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proton                      Shell

               +
                   N
                       -
                   +
           -   N




electron                   neutron
He     Li
                   Li shorthand

2p+         3 p+           3 p+   2e– 1e–
2 n0        4 n0           4 n0
Be                B
                                     Al
     4 p+                 5 p+                13 p+
     5 n°                 6 n°                14 n°




     O                     Na

         8 p+   2e– 6e–         11 p+ 2e– 8e– 1e–
         8 n°                   12 n°
• He proposed that electron behaves
  like a wave, specifically a standing
  wave. A standing wave is a wave
  that does not travel down its medium.
• A standing wave is obtained when one
  point (called the node) in the middle
  of the wave is stationary.
• UNCERTAINTY PRINCIPLE
• States that there is NO way to determine
  both the precise location and momentum
  (mass X velocity) of small particles at the
  same time.
• Principle implies that if we could measure
  the momentum of an electron
  accurately, we could NOT determine its
  location at the same time.
• Corresponds to the
  energy level
  numbers. As (n)
  increases, the average
                            +
                                N
  distance of an electron           K   L M
  from the nucleus also     N
                                +
  increases.                n=1
• The larger the (n) the    n=2
  larger the atomic         n=3
  orbital.                  n= so on…
• AZIMUTHAL
• The sublevels that
  describes the shape of
  the atomic orbitals.
                           +
                               N
                                   K   L M
• Examples:                    +
                           N
   =0        s orbital
                           n=1
   =1        p orbital     n=2
   =0        d orbital     n=3
   =1        f orbital     n= so on…
PRINCIPAL              POSSIBLE
ENERGY LEVEL   (n – 1)     VALUES:      SUBLEVELS
     (n)                 0 TO (n – 1)
      1        1–1=0           0             s
      2        2–1=1          0,1           s,p
      3        3–1=2         0,1,2         s,p,d
      4        4–1=3        0,1,2,3       s,p,d,f
      5        5–1=4       0,1,2,3,4     s,p,d,f,g
      6        6–1=5      0,1,2,3,4,5   s,p,d,f,g,h
• Describes the orientation
  of the atomic orbital in
  space. The magnetic quantum
  number can only have (2 X 1)
  integral values for a particular .
                                       +
                                           N
• Example:                                       K   L M
                                       N
                                             +
                   =1
                                       n=1
   [ (2 X 1) + 3] or 3 m
                                       n=2
Values. These 3 m values               n=3
       are -1, 0, and +1
                                       n= so on…
Number of
        SUBLEVEL    2 + 1        m VALUES         Atomic Orbital

1   0     1s       2(0) + = 1          0               1
2   0     2s       2(0) + = 1          0               1
3   1     2p       2(1) + = 3      1, 0, -1            3
    0     3s       2(0) + = 1          0               1
    1     3p       2(1) + = 3      1, 0, -1            3
    2     3d       2(2) + = 5   2, 1, 0, -1, -2        5
• Describes the spin
  direction of an electron.
  There are only two
  possible values for the
                              +
  electron spin quantum           N
                                      K   L M
  number, and these are +     N
                                  +
  ½ and – ½.
                              n=1
• ms = + ½ (clockwise)
                              n=2
• ms = - ½ (counter-          n=3
  clockwise)
                              n= so on…
• Wolfgang Pauli
• States that no two electron can be described by
  the same four quantum numbers.
• Two electrons may have the same first three
  quantum numbers (           ) but these two
  electrons must have different spins
•
• Principle applies the laws in QUANTUM MECHANICS
  to the distribution of electrons among energy levels
  in the ground states (most stable states) of atoms.
• The word AUFBAU means “building        up” in
  german.
•
E
              4d
N   5s
         4p
E   4s
              3d
         3p
R   3s
         2p
G   2s
    1s
Y
2 ways of
              spdf notation
  writing for H, atomic # = 1
 configs.         1       # of e
  One is      1s
called the
  spdf
notation.                value of l
            value of n
Electron Arrangement in Atoms
Electrons in atoms are arranged as:


SHELLS (n)

SUBSHELLS (l)

ORBITALS (ml)

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Quantum mechanics

  • 1.
  • 2.
  • 3. proton Shell + N - + - N electron neutron
  • 4. He Li Li shorthand 2p+ 3 p+ 3 p+ 2e– 1e– 2 n0 4 n0 4 n0
  • 5. Be B Al 4 p+ 5 p+ 13 p+ 5 n° 6 n° 14 n° O Na 8 p+ 2e– 6e– 11 p+ 2e– 8e– 1e– 8 n° 12 n°
  • 6. • He proposed that electron behaves like a wave, specifically a standing wave. A standing wave is a wave that does not travel down its medium. • A standing wave is obtained when one point (called the node) in the middle of the wave is stationary.
  • 7. • UNCERTAINTY PRINCIPLE • States that there is NO way to determine both the precise location and momentum (mass X velocity) of small particles at the same time. • Principle implies that if we could measure the momentum of an electron accurately, we could NOT determine its location at the same time.
  • 8.
  • 9.
  • 10.
  • 11.
  • 12.
  • 13. • Corresponds to the energy level numbers. As (n) increases, the average + N distance of an electron K L M from the nucleus also N + increases. n=1 • The larger the (n) the n=2 larger the atomic n=3 orbital. n= so on…
  • 14. • AZIMUTHAL • The sublevels that describes the shape of the atomic orbitals. + N K L M • Examples: + N =0 s orbital n=1 =1 p orbital n=2 =0 d orbital n=3 =1 f orbital n= so on…
  • 15. PRINCIPAL POSSIBLE ENERGY LEVEL (n – 1) VALUES: SUBLEVELS (n) 0 TO (n – 1) 1 1–1=0 0 s 2 2–1=1 0,1 s,p 3 3–1=2 0,1,2 s,p,d 4 4–1=3 0,1,2,3 s,p,d,f 5 5–1=4 0,1,2,3,4 s,p,d,f,g 6 6–1=5 0,1,2,3,4,5 s,p,d,f,g,h
  • 16. • Describes the orientation of the atomic orbital in space. The magnetic quantum number can only have (2 X 1) integral values for a particular . + N • Example: K L M N + =1 n=1 [ (2 X 1) + 3] or 3 m n=2 Values. These 3 m values n=3 are -1, 0, and +1 n= so on…
  • 17. Number of SUBLEVEL 2 + 1 m VALUES Atomic Orbital 1 0 1s 2(0) + = 1 0 1 2 0 2s 2(0) + = 1 0 1 3 1 2p 2(1) + = 3 1, 0, -1 3 0 3s 2(0) + = 1 0 1 1 3p 2(1) + = 3 1, 0, -1 3 2 3d 2(2) + = 5 2, 1, 0, -1, -2 5
  • 18. • Describes the spin direction of an electron. There are only two possible values for the + electron spin quantum N K L M number, and these are + N + ½ and – ½. n=1 • ms = + ½ (clockwise) n=2 • ms = - ½ (counter- n=3 clockwise) n= so on…
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  • 20. • Wolfgang Pauli • States that no two electron can be described by the same four quantum numbers. • Two electrons may have the same first three quantum numbers ( ) but these two electrons must have different spins •
  • 21. • Principle applies the laws in QUANTUM MECHANICS to the distribution of electrons among energy levels in the ground states (most stable states) of atoms. • The word AUFBAU means “building up” in german. •
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  • 24. E 4d N 5s 4p E 4s 3d 3p R 3s 2p G 2s 1s Y
  • 25. 2 ways of spdf notation writing for H, atomic # = 1 configs. 1 # of e One is 1s called the spdf notation. value of l value of n
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  • 32. Electron Arrangement in Atoms Electrons in atoms are arranged as: SHELLS (n) SUBSHELLS (l) ORBITALS (ml)