Oxygen treatment improves water quality in supercritical power plants by reducing flow-assisted corrosion and impurities that cause turbine blade deposits. It works by dosing oxygen gas at the deaerator and condensate polishing unit outlet to produce stable iron oxide layers that minimize corrosion. The advantages of oxygen treatment include virtually no iron transport, reduced flow-assisted corrosion, less frequent regeneration of condensate polishers, and a broad effective pH range.