This document summarizes a study that used polyamide thin film composite reverse osmosis membrane filtration to treat edible oil wastewater emulsions. The membrane was characterized and its performance was tested for treating wastewater with oil concentrations between 3000-6000 mg/L. Experimental results showed that adding an activated carbon pre-treatment unit prior to the reverse osmosis membrane increased chemical oxygen demand removal from 94% to 99% and permeate flux from 34 L/m2hr to 75 L/m2hr. The reverse osmosis membrane filtration coupled with activated carbon was found to be an effective hybrid technique for removing over 99% of contaminants from high concentration edible oil wastewater.
Dewatering Waste Activated Sludge Using Greenhouse-Gas Flotation followed by ...Medhat Elzahar
The aim of this study is to develop a simple method
for dewatering waste-activated sludge (WAS) for easier reuse
and safer disposal of sludge. The paper builds on the success of
a new flotation technique developed in previous research by the
author utilizing the high water solubility of CO2 gas along with
the model-gas (80%N2+20%CO2). The paper introduces a
simple laboratory model for dewatering WAS in two stages,
flotation followed by centrifugation. The first stage enables
recycling a mixture of greenhouse gases containing 20% of CO2
and 80% of N2 gases by volume. The second stage uses a simple
centrifuge model for dewatering WAS. Experiments were
carried out to reduce the moisture content and volume of WAS.
This was executed by generating low pressure using centrifugal
force introduced by a simple centrifuge apparatus. Using the
experimental dewatering model, promising results were
obtained for dewatering WAS. Furthermore, additional data
were obtained, such as the effect of temperature on the
efficiency of dewater-ability. It is hoped that the results of this
study will lead to more study for the efficient reuse of
greenhouse gases. This can happen by collecting and recycling
industrial emissions of fossil fuels then utilizing them in
wastewater and sludge treatment, thereby decreasing the
resulting harmful effects of these gases on global warming.
Optimization of ultrasonicated membrane anaerobic system (umas) for sewage sl...eSAT Journals
Abstract Ultrasonicated Membrane Anaerobic System UMAS was successfully used for sewage sludge treatment and biogas production. Central Composite Design and Response Surface Methodology were used to determine the optimum conditions in which UMAS produce a maximum content of methane in the biogas produced. The effects of three variables namely pH, chemical oxygen demand (COD) and organic loading rate (OLR) on methane content were evaluated individually and interactively. The optimum conditions obtained were pH 7.74, COD 1061.06 Mg/l and OLR 0.90 kg/m3d. The predicted maximum percentage of methane was 89.72 % and confirmed close to RSM result. Keywords: Optimization, Response Surface Methodology, Sewage Sludge, Ultrasonic, Membrane, Anaerobic Digestion.
IJRET : International Journal of Research in Engineering and Technology is an international peer reviewed, online journal published by eSAT Publishing House for the enhancement of research in various disciplines of Engineering and Technology. The aim and scope of the journal is to provide an academic medium and an important reference for the advancement and dissemination of research results that support high-level learning, teaching and research in the fields of Engineering and Technology. We bring together Scientists, Academician, Field Engineers, Scholars and Students of related fields of Engineering and Technology
Dewatering Waste Activated Sludge Using Greenhouse-Gas Flotation followed by ...Medhat Elzahar
The aim of this study is to develop a simple method
for dewatering waste-activated sludge (WAS) for easier reuse
and safer disposal of sludge. The paper builds on the success of
a new flotation technique developed in previous research by the
author utilizing the high water solubility of CO2 gas along with
the model-gas (80%N2+20%CO2). The paper introduces a
simple laboratory model for dewatering WAS in two stages,
flotation followed by centrifugation. The first stage enables
recycling a mixture of greenhouse gases containing 20% of CO2
and 80% of N2 gases by volume. The second stage uses a simple
centrifuge model for dewatering WAS. Experiments were
carried out to reduce the moisture content and volume of WAS.
This was executed by generating low pressure using centrifugal
force introduced by a simple centrifuge apparatus. Using the
experimental dewatering model, promising results were
obtained for dewatering WAS. Furthermore, additional data
were obtained, such as the effect of temperature on the
efficiency of dewater-ability. It is hoped that the results of this
study will lead to more study for the efficient reuse of
greenhouse gases. This can happen by collecting and recycling
industrial emissions of fossil fuels then utilizing them in
wastewater and sludge treatment, thereby decreasing the
resulting harmful effects of these gases on global warming.
Optimization of ultrasonicated membrane anaerobic system (umas) for sewage sl...eSAT Journals
Abstract Ultrasonicated Membrane Anaerobic System UMAS was successfully used for sewage sludge treatment and biogas production. Central Composite Design and Response Surface Methodology were used to determine the optimum conditions in which UMAS produce a maximum content of methane in the biogas produced. The effects of three variables namely pH, chemical oxygen demand (COD) and organic loading rate (OLR) on methane content were evaluated individually and interactively. The optimum conditions obtained were pH 7.74, COD 1061.06 Mg/l and OLR 0.90 kg/m3d. The predicted maximum percentage of methane was 89.72 % and confirmed close to RSM result. Keywords: Optimization, Response Surface Methodology, Sewage Sludge, Ultrasonic, Membrane, Anaerobic Digestion.
IJRET : International Journal of Research in Engineering and Technology is an international peer reviewed, online journal published by eSAT Publishing House for the enhancement of research in various disciplines of Engineering and Technology. The aim and scope of the journal is to provide an academic medium and an important reference for the advancement and dissemination of research results that support high-level learning, teaching and research in the fields of Engineering and Technology. We bring together Scientists, Academician, Field Engineers, Scholars and Students of related fields of Engineering and Technology
Optimum Conditions for the Removal of Cadmium from Aqueous Solution with Bamb...theijes
The performance of two varieties of Bamboo activated carbon (CABC washed and CABC unwashed), produced by chemical activation with ZnCl2, was evaluated through batch adsorption studies for the removal of Cadmium from aqueous solution. The effects of adsorbent dose, initial concentration of cadmium, agitation time, adsorbate p and, particle size were used as variables to obtain the optimum conditions for the removal of cadmium. Results obtained revealed that as the adsorbent dose increased, the amount adsorbed per unit mass decreased indicating that more active sites were utilized at smaller adsorbent dose. Also, the effects of initial cadmium concentration showed that percentage removal rate increased with increase in cadmium concentration due to availability of more metal ions at higher concentrations. Thus, all the carbons achieved at least 82.62% removal at initial Cadmium concentration of 50mg/l. The optimum pH was 5 and 7 for CABC unwashed and CABC washed respectively while the optimum particle size was 50μm for all the carbon tested. Furthermore, CABC unwashed performed better as an adsorbent because it achieved 71.48% removal of Cadmium in 60 minutes, while CABC washed achieved 69.46% removal in 120mins.
Treatability study of cetp wastewater using physico chemical process-a case s...eSAT Publishing House
IJRET : International Journal of Research in Engineering and Technology is an international peer reviewed, online journal published by eSAT Publishing House for the enhancement of research in various disciplines of Engineering and Technology. The aim and scope of the journal is to provide an academic medium and an important reference for the advancement and dissemination of research results that support high-level learning, teaching and research in the fields of Engineering and Technology. We bring together Scientists, Academician, Field Engineers, Scholars and Students of related fields of Engineering and Technology.
Treatment of Effluent from Granite Cutting Plant by Using Natural Adsorbents ...IJERD Editor
Granite cutting plant is one such industry that releases polluting and turbid effluent. The residue from all these processes is discharged with water as an effluent. The effluent mainly contains many solids that harm the environment. Hence it requires treatment techniques before disposal. Several conventional methods are available for removal of contaminants like coagulation, adsorption, polyelectrolyte methods and biological methods. Most of them are cost prohibitive. The reduction of solids concentration in the effluent before disposal by using the techniques, coagulation followed by adsorption using natural adsorbents, like rice husk carbon and saw dust carbon, in contrast to the usage of activated carbon as it is costly. From a local Granite cutting plant near Anantapur, the effluent is collected and its physico-chemical characteristics are estimated and found to be pH(7.5), TS(4240mg/l), TSS(21560mg/l), TDS(12373mg/l).Effluent obtained is subjected to coagulation by potash alum followed by adsorption using saw dust carbon and rice husk carbon.
Optimizing the Reverse Osmosis Process Parameters by Maximizing Recovery by T...QUESTJOURNAL
ABSTRACT: In this study, the effects of Operating Pressure, Potential Hydrogen, Oxidation Reduction Potential and Anti Scaling Agent on multi responses like Permeate, COD, Total Solids, Conductivity and Hardness in the Reverse Osmosis Process were experimentally investigated on RO 8100 ST8 PT44 400Wl machine. The settings of RO parameters were determined by using Taguchi’s experimental design method. Orthogonal arrays of Taguchi, the signal-to-noise (S/N) ratio, the analysis of variance (ANOVA) are employed to find the optimal levels and to analyze the effect of the RO parameters. Results show that potential of hydrogen, operating pressure, oxidation reduction potential and anti scaling agent are the four Parameters that influence the Permit more effectively and COD, Total Solids, Conductivity and Hardness respectively. Improvement in recovery of RO process is achieved with optimize setting. Finally, the ranges for best RO conditions are proposed for ZLD process.
Anaerobic Treatment of Textile Wastewater using EGSBIJSRD
In this study expanded granular sludge bed (EGSB) reactor has been used to investigate the removal efficiency of chemical oxygen demand (COD), and color of textile wastewater. Synthetic Textile wastewater was treated in an EGSB reactor seeded with non granular anaerobic sludge from UASB reactor treating sugar mill wastewater of Badagandi sugar mill at Badagandi village, Bagalkot district, Karnataka, India and active septic tank. The initial volatile suspended solid concentration was 20.40 g/L. The study was carried out at ambient temperature 29ºC to 37ºC in the laboratory scale reactors of 8.4 L effective volume. Reactor was fed with macro and micro nutrients. Successful reactor startup with granulation was achieved within 13 days of operation using Chitosan as polymer. During startup the hydraulic retention times (HRT) was kept constant for 12 hrs. A maximum COD removal efficiency of 89.95% was achieved at organic loading rate (OLR) of about 8 KgCOD/m3/d. And the maximum bio gas production was 20.4 l/d. During operation period synthetic textile wastewater was fed step by step with increasing concentration of 25%, 50% and 75% of influent COD (5000 mg/L) respectively. Loading was increased by reducing HRT to 6 hrs, 3 hrs, 1.5 hrs and 1 hr respectively. Results indicated that anaerobic treatment of textile wastewater was possible with the supplementation of an external carbon source in the form of glucose (600mg/L). The corresponding maximum COD and color removals were 78.4% and 69% respectively for HRT of 1.5 hrs and OLR of 80 Kg COD/m3/d at ambient temperature.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
International Journal of Engineering Research and Development (IJERD)IJERD Editor
journal publishing, how to publish research paper, Call For research paper, international journal, publishing a paper, IJERD, journal of science and technology, how to get a research paper published, publishing a paper, publishing of journal, publishing of research paper, reserach and review articles, IJERD Journal, How to publish your research paper, publish research paper, open access engineering journal, Engineering journal, Mathemetics journal, Physics journal, Chemistry journal, Computer Engineering, Computer Science journal, how to submit your paper, peer reviw journal, indexed journal, reserach and review articles, engineering journal, www.ijerd.com, research journals,
yahoo journals, bing journals, International Journal of Engineering Research and Development, google journals, hard copy of journal
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
Optimum Conditions for the Removal of Cadmium from Aqueous Solution with Bamb...theijes
The performance of two varieties of Bamboo activated carbon (CABC washed and CABC unwashed), produced by chemical activation with ZnCl2, was evaluated through batch adsorption studies for the removal of Cadmium from aqueous solution. The effects of adsorbent dose, initial concentration of cadmium, agitation time, adsorbate p and, particle size were used as variables to obtain the optimum conditions for the removal of cadmium. Results obtained revealed that as the adsorbent dose increased, the amount adsorbed per unit mass decreased indicating that more active sites were utilized at smaller adsorbent dose. Also, the effects of initial cadmium concentration showed that percentage removal rate increased with increase in cadmium concentration due to availability of more metal ions at higher concentrations. Thus, all the carbons achieved at least 82.62% removal at initial Cadmium concentration of 50mg/l. The optimum pH was 5 and 7 for CABC unwashed and CABC washed respectively while the optimum particle size was 50μm for all the carbon tested. Furthermore, CABC unwashed performed better as an adsorbent because it achieved 71.48% removal of Cadmium in 60 minutes, while CABC washed achieved 69.46% removal in 120mins.
Treatability study of cetp wastewater using physico chemical process-a case s...eSAT Publishing House
IJRET : International Journal of Research in Engineering and Technology is an international peer reviewed, online journal published by eSAT Publishing House for the enhancement of research in various disciplines of Engineering and Technology. The aim and scope of the journal is to provide an academic medium and an important reference for the advancement and dissemination of research results that support high-level learning, teaching and research in the fields of Engineering and Technology. We bring together Scientists, Academician, Field Engineers, Scholars and Students of related fields of Engineering and Technology.
Treatment of Effluent from Granite Cutting Plant by Using Natural Adsorbents ...IJERD Editor
Granite cutting plant is one such industry that releases polluting and turbid effluent. The residue from all these processes is discharged with water as an effluent. The effluent mainly contains many solids that harm the environment. Hence it requires treatment techniques before disposal. Several conventional methods are available for removal of contaminants like coagulation, adsorption, polyelectrolyte methods and biological methods. Most of them are cost prohibitive. The reduction of solids concentration in the effluent before disposal by using the techniques, coagulation followed by adsorption using natural adsorbents, like rice husk carbon and saw dust carbon, in contrast to the usage of activated carbon as it is costly. From a local Granite cutting plant near Anantapur, the effluent is collected and its physico-chemical characteristics are estimated and found to be pH(7.5), TS(4240mg/l), TSS(21560mg/l), TDS(12373mg/l).Effluent obtained is subjected to coagulation by potash alum followed by adsorption using saw dust carbon and rice husk carbon.
Optimizing the Reverse Osmosis Process Parameters by Maximizing Recovery by T...QUESTJOURNAL
ABSTRACT: In this study, the effects of Operating Pressure, Potential Hydrogen, Oxidation Reduction Potential and Anti Scaling Agent on multi responses like Permeate, COD, Total Solids, Conductivity and Hardness in the Reverse Osmosis Process were experimentally investigated on RO 8100 ST8 PT44 400Wl machine. The settings of RO parameters were determined by using Taguchi’s experimental design method. Orthogonal arrays of Taguchi, the signal-to-noise (S/N) ratio, the analysis of variance (ANOVA) are employed to find the optimal levels and to analyze the effect of the RO parameters. Results show that potential of hydrogen, operating pressure, oxidation reduction potential and anti scaling agent are the four Parameters that influence the Permit more effectively and COD, Total Solids, Conductivity and Hardness respectively. Improvement in recovery of RO process is achieved with optimize setting. Finally, the ranges for best RO conditions are proposed for ZLD process.
Anaerobic Treatment of Textile Wastewater using EGSBIJSRD
In this study expanded granular sludge bed (EGSB) reactor has been used to investigate the removal efficiency of chemical oxygen demand (COD), and color of textile wastewater. Synthetic Textile wastewater was treated in an EGSB reactor seeded with non granular anaerobic sludge from UASB reactor treating sugar mill wastewater of Badagandi sugar mill at Badagandi village, Bagalkot district, Karnataka, India and active septic tank. The initial volatile suspended solid concentration was 20.40 g/L. The study was carried out at ambient temperature 29ºC to 37ºC in the laboratory scale reactors of 8.4 L effective volume. Reactor was fed with macro and micro nutrients. Successful reactor startup with granulation was achieved within 13 days of operation using Chitosan as polymer. During startup the hydraulic retention times (HRT) was kept constant for 12 hrs. A maximum COD removal efficiency of 89.95% was achieved at organic loading rate (OLR) of about 8 KgCOD/m3/d. And the maximum bio gas production was 20.4 l/d. During operation period synthetic textile wastewater was fed step by step with increasing concentration of 25%, 50% and 75% of influent COD (5000 mg/L) respectively. Loading was increased by reducing HRT to 6 hrs, 3 hrs, 1.5 hrs and 1 hr respectively. Results indicated that anaerobic treatment of textile wastewater was possible with the supplementation of an external carbon source in the form of glucose (600mg/L). The corresponding maximum COD and color removals were 78.4% and 69% respectively for HRT of 1.5 hrs and OLR of 80 Kg COD/m3/d at ambient temperature.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
International Journal of Engineering Research and Development (IJERD)IJERD Editor
journal publishing, how to publish research paper, Call For research paper, international journal, publishing a paper, IJERD, journal of science and technology, how to get a research paper published, publishing a paper, publishing of journal, publishing of research paper, reserach and review articles, IJERD Journal, How to publish your research paper, publish research paper, open access engineering journal, Engineering journal, Mathemetics journal, Physics journal, Chemistry journal, Computer Engineering, Computer Science journal, how to submit your paper, peer reviw journal, indexed journal, reserach and review articles, engineering journal, www.ijerd.com, research journals,
yahoo journals, bing journals, International Journal of Engineering Research and Development, google journals, hard copy of journal
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
International Refereed Journal of Engineering and Science (IRJES)irjes
International Refereed Journal of Engineering and Science (IRJES) is a leading international journal for publication of new ideas, the state of the art research results and fundamental advances in all aspects of Engineering and Science. IRJES is a open access, peer reviewed international journal with a primary objective to provide the academic community and industry for the submission of half of original research and applications
Evaluation of leachate turbidity reduction in sanitary landfills following a ...TELKOMNIKA JOURNAL
This study evaluates the reduction of leachate turbidity in landfills after applying a mixture of banana starch and thermal water. Principal component analysis was applied to study the combined effect with four variables: pH, concentration of starch and thermal water mixture, rapid mixing speed and slow mixing speed. The experimental design involved 16 experiments with repetition in the jar test to obtain the optimum dose while measuring turbidity as a response variable. The results showed that after the oxidation process of organic matter, under optimal conditions determined in the experiment, the mixture of starch and thermal water contributed to the reduction of leachate turbidity by 29.1%.
Removal of Polyaromatic Hydrocarbons from WaterIJMERJOURNAL
ABSTRACT: Unsaturated cyclic aromatic compounds that are present at high concentrations in the crude oil, are including benzene, toluene and xylene. They can be an important source of water pollution. Benzo pyrene indicate the presence of these compounds in contaminated water into the environment. These compounds into the environment as a result of incomplete combustion of fossil fuels as a source of natural or man-made. These compounds are highly carcinogenic effects that enter the body through the air or food will be available. The use of columns filled with water from organic absorbent material is highly effective in removing the material. The use of nanoparticles for the removal of these contaminants is very appropriate that these coatings use to extract and measure the batch of hydrocarbons and polycyclic aromatic of samples of contaminated water. The Nanocomposites can be produced easily and in addition to longevity of good stability as well. Zeolite nanoparticles and carbon nanotubes are from other suitable methods. Carbon nanotubes are a lot of electrons on the surface that can be paired with aromatic pollution. The aromatics as electron acceptor and electron donor sheets of graphene to act as the effective removal of aromatic pollutants play an important role. In this paper the Titania in photocatalytic process use to remove contaminants to harmless by-products and recycling is much better than other known methods.The Cyclodextrin Mesostructured Silica Nanoparticles and magnetic Nano particle are suitable to remove PAHs from water resources too that is very simple to use. Hope that using the nanoparticles have a big change in removal of water and sanitation
Characterization and the Kinetics of drying at the drying oven and with micro...Open Access Research Paper
The objective of this work is to contribute to valorization de Nephelium lappaceum by the characterization of kinetics of drying of seeds of Nephelium lappaceum. The seeds were dehydrated until a constant mass respectively in a drying oven and a microwawe oven. The temperatures and the powers of drying are respectively: 50, 60 and 70°C and 140, 280 and 420 W. The results show that the curves of drying of seeds of Nephelium lappaceum do not present a phase of constant kinetics. The coefficients of diffusion vary between 2.09.10-8 to 2.98. 10-8m-2/s in the interval of 50°C at 70°C and between 4.83×10-07 at 9.04×10-07 m-8/s for the powers going of 140 W with 420 W the relation between Arrhenius and a value of energy of activation of 16.49 kJ. mol-1 expressed the effect of the temperature on effective diffusivity.
WRI’s brand new “Food Service Playbook for Promoting Sustainable Food Choices” gives food service operators the very latest strategies for creating dining environments that empower consumers to choose sustainable, plant-rich dishes. This research builds off our first guide for food service, now with industry experience and insights from nearly 350 academic trials.
Willie Nelson Net Worth: A Journey Through Music, Movies, and Business Venturesgreendigital
Willie Nelson is a name that resonates within the world of music and entertainment. Known for his unique voice, and masterful guitar skills. and an extraordinary career spanning several decades. Nelson has become a legend in the country music scene. But, his influence extends far beyond the realm of music. with ventures in acting, writing, activism, and business. This comprehensive article delves into Willie Nelson net worth. exploring the various facets of his career that have contributed to his large fortune.
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Introduction
Willie Nelson net worth is a testament to his enduring influence and success in many fields. Born on April 29, 1933, in Abbott, Texas. Nelson's journey from a humble beginning to becoming one of the most iconic figures in American music is nothing short of inspirational. His net worth, which estimated to be around $25 million as of 2024. reflects a career that is as diverse as it is prolific.
Early Life and Musical Beginnings
Humble Origins
Willie Hugh Nelson was born during the Great Depression. a time of significant economic hardship in the United States. Raised by his grandparents. Nelson found solace and inspiration in music from an early age. His grandmother taught him to play the guitar. setting the stage for what would become an illustrious career.
First Steps in Music
Nelson's initial foray into the music industry was fraught with challenges. He moved to Nashville, Tennessee, to pursue his dreams, but success did not come . Working as a songwriter, Nelson penned hits for other artists. which helped him gain a foothold in the competitive music scene. His songwriting skills contributed to his early earnings. laying the foundation for his net worth.
Rise to Stardom
Breakthrough Albums
The 1970s marked a turning point in Willie Nelson's career. His albums "Shotgun Willie" (1973), "Red Headed Stranger" (1975). and "Stardust" (1978) received critical acclaim and commercial success. These albums not only solidified his position in the country music genre. but also introduced his music to a broader audience. The success of these albums played a crucial role in boosting Willie Nelson net worth.
Iconic Songs
Willie Nelson net worth is also attributed to his extensive catalog of hit songs. Tracks like "Blue Eyes Crying in the Rain," "On the Road Again," and "Always on My Mind" have become timeless classics. These songs have not only earned Nelson large royalties but have also ensured his continued relevance in the music industry.
Acting and Film Career
Hollywood Ventures
In addition to his music career, Willie Nelson has also made a mark in Hollywood. His distinctive personality and on-screen presence have landed him roles in several films and television shows. Notable appearances include roles in "The Electric Horseman" (1979), "Honeysuckle Rose" (1980), and "Barbarosa" (1982). These acting gigs have added a significant amount to Willie Nelson net worth.
Television Appearances
Nelson's char
UNDERSTANDING WHAT GREEN WASHING IS!.pdfJulietMogola
Many companies today use green washing to lure the public into thinking they are conserving the environment but in real sense they are doing more harm. There have been such several cases from very big companies here in Kenya and also globally. This ranges from various sectors from manufacturing and goes to consumer products. Educating people on greenwashing will enable people to make better choices based on their analysis and not on what they see on marketing sites.
"Understanding the Carbon Cycle: Processes, Human Impacts, and Strategies for...MMariSelvam4
The carbon cycle is a critical component of Earth's environmental system, governing the movement and transformation of carbon through various reservoirs, including the atmosphere, oceans, soil, and living organisms. This complex cycle involves several key processes such as photosynthesis, respiration, decomposition, and carbon sequestration, each contributing to the regulation of carbon levels on the planet.
Human activities, particularly fossil fuel combustion and deforestation, have significantly altered the natural carbon cycle, leading to increased atmospheric carbon dioxide concentrations and driving climate change. Understanding the intricacies of the carbon cycle is essential for assessing the impacts of these changes and developing effective mitigation strategies.
By studying the carbon cycle, scientists can identify carbon sources and sinks, measure carbon fluxes, and predict future trends. This knowledge is crucial for crafting policies aimed at reducing carbon emissions, enhancing carbon storage, and promoting sustainable practices. The carbon cycle's interplay with climate systems, ecosystems, and human activities underscores its importance in maintaining a stable and healthy planet.
In-depth exploration of the carbon cycle reveals the delicate balance required to sustain life and the urgent need to address anthropogenic influences. Through research, education, and policy, we can work towards restoring equilibrium in the carbon cycle and ensuring a sustainable future for generations to come.
Artificial Reefs by Kuddle Life Foundation - May 2024punit537210
Situated in Pondicherry, India, Kuddle Life Foundation is a charitable, non-profit and non-governmental organization (NGO) dedicated to improving the living standards of coastal communities and simultaneously placing a strong emphasis on the protection of marine ecosystems.
One of the key areas we work in is Artificial Reefs. This presentation captures our journey so far and our learnings. We hope you get as excited about marine conservation and artificial reefs as we are.
Please visit our website: https://kuddlelife.org
Our Instagram channel:
@kuddlelifefoundation
Our Linkedin Page:
https://www.linkedin.com/company/kuddlelifefoundation/
and write to us if you have any questions:
info@kuddlelife.org
Artificial Reefs by Kuddle Life Foundation - May 2024
Oily wastewater treatment using polyamide thin film composite membrane
1. membranes
Article
Oily Wastewater Treatment Using Polyamide Thin
Film Composite Membrane Technology
Sarah Elhady 1, Mohamed Bassyouni 2,3,* , Ramadan A. Mansour 4, Medhat H. Elzahar 5,6 ,
Shereen Abdel-Hamid 7, Yasser Elhenawy 8 and Mamdou Y. Saleh 5,9
1 Public Works Department of Sanitary and Environmental Engineering, the High Institute of Engineering and
Technology in New Damietta, New Damietta 34518, Egypt; sarahelhady1990@gmail.com
2 Department of Chemical Engineering, Faculty of Engineering, Port Said University, Port Said 42526, Egypt
3 Materials Science Program, University of Science and Technology, Zewail City of Science and Technology,
October Gardens, 6th of October, Giza 12578, Egypt
4 Chemical Engineering Department, Higher Institute of Engineering and Technology, New Damietta,
Damietta 34518, Egypt; drramdanelkatep@yahoo.com
5 Sanitary and Environmental Engineering, Faculty of Engineering, Port Said 42526, Egypt;
melzahar@yahoo.com (M.H.E.); mamsaleh29@yahoo.com (M.Y.S.)
6 Department of Civil Engineering, Giza Engineering Institute, Elmoneeb, Giza 12511, Egypt
7 Department of Chemical Engineering, Egyptian Academy for Engineering and Advanced Technology,
Affiliated to Ministry of Military Production, Al Salam city 3056, Egypt; Shereenahmed@eaeat.edu.eg
8 Department of Mechanical Engineering, Faculty of Engineering, Port Said University,
Port Fouad 42526, Egypt; dr_yasser@eng.psu.edu.eg
9 High Institute of Engineering and Technology, El-Manzala, Ad Daqahliyah 35642, Egypt
* Correspondence: migb2000@hotmail.com; Tel.: +2-011-596-75357
Received: 29 February 2020; Accepted: 26 April 2020; Published: 28 April 2020
Abstract: In this study, polyamide (PA) thin film composite (TFC) reverse osmosis (RO) membrane
filtration was used in edible oil wastewater emulsion treatment. The PA-TFC membrane was
characterized using mechanical, thermal, chemical, and physical tests. Surface morphology and
cross-sections of TFCs were characterized using SEM. The effects of edible oil concentrations, average
droplets size, and contact angle on separation efficiency and flux were studied in detail. Purification
performance was enhanced using activated carbon as a pre-treatment unit. The performance of
the RO unit was assessed by chemical oxygen demand (COD) removal and permeate flux. Oil
concentration in wastewater varied between 3000 mg/L and 6000 mg/L. Oily wastewater showed
a higher contact angle (62.9◦) than de-ionized water (33◦). Experimental results showed that the
presence of activated carbon increases the permeation COD removal from 94% to 99%. The RO
membrane filtration coupled with an activated carbon unit of oily wastewater is a convenient hybrid
technique for removal of high-concentration edible oil wastewater emulsion up to 99%. Using
activated carbon as an adsorption pre-treatment unit improved the permeate flux from 34 L/m2hr to
75 L/m2hr.
Keywords: edible oil; reverse osmosis; COD; oil droplets size
1. Introduction
The increased need for edible oil all over the world has resulted in the development of many edible
oil plants, leading to the disposal of huge amounts of wastewater. Palm, olive, soybean, cottonseed,
and sunflower are considered the main sources for extracting edible oil [1]. Persistent market research
(PMR) has reported that the global oil market value is predicted to increase to 130.3 billion US$ by 2024,
recording a compound annual growth rate of 5.1%. In 2018, global consumption of vegetable oils was
Membranes 2020, 10, 84; doi:10.3390/membranes10050084 www.mdpi.com/journal/membranes
2. Membranes 2020, 10, 84 2 of 17
197.33 million metric tons (MMTs) with an annual production of 203.83 MMTs [2]. Treatment of edible
oil industry effluents is considered a major environmental issue. Generally, washing, degumming,
de-acidification, deodorization, and neutralization operations are the main sources of oily wastewater
discharges. Oily wastewater includes mainly nutrient contents, organic compounds in terms of
biological oxygen demand (BOD) and chemical oxygen demand (COD), total suspended solids (TSS),
and lipids. Thus, disposal of untreated oily wastewater effluents can result in pollution of soil, water,
and air. The waste streams which are emitted without any treatment cause environmental problems
such as danger to aquatic life and irreversible damage due to the fact of their high organic concentration
and rapid de-oxygenation of water [3,4]. Moreover, wastewater from vegetable edible oil industries
contains a higher fraction of slowly biodegradable contents, hence, causing noteworthy environmental
issues such as ground and surface water pollution. Accordingly, odor nuisance, water color, and low
soil quality can be addressed and reported, taking into consideration environmental issues and human
health. Therefore, it is necessary to treat oily wastewater effluents to meet environmental regulations
and standards.
Physical and chemical oily wastewater characteristics depend mainly on the type of edible
oil industry where high organic and inorganic pollutants are varied. Numerous methods have
been applied for treating pollution in edible oil wastewater [5–9]. Traditional techniques, such as
coagulation/flocculation, adsorption, dissolved air flotation (DAF), are normally insufficiently effective
to solve the problem, particularly when the oil particles are finely dispersed [10–13]. Recently,
membrane separation and filtration of oily wastewater have gained significant attention because
of its ability to remove most chemicals and microbic contents [14]. It is worth mentioning that the
quality of the treated water is mostly consistent with the influent variations. Additionally, it can
be used in recycling of selected waste streams for different applications. Membrane technology is
used to obtain stable permeate and rejected stream quality which can be reused and recycled in
desired applications [15–20]. Microfiltration and ultrafiltration processes to treat oily wastewater
have previously been reported [21,22]. Masoudnia et al. (2015) employed microfiltration (MF) using
polyvinylidene fluoride (PVDF) membrane for wastewater from the edible oil industry [23]. However,
it was found that membrane performance decreased with time due to the fact of fouling issues [24].
Membrane fouling may include pore blocking, chemical degradation, and cake formation on the surface
of membrane due to the presence of microbes or impurities gathering in the form of inorganic and
organic matters. Additionally, this process leads to shorter life expectancy of the membrane. Polymeric
and ceramic membranes have been employed in oily wastewater treatment [25,26]. Most organic
membranes offer several benefits such as low cost and high removal efficiency. However, they cannot
withstand the high temperature, pressure, and fouling that limit the membrane regeneration [27].
Membrane fouling as a result of the accumulation of impurities has always been a challenge and
limits membrane applications [28]. Chemicals to clean fouling increase the cost and energy demand.
Coupling of feed water pretreatment to the membrane unit is a possible solution to reduce the fouling
issue [29]. Thus, in order to decrease membrane fouling, pre-treatment of the unit is often preferred
(including coagulation, adsorption, filtration, or oxidation) [30–32]. It is supposed that oil droplets
and colloids are destabilized and gathered, forming larger flocs within coagulation pretreatment units
which can be removed easily by membrane filtration [33].
Modification of the membrane structure to be more hydrophilic is another solution to mitigate
fouling formation [14]. Various membrane treatment types (namely, UF, Nanofiltration (NF) anaerobic
membrane system, RO, and MF) have been reported as oily wastewater treatments [34]. The COD
and turbidity measurements of permeate stream must be measured in order to estimate the optimal
conditions for oily wastewater treatment [35]. Šereš et al. (2016) have successfully removed up to 99%
of turbidity and 85% of COD from oily wastewater using microfiltration ceramic membrane. Its pore
size (200 nm) and transmembrane pressure operated up to 3 bar [36]. Reverse osmosis is able to treat
oily wastewater. It is generally used to avoid membrane fouling problems [34]. Stoller et al. (2016) used
hybridizing membrane systems, including UF, NF, and RO, for the treatment of olive oil processing
3. Membranes 2020, 10, 84 3 of 17
wastewater [37]. Azmi et al. studied a UF and RO hybrid membrane system on palm oil/water
emulsion. Removal of BOD and turbidity up to 98.9% and 99%, respectively, were obtained [38].
In another study, the same research team used sand filtration and coagulation/flocculation before the
membrane unit for oily wastewater treatment [39]. A remarkable reduction in COD (95%) and BOD
(95%) was recorded. In this study, an activated carbon adsorption unit was used for pretreatment.
The present investigation aimed to identify the optimum conditions allowed for the permeate stream
suitable for recycling or to be discharged into water sewage with no risk of toxicity to the ecosystem.
Coupling of the adsorption unit to RO was investigated in a hybrid mode. The treatment processes
were compared based on their efficiency in COD and turbidity removals. It was concluded that this
coupling of treatment units was able to purify edible oil wastewater emulsion and treated water to
meet standards.
2. Materials and Methods
Polyoxyethylene sorbatin monolaurate “Tween 20” (C58H11O26, MWt = 1227.72 g/mol) was used
as a surfactant. Oily wastewater was synthesized by mixing 5 mLof soybean oil and 1 L of distilled
water in the presence 1 mL of Tween 20. The oily wastewater emulsion was mixed mechanically for
3.5 h at a mixing rate of 300 rpm. The stability of the oily wastewater emulsion was observed after
24 h. The mixture showed a uniform and stable white emulsion. The PA-TFC RO membrane in a spiral
wound structure was investigated. The Membrane model (TW 30-1812-75) was installed—length: 0.26;
diameter: 0.05 m; maximum service temperature and pressure: 45 ◦C and 1.034 MPa, respectively;
applied pressure: 0.86 MPa; and allowable range of pH: 2 to 10. The pores’ size ranged from 0.67 nm to
0.78 nm [40]. The maximum flow rate of was 0.0076 m3/min. The granular activated carbon (GAC)
filter was installed as an adsorption pretreatment unit. The column dimensions were 63.5 mm and
(height) 254 mm. The GAC filter was fixed to reduce total suspended solids and chemicals resulting in
undesired tastes and odors and volatile organic chemicals (VOCs). The GAC is capable of delivering up
to 0.0038 m3 per minute of treated water. A high-pressure pump (PKM60) with dimensions 0.0254 m ×
0.0254 m, Qmax “0.04 m3/min”, and “2850 rpm” was installed to pump the water–oil emulsion across
the membrane surface. An analysis of oil wastewater and treated water was conducted in terms of
turbidity, oil and grease, and COD.
2.1. Measuring and Analysis
2.1.1. Chemical Oxygen Demand (COD)
Chemical oxygen demand for all oily wastewater samples (feed, permeate, and rejection) was
measured by COD photometer (LaMotte, Chestertown, MD, USA). Sample (0.2 mL) was added into
digested solution (High range: 200–15,000 mg/L) consisting of a strong oxidizing agent (potassium
dichromate), mercuric sulfate, and sulfuric acid. The water mixture was then heated for 120 min in a
COD heater at 150 ◦C. By the end of oxidation, the COD was measured using a spectrophotometer.
2.1.2. Turbidity
The samples of feed, permeate, and rejection were analyzed for total suspended solids in terms of
turbidity using a turbidity meter (Lovibond meter, Lovibond company, Sarasota, FL, USA) expressed
as nephelometric turbidity units (NTUs).
2.1.3. Thermogravimetric Analysis (TGA)
Thermal stability of polyester support, polysulfone, and polyamide layers were characterized
using TGA (TGA Q500 V20.10 Build 36, TA Company, Tokyo, Japan). Thermogravimetric analysis
is considered a proper method to quantitatively examine the thermal stability of polymeric
membrane materials.
4. Membranes 2020, 10, 84 4 of 17
2.1.4. Fourier-Transform Infrared Spectroscopy (FTIR)
The membrane model (TW 30-1812-75) was investigated using FTIR analysis (Avatar 370 Nicolet
Spectrometer, Madison, CA, USA) to characterize and identify chemical bonds.
2.1.5. Scanning Electron Microscopy (SEM)
The thin film composite RO membrane was freeze-fractured and gold coated using an S150A
SPUTTER COATER SEM (Edwards High Vacuum = 7.5 mbar). Surface morphology and cross-sections
of TFC membranes were investigated using scanning electron microscopy (SEM, Quanta 250 FEG, FEI
Company, Tokyo, Japan).
2.1.6. Mechanical Testing
The strength of the RO membrane was measured using a (Tinius Olsen H25KS, Shanghai, China)
tensile instrument by providing load coaxial style.
2.1.7. Average oil Particle Size
The size distribution of oil droplets in the oily wastewater feed was determined using a laser
particle size analyzer (Nicomp Nano size, 380 ZLS, Santabarbara, CA, USA).
2.1.8. Dynamic Wetting
Each sample was cut to a size of 10 mm × 50 mm with sharp scissors. The TFC-PA specimen was
immersed into oily wastewater and water samples. The weight of the absorbed water was measured.
The dynamic water absorption was plotted versus time.
2.1.9. Contact Angle
To study the effect of edible oil on the hydrophobicity of the PA-THF RO membrane, the surface
contact angle of the membrane was measured based on the sessile drop method via a contact angle
measuring instrument (OCA 15EC contact angle model, GmbH, Filderstadt, Germany). The reported
results were the average contact angle of deionized water droplets and oily wastewater at five different
locations on each sample.
2.1.10. Oil and Grease
The oil concentration was determined using the hexane extraction gravimetric method. One
hundred and twenty-five milliliters of oily wastewater samples were added to ethanol (20 mL) and
sulfuric acid (20 mL). Mixtures were well shaken in a separation funnel. After fifteen minutes, two
layers were separated, and the supernatant layer containing the oil (organic layer) was collected.
The weight (wt) of the beaker before and after separation was recorded. Then, the oil concentration
was calculated as given in Equation (1).
Oil concentration =
wt (mg)
volume of sample (ml) × 1000
(1)
2.2. Experimental Setup and Operation
The tank, made from acrylic for mixing the water–oil emulsion, is shown in Figure 1. The tank’s
dimensions were 0.4 m in diameter and 0.7 m in height with a total volume of 0.05 m3 and a rotational
speed of 300 rpm for the stainless-steel mixer.
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5
Figure 1. Mixing tank for preparation of nano-emulsion oil in water.
Figure 2a shows the schematic diagram of the PA-TFC RO membrane filtration unit and the
facilities. The membrane was washed using de-ionized water for fifteen minutes before the treatment
process to ensure that the RO had reached maximum force. The synthetic wastewater/oil emulsion
was fed in mechanically stirred tanks, 0.04 m3, in the presence of surfactant (Tween 20). The oily
wastewater was pumped to the RO unit under a constant pressure of 8.5 bar. The oil concentration
in wastewater varied from 3 g/L to 6 g/L. The treated water was collected from the RO unit,
determined by collected permeate water in vessel. The permeate flow rate was measured regularly
to calculate flux. The permeate, rejected, and feed water contents were tested for COD, oil and grease,
and turbidity. The rejected wastewater stream was analyzed to determine oil content in the oily
wastewater. To control the membrane fouling, a pre-treatment adsorption unit of activated carbon
was installed. In the feed pretreatment unit, adsorption GAC was applied to remove suspended
solids and organic constituents. The pretreatment process plays a crucial role for treatment process
of high concentration edible oil wastewater in oil industries that would block the membrane and
reduce its lifetime. A process flow diagram (PFD) of the pre-adsorption unit and membrane filtration
process are shown in Figure 2b. After oily wastewater treatment using the hybrid system (i.e., GAC
and RO membrane), the treated water sample was tested for possible irrigation or discharge into the
sewage network. The oil contents were determined in the rejected stream for recycling highly
concentrated oily wastewater streams in the production of soap as a step towards a zero discharge
system [41]. Turbidity and COD were measured in each process to study the efficiency of oil removal.
Figure 1. Mixing tank for preparation of nano-emulsion oil in water.
Figure 2a shows the schematic diagram of the PA-TFC RO membrane filtration unit and the
facilities. The membrane was washed using de-ionized water for fifteen minutes before the treatment
process to ensure that the RO had reached maximum force. The synthetic wastewater/oil emulsion
was fed in mechanically stirred tanks, 0.04 m3, in the presence of surfactant (Tween 20). The oily
wastewater was pumped to the RO unit under a constant pressure of 8.5 bar. The oil concentration in
wastewater varied from 3 g/L to 6 g/L. The treated water was collected from the RO unit, determined
by collected permeate water in vessel. The permeate flow rate was measured regularly to calculate flux.
The permeate, rejected, and feed water contents were tested for COD, oil and grease, and turbidity. The
rejected wastewater stream was analyzed to determine oil content in the oily wastewater. To control
the membrane fouling, a pre-treatment adsorption unit of activated carbon was installed. In the feed
pretreatment unit, adsorption GAC was applied to remove suspended solids and organic constituents.
The pretreatment process plays a crucial role for treatment process of high concentration edible oil
wastewater in oil industries that would block the membrane and reduce its lifetime. A process flow
diagram (PFD) of the pre-adsorption unit and membrane filtration process are shown in Figure 2b.
After oily wastewater treatment using the hybrid system (i.e., GAC and RO membrane), the treated
water sample was tested for possible irrigation or discharge into the sewage network. The oil contents
were determined in the rejected stream for recycling highly concentrated oily wastewater streams
in the production of soap as a step towards a zero discharge system [41]. Turbidity and COD were
measured in each process to study the efficiency of oil removal.
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Figure 2. The diagram of an edible oil wastewater treatment unit using (a) a polyamide (PA) thin film
composite (TFC) reverse osmosis (RO) membrane (b) pretreatment unit with a powder carbon filter.
Percentage oil rejection and flux
In the RO membrane unit, the separation efficiency was determined in terms of rejection (%) of
COD, turbidity or oil and grease as given in Equation (2) [5]:
R(%) =
CF CP
CF
× 100 (2)
The CP is the concentration of oil in permeate stream; CF is the oil concentration in the feed.
The water flux (Jω) is the volume of permeate (V) that is collected per unit membrane surface
area (a) per unit time (t). Water flux is determined as given in Equation (3):
Jω =
V
a × t
(3)
3. Results and Discussion
3.1. Membrane Characterization
3.1.1. Surface Morphology
(a)
(b)
Figure 2. The diagram of an edible oil wastewater treatment unit using (a) a polyamide (PA) thin film
composite (TFC) reverse osmosis (RO) membrane (b) pretreatment unit with a powder carbon filter.
Percentage Oil Rejection and Flux
In the RO membrane unit, the separation efficiency was determined in terms of rejection (%) of
COD, turbidity or oil and grease as given in Equation (2) [5]:
R(%) =
CF − CP
CF
× 100 (2)
The CP is the concentration of oil in permeate stream; CF is the oil concentration in the feed.
The water flux (Jω) is the volume of permeate (V) that is collected per unit membrane surface
area (a) per unit time (t). Water flux is determined as given in Equation (3):
Jω =
V
a × t
(3)
7. Membranes 2020, 10, 84 7 of 17
3. Results and Discussion
3.1. Membrane Characterization
3.1.1. Surface Morphology
Polyamide thin film composite contains three layers of thin film PA, polysulfone, and a supported
layer of polyester. The SEM images of the TFC membrane were investigated before and after oily
wastewater treatment to analyze microscopic structure of the membrane. Cross-sectional images of
the TFC were taken after the cutting with freeze-fracturing. Figure 3a shows cross-sectional images
which show the RO polyamide membrane consisting of three layers: a thin selective layer on the upper
surface (0.22 µm), a microporous interlayer (about 17.21 µm), and polyester acting as structural support
(92.61 µm). The SEM micrographs of pristine membrane are shown in Figure 3b. Membrane surface
morphology after wastewater treatment is shown in Figure 3c. It was found that oil droplets absorbed
on the surface of the TFC membrane. In the absence of the GAC unit, most of the membrane pores
were blocked, resulting in a decrease in membrane flux. Zhao et al. (2015) reported similar results on
polyvinylchloride ultrafiltration membranes blocking in oily wastewater treatment [42].
Membranes 2020, 10, x FOR PEER REVIEW 7 of 17
7
Polyamide thin film composite contains three layers of thin film PA, polysulfone, and a supported
layer of polyester. The SEM images of the TFC membrane were investigated before and after oily
wastewater treatment to analyze microscopic structure of the membrane. Cross-sectional images of
the TFC were taken after the cutting with freeze-fracturing. Figure 3a shows cross-sectional images
which show the RO polyamide membrane consisting of three layers: a thin selective layer on the
upper surface (0.22 µm), a microporous interlayer (about 17.21 µm), and polyester acting as structural
support (92.61 µm). The SEM micrographs of pristine membrane are shown in Figure 3b. Membrane
surface morphology after wastewater treatment is shown in Figure 3c. It was found that oil droplets
absorbed on the surface of the TFC membrane. In the absence of the GAC unit, most of the membrane
pores were blocked, resulting in a decrease in membrane flux. Zhao et al. (2015) reported similar
results on polyvinylchloride ultrafiltration membranes blocking in oily wastewater treatment [42].
Figure 3. (a) Cross-section of an RO membrane, (b) surface morphology before oily wastewater
treatment, and (c) surface morphology after oily wastewater treatment.
3.1.2. Contact Angle
Hydrophilicity is one of the most crucial parameters that influences the permeability and
antifouling process of the membrane surface. A low contact angle refers to the high hydrophilicity of
(b) (c)
(a)
Figure 3. (a) Cross-section of an RO membrane, (b) surface morphology before oily wastewater
treatment, and (c) surface morphology after oily wastewater treatment.
8. Membranes 2020, 10, 84 8 of 17
3.1.2. Contact Angle
Hydrophilicity is one of the most crucial parameters that influences the permeability and
antifouling process of the membrane surface. A low contact angle refers to the high hydrophilicity
of the surface. Contact angles of the TFC membrane were measured using advancing contact angle
methods. As shown in Figure 4, the contact angle of water on the surface was 33◦, while the average
contact angle of oily wastewater on the membrane surface was 62.9◦. These results suggest that the
membrane in water was more hydrophilic than oil.
Membranes 2020, 10, x FOR PEER REVIEW 8 of 17
8
the surface. Contact angles of the TFC membrane were measured using advancing contact angle
methods. As shown in Figure 4, the contact angle of water on the surface was 33°, while the average
contact angle of oily wastewater on the membrane surface was 62.9°. These results suggest that the
membrane in water was more hydrophilic than oil.
Figure 4. Contact angles of (A) water and (B) oil on the membrane surface.
3.1.3. Mechanical Test
Figure 5 shows the results of the stress–strain behavior of the TFC membrane. The tensile
strength was found to be 52 MPa, and the Young’s modulus was 1000 MPa. The mechanical testing
results are listed in Table 1.
Figure 5. The stress–strain curve for PA-TFC reverse osmosis membrane.
Table 1. Mechanical properties of polyamide membrane.
Polyamide Thin Film Composite
Property
51.15
Tensile strength, MPa
1000
Young’s modulus, MPa
Figure 4. Contact angles of (A) water and (B) oil on the membrane surface.
3.1.3. Mechanical Test
Figure 5 shows the results of the stress–strain behavior of the TFC membrane. The tensile strength
was found to be 52 MPa, and the Young’s modulus was 1000 MPa. The mechanical testing results are
listed in Table 1.
Membranes 2020, 10, x FOR PEER REVIEW 8 of 17
8
the surface. Contact angles of the TFC membrane were measured using advancing contact angle
methods. As shown in Figure 4, the contact angle of water on the surface was 33°, while the average
contact angle of oily wastewater on the membrane surface was 62.9°. These results suggest that the
membrane in water was more hydrophilic than oil.
Figure 4. Contact angles of (A) water and (B) oil on the membrane surface.
3.1.3. Mechanical Test
Figure 5 shows the results of the stress–strain behavior of the TFC membrane. The tensile
strength was found to be 52 MPa, and the Young’s modulus was 1000 MPa. The mechanical testing
results are listed in Table 1.
Figure 5. The stress–strain curve for PA-TFC reverse osmosis membrane.
Table 1. Mechanical properties of polyamide membrane.
Polyamide Thin Film Composite
Property
51.15
Tensile strength, MPa
1000
Young’s modulus, MPa
Figure 5. The stress–strain curve for PA-TFC reverse osmosis membrane.
9. Membranes 2020, 10, 84 9 of 17
Table 1. Mechanical properties of polyamide membrane.
Property Polyamide Thin Film Composite
Tensile strength, MPa 51.15
Young’s modulus, MPa 1000
3.1.4. Thermogravimetric Analysis (TGA)
Thermogravimetric analysis (TGA) of the reverse osmosis membrane was performed under
nitrogen atmosphere as shown in Figure 6. Four weight-loss stages can be observed in the TGA curve.
Weight loss at an average temperature 100 ◦C can be attributed to water loss. The second stage at an
average temperature 304–551 ◦C refers to the thermal degradation range of the supported polyester
layer. The third stage at an average temperature 450–550 ◦C can be attributed to polyamide loss.
The fourth stage shows the weight loss of the polysulfone layer, starting from 590 ◦C.
Membranes 2020, 10, x FOR PEER REVIEW 9 of 17
3.1.4. Thermogravimetric Analysis (TGA)
Thermogravimetric analysis (TGA) of the reverse osmosis membrane was performed under
nitrogen atmosphere as shown in Figure 6. Four weight-loss stages can be observed in the TGA curve.
Weight loss at an average temperature 100°C can be attributed to water loss. The second stage at an
average temperature 304–551°C refers to the thermal degradation range of the supported polyester
layer. The third stage at an average temperature 450–550°C can be attributed to polyamide loss. The
fourth stage shows the weight loss of the polysulfone layer, starting from 590°C.
Figure 6. TGA for the reverse osmosis membrane.
3.1.5. Fourier Transform-Infrared Spectroscopy FTIR
The FTIR was used to analyze the chemical composition of the top surface of membrane (PA),
and PSF and polyester-supported layer. The infrared spectra of TFC membrane showed the main
characteristic peaks of PA layer and polysulfone-supporting layer as shown in Figure 7 and listed in
Table 2.
Figure 6. TGA for the reverse osmosis membrane.
3.1.5. Fourier Transform-Infrared Spectroscopy FTIR
The FTIR was used to analyze the chemical composition of the top surface of membrane (PA),
and PSF and polyester-supported layer. The infrared spectra of TFC membrane showed the main
characteristic peaks of PA layer and polysulfone-supporting layer as shown in Figure 7 and listed in
Table 2.
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10
Figure 7. FTIR spectra for TFC-PA membrane and polysulfone (PSF) support layer.
Table 2. The main characteristic peaks for PA and PSF.
PA PSF
Range
(cm−1)
Assignment
Range
(cm−1)
Assignment
840.39 aromatic hydrogen, isolated 727.89 Aromatic hydrogen
1105.05 - 870.12
Hydrogen deformation of para-substituted
phenyl groups.
1155.67 C–N bending 1248.53
C–O–C asymmetric stretching vibration of the
aryl–O–aryl group
1242.98 C–N bending 1581.03
Aromatic in-plane ring bend stretching
vibration
1493.59 Aromatic ring breathing 3064.54 O–H aromatic stretching
1590.13
C=O band of an amide group, C–N
stretching, and C–N–C deformation
vibration in a secondary amide group
- -
3420.93 N–H (and O–H) - -
3647.56 O–H aromatic stretching bands - -
3.2. Effect of Oil Particle Size on Separation Efficiency
Oil particles that are captured on the PA-TFC RO membrane surface affect separation efficiency
across membrane filtration. The PA-TFC RO membrane’s capacity may vary depending on the
particle size variation in the oily wastewater as shown in Figure 8. The distribution of oil droplets’
size was measured for six samples of emulsion to study the effect of oil particle size on the separation
efficiency. It was found that the separation performance improves as the oil particles’ sizes increase.
This can be attributed to the coalescence of oil particle droplets where these are retained on thin film
membrane. Thus, rejection efficiency increased from 94% to 99% with the increase of oil concentration
as well as the average droplet size. Similar trends were observed by Chakrabarty et al. [43] and Mittal
et al. [44].
Figure 7. FTIR spectra for TFC-PA membrane and polysulfone (PSF) support layer.
Table 2. The main characteristic peaks for PA and PSF.
PA PSF
Range (cm−1) Assignment Range (cm−1) Assignment
840.39 aromatic hydrogen, isolated 727.89 Aromatic hydrogen
1105.05 - 870.12
Hydrogen deformation of
para-substituted phenyl groups.
1155.67 C–N bending 1248.53
C–O–C asymmetric stretching
vibration of the aryl–O–aryl group
1242.98 C–N bending 1581.03
Aromatic in-plane ring bend
stretching
vibration
1493.59 Aromatic ring breathing 3064.54 O–H aromatic stretching
1590.13
C=O band of an amide group, C–N
stretching, and C–N–C deformation
vibration in a secondary amide group
- -
3420.93 N–H (and O–H) - -
3647.56 O–H aromatic stretching bands - -
3.2. Effect of Oil Particle Size on Separation Efficiency
Oil particles that are captured on the PA-TFC RO membrane surface affect separation efficiency
across membrane filtration. The PA-TFC RO membrane’s capacity may vary depending on the particle
size variation in the oily wastewater as shown in Figure 8. The distribution of oil droplets’ size was
measured for six samples of emulsion to study the effect of oil particle size on the separation efficiency.
It was found that the separation performance improves as the oil particles’ sizes increase. This can be
attributed to the coalescence of oil particle droplets where these are retained on thin film membrane.
Thus, rejection efficiency increased from 94% to 99% with the increase of oil concentration as well as
the average droplet size. Similar trends were observed by Chakrabarty et al. [43] and Mittal et al. [44].
3.3. Dynamic Wetting
All membranes demonstrated water absorption curves that rose sharply within 20 s. Further
immersion occurred after 20 s up to 90 s, inducing a plateau in all curves. Early in the immersion period,
instantaneous water absorption was observed for all membranes. After 20 s all curves plateaued,
showing that all membranes could only absorb a certain number of water molecules. This observation
confirms the hydrophilic behavior of the TFC membrane. The absorption curve of the TFC membrane
11. Membranes 2020, 10, 84 11 of 17
can be seen in Figure 9. Oil contents considerably decreased the water absorption properties of the RO
membrane. This can be attributed to the higher contact angles.
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Figure 8. Effect of oil particle size on separation efficiency, average oil droplet size (a–f) and (g) effect
of average oil droplet size on membrane separation.
3.3. Dynamic Wetting
All membranes demonstrated water absorption curves that rose sharply within 20 s. Further
immersion occurred after 20 s up to 90 s, inducing a plateau in all curves. Early in the immersion
Figure 8. Effect of oil particle size on separation efficiency, average oil droplet size (a–f) and (g) effect
of average oil droplet size on membrane separation.
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period, instantaneous water absorption was observed for all membranes. After 20 s all curves
plateaued, showing that all membranes could only absorb a certain number of water molecules. This
observation confirms the hydrophilic behavior of the TFC membrane. The absorption curve of the
TFC membrane can be seen in Figure 9. Oil contents considerably decreased the water absorption
properties of the RO membrane. This can be attributed to the higher contact angles.
Figure 9. Water and oily wastewater absorption of the thin film composite membrane.
3.4. Effect of Time on Permeate Flux
The fluxes of permeate oily wastewater were taken every 50 min, starting from 5 min. Figure 10
shows that the initial flux in case of RO and RO and adsorption pretreatment hybrid system were 34
L/m2·h and 75 L/m2·h, respectively. The initial flux was the maximum value at constant pressure 8.5
bar. This phenomenon can be attributed to the lowest value of mass transfer resistance at the
beginning. At the membrane surface, permeate flow rate reduces with time and concentration
polarization increases. A decrease in flux was recorded as a result of increased mass transfer
resistance, so fouling is often considered in the form of decreasing permeate flux over time [45–49].
Membrane blocking leads to a decrease in membrane performance because of suspended solids
accumulating on the outer layer. This could be observed in the RO unit without an adsorption unit.
Differences in fouling behavior between the oily wastewater treatment using RO and the RO hybrid
system were expected as a result of the differences in the rate of fouling.
Figure 9. Water and oily wastewater absorption of the thin film composite membrane.
3.4. Effect of Time on Permeate Flux
The fluxes of permeate oily wastewater were taken every 50 min, starting from 5 min. Figure 10
shows that the initial flux in case of RO and RO and adsorption pretreatment hybrid system were
34 L/m2·h and 75 L/m2·h, respectively. The initial flux was the maximum value at constant pressure
8.5 bar. This phenomenon can be attributed to the lowest value of mass transfer resistance at the
beginning. At the membrane surface, permeate flow rate reduces with time and concentration
polarization increases. A decrease in flux was recorded as a result of increased mass transfer resistance,
so fouling is often considered in the form of decreasing permeate flux over time [45–49]. Membrane
blocking leads to a decrease in membrane performance because of suspended solids accumulating
on the outer layer. This could be observed in the RO unit without an adsorption unit. Differences in
fouling behavior between the oily wastewater treatment using RO and the RO hybrid system were
expected as a result of the differences in the rate of fouling.
Membranes 2020, 10, x FOR PEER REVIEW 13 of 17
Figure 10. Effect of time separation on flux.
3.5. Effect of Oil Concentration on Separation Efficiency
The effect of the oil concentration on the separation performance was determined at a constant
pressure of 0.85 MPa, as listed in Table 1, which describes the maximum concentration of suspended
solid in terms of turbidity and COD removal. The results are presented in Figures 11 and 12, showing
that the oil removal increases with an increase in feed concentration. Separation efficiency improves
with the increase in oil concentration which can be attributed to the formation of larger oil droplets.
Figure 10. Effect of time separation on flux.
13. Membranes 2020, 10, 84 13 of 17
3.5. Effect of Oil Concentration on Separation Efficiency
The effect of the oil concentration on the separation performance was determined at a constant
pressure of 0.85 MPa, as listed in Table 3, which describes the maximum concentration of suspended
solid in terms of turbidity and COD removal. The results are presented in Figures 11 and 12, showing
that the oil removal increases with an increase in feed concentration. Separation efficiency improves
with the increase in oil concentration which can be attributed to the formation of larger oil droplets.
Furthermore, oil droplets separated by the membrane form a gel layer on the membrane surface [43].
Thus, removal can be improved. However, the flux decreases in the absence of an adsorption
pretreatment unit. The average removal of oil in terms of COD reached 97.4%. The performance of
membrane showed high COD removal. The COD of the permeate stream was within the allowable
levels (1100 ppm) for the discharge of wastewater into sewage networks.
Table 3. Effect of oil concentration on the properties of treated water.
Feed COD
Concentration
(mg/L)
Permeate COD
Concentration
(mg/L)
Separation
Efficiency %
Feed Turbidity
(NTUs)
Permeate
Turbidity (NTUs)
5653 386 97.4 990 1.28
4343 490 95.35 980 1.22
3591 528 94.53 870 1.84
3299 521 94.12 850 1.6
Membranes 2020, 10, x FOR PEER REVIEW 14 of 17
Figure 11. Effect of feed concentration on permeate COD.
Figure 11. Effect of feed concentration on permeate COD.
14. Membranes 2020, 10, 84 14 of 17
14
Figure 11. Effect of feed concentration on permeate COD.
Figure 12. Effect of feed concentration on removal efficiency.
3.6. Effect of Adsorption Pretreatment unit on Membrane Filtration Performance
Permeate flux decreased as a result of membrane fouling and concentration polarization. Using
activated carbon pretreatment unit led to a decrease in suspended solids’ load on membrane
filtration. Oil removal improved to 99.9% in the presence of a pre-treatment unit as listed in Table 2.
Oil concentration in terms of COD in the permeate stream was less than 100 mg/L which meets the
national discharge standards of wastewater.
Figure 12. Effect of feed concentration on removal efficiency.
3.6. Effect of Adsorption Pretreatment unit on Membrane Filtration Performance
Permeate flux decreased as a result of membrane fouling and concentration polarization. Using
activated carbon pretreatment unit led to a decrease in suspended solids’ load on membrane filtration.
Oil removal improved to 99.9% in the presence of a pre-treatment unit as listed in Table 4. Oil
concentration in terms of COD in the permeate stream was less than 100 mg/L which meets the national
discharge standards of wastewater.
Table 4. Effect of pretreatment on permeate characteristics.
Oil Concentration of
Feed (mg/L)
Oil Concentration of
Permeate before
Pretreatment
(mg/L)
Oil Concentration of
Permeate after
Pretreatment and RO
(mg/L)
Rejection %
5653 105 4.8 99.91
4343 219 5.3 99.87
3591 186 4.3 99.88
3299 235 3.2 99.90
4. Conclusions
The reverse osmosis thin film composite membrane showed good results in the treatment of oily
wastewater produced from the edible oil industry. Removal of turbidity, COD, and oil removal at
fixed flux was achieved using RO and an adsorption unit hybrid system. An activated carbon unit as
a pretreatment unit showed better efficiency and higher permeate flux. Membrane filtration using
a reverse osmosis membrane was conducted to remove edible oil and suspended solids from oily
wastewater. An RO membrane was characterized using FTIR, SEM, contact angle, mechanical analysis,
and TGA. The PA-TFC membrane showed a promising separation process for treatment of wastewater
effluent from edible oil. Significant removal of COD and turbidity can be accomplished using RO.
Higher flux and better membrane performance can be achieved using an RO membrane filtration
coupled with an activated carbon unit. A concentration of oil up to 6000 mg/L can be effectively
improved to 99.9%.
Author Contributions: Conceptualization, methodology S.E., R.A.M.; formal analysis, investigation M.H.E.,
S.A.-H. and Y.E.; data curation, M.B., Y.E.; writing—original draft preparation, S.E. and S.A.-H.; writing—review
15. Membranes 2020, 10, 84 15 of 17
and editing, M.S., M.B.; supervision, R.A.M, M.H.E. and M.Y.S. All authors have read and agreed to the published
version of the manuscript.
Funding: This research received no external funding.
Conflicts of Interest: The authors declare no conflict of interest.
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