2. Some Properties of Nuclei
• Atomic number Z: number of protons in nucleus
(sometimes called charge number)
• Neutron number N: number of neutrons in
nucleus
• Mass number A = Z + N: number of nucleons
(neutrons plus protons) in nucleus
3. Some Properties of Nuclei
X
A
Z
56
26
mass number 56
Fe iron :
atomic number 26
26 protons and 56 – 26 = 30 neutrons
18 18
9 F F
12 13
6 6
11 14
6 6
C 98.9% C 1.1%
C and C:
produced in lab or by cosmic rays
4. Quick Quiz 43.1 Part I
The three nuclei 12C, 13N, and 14O have the same
number of what type of particle?
(a) protons
(b) neutrons
(c) nucleons
5. Quick Quiz 43.1 Part I
The three nuclei 12C, 13N, and 14O have the same
number of what type of particle?
(a) protons
(b) neutrons
(c) nucleons
6. Quick Quiz 43.1 Part II
The three nuclei 12N, 13N, and 14N have the same
number of what type of particle?
(a) protons
(b) neutrons
(c) nucleons
7. Quick Quiz 43.1 Part II
The three nuclei 12N, 13N, and 14N have the same
number of what type of particle?
(a) protons
(b) neutrons
(c) nucleons
8. Quick Quiz 43.1 Part III
The three nuclei 14C, 14N, and 14O have the same
number of what type of particle?
(a) protons
(b) neutrons
(c) nucleons
9. Quick Quiz 43.1 Part III
The three nuclei 14C, 14N, and 14O have the same
number of what type of particle?
(a) protons
(b) neutrons
(c) nucleons
10. Charge and Mass
2
2 27 8
1.660 539 10 kg 2.997 92 10 m/s
= 931.494 MeV
R
E mc
11. The Size and Structure of Nuclei
2 1 2
0
1
0 0 0
2
E
e
K U
q q
mv k
d
1 2
2 2
2
2
2
2 2
4
e e
e
e Ze
q q
d k k
mv mv
Ze
k
mv
15
1 fm 10 m
12. The Size and Structure of Nuclei
1/3 15
with 1.2 10 m 1.2 fm
r aA a
13. Example 43.1:
The Volume and Density of a Nucleus
Consider a nucleus of mass number A, containing
protons and neutrons, each with mass approximately
equal to m.
(A) Find an approximate expression for the mass of the
nucleus.
nucleus
m Am
14. Example 43.1:
The Volume and Density of a Nucleus
(B) Find an expression for the volume of this nucleus in
terms of A.
3 3
nucleus
4 4
3 3
V r a A
15. Example 43.1:
The Volume and Density of a Nucleus
(C) Find a numerical value for the density of this
nucleus.
nucleus
3 3
4
nucleus 3 4
m Am m
V a A a
27
3
15
17 3
1.67 10 kg
4 1.2 10
2.3 10 kg/m
16. Example 43.1:
The Volume and Density of a Nucleus
What if the Earth could be compressed until it had this
density? How large would it be?
24
7 3
17 3
5.97 10 kg
2.6 10 m
2.3 10 kg/m
E
M
V
1/3
7 3
1/3
3
2
3 2.6 10 m
4 3
3 4 4
1.8 10 m
V
V r r
r
20. The Liquid-Drop Model
Four major effects influence binding energy of
nucleus in liquid-drop model:
1. Volume effect
2. Surface effect
3. Coulomb repulsion effect
2
/
e
k e r 1/3
3 1 /
C Z Z A
4. Symmetry effect
2
4 /
C N Z A
21. The Liquid-Drop Model
2
2/3
1 2 3 4
1/3
1
b
Z Z N Z
E C A C A C C
A
A
1
2
3
4
15.7 MeV
17.8 MeV
0.71 MeV
23.6 MeV
C
C
C
C
X 931.494 MeV/u
A
b n Z
E ZM H Nm M
22. Example 43.2: Applying the Semiempirical
Binding-Energy Formula
The nucleus 64Zn has a tabulated binding energy of
559.09 MeV. Use the semiempirical binding-energy
formula to generate a theoretical estimate of the
binding energy for this nucleus.
1
2/3
2/3
2
3 1/3 1/3
2 2
4
15.7 MeV 64 1005 MeV
C 17.8 MeV 64 285 MeV
1 30 29
0.71 MeV 154 MeV
64
34 30
C 23.6 MeV 5.90 MeV
64
C A
A
Z Z
C
A
N Z
A
1005 MeV 285 MeV 154 MeV 5.90 MeV 560 MeV
b
E
31. Half-Life
1/2
0
0 0
2
T
t N
N N e N e
The half-life of a
radioactive substance
is the time interval
during which half of
a given number of
radioactive nuclei
decay.
1/2
2 T
e
1/2
ln 2 0.693
T
0
1
2
n
N N
10
1 Ci 3.7 10 decays/s
1 Bq 1 decay/s
32. Quick Quiz 43.2
On your birthday, you measure the activity of a sample
of 210Bi, which has a half-life of 5.01 days. The activity
you measure is 1.000 Ci. What is the activity of this
sample on your next birthday?
(a) 1.000 Ci
(b) 0.2 Ci
(c) 0.01 Ci
(d) 1022 Ci
33. Quick Quiz 43.2
On your birthday, you measure the activity of a sample
of 210Bi, which has a half-life of 5.01 days. The activity
you measure is 1.000 Ci. What is the activity of this
sample on your next birthday?
(a) 1.000 Ci
(b) 0.2 Ci
(c) 0.01 Ci
(d) 1022 Ci
34. Example 43.3:
How Many Nuclei Are Left?
The isotope carbon-14, 6
14
C, is radioactive and has a
half-life of 5 730 years. If you start with a sample of
1 000 carbon-14 nuclei, how many nuclei will still be
undecayed in 25 000 years?
25000 yr
4.363
5730 yr
n
4.363
0
1 1
1000 49
2 2
n
N N
35. Example 43.4:
The Activity of Carbon
At time t = 0, a radioactive sample contains 3.50 g of
pure 6
11
C , which has a half-life of 20.4 min.
(A) Determine the number N0 of nuclei in the sample at
t = 0.
6
7
3.50 10 g
3.18 10 mol
11.0 g/mol
n
7 23
0
17
3.18 10 mol 6.02 10 nuclei/mol
1.92 10 nuclei
N
36. Example 43.4:
The Activity of Carbon
(B) What is the activity of the sample initially and after
8.00 h?
17
0 0 0
1/2
4 1 17 14
0.693 0.693 1 min
1.92 10
20.4 min 60 s
5.66 10 s 1.92 10 1.09 10 Bq
R N N
T
4 1 4
5.66 10 s 2.88 10 s
14
0
6
1.09 10 Bq
8.96 10 Bq
t
R R e e
37. Example 43.5:
A Radioactive Isotope of Iodine
A sample of the isotope 131
I, which has a half-life of
8.04 days, has an activity of 5.0 mCi at the time of
shipment. Upon receipt of the sample at a medical
laboratory, the activity is 2.1 mCi. How much time has
elapsed between the two measurements?
0 0
ln
t
R R
e t
R R
1/2
0 0
1
ln ln
ln 2
T
R R
t
R R
8.04 d 2.1 mCi
ln 10 d
0.693 5.0 mCi
t
39. Alpha Decay
4 4
2 2
X Y He
A A
Z Z
238 234 4
92 90 2
226 222 4
88 86 2
U Th He
Ra Rn He
0
R
E K
2
X Y
R
Q E M M M c
X Y 931.494 MeV/u
Q M M M
41. Quick Quiz 43.3
Which of the following is the correct daughter nucleus
associated with the alpha decay of 72
157
Hf?
(a) 72
153
Hf
(b) 70
153
Yb
(c) 70
157
Yb
42. Quick Quiz 43.3
Which of the following is the correct daughter nucleus
associated with the alpha decay of 72
157
Hf?
(a) 72
153
Hf
(b) 𝟕𝟎
𝟏𝟓𝟑
𝐘𝐛
(c) 70
157
Yb
43. Example 43.6:
Mass Change in a Radioactive Decay
The 216Po nucleus is unstable and exhibits
radioactivity. It decays to 212Pb by emitting an alpha
particle. The relevant masses, in atomic mass units, are
mi = m(216Po) = 216.001 914 u and
mf = m(212Pb) + m(4He) = 211.991 898 u + 4.002 603 u.
(A) Find the mass change of the system in this decay.
29
211.991 898 u + 4.002 603 u 216.001 914 u
0.007413 u 1.23 10 kg
f i
m m m
44. Example 43.6:
Mass Change in a Radioactive Decay
(B) Find the Q value for this decay.
2
2
29 8
12
1.23 10 kg 3.00 10 m/s
1.11 10 J 6.92 MeV
R
Q E m c
45. Example 43.7:
The Energy Liberated When Radium Decays
The 226Ra nucleus undergoes alpha decay.
(A) Calculate the Q value for this process.
The masses are 226.025 408 u for 226Ra,
222.017 576 u for 222Rn, and 4.002 603 u
for 2
4
He.
X Y 931.494 MeV/u
= 226.025 408 u 222.017 576 u 4.002 603 u
931.494 MeV/u
0.005 229 u 931.494 MeV/u 4.87 MeV
Q M M M
46. Example 43.7:
The Energy Liberated When Radium Decays
(B) What is the kinetic energy of the alpha particle after
the decay?
Y Y
0 M v M v
2 2
Y Y
1 1
2 2
R
E K Q K Q M v M v
2
2 2
Y
Y Y
Y Y
Y Y
1 1 1
1
2 2 2
M v M
Q M v M M v
M M
M M M
K K Q
M M M
222
4.87 MeV 4.78 MeV
222 4
K
48. Beta Decay
1
1
X Y e incomplete expression
X Y e incomplete expression
A A
Z Z
A A
Z Z
14 14
6 7
12 12
7 6
C N e incomplete expression
N C e incomplete expression
54. Quick Quiz 43.4
Which of the following is the correct daughter nucleus
associated with the beta decay of 72
184
Hf?
(a) 72
183
Hf
(b) 73
183
Yb
(c) 73
184
Ta
55. Quick Quiz 43.4
Which of the following is the correct daughter nucleus
associated with the beta decay of 72
184
Hf?
(a) 72
183
Hf
(b) 73
183
Yb
(c) 𝟕𝟑
𝟏𝟖𝟒
𝐓𝐚
57. Conceptual Example 43.8:
The Age of Iceman
In 1991, German tourists discovered the well-preserved
remains of a man, now called “Ötzi the Iceman,” trapped
in a glacier in the Italian Alps. Radioactive dating with
14C revealed that this person was alive approximately
5 300 years ago. Why did scientists date a sample of Ötzi
using 14C rather than 11C, which is a beta emitter having
a half-life of 20.4 min?
58. Example 43.9:
Radioactive Dating
A piece of charcoal containing 25.0 g of carbon is found in some
ruins of an ancient city. The sample shows a 14C activity R of 250
decays/min. How long has the tree from which this charcoal came
been dead?
1/2
0 0
1
ln ln
ln 2
T
R R
t
R R
1/2
0 1/2 0 0
ln 2/ / ln 2
A A
RMT
R R
R T r m M N r mN
1 7
12 23 1
0
250 min 12.0 g/mol 5730 yr 3.156 10 s 1 min
0.667
1 yr 60 s
1.3 10 25.0 g 6.022 10 mol ln 2
R
R
3
5730 yr
ln 0.667 3.4 10 yr
ln 2
t
59. Gamma Decay
X* X
A A
Z Z
12 12
5 6
12 12
6 6
B C* e
C* C
64. Nuclear Reactions
a X Y b
X a, b Y
2
a X Y b
Q M M M M c
4
7
Li p, He
1 7 4 4
1 3 2 2
H Li He He
1 19 16 4
1 9 8 2
H F O He
23 21
avg
3 3
1.38 10 J/K 300 K 6.21 10 J 0.04 eV
2 2
B
K k T
1 1 1
0 n X X* X
A A A
X Z Z
70. Quick Quiz 43.5
When a nucleus undergoes fission, the two daughter
nuclei are generally radioactive. By which process are
they most likely to decay?
(a) alpha decay
(b) beta decay (e)
(c) beta decay (e+)
71. Quick Quiz 43.5
When a nucleus undergoes fission, the two daughter
nuclei are generally radioactive. By which process are
they most likely to decay?
(a) alpha decay
(b) beta decay (e)
(c) beta decay (e+)
72. Quick Quiz 43.6
Which of the following are possible fission reactions?
1 235 140 94 1
0 92 54 38 0
1 235 132 101 1
0 92 50 42 0
1 239 137 97 1
0 94 53 41 0
a n U Xe Sr 2 n
b n U Sn Mo 3 n
c n Pu I Nb 3 n
73. Quick Quiz 43.6
Which of the following are possible fission reactions?
1 239 137 97 1
0 94 53 41 0
c n Pu I Nb 3 n
1 235 140 94 1
0 92 54 38 0
1 235 132 101 1
0 92 50 42 0
a n + U Xe + Sr + 2 n
b n + U Sn + Mo + 3 n
→
→
74. Example 43.10:
The Energy Released in the Fission of 235U
Calculate the energy released when 1.00 kg
of 235U fissions, taking the disintegration
energy per event to be Q = 208 MeV.
A A
m
N nN N
M
3
23 1
26
1.00 10 g
6.02 10 mol 208 MeV
235 g/mol
5.33 10 MeV
A
m
E NQ N Q
M
13
26 7
6
1.60 10 J 1 kWh
5.33 10 MeV 2.37 10 kWh
1 MeV 3.60 10 J
E
80. Safety and Waste Disposal
Philippsburg Nuclear Power Plant, Germany
81. Nuclear Fusion
1 1 2
1 1 1
1 2 3
1 1 2
H H H e
H H He
1 3 4
1 2 2
3 3 4 1 1
2 2 2 1 1
H He He e
He He He H H
82. Quick Quiz 43.7
In the core of a star, hydrogen nuclei combine in fusion reactions.
Once the hydrogen has been exhausted, fusion of helium nuclei
can occur. If the star is sufficiently massive, fusion of heavier and
heavier nuclei can occur once the helium is used up. Consider a
fusion reaction involving two nuclei with the same value of A.
For this reaction to be exothermic, which of the following values
of A are impossible?
(a) 12
(b) 20
(c) 28
(d) 64
83. Quick Quiz 43.7
In the core of a star, hydrogen nuclei combine in fusion reactions.
Once the hydrogen has been exhausted, fusion of helium nuclei
can occur. If the star is sufficiently massive, fusion of heavier and
heavier nuclei can occur once the helium is used up. Consider a
fusion reaction involving two nuclei with the same value of A.
For this reaction to be exothermic, which of the following values
of A are impossible?
(a) 12
(b) 20
(c) 28
(d) 64
84. Terrestrial Fusion Reactions
2 2 3 1
1 1 2 0
2 2 3 1
1 1 1 1
2 3 4 1
1 1 2 0
H H He n 3.27 MeV
H H H H 4.03 MeV
H H He n 17.59 MeV
Q
Q
Q
86. Example 43.11:
The Fusion of Two Deuterons
For the nuclear force to overcome the repulsive
Coulomb force, the separation distance between two
deuterons must be approximately 1.0 1014 m.
(A) Calculate the height of the potential barrier due to
the repulsive force.
2
2 19
9 2 2
1 2
14
14
1.60 10 C
8.99 10 N m /C
1.0 10 m
2.3 10 J 0.14 MeV
E e e
e
q q
U k k
r r
87. Example 43.11:
The Fusion of Two Deuterons
(B) Estimate the temperature required for a deuteron to
overcome the potential barrier, assuming an energy of
3
2
kBT per deuteron (where kB is Boltzmann’s constant).
14
B
3
1.1 10 J
2
k T
14
8
23
2 1.1 10 J
5.6 10 K
3 1.38 10 J/K
T
88. Example 43.11:
The Fusion of Two Deuterons
(C) Find the energy released in the deuterium–
deuterium reaction
3.016 049 u 1.007 825 u 4.023 874 u
4.028 204 u 4.023 874 u 0.004 33 u
0.004 33 u 931.494 MeV/u 4.03 MeV
1 2 3 1
1 1 1 1
H H H H
89. Example 43.11:
The Fusion of Two Deuterons
Suppose the tritium resulting from the reaction in part
(C) reacts with another deuterium in the reaction
2 3 4 1
1 1 2 0
H H He n
How much energy is released in the sequence of two
reactions?
3 2.014 102 u 6.042 306 u
4.002 603 u 1.007 825 u 1.008 665 6.019 093 u
Excess mass: 0.023 213 u
96. Advantages and Problems of Fusion
Advantages:
1. Low cost and abundance of fuel (deuterium)
2. Impossibility of runaway accidents
3. Decreased radiation hazard
Disadvantages:
1. Scarcity of lithium
2. Limited supply of helium
3. Structural damage and induced radioactivity
98. Units of Radiation Doses
Roentgen (R): amount of ionizing radiation that
produces an electric charge of 3.33 1010 C in 1 cm3
of air under standard conditions
Rad: amount of radiation that increases the energy of 1
kg of absorbing material by 1 102 J
102. Uses of Radiation from the Nucleus:
Materials Analysis
Data acquired through neutron activation
analysis: “gamma profile”
1 65 66 66
0 29 29 30
n Cu Cu Zn e
103. Uses of Radiation from the Nucleus:
Materials Analysis
Napoleon Bonaparte
106. Nuclear Magnetic Resonance and
Magnetic Resonance Imaging
1
I I
27
5.05 10 J/T
2
n
p
e
m
proton 2.7928 n
neutron 1.9135 n