulphur)and O (oxygen) using ASTM D 874, ASTM D 4530, ASTM D 5453 and ASTM D 1160 respectively (Behling et al., 2012). 2.4 Analytical Techniques Proximate analysis of the MSW was carried out using the method suggested by Elmer (1966) to determine the moisture content M’o (in weight percent (w/o) by driving off the free moisture at ~ 107o C for approximately 1 hour. The volatile matter content (V’, w/o) was determined by driving off volatile hydrocarbons CO, CO2 and combine H2O at ~ 950o C. The refuse was then burned and the inorganic residue was the ash content (A’, w/o). The fixed carbon ( ) was calculated by difference as shown by Equation (1) (Weisman and Eckart 1985).         owsowowowf AVMC //// 100  (1) 2.4.1 Ultimate Analysis This is an elemental quantitative evaluation of the total carbon (C’, w/o), hydrogen (H’, w/o), nitrogen (N’, w/o), sulphur (S’, w/o), oxygen (O’, w/o) percentages after removal of the moisture and ash (Tabatabai, 1974). This analysis was performed using classic oxidation, decomposition, and/or reduction technique (Golightly and Simon, 1989) to determine, C (carbon content, w/o), H (hydrogen, w/o), N (nitrogen, w/o) and S (sulphur, w/o). Oxygen O’ (w/o) was calculated by difference using Equation (2) (Weisman and Eckart 1985; Lee and Hauffman, 2001):               owsowoowowowowow AMSNHCO /////// 100  (2) 2.4.1 Heating or Calorific Value Since the elemental composition has been known during the ultimate analysis, the ash free, dry heating value was calculated to within 2% accuracy using the empirical Dulong- Berthelot relationship (Weisman and Eckart 1985):   S NO HCQd 2.22 8 1 34537.81         (3) All calculations, data interpretation and mathematical modelling were carried out using basic Statistics while graphs were generated using Microsoft Excel, 2010. The average or mean deviation (M.D) and standard deviation (S. D) were obtained using the statistical formulas in Equations (4) and (5) respectively. ( ) ∑ ( ) (4)
  • 4. Oumarou et al.: Statistical Modelling of the Energy Content of Municipal Solid Wastes in Northern Nigeria. AZOJETE, 12:103-109. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng 106 ( ) √ ∑ ( ) (5) 3. Results and Discussion Physical characterization of the MSW showed that wood, grass, metal, plastic, food remnants, leaves, glass and paper were present in varying proportions in all waste samples in the study area. Table 1 shows the source of secondary data for the model to be generated. Table 1: Physical Composition of the Waste in the Study Area Locality Components (%) Wood Grass Paper Leaves Food remnants Plastic Metal Glass Kano 28.46 6.57 9.66 8.92 6.79 18.99 12.58 8.00 Damaturu 16.62 11.48 3.58 16.24 6.03 38.20 3.64 4.21 Maiduguri 27.28 5.59 6.69 13.17 6.17 32.56 2.94 5.599 Dutse 19.04 5.73 11.34 19.14 5.94 23.93 6.46 8.39 Bauchi 22.28 6.29 14.86 13.83 5.12 24.93 7.80 4.87 Katsina 24.75 6.05 10.52 15.57 4.35 20.46 9.76 8.54 Sokoto 20.07 5.02 8.82 8.54 6.88 17.63 15.85 7.35 Gusau 17.99 17.11 8.18 14.99 8.03 16.27 10.73 6.70 BirninKebbi 19.78 5.35 9.82 5.48 5.98 34.58 12.96 6.04 (Source: Oumarou et al., 2012a and b) MSW characteristics form each city of the study area such as the basic constituents of the waste are considered. Of prime importance are the moisture content, ash content and volatile matter. These form the basis of the model, which is empirical in nature. Thus a linear regression mathematical model developed using the knowledge of the physical component of the MSW in the study area is as shown in equation below: dQ =1.0325 – 0.0011a +0.2254b – 0.0046c – 0.0068d + 0.3184e – 0.0119f – 0.0053g + 0.1099h. (6) where: dQ is the calorific value of the MSW and represents the independent variable of the model. Variables a, b, c, d e, f, g and h represent the percentage composition, after drying, of Wood, Grass, Paper, Leaves, Food remnants, Plastic, Metal and Glass respectively. Table 2: Average Actual and Predicted Generated Values of Calorific Values of MSW in the Study Area.
  • 5. Arid Zone Journal of Engineering, Technology and Environment, August, 2016; Vol. 12: 103-109. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng 107 Locality Actual Calorific value (MJ/kg) Predicted Calorific Value (MJ/kg) Kano 5.667 5.1255 Katsina 5.345 5.3837 Maiduguri 5.078 4.3191 Damaturu 5.277 4.6152 Dutse 5.379 4.0908 Bauchi 5.476 4.2431 Gusau 5.362 4.7479 Sokoto 5.164 7.7724 BirninKebbi 5.494 7.9444 Average Deviation (A.D) = 5.03%, Standard Deviation (S. D) = 5.29% A comparative analysis of the results in Table 2 show an agreement of 69.6% say 70% between the actual experimental values of the calorific values and those values predicted by the statistical model. This model takes into consideration all the components of the MSW even though some components such as glass, metal and some plastics could easily find their ways back to the usefulness stream. These organic and biodegradable components of the refuse (Table 1), which account for an average of 57% of the total refuse, would need to be separated at first, then recycled, composted or re-used. Other components such as wood, leaves, paper, certain category of plastic from which very little or no other future benefits could be derived, and grass would be left over. Energy policies either local or national are directed by the three main objectives, namely the security of supply, the competitiveness of the energy market, and the environmental protection (Doukas et al., 2008). Even though this research is not directly focused towards the development of an energy policy, it would assist in achieving some the keys objectives; namely the security of supply and the environmental protection. The fact that energy policy is developed through a number of social and economic challenges makes this model suitable to the local waste management schemes which are largely based on the informal sector, made of scavengers and town/ city cleaners often grouped now into associations, groups. Waste management is not only about removing waste from the environment and returning it as new products or raw material. It is also a tool of social integration and economic well-being. A collection scenario focused on material recovery and recycling from municipal solid wastes in a selected metropolis of the Sub-Saharan region of Nigeria and Niger republic was designed. The scenario involved 2000 respondents/participants operating at open dump areas. Data obtained were analyzed using simple statistical methods and their findings revealed an annual estimate of the recovery as 16.8 tons of bottles/glasses, 158.4 tons of plastics/rubber, and 264 tons of metal. It also indicated that considerable amount of money could be made from material
  • 6. Oumarou et al.: Statistical Modelling of the Energy Content of Municipal Solid Wastes in Northern Nigeria. AZOJETE, 12:103-109. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng 108 recovery and recycling. These recoverables have paved great means of livelihood to many people involved in this activity. In addition to this, governments must pose suitable environmental and economic policies and the free market imposes the necessary energy changes. 4. Conclusion At present there are no environmental models in the study area that take care of energy potentials of municipal solid wastes. The present approach integrates the impacts of regional socio-demographic and economic dynamics on the municipal solid waste generation. A qualitative approach was combined with the econometric methodology in order to assess these relationships for nine heterogeneous cities representing the northern Nigeria. The results showed that the model, with about 70% agreement, can be implemented as a helpful decision support tool for energy policy set-up. In future work, this model will be statistically refined by eliminating all components of the municipal solid waste from which a secondary or additional value could be derived (especially glass, metal, plastics, organic components). Nomenclature dQ - dry heating value, MJ/kg. M’o(w/o) – moisture content in weight percent V’ (w/o) - volatile matter content in weight percent A’ (w/o) - ash content in weight percent ( ) -fixed carbon content in weight percent (C’, w/o) - total carbon in weight percent (H’, w/o)– total hydrogen in weight percent (N’, w/o) – total nitrogen in weight percent (S’, w/o) – total sulphur in weight percent (O’, w/o) – total oxygen in weight percent C (w/o) - carbon content in weight percent H (w/o)- hydrogen content in weight percent N (w/o) – nitrogen content in weight percent S (w/o)- sulphur content in weight percent O’ (w/o) - Oxygen content in weight percent References Behling, J., Krüger, B., Danz, P., Marzi, T. and Wirtz, S. 2012. New methods for the characterization of refuse derived fuels and wastes. Waste Management, pp. 479- 490, downloaded from www.vivis.de/phocadownload/2012_wm/2012_WM_479_490_Behling.pdf. Beigl, P., Wassermann, G., Schneider, F. and Salhofer, S. 2003. Forecasting Municipal Solid Waste Generation in Major European Cities. Institute of Waste Management, BOKU – University of Natural Resources and Applied Life Sciences, Vienna, Austria.
  • 7. Arid Zone Journal of Engineering, Technology and Environment, August, 2016; Vol. 12: 103-109. ISSN 1596-2490; e-ISSN 2545-5818, www.azojete.com.ng 109 Doukas, H., Patlitzianas, KD., Kagiannas, AG. and Psarras, J. 2008. Energy Policy Making: An Old Concept or a Modern Challenge; Energy Sources, Part B, 3:362–371. Elmer, RK. 1966. Chemical Analyses of Refuse Components. National Incineration Conference (ASME) New York, pp. 84-88. FAO. 2016. Environment and Natural Resources Working Paper- Energy for Agriculture. Natural Resources Management and Environment Department, Food and Agricultural Organization of the United Nations, Rome: Available at: http://www.fao.org/nr/index_en.htm, Accessed on January 26, 2016. Filip, K. and Niko, S. 2013. Combustion of Municipal Solid Waste for Power Production. In Advances in Internal Combustion Engines and Fuel Technologies, Licensee InTech. Available at: (http://creativecommons.org/licenses/by/3.0, Accessed on February 26, 2016. Golightly, DW. and Simon, FO. 1989. Methods for Sampling and Inorganic Analysis of Coal. US. Geological Survey bulletin, United States Government Printing Office. Karajgi, SB., Udaykumar, RY. and Kamalapur, GD. 2012. Modelling of Power Generation using Municipal Solid Waste in India. International Journal of Electrical and Computer Engineering (IJECE), 2(2): 197-202. Lee, CC. and Huffman, GL. 2001. Solid Waste Calculations. Thermodynamics used in Environmental Engineering, part 2. U.S. Environmental Protection Agency, Cincinnati, Ohio, pp: 2.47. National Bureau for Statistics 2006. The National Population Census. Annual report, Nigeria, 2006, 01-07. Oumarou, MB., Dauda, M., Suleiman, AT. and Babagana, MT. 2012a. Characterization and Generation of Municipal Solid Wastes in North Eastern Nigeria. Continental Journal of Renewable Energy, 3(1): 1 – 7, http://www.wiloludjournal.com. Oumarou, MB., Dauda, M., Abdulrahim, AT. and Abubakar, AB. 2012b. Characterization and Generation of Municipal Solid Waste in North Central Nigeria. International Journal of Modern Engineering Research, 2(5): 3669-3672. Tabatabai, MA. 1974. Determination of Sulphates in Water Samples. Sulphur Institute Journal, 10: 11-13. Weisman, J. and Eckart, R. 1985. Modern Power Plant Engineering, 2nd edition, Prentice Hall International, New Delhi.