This document discusses Sorona, a new polymer platform developed by DuPont based on 1,3-propanediol. 1,3-propanediol can be produced biologically from corn sugar through fermentation, offering economic and environmental advantages over conventional production methods. Sorona polymer has unique mechanical properties due to its molecular structure, including high elastic recovery. These properties provide benefits for textile applications. The document also describes the development and commercialization of the biological production process for 1,3-propanediol and the manufacturing of Sorona polymer.
In which process yarn is conditioned for better performance (such as strength, serviceability, luster, handle etc) is called yarn conditioning. Textile fibers are subjected to various physical operations to make in to a yarn. For example cotton fiber passes through opening, carding, drawing and spinning to become a yarn. During these phases the original moisture content on the fiber would have been lost and some static electricity would be carried by the fiber. The amount of static current carried by yarn changes from fiber to fiber. Similarly the strength of any fiber depends up on how close the present moisture content is to the original natural value.
Industrial Garments Washing is one of the major important parts for Textile sector. By industrial garments washing we can remove dust, dirt and infections material. For improving special look on garments as per fashion requirement. Garment washing is normally done after stitching. According to fashion trend and customer demand buyers ask for garment washing. For the washing apparel buyers mention exactly what types of washing they need for the order.
In which process yarn is conditioned for better performance (such as strength, serviceability, luster, handle etc) is called yarn conditioning. Textile fibers are subjected to various physical operations to make in to a yarn. For example cotton fiber passes through opening, carding, drawing and spinning to become a yarn. During these phases the original moisture content on the fiber would have been lost and some static electricity would be carried by the fiber. The amount of static current carried by yarn changes from fiber to fiber. Similarly the strength of any fiber depends up on how close the present moisture content is to the original natural value.
Industrial Garments Washing is one of the major important parts for Textile sector. By industrial garments washing we can remove dust, dirt and infections material. For improving special look on garments as per fashion requirement. Garment washing is normally done after stitching. According to fashion trend and customer demand buyers ask for garment washing. For the washing apparel buyers mention exactly what types of washing they need for the order.
Moisture management and wicking behaviour of textilesBadanayak
A seminar entitled 'Moisture management and wicking behaviour of textiles', presented in department of Textile and Apparel Designing, College of Community Science, UAS, Dharawad, by Pratikhya Badanayak and Dr. Jyoti Vastrad.
Wrinkle free resin finishing is a process to apply chemical resin onto fabrics functioning crosslinking between hydrogen bonds in order to enhance stability, on other words, fabrics are prevent to wrinkling. The ability of a fabric to recover to a definite degree is called crease recovery of the fabric.Tendency of fabrics made by cellulose, regenerated cellulose and blends with synthetic fibers to wrinkle after washing, tumble drying and wearing are higher. Today everybody wishes for that his/her dress retains just ironed shape. Wrinkle free finishes provide wrinkle free and soft look fabric. Wrinkle free finishes are broadly used in the textile industry to impart wrinkle-resistance to cellulosic materials such as cotton fabric.
Filament-core yarns are produced to take advantage of both filament and staple fibre properties. They offer good strength and uniformity without sacrificing the staple fibre yarn-like surface characteristics. Core-spun yarns containing spandex provide fabric designers with broad possibilities, because such stretchable yarns can be constructed with a wide range of properties using virtually any type of hard fibres as the cover yarn. However, a disadvantage of the core yarns is that the staple fibre sheath may slip along the filament when being pulled to pass over or when being rubbed by machine parts during further mechanical processes. But it is very easy to produce core-spun yarn containing spandex in a conventional ring frame after doing some modification of the machine.
This PPT are used for textile engineering students, textile technology who takes textile testing courses. the PPt prepared from different books and NPTEL textile engineering web site.
importance of fibre finess,influences of fibre finess ,effect on stiffness , effect on torsional rigidity, reflection of light , dye absoprtion, method of measurement ,gravimetric method, micronaire
Moisture management and wicking behaviour of textilesBadanayak
A seminar entitled 'Moisture management and wicking behaviour of textiles', presented in department of Textile and Apparel Designing, College of Community Science, UAS, Dharawad, by Pratikhya Badanayak and Dr. Jyoti Vastrad.
Wrinkle free resin finishing is a process to apply chemical resin onto fabrics functioning crosslinking between hydrogen bonds in order to enhance stability, on other words, fabrics are prevent to wrinkling. The ability of a fabric to recover to a definite degree is called crease recovery of the fabric.Tendency of fabrics made by cellulose, regenerated cellulose and blends with synthetic fibers to wrinkle after washing, tumble drying and wearing are higher. Today everybody wishes for that his/her dress retains just ironed shape. Wrinkle free finishes provide wrinkle free and soft look fabric. Wrinkle free finishes are broadly used in the textile industry to impart wrinkle-resistance to cellulosic materials such as cotton fabric.
Filament-core yarns are produced to take advantage of both filament and staple fibre properties. They offer good strength and uniformity without sacrificing the staple fibre yarn-like surface characteristics. Core-spun yarns containing spandex provide fabric designers with broad possibilities, because such stretchable yarns can be constructed with a wide range of properties using virtually any type of hard fibres as the cover yarn. However, a disadvantage of the core yarns is that the staple fibre sheath may slip along the filament when being pulled to pass over or when being rubbed by machine parts during further mechanical processes. But it is very easy to produce core-spun yarn containing spandex in a conventional ring frame after doing some modification of the machine.
This PPT are used for textile engineering students, textile technology who takes textile testing courses. the PPt prepared from different books and NPTEL textile engineering web site.
importance of fibre finess,influences of fibre finess ,effect on stiffness , effect on torsional rigidity, reflection of light , dye absoprtion, method of measurement ,gravimetric method, micronaire
She today gives all the scores of her hardcore creative potentiality to her God, Family, few old friends and three Gurus - Mr.Rakesh Shrestha, Mr.Sandeep Marwah (Managing Director, AAFT) & Mr.Arun Anand (Photography department, Head - AAFT).
Chandni has always been a photography globe trotter and carries different cultures in her vibrant personality.She speaks, "what i learned all the span of my work while capturing the most natural and whimsical images is that
i could feel the spiritual presence of the universal powers in everything i struggle to produce & the beautiful blessings being showered on my creativity."
With 35+ years of experience across the food science and packaging spectrum, Dr Claire Sand, owner and founder of Packaging Technology & Research, helps clients achieve
more sustainable packaging,
increase shelf life/prevent food waste,
leverage food packaging innovations,
address food package optimization
and serves the food and packaging industry as
a food packaging expert witness
adjunct professor
columnist for Food Technology and Packaging Digest
Want to know more about how this article affects your business? Reach out to Dr. Sand on LinkedIn - https://www.linkedin.com/in/clairekoelschsand
Want to keep learning from Dr. Sand? View more of her presentations and articles at https://www.packagingtechnologyandresearch.com/insights.html
Dr. Claire Sand | Owner, Packaging Technology & Research, LLC; Adjunct Professor, CalPoly and Michigan State University; Columnist for Food Technology Magazine and Packaging Digest http://www.packagingtechnologyandresearch.com/
Study of Bio-Nano Composite of Poly-Lactic Acid for Food Packaging- A Reviewpaperpublications3
Abstract: The impact of environment, economic and safety challenges have provoked the need to partially substitute petrochemical based polymer with bio degradable ones. [Poly lactic acid] PLA is the leading biodegradable polymer but its applications are limited by its relatively high cost, poor impact strength and barrier properties, which may be improved by adding reinforcing compounds (fillers), forming composites. Most reinforced materials present poor matrix–filler interactions, which tend to improve with decreasing filler dimensions. The use of fillers with at least one nanoscale dimension (nanoparticles) produces nanocomposites. Nanoparticles have proportionally larger surface area than their microscale counterparts, which favors the filler–matrix interactions and the performance of the resulting material.
Applications of nanomaterials in combination with PLA structures for creating new PLA nanocomposite with greater abilities are also covered. These approaches may modify PLA weakness for some food packaging applications. Nanotechnology approaches are being broadened in food science, especially in packaging material science with high performance and low concentrations and prices, so this category of nano-research is estimated to be revolutionary in food packaging science in the near future. The linkage of the 100% bio originated material and nanomaterial opens new windows for becoming independent, primarily, of petrochemical based polymers and, secondarily, for answering environmental and health concerns will undoubtedly be growing with time.
This study seeks to overcome PLA limitations by reinforcing PLA with nanoparticles and low-cost agricultural residues. The work presented in this thesis focuses on exploration of following relevant aspects:
• Preparation of PLA nanocomposite from LA [lactic acid].
• Reinforcement of various fillers during preparation.
• Testing of the formed nanomaterial to study the enhanced properties for sustainable green food packaging.
• Comparative study of the newly formed nanocomposites with respect to its properties
Nanotechnology has demonstrated a great potential to provide important changes in food packaging sector.
Nanocomposites are promising to expand the use of bio-degradable polymer, since the addition of nanoreinforcement has been related to improvement in overall performance of biopolymers, making them more competitive in a market dominated by non-biodegradable materials.
This research deals with study of Degradation
behavior of starch blended with different percentage of
polypropylene (PP) .Twin screw extruder at 160- 190 °C and 50
rpm is used for manufacture of blend sheet. Degradation test
achieved according to ASTM standard (D 638 IV and D570-98).
Studies on their degradation properties were carried out by Soil
burial test, Water absorption test and Hydrolysis test. The
morphology test of the polypropylene / starch blend samples
was obviously seen in the (Dino- Light- Digital Microscope),
Results of soil burial test show that tensile strength and
percentage of elongation of polypropylene / starch blend
decrease with increasing the starch content and burial time. The
hydrolysis test show the weight losses increasing with the
increasing amount of starch. High percent of polypropylene
found to decrease the amount of water absorption of the blend.
The physical appearance and morphology studies of
polypropylene / starch blend after burial test in soil and
hydrolysis in water environment showed that all blend samples
was obviously changed after 90-day study period, whereas the
pure polypropylene samples remained unchanged
Powerpoint presentation on bioplastics, history of bioplastics, Producing bioplastics, Biodegradable polymers, PHB: case study. producing PHB, History of PHB, Strains to produce PHB, applications of PHB, Companies using PHB, Companies using bioplastics, Current status of Bioplastic, Potential of Bioplastics, Conclusion
Biopolymers for Paperboard Extrusion Coating and Converting - SPE FlexPackCon...C. Carey Yang, Ph.D.
Biopolymers have shown promising options for sustainable packaging applications. This article presents an overview of challenges and opportunities in biopolymers for paperboard extrusion coating and converting processes. Material properties, extrusion coating process and equipment requirements, regulatory compliance, and downstream converting are reviewed. The latest developments and emerging trends in biopolymer technology and innovation are discussed.
The present invention relates to new thermoplastic polymeric compositions useful for the production, by hot extrusion, of biodegradable, compostable products and packaging, having at the same time performances and costs comparable to those of products obtained with traditional non-biodegradable thermoplastic polymeric materials, such as polyolefins.
Abrasive jet micro-machining (AJM), in which abrasive parti-cles are accelerated by air and directed toward a target, has beenused to make components for micro-electromechanical (MEMS) and micro-fluidic capillary electrophoresis devices . One ofthe disadvantages of AJM is that the compressed air jet used topropel the erodent particles diverges significantly after the noz-zle exit, increasing the size of the blast zone and the width of thesmallest channel or hole that can be machined without the use of a patterned erosion-resistant mask that defines the micro-featureedges . Abrasive slurry jet micro-machining (ASJM) is similar to AJM except that pressurized water, instead of air, is used to accel-erate the suspended abrasive particles such as garnet or alumina(Al2O3). In both AJM and ASJM, the material removal occurs by ero-sion. However, for the same jet dimension and flow speed, slurryjets have a much lower divergence angle than air jets , allow-ing for the micro-machining of small features without the use ofpatterned masks.
From biodegradable to long-term polyurethanes: In vitro fibroblasts adhesion ...IJERA Editor
Among the synthetic polymers, polyurethanes are one of the most important polymers applied in Tissue
Engineering (TE). Their segmented block structure enables the control of different properties, such as,
biocompatibility, blood compatibility, mechanical properties and also biodegradability. In this work,
polyurethane membranes were obtained using the electrospinning apparatus. Fibroblasts cells were seeded on the
membrane and the morphology, structure and cell adhesion and proliferation were studied using Scanning
Electron Microscopy (SEM). Finally, the degradation behavior of the membranes was investigated by in vitro
degradation studies. SEM results showed that the membrane presents high porosity, high surface area:volume
ratio, it was observed a random fiber network. In vitro evaluation of fibroblasts cells showed that fibroblasts
adhered and spread over the membrane surface and in vitro degradation study showed that the developed
membrane can be considered a non-degradable polyurethane. This study supports further investigations of
electrospun membranes as long-term devices for TE applications.
As we know polyester is a synthetic fiber and has
more crystalline structure than natural fibers. In continuous
dyeing of polyester by pad-Thermosol process, there are many
advantages such as bulk production, low-cost, good efficiency etc.
But during dyeing process there is a severe problem occurs that
is dye migration .in order to control the dye migration different
migration inhibitors are used in this project. Both natural and
synthetic migration inhibitors are applied on the 100% polyester
fabric in order to compare that which migration inhibitor hives
better results on the pad-Thermosol process.
After comparing the different properties of the both migration
inhibitors the synthetic inhibitors found more efficient then the
natural one. The following tests were conducted during project:
Migration test, tensile strength, color strength, bending length,
light fatness.
Synthetic migration inhibitors gives better results for the tests
which were conducted .but there is a problem that the synthetic
migration inhibitors are not environmental friendly and they are
costly then natural migration inhibitors.
BIO-BASED ADDITIVES TO IMPROVE THE PERFORMANCE & PROCESSING OF BIOPOLYMERS
New Polymer for Future - Sorona(R)
1. A New Polymer Platform for the Future — Sorona
from Corn Derived 1,3-Propanediol
Joseph V. Kurian1,2
Responding to environmental, sustainability, business, and market factors, DuPont has
commercialized a new polymer platform, SoronaÒ, based on 1,3-propanediol. The physical
and chemical property advantages over other polymers are described. The diol component of
this polymer, 1,3-propanediol, has been demonstrated to be manufacturable via biological
(fermentation) process from corn sugar. The economic, environmental, and process/product
quality advantages of bio-PDO over conventional diols are discussed.
KEY WORDS: SoronaÒ
polymer; 1,3-propanediol; bio-process; sustainability.
INTRODUCTION: DEVELOPMENT
OF SUSTAINABLE TECHNOLOGIES
Several factors arising over the last quarter of the
20th century have led to increased global interest in
bio-derived materials and biotechnology:
1. Instability of price and availability of crude oil as
a chemical process feedstock;
2. Increased attention to recyclability of manufac-
tured products;
3. An added economic stimulus for emission reduc-
tion, brought about by the Kyoto protocol.
These factors influence how global manufactur-
ing companies manage themselves for both present
and future. An example is E. I. du Pont de Nemours
and Company, just starting its third century.
In its latest move towards sustainability, DuPont
has set ambitious goals for increased use of renewable
resources for both feedstock and energy, reduction of
greenhouse gas emissions, and zero growth in energy
use.
The strategy to meet the first of these targets
includes the use of biological processes to make
products from renewable raw materials. In support
of that strategy, DuPont formed the Bio-Based
Materials business (BBM) unit in 2000. BBM’s first
commercial product is the SoronaÒ
family of
poly(trimethylene terephthalate) (PTT, or ‘‘3GT’’)
polymers.
Other companies share the DuPont view of sus-
tainable growth. Concurrently, Dow Chemical
Company in a joint venture with Cargill has recently
commercialized the NatureWorksä family of poly-
lactic acid (PLA) biodegradable polymers.
HISTORY AND DEVELOPMENT OF SORONAÒ
Polyester is the most widely used synthetic fiber
in the world today, in apparel, home furnishings and
industrial applications. Since its invention more than
50 years ago, the dominant polyester has been poly-
ethylene terephthalate, also called PET or 2GT.
Other varieties of the polymer have been known since
the beginning. For example, instead of reacting eth-
ylene glycol with the terephthalic acid ingredient to
make 2GT, one could use 1,4-butanediol to make
4GT or 1,3-propanediol for 3GT. The unique prop-
erties and attributes of 3GT polymer and fibers have
1
Sorona RD, Bio-Based Materials, E. I. du Pont de Nemours
and Company, Wilmington, DE, USA.
2
To whom all correspondence should be addressed.
E-mail: joseph.v.kurian@usa.dupont.com.
Journal of Polymers and the Environment, Vol. 13, No. 2, April 2005 (Ó 2005)
DOI: 10.1007/s10924-005-2947-7
159
1566-2543/05/0400-0159/0 Ó 2005 Springer Science+Business Media, Inc.
2. been known for many years. 3GT fibers were re-
ported to have better elastic recovery and lower
modulus versus PET and PBT [1]. Until recently,
three factors have effectively kept 3GT polymer
off the market: the relatively high cost of the
1,3-propanediol; inability to make high quality
polymer for downstream end-uses; and more difficult
polymer process requirements compared to 2GT.
Since the 1990s, however, significant develop-
ments have taken place to improve the business
prospects for 3GT. More economical methods have
been established for producing 1,3-propanediol
(‘‘PDO,’’ also called 3G) in commercial quantities
from petrochemical sources. Production of PDO has
been demonstrated to be feasible from renewable re-
sources as well, via biological processes [2–5]. Finally,
continuous polymerization processes have been re-
fined to enable commercial manufacture of 3GT
polymer to ‘‘fiber-grade’’ standards of quality and
uniformity. In the last decade, DuPont has generated
over 100 patents related to the cost-effective pro-
duction, processing, and applications of 3GT. A few
of those patents are listed at the end of this article.
UNIQUE PROPERTIES OF SORONAÒ
Molecular Structure and Effects on Mechanical
Properties [1,6,7]
SoronaÒ
3GT polymer is one member of a family
of polymers based on fiber-grade 1,3-propanediol. It
is a linear crystallizable polymer with a melting
temperature of about 228 °C and a glass transition
temperature of about 50 °C. The structure of 3GT
polymer is shown in Fig. 1.
The structure of PTT has been studied extensively
[3–5]. The beneficial properties of SoronaÒ
3GT
polymer are derived from a unique, semi-crystalline
molecular structure featuring a pronounced ‘‘kink,’’
as shown in Fig. 2.
The 3GT polymer shape is a consequence of the
convolutions of the bonds in the trimethylene con-
stituent. This zigzag shape means that tensile or
compressive forces translate at the molecular level to
bending and twisting of bonds, rather than simply
stretching. This is analogous to the tensile behavior of
a coil spring compared to a straight wire.
When the polymer is cooled from a liquid state,
it forms crystalline and amorphous regions. The
crystalline regions contribute most significantly to the
elastic properties of the solidified polymer. With
3GT, the modulus of the crystalline regions is sig-
nificantly lower than that of other commercial poly-
mers, e.g., PET (see Fig. 3). The fiber can take an
appreciable level of applied strain (up to 15–20%),
and recover completely, e.g., no permanent set, when
forces are removed (see Fig. 4).
Table I compares properties of SoronaÒ
3GT
with other synthetic and natural fibers (Handbook of
Fiber Chemistry, Lewin, M., and Pearce, E.M., Eds.,
2nd Edition, Marcel Dekker Inc., New York, 1998)
and with polylactic acid (PLA), another bio-derived
polymer.
In addition to its unique stretch-recovery char-
acteristics, SoronaÒ
3GT provides all the advantages
Fig. 1. Molecular structure of 3GT.
Fig. 2. Molecular shape and crystal structure of 3GT.
Fig. 3. Comparison of tensile characteristics.
160 Kurian
3. generally associated with polyesters, i.e., excellent
physical and chemical properties, dimensional sta-
bility, low moisture absorption, easy care, good
weather resistance, easy processability and recycla-
bility. SoronaÒ
polymer can be easily modified to
achieve desirable functional properties as well.
Other Properties
SoronaÒ
offers several advantages over both
conventional polyester (PET) and nylon. It can be
effectively disperse-dyed at 100 °C eliminating the
need for carriers or pressurization in the dyeing
process (see Fig. 5). Once dyed, the fabric exhibits
deeper shades and superior washfastness over other
products.
Other advantages of SoronaÒ
become more evi-
dent in actual use conditions. The fiber is highly
resistant to most stains without the need for surface
treatment with additives or coatings. It resists UV
degradation better than other fibers, and exhibits
both low water absorption and low electrostatic
charging.
Environmental Footprint
The world is increasingly looking at the envi-
ronmental consequences of a product throughout its
life, from raw material through ultimate disposal (see
Fig. 6). In this area, SoronaÒ has a number of
advantages over other polymers.
Greenhouse gas emission in the manufacture of
bio-PDO has been demonstrated to be about 40%
less than for petrochemical PDO.
The overall 3GT polymerization process is more
energy efficient than PET.
Polymerization and downstream processing of
SoronaÒ saves energy compared to PET due to
lower temperatures required, both for processes
involving remelt and for dyeing.
Recycling of SoronaÒ is made much easier by the
absence of heavy metals in the product, compared
to PET and Nylon.
Table I. Polymer and Fiber Properties
Synthetic fibers Melt spinnable natural based Natural fibers
Fiber Property Nylon 6,6 Nylon 6 PET Acrylics SoronaÒ
3GTa
PLAb
Rayon Cotton Silk Wool
Specific gravity 1.14 1.14 1.39 1.18 1.33 1.25 1.52 1.52 1.34 1.31
Tg (o
C) 40–55 40–60 70–80 45–55 55–60 – – – –
Tm (o
C) 265 220 260 320
(degrades)
228 130–175 None None None None
Tenacity (g/d) 6–10 5.5 6.0 4.0 4-5 6.0 2.5 4.0 4.0 1.6
Moisture regain (%) 4.0 4.1 0.2–0.4 1.0–2.0 0.2–0.3 0.4–0.6 11 7.5 10 14–18
Elastic recovery (5% strain) 89 89 65 50 100 93 32 52 52 69
Refractive index 1.54 1.52 1.54 1.50 1.57 1.35–1.45 1.52 1.53 1.54 1.54
a
SoronaÒ
3GT polymer is currently produced using a chemical process. Full scale commercialization of bio-derived polymer is expected by
end of 2004.
b
Data for PLA is taken from ‘‘Fibers and Fabrics Properties Comparison,’’ downloaded 8/15/2003 from Dow/Cargill website, http://
www.cargilldow.com/ingeo/applications_apparel.asp.
Fig. 5. Comparison of dyeing characteristics.
Fig. 4. Comparison of stretch recovery characteristics.
161A New Polymer Platform for the Future — SoronaÒ
from Corn Derived 1,3-Propanediol
4. PDO AND BIO-PDO
SoronaÒ
3GT is made from 1,3-propanediol
(PDO) and either dimethyl terephthalate (DMT) or
terephthalic acid (TPA). Other materials used in the
manufacture of 3GT include an organo titanium
catalyst [8–11], and a delustrant (TiO2).
PDO is a colorless, odorless liquid. The basic
properties of PDO are summarized in Table II, and a
typical product specification for polymer manufac-
ture is shown in Table III.
PDO from Traditional (Chemical) Sources [12, 13]
Development of SoronaÒ
took place within a
business model that requires the commercial success
of a product to be established independently of
environmental or sustainability considerations. Con-
sequently, early product development and commer-
cialization were undertaken with PDO made from
conventional chemical processes, two examples of
which are listed below.
A. The Degussa process consists of the following
three steps:
1. Oxidation of propylene to acrolein
CH2=CHCH3 + O2 ! CH2=CHCHO
2. Selective hydration to 3-hydroxypropionaldehyde
(3-HPA)
CH2=CHCHO + H2O ! OCHCH2CH2OH
3. Catalytic hydrogenation to 1,3-propanediol
(PDO)
OCHCH2CH2OH + H2 ! HO(CH2)3OH
B. Shell Chemical uses a two-step process:
1. Hydroformylation of ethylene oxide to 3-HPA.
=n
O
H2CÀCH2
þCO þ H2 ! OCHCH2CH2OH
2. Catalytic hydrogenation to 1,3-propanediol
(PDO)
OCHCH2CH2OH + H2 ! HO(CH2)3OH
Bio-PDO [2–5]
The need for development of a biological source/
process for PDO grew out of several factors:
Difficulty and cost of producing ‘‘polymer and
fiber-grade’’ PDO;
Raw Material
Acquisition
Raw Materials Energy
Waste
ManagementRecycle
Use/Reuse/
Maintenance
Transportation
Transportation
Manufacturing
Air
Emissions
Waterborne
Wastes
Solid
Wastes
Co-products
Fig. 6. Product life cycle: environmental effects.
Table II. Basic Properties of 1,3-Propanediol (PDO)
CAS number 504-63-2
Chemical structure, HOCH2CH2CH2OH
Chemical formula C3H8O2
Molecular weight 76.1
Viscosity at room temperature 52 cp
Specific gravity 1.05
Boiling point 214 °C
Freezing point )32 °C
Refractive index 1.4386
Table III. Specific Analytical Properties of 1,3-Propanediol (PDO)
Used for Polymer Manufacture
Purity (GC) 99.9%
Color (APHA, ASTM D1209) 5
Water content 0.05% max.
Ash content 0.001% by weight.
162 Kurian
5. The demonstrated efficiency of early trials of bio-
PDO processes, which showed the potential to be
economically competitive with established pro-
cesses;
Lower levels of greenhouse gases from bio-pro-
cesses;
The commitment of DuPont to integrated science,
which includes biological science and biotechnol-
ogy;
The company’s unique position to integrate bio-
technology with its longstanding competency in
polymer and fiber technology.
Initial development of biologically manufactured
PDO has been with corn sugar, well known as a
plentiful and inexpensive raw material. Conversion of
glucose to PDO has been known to occur in nature in
two stages: first by yeast to an intermediate product,
glycerol, then by bacteria to PDO or 3G (Fig. 7).
DuPont and Genencor International have jointly
developed a bacterium (‘‘biocatalyst’’) to do both
steps in a single fermentation stage. DuPont and Tate
Lyle, a major corn based products company with
expertise in fermentation processes, partnered to
develop the manufacturing process based on this
biocatalyst. The process is represented in Fig. 8, and
the facility in Fig. 9.
The trial product was confirmed to have attributes
and quality equivalent or superior to chemically pro-
duced PDO. For example, the results of purity tests of
bio-based PDO and conventional (Wesseling) PDO
are shown in Fig. 10. In summary, the percentage of
impurities in Bio-PDO is around one-tenth the amount
of impurities in chemical PDO (0.003% versus
0.032%).
POLYMER MANUFACTURE [8–10, 14, 15, 24]
The DuPont 3GT process technology was
developed for retrofitting to existing 2GT facilities.
One such converted facility is located at the DuPont
site at Kinston, NC, USA, which has been making
commercial quantities of 3GT polymer for several
years. A schematic diagram of a typical Continuous
Polymerization (CP) process is shown in Fig. 11.
Typical properties of CP polymer, as reflected
in the current DuPont specification, are shown in
Table IV.
Molecular weight analysis of a representative
sample from commercial production is given below.
Number average molecular weight
Mn ¼ 30,300
Weight average molecular weight
Mw ¼ 56,300
Z average molecular weight Mz ¼ 85,900
Mw/Mn ¼ 1.86
(The analysis is by SEC triple detection, using
HFIP solvent. The refractive-index detector chro-
matogram is shown in Fig. 12 below).
Melt Viscosity Characteristics
The behavior of SoronaÒ 3GT polymer in the
melt state is similar to other condensation polymers.
Fig. 7. Conversion of glucose to PDO occurs in two steps in nature.
Fig. 8. Pictorial representation of process: Corn to PDO.
163A New Polymer Platform for the Future — SoronaÒ
from Corn Derived 1,3-Propanediol
6. That is, at low shear rates the viscosity is nearly
constant (Newtonian) and at higher shear rates vis-
cosity decreases with increasing shear rate approach-
ing a power-law relationship. Viscous behavior
measurements for a melted production sample of
SoronaÒ polymer are shown for several melt temper-
atures in Fig. 13 below.
POLYMER PROCESSING, APPLICATION AND
END-USES
SoronaÒ
3GT polymer can be converted into a
variety of products by conventional methods on
existing equipment. The significant differences of
SoronaÒ 3GT in processing are lower melt temper-
ature (comparable to Nylon 6 or polypropylene),
lower modulus, higher stretch, and better stretch
recovery. In end-use performance, SoronaÒ
polymer
exhibits mechanical properties equal to or in some
cases better than nylons, (e.g., Nylon 6, Nylon 6,6) in
99.95
99.96
99.97
99.98
99.99
100
Bio Wesseling
Fig. 10. Purity comparison of bio and chemical (Wesseling) PDO.
Fig. 9. Pilot scale fermentation facility of Tate Lyle, Decatur IL, USA.
Excess PDO
MeOH Vacuum Jets
Flasher
Prepolymerizer
Additiv
Cataly
DMT
PDO
Finisher
Ester Exchanger Sorona®
Fig. 11. Continuous polymerization process.
164 Kurian
7. combination with chemical properties equal to or
better than PET.
Fibers for Apparels and Carpets
Lower melt temperature compared to 2GT and
Nylon 6,6 allows spun-dyed yarn with a greater
variety of pigments/colors. 3GT fiber can be spun on
‘‘short stack’’ spinning machines originally built for
Nylon 6 and polypropylene bulk continuous filament
(BCF) yarns. [16–18] Draw [19], windup, texturing
[20], weaving, knitting, and tufting performance are
comparable to PET once the equipment is properly
adjusted for the mechanical properties of 3GT.
The most significant advantages of SoronaÒ
3GT fiber for apparel are softness and natural
hand, printability and easy dyeability. Additionally,
resistance to chlorine and UV add value in
outdoor/sport markets. 3GT fibers can be blended
with other natural (e.g., cotton, wool, etc.) or
synthetic (e.g., PET, acrylics, etc.) fibers for
enhanced softness, stretch recovery and other
functional attributes.
For floor coverings, SoronaÒ
can be made in a
variety of colors and styles with good dye uniformity.
It offers superior bulk, resilience, texture retention,
stain resistance, easy dry, and a softer feel. They’re
resistant to fading in the presence of UV or chlorine,
and they have low electrostatic properties. 3GT is as
easy to recycle as PET polyester.
Films
3GT can be cast into films at settings comparable
to polypropylene or Nylon 6. Process optimization is
required to eliminate film brittleness of cast films.
Biaxially oriented films can also be prepared using
3GT. Modified 3GT polymers (e.g., copolymers with
isophthalic acid, etc.) or blends of 3GT with other
commercially available polymers (2GT, 4GT, etc.)
can be successfully used in films to obtain desirable
property advantages and increased value. For exam-
Table IV. Properties of Continuously Polymerized 3GTa
Limits
Property Aim Min Max Test method
Intrinsic viscosity 1.02 1.01 1.03 TM-0590-91
Color, Hunter b – 5 8 GEN-07
Color, Hunter L – 80 – GEN-07
COOH, leq/g – – 15 TM-1145-91
Melting Point, deg C 228 224 232 SP-509
TiO2, wt% 0.30 0.27 0.33 TM-1090-90
Moisture, ppm (as packaged) – – 500 SP 525
Pellet size, wt. of 50 pellets, g 1.6 1.4 1.8 GEN-08
Appearance No foreign substances,
dust, or gross particles
Visual
Package description Lined Gaylord boxes, 1475 lbs
(670 kg) nominal per box
a
Product: SoronaÒ
Polymer (a trademark of E. I. du Pont de Nemours and Company).
Type: Semi-dull Homopolymer.
Process: Continuous Polymerization (CP).
Specification date: March 30, 2001.
Fig. 12. Size exclusion chromatogram (SEC) of production sample
of SoronaÒ polymer (RI detector).
165A New Polymer Platform for the Future — SoronaÒ
from Corn Derived 1,3-Propanediol
8. ple, the combination of properties of 3GT (oxygen
and water vapor barrier, printability and heat seala-
bility) means that in many food packaging applica-
tions a single 3GT or modified 3GT layer may replace
several layers of presently manufactured laminated
films. [21]
Nonwovens
The suitability of SoronaÒ
polymer has been
demonstrated for various nonwoven processes
including flash spinning [22] Advantages in properties
over other polymers include softness, handfeel,
drapability, air permeability, stretch recovery, print-
ability, and heat fusability.
Engineering Components
All conventional thermoplastic formation
techniques can be used with 3GT: injection mold-
ing, pressure molding, blow molding, casting,
rotary molding, etc. with attention paid to mini-
mize melt time. Otherwise, molding processes are
comparable to Nylon 6, PBT, PET, or polypro-
pylene[23]. 3GT molding conditions are similar to
that of PBT.
As with many other plastics, the addition of glass
fiber reinforcement significantly increases tensile
strength, modulus of elasticity, bending strength and
modulus, impact strength, and heat deflection tem-
perature in molded parts of 3GT. In addition to glass
fibers, other natural fibers can be incorporated in
3GT to take advantage of lower process temperature
and to increase total bio-derived materials content in
the final product.
CREATING THE FUTURE
Direction and Vision
The development and commercialization of bio-
based SoronaÒ
3GT by DuPont is consistent with the
sustainable growth objectives of the company in its
third century and beyond, through
Knowledge intensity: increased knowledge
component of our products
Productivity improvement: reduced capital,
environmental footprint, energy/resource
usage, waste, emissions, and social cost
Integrated science: historically, chemistry and
physics; in the future, chemistry, biology,
physics, and information science
Realization
Carrying these principles forward, by DuPont
and others, will lead to
Greater use of renewable biological resources
such as crop vegetation
Further development of biological manufac-
turing processes, e.g., fermentation, (‘‘biore-
finery’’) for intermediates and end products
Products with integrated information tech-
nology, such as ‘‘smart’’ garments that auto-
matically sense need for insulation versus
cooling/ventilation and respond accordingly
400
500
600
700
1 10 100 1000
255˚C
260˚C
265˚C
255˚C Cross
260˚C Cross
265˚C Cross
Viscosity(Pa.s)
Shear Rate (s-1)
Fig. 13. Melt viscosity traces of production sample of SoronaÒ polymer.
166 Kurian
9. CONCLUSIONS
SoronaÒ
polymer provides functionality and
attributes different from that of other polymeric
materials in the market today. To be successful, in
addition to being a bio-derived material, products
also need to provide value and functionality. With
SoronaÒ
polymer, either alone or in conjunction with
other polymers, a variety of functionalities can be
developed. From the PDO based platform other
similar polymers can also be developed to satisfy
growing needs of society. Figure 14 represents the
combination of attributes central to the DuPont
product strategy for sustainable growth and envi-
ronmental responsibility.
REFERENCES
1. M. Ward and M. A. Wilding (1976) J. Poly. Sci., Pol. Phy. 14,
263–274.
2. EP 1204755 Process for the biological production of 1,3-
propanediol.
3. EP 1076708 Method of production of 1,3-propanediol by
recombinant organisms comprising genes for vitamin B-12
transport.
4. WO 0112833 Process for biological production of 1,3-pro-
panediol with high titer.
5. WO 0111070 1,3-propanediol and polymer derivatives from a
fermentable carbon source.
6. J. Desborough, I. H. Hall and J. Z. Neisser (1979) Polymer 20,
545–552.
7. R. Jakeways (1975) J. Polymer Sci. Pol. Phys. 13, 799–813.
8. US Patent 6,281,325 Preparation of Poly(trimethylene tere-
phthalate).
9. WO 0158980 Continuous process for producing Poly(trim-
ethylene terephthalate).
10. US Patent 6,353,062 also EP 1254188 Continuous process for
production of Poly(trimethylene terephthalate).
11. US 6,255,442 Esterification process.
12. US Patent 6,140,546 Process for the production of 1,3-
propanediol.
13. US Patent 6,284,930 Process for the production of
3-hydroxypropanol.
14. US 6,331,264 Low emission polymer compositions.
15. US 6,325,945 Process of making a polyester or polyol.
16. US Patent 6,458,455 Poly(trimethylene terephthalate) tetra-
channel cross-section staple fiber.
17. US Patent 6,383,632 Fine denier yarn from poly(trimethylene
terephthalate).
18. EP 1183409 Poly(trimethylene terephthalate) yarns.
19. US Patent 6,287,688 Partially oriented poly(trimethylene
terephthalate) yarns.
20. US Patent 6,333,106 Draw textured poly(trimethylene tere-
phthalate) yarn.
21. US Patent application 20020012807 A1 (1/31/2002) Low
temperature heat sealable polyester film and method for
producing same.
22. US Patent 6,458,304 Flash spinning process and solutions of
polyester.
23. US Patent 6,245,844 also EP 1114095 Nucleating agent for
polyesters.
24. US 6,277,289, also WO 0102305; EP 1200358 Treatment of
aqueous aldehyde waste streams.
Fig. 14. Strategy for sustainable development and environmental
responsibility.
167A New Polymer Platform for the Future — SoronaÒ
from Corn Derived 1,3-Propanediol