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GROUNDWATER PATHWAYS FOR CONTAMINANT
TRANSPORT FROM AGRICULTURAL AREAS TO THE GREAT
BARRIER REEF
M. PINTO I JUNE 2016
CURRENT ISSUE
IMPACTS OF EXCESS NUTRIENT INPUT TO THE GBR – ECOSYSTEM
LOSS
Reduction in coral growth
Shift in the relative
abundance and
composition of corals
Degradation of estuarine
waters
Shift in the relative
abundance and
composition of algae
Eutrophication
Increase in the global
nutrient cycling
Modifications in the
community structure
Promote the growth of
undesirable species of
macroalgae
Impairment of
photosynthetic activity
Growth of
Cyanobacterium: Lyngbya
majuscule
IMPACTS OF EXCESS NUTRIENT INPUT TO THE GBR
 Society
 Aesthetic conditions
 Economic value
 GBR’s inshore marine environment “poor”
• Cape York  poor
• Wet Tropics  poor
• Mackay Whitsundays  poor
• Fitzroy and Burnett Mary  poor
• Burdekin  moderate
BIOCHEMICAL PROCESSES OF GROUNDWATER TRANSPORTATION –
SOIL PROFILE
 Quantity + speed of groundwater
• permeability
• Porosity
 Soil profile
• zoot zone
• soil moisture zone
• intermediate zone
• capillary zone water table
• saturated zone/groundwater zone
It is important to understand the soil profile in which nitrate and prosperous
transported. The quantity and speed of groundwater flow is highly dependen
permeability and the porosity of the soil. Typically, the soil profile in which g
travels consists of zoot zone  soil moisture zone intermediate zone  c
water table  satu
zone
zone.
Soil Profile
Conceptualised illustration of all biochemical processes involved in Nitrogen
and Phosphorus flows from agricultural areas to the Reef
NUMERICAL MODELS FOR THE DETECTION OF CONTAMINATED
GROUNDWATER
Areas of
Numerical
Model
Development
Mulgrave
River Basin
Johnstone
River Basin
Tully-
Marray
River Basin
Lower
Burdekin
Lower
Herbert
River Basin
POLLUTANT MANAGEMENT METHODOLOGIES
 Reduce herbicide quantities
 Dilute N and P concentrations
 Implement of monitoring wells
 Execution of monitoring programs
 Identification of existing boundaries contaminated
plumes
 Cleaning of groundwater pollution
 Adhering groundwater development to the quality
protection
 Development numerical models to detect
groundwater contaminated sites
CURRENT AND FUTURE PROJECTS
 Reef Extension program
 Farm Management Systems
 Mackay Whitsundays Sustainable Landscapes program
 Rural Water Use Efficiency (RWUE) initiative
 Community-based water quality monitoring through
‘Waterwatch’
 ‘Fertcare’ program
 ‘Six Easy Steps’ for pesticide control in sugarcane
 AgForward program
GROUNDWATER INVESTIGATIONS NEAR BARRATTA CREEK
NORTHCOTE
 Aim: to determine the likelihood and quantity of contaminated
groundwater discharge in to the Great Barrier Reef
 Location: Barratta Creek at Northcote
 Data sampling no.1
• Four bores: RN 11910204, RN 11911173, RN 11911174 and RN 11911175
• Sampling period: May 2012-April 2013
 Data sampling no. 2
• Outputs generated by the gauging station no. 119101A
• Sampling period: February 1977 to December 2015
BORES AND ITS CORRESPONDING NUMBERS INSTALLED NEAR
BARRATTA CREEK AT NORTHCOTE
FINDINGS FROM GROUNDWATER
INVESTIGATIONS - RAINFALL
 High degree of hydraulic connectivity  RN 11911173
 water height in the bore mirrors the river height
 Intense rainfall events;
• March 2011
• July 2012-August 2012
• January-February 2013
FINDINGS FROM GROUNDWATER INVESTIGATIONS –
NITRATE+NITRITE AND PHOSPHATE CONCENTRATIONS
 Data sampling no.1
• Increase in N levels  RN11911173, RN11911174 and RN1191117
 intense rainfall events
• Low phosphate concentrations  RN11911173
• Precipitation of phosphate onto soil
• Fe (II) is oxidised to Fe (III), as iron (III)
CONCENTRATIONS OF NITRATE+NITRITE AS N SOLUBLE PRESENT IN ALL BORES
LOCATED NEAR BARRATTA CREEK AT NORTHCOTE
0.0000
0.1000
0.2000
0.3000
5/4/2012
6/4/2012
7/4/2012
8/4/2012
9/4/2012
10/4/2012
11/4/2012
12/4/2012
1/4/2013
2/4/2013
3/4/2013
4/4/2013
Milligrams/Litre
Date
Concentrations of nitrate+nitrite as N soluble
present in bore RN11911173
0.0000
0.0050
0.0100
5/4/2012
6/4/2012
7/4/2012
8/4/2012
9/4/2012
10/4/2012
11/4/2012
12/4/2012
1/4/2013
2/4/2013
3/4/2013
4/4/2013
Milligrams/Litre
Date
Concentrations of nitrate+nitrite as N soluble
present in bore RN11911174
0.0000
0.0500
0.1000
5/4/2012
6/4/2012
7/4/2012
8/4/2012
9/4/2012
10/4/2012
11/4/2012
12/4/2012
1/4/2013
2/4/2013
3/4/2013
4/4/2013
Milligrams/Litre
Date
Concentrations of nitrate+nitrite as N soluble
present in bore RN11911175
0.0000
0.5000
1.0000
1.5000
6/7/2012
7/7/2012
8/7/2012
9/7/2012
10/7/2012
11/7/2012
12/7/2012
1/7/2013
2/7/2013
3/7/2013
4/7/2013
Milligrams/Litre Date
Concentrations of nitrate+nitrite as N soluble
present in 11910204
CONCENTRATIONS OF TOTAL REACT P (ORTHO P) - SOLUBLE (FLDF) PRESENT IN ALL
BORES LOCATED NEAR BARRATTA CREEK AT NORTHCOTE
0.0000
0.1000
0.2000
0.3000
5/4/2012
6/4/2012
7/4/2012
8/4/2012
9/4/2012
10/4/2012
11/4/2012
12/4/2012
1/4/2013
2/4/2013
3/4/2013
4/4/2013
Milligrams/Litre
Date
Concentrations of Total React P (Ortho P) -
soluble (FldF) present in bore RN11911173
0.0000
0.0500
0.1000
0.1500
5/4/2012
6/4/2012
7/4/2012
8/4/2012
9/4/2012
10/4/2012
11/4/2012
12/4/2012
1/4/2013
2/4/2013
3/4/2013
4/4/2013
Milligrams/Litre
Date
Concentrations of Total React P (Ortho P) -
soluble (FldF) present in bore RN11911174
0.0000
0.0500
0.1000
0.1500
5/4/2012
6/4/2012
7/4/2012
8/4/2012
9/4/2012
10/4/2012
11/4/2012
12/4/2012
1/4/2013
2/4/2013
3/4/2013
4/4/2013
Milligrams/Litre
Date
Concentrations of Total React P (Ortho P) - soluble
(FldF) present in bore RN11911175
0.0000
0.0100
0.0200
0.0300
0.0400
6/7/2012
7/7/2012
8/7/2012
9/7/2012
10/7/2012
11/7/2012
12/7/2012
1/7/2013
2/7/2013
3/7/2013
4/7/2013
Milligrams/Litre Date
Concentrations of Total React P (Ortho P) -
soluble (FldF) present in bore RN11910204
FINDINGS FROM GROUNDWATER INVESTIGATIONS –
NITRATE+NITRITE AND PHOSPHATE CONCENTRATIONS
 Data sampling no.2
• Increase in N and P concentrations throughout the years
• Reason 1: Denitrification may be inexistent in groundwater near Barratta
Creek
• Reason 2: Quantity of nitrate used by farmers on crops have increased
throughout
the years
INCREASING TREND IN THE CONCENTRATIONS OF NITRATE, TOTAL NITROGEN, ORGANIC
NITROGEN AND NITRITE IN BARRATTA CREEK AT NORTHCOTE STATION 119101A
0
2
4
6
8
10
12
14
2/10/1977
2/10/1978
2/10/1979
2/10/1980
2/10/1981
2/10/1982
2/10/1983
2/10/1984
2/10/1985
2/10/1986
2/10/1987
2/10/1988
2/10/1989
2/10/1990
2/10/1991
2/10/1992
2/10/1993
2/10/1994
2/10/1995
2/10/1996
2/10/1997
2/10/1998
2/10/1999
2/10/2000
2/10/2001
2/10/2002
2/10/2003
2/10/2004
2/10/2005
2/10/2006
2/10/2007
2/10/2008
2/10/2009
2/10/2010
2/10/2011
2/10/2012
2/10/2013
2/10/2014
2/10/2015
Milligrams/Litre
Date
Nitrate as… Total Nitrogen… Organic… Nitrate+nitrite as…
INCREASING TREND IN THE CONCENTRATIONS OF TOTAL PHOSPHORUS AND TOTAL REACT P
(ORTHO P) - SOLUBLE (FLDF) BARRATTA CREEK AT NORTHCOTE STATION 119101A
0
0.05
0.1
0.15
0.2
Nilligrams/Litre
Date
Total Phosphorus
as P (mg/L)
Total React P (Ortho P)
- soluble (FldF)
COMPARISON OF N AND P CONCENTRATIONS AGAINST AUSTRALIAN AND NEW ZEALAND
TRIGGER VALUES FOR TOXICANTS AND THE QUEENSLAND WATER QUALITY GUIDELINES
(QWQGS)
 Nitrogen concentrations
• Median concentration  RN11919204 exceeds QWQGs
• 95th percentile  RN11919204 exceeds ANZECC
 Phosphorus concentrations
•Median concentrations  RN 11911173 and RN 11911174 exceeds
QWQGs
 Gauge station 119191A N and P concentrations
• Median concentrations exceeds QWQGs
• 95th percentile  nitrogen concentrations exceeds ANZECC
COMPARISON OF N AND P CONCENTRATIONS AGAINST AUSTRALIAN AND NEW ZEALAND
TRIGGER VALUES FOR TOXICANTS AND THE QUEENSLAND WATER QUALITY GUIDELINES
(QWQGS)
May 2012 - April 2013
Gauge Station 119101A
(1977-2015)
May 2012 - April 2013
Gauge Station 119101A
(1977-2015)
Range 0.0010-1.2700 0.0010-0.0330
Median 1.1050 0.0140
95th percentile 1.2570 0.0310
Range 0.0010-0.0830 0.0120-0.1270
Median 0.0030 0.0420
95th percentile 0.0445 0.1270
Range 0.0030-0.0090 0.0880-0.1360
Median 0.0030 0.1170
95th percentile 0.0063 0.1320
Range 0.0030-0.2000 0.0010-0.1920
Median 0.0030 0.0010
95th percentile 0.0895 0.0680
Phosphate phosphorus as P (mg/L)
0.02
Range = 0.033-0.1722
Median = 0.083
95th Percentile = 0.14
RN 11911175
RN 11911174
RN 11911173
ANZECC and ARMCANZ (2000) 0.2**
RN 11910204
Range = 0.003-2.7
Median= 0.1514
95th Perentile = 1.3
Nitrate+nitrite as N soluble (mg/L)
QWQG 0.06
FINDINGS FROM GROUNDWATER INVESTIGATIONS – AMMONIUM
CONCENTRATIONS
 Bores closest to the creek  reduction in N and P concentrations  increase in ammonium
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
11911173 11911174 11911175 11910204
Ammonia as N 0.811929 0.057909 0.082231 0.083571
Nitriate + Nitrite 0.0236 0.0038 0.0101 0.833
Phosphate as P 0.0146 0.1148 0.0513 0.0154
Meanconcentration(milligrams/litre)
Bore Number
Mean ammonium-N, nitrate+nitrite and phosphate-P concentrations in bore located near
Barratta Creek at Northcote
Ammonia as N
Nitriate + Nitrite
Phosphate as P
0
1
2
5/4/2012
6/4/2012
7/4/2012
8/4/2012
9/4/2012
10/4/20…
11/4/20…
12/4/20…
1/4/2013
2/4/2013
3/4/2013
4/4/2013
Milligrams/Litre
Date
Concentrations of
Ammonia present in the water analysis for bore
RN11911173
0
0.1
0.2
5/4/2012
6/4/2012
7/4/2012
8/4/2012
9/4/2012
10/4/20…
11/4/20…
12/4/20…
1/4/2013
2/4/2013
3/4/2013
4/4/2013
Milligrams/Litre
Date
Concentrations of
Ammonia present in the water analysis for bore
RN11911174
0
0.5
1
1.5
Milligrams/Litre
Date
Concentrations of
Ammonia present in the water analysis for bore
RN11910204
0
0.1
0.2
Milligrams/Litre
Date
Concentrations of
Ammonia present in the water analysis for bore
RN11911175
CONCENTRATIONS OF AMMONIA PRESENT IN ALL BORES LOCATED NEAR
BARRATTA CREEK AT NORTHCOTE
CONCENTRATIONS OF AMMONIA PRESENT IN BARRATTA CREEK AT
NORTHCOTE STATION 119101A
0
0.05
0.1
0.15
0.2
0.25
Milligrams/Litre
Date
FINDINGS FROM GROUNDWATER INVESTIGATIONS – AMMONIUM
CONCENTRATIONS
 Elevated ammonium concentrations, Justification 1
• Result of dissimilatory nitrate reduction to ammonium (DNRA)
• High carbon to nitrate+nitrite concentration 
• transformation of nitrate-N to ammonium-N
11911173 11911174 11911175 11910204
Nitriate + Nitrite 0.0236 0.0038 0.0101 0.833
DOC 2.1300 0.8778 1.6889 0.5000
0
0.5
1
1.5
2
2.5
Meanconcentration(Milligrams/litre)
Bore Number
Mean nitrate+nitrite and DOC concentrations in bore located
near Barratta Creek at Northcote
FINDINGS FROM GROUNDWATER INVESTIGATIONS – AMMONIUM
CONCENTRATIONS
 Elevated ammonium concentrations, Justification 2
• Decomposition of organic material by removing nitrate nitrogen gas  ammonium
FINDINGS FROM GROUNDWATER INVESTIGATIONS – DISSOLVED
OXYGEN CARBON (DOC)
 Riparian zone  dense stands of permanent + deep rooted vegetation 
higher concentrations of DOC
 Increase DOC  remove nitrate from groundwater
 DOC concentrations above 2 mg/L  electrons for denitrification
 Depletion of nitrate from groundwater  shallow aquifers that of 5 to 8 m of
groundwater flow
FINDINGS FROM GROUNDWATER INVESTIGATIONS – DISSOLVED
OXYGEN CARBON (DOC)
 Increase in DOC concentrations
• RN11911173
• RN11911174 Rainfall event January/February 2013
• RN11911175
 Low and steady concentrations
• RN11910204
• average DOC 0.5 mg/L
 DOC concentrations are lower that 2mg/L
• DOC increase due to rainfall
• Denitrification inexistent
CONCENTRATIONS OF DISSOLVED ORGANIC CARBON PRESENT IN ALL FOUR
BORES LOCATED NEAR BARRATTA CREEK AT NORTHCOTE
0.0000
2.0000
4.0000
6/7/2012
7/7/2012
8/7/2012
9/7/2012
10/7/2012
11/7/2012
12/7/2012
1/7/2013
2/7/2013
3/7/2013
4/7/2013
Milligrams/Litre
Date
Concentrations of Dissolved Organic Carbon
present in bore RN11911173
0.0000
5.0000
10.0000
6/7/2012
7/7/2012
8/7/2012
9/7/2012
10/7/2012
11/7/2012
12/7/2012
1/7/2013
2/7/2013
3/7/2013
4/7/2013
Milligrams/Litre
Date
Concentrations of Dissolved Organic Carbon
present bore RN11911175
0.0000
1.0000
2.0000
3.0000
6/7/2012
7/7/2012
8/7/2012
9/7/2012
10/7/2012
11/7/2012
12/7/2012
1/7/2013
2/7/2013
3/7/2013
4/7/2013
Milligrams/Litre
Date
Concentrations of Dissolved Organic Carbon
present in bore RN11911174
0.0000
0.2000
0.4000
0.6000
6/7/2012
7/7/2012
8/7/2012
9/7/2012
10/7/2012
11/7/2012
12/7/2012
1/7/2013
2/7/2013
3/7/2013
4/7/2013
Milligrams/Litre Date
Concentrations of Dissolved Organic Carbon
present in bore RN11910204
FINDINGS FROM GROUNDWATER INVESTIGATIONS – SPECIFIC CONDUCTIVITY
 Highly variable conductivity levels
 Assumption  each bore draws from
different aquifers
 RN 1191173  closest to the creek 
significant specific conductivity (SC) variations
 SC of samples had a reduction in variations
during rainfall events
Figure 39: Specific conductivity
measured in bores at Barratta Creek
(Vardy, et al., 2015)
FINDINGS FROM GROUNDWATER INVESTIGATIONS – SPECIFIC
CONDUCTIVITY
Increasing conductivity measurements in the Barratta Creek at Northcote gauging station
119191A
0
100
200
300
400
500
600
700
4/29/1983
4/29/1984
4/29/1985
4/29/1986
4/29/1987
4/29/1988
4/29/1989
4/29/1990
4/29/1991
4/29/1992
4/29/1993
4/29/1994
4/29/1995
4/29/1996
4/29/1997
4/29/1998
4/29/1999
4/29/2000
4/29/2001
4/29/2002
4/29/2003
4/29/2004
4/29/2005
4/29/2006
4/29/2007
4/29/2008
4/29/2009
4/29/2010
4/29/2011
4/29/2012
4/29/2013
4/29/2014
4/29/2015
μS/cm
Date
Conductivity (at 25C FLD) measurements in
Barratta Creek at Northcote Station 119101A
UNCERTAINTIES AND LIMITATIONS – KNOWLEDGE GAPS
UNCERTAINTIES AND LIMITATIONS – KNOWLEDGE GAPS
UNCERTAINTIES AND LIMITATIONS – KNOWLEDGE GAPS
UNCERTAINTIES AND LIMITATIONS – DATA GAPS
UNCERTAINTIES AND LIMITATIONS – DATA GAPS

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M. pinto n8848489 project 1_presentation

  • 1. GROUNDWATER PATHWAYS FOR CONTAMINANT TRANSPORT FROM AGRICULTURAL AREAS TO THE GREAT BARRIER REEF M. PINTO I JUNE 2016
  • 3. IMPACTS OF EXCESS NUTRIENT INPUT TO THE GBR – ECOSYSTEM LOSS Reduction in coral growth Shift in the relative abundance and composition of corals Degradation of estuarine waters Shift in the relative abundance and composition of algae Eutrophication Increase in the global nutrient cycling Modifications in the community structure Promote the growth of undesirable species of macroalgae Impairment of photosynthetic activity Growth of Cyanobacterium: Lyngbya majuscule
  • 4. IMPACTS OF EXCESS NUTRIENT INPUT TO THE GBR  Society  Aesthetic conditions  Economic value  GBR’s inshore marine environment “poor” • Cape York  poor • Wet Tropics  poor • Mackay Whitsundays  poor • Fitzroy and Burnett Mary  poor • Burdekin  moderate
  • 5. BIOCHEMICAL PROCESSES OF GROUNDWATER TRANSPORTATION – SOIL PROFILE  Quantity + speed of groundwater • permeability • Porosity  Soil profile • zoot zone • soil moisture zone • intermediate zone • capillary zone water table • saturated zone/groundwater zone It is important to understand the soil profile in which nitrate and prosperous transported. The quantity and speed of groundwater flow is highly dependen permeability and the porosity of the soil. Typically, the soil profile in which g travels consists of zoot zone  soil moisture zone intermediate zone  c water table  satu zone zone. Soil Profile
  • 6. Conceptualised illustration of all biochemical processes involved in Nitrogen and Phosphorus flows from agricultural areas to the Reef
  • 7. NUMERICAL MODELS FOR THE DETECTION OF CONTAMINATED GROUNDWATER Areas of Numerical Model Development Mulgrave River Basin Johnstone River Basin Tully- Marray River Basin Lower Burdekin Lower Herbert River Basin
  • 8. POLLUTANT MANAGEMENT METHODOLOGIES  Reduce herbicide quantities  Dilute N and P concentrations  Implement of monitoring wells  Execution of monitoring programs  Identification of existing boundaries contaminated plumes  Cleaning of groundwater pollution  Adhering groundwater development to the quality protection  Development numerical models to detect groundwater contaminated sites
  • 9. CURRENT AND FUTURE PROJECTS  Reef Extension program  Farm Management Systems  Mackay Whitsundays Sustainable Landscapes program  Rural Water Use Efficiency (RWUE) initiative  Community-based water quality monitoring through ‘Waterwatch’  ‘Fertcare’ program  ‘Six Easy Steps’ for pesticide control in sugarcane  AgForward program
  • 10. GROUNDWATER INVESTIGATIONS NEAR BARRATTA CREEK NORTHCOTE  Aim: to determine the likelihood and quantity of contaminated groundwater discharge in to the Great Barrier Reef  Location: Barratta Creek at Northcote  Data sampling no.1 • Four bores: RN 11910204, RN 11911173, RN 11911174 and RN 11911175 • Sampling period: May 2012-April 2013  Data sampling no. 2 • Outputs generated by the gauging station no. 119101A • Sampling period: February 1977 to December 2015
  • 11. BORES AND ITS CORRESPONDING NUMBERS INSTALLED NEAR BARRATTA CREEK AT NORTHCOTE
  • 12. FINDINGS FROM GROUNDWATER INVESTIGATIONS - RAINFALL  High degree of hydraulic connectivity  RN 11911173  water height in the bore mirrors the river height  Intense rainfall events; • March 2011 • July 2012-August 2012 • January-February 2013
  • 13. FINDINGS FROM GROUNDWATER INVESTIGATIONS – NITRATE+NITRITE AND PHOSPHATE CONCENTRATIONS  Data sampling no.1 • Increase in N levels  RN11911173, RN11911174 and RN1191117  intense rainfall events • Low phosphate concentrations  RN11911173 • Precipitation of phosphate onto soil • Fe (II) is oxidised to Fe (III), as iron (III)
  • 14. CONCENTRATIONS OF NITRATE+NITRITE AS N SOLUBLE PRESENT IN ALL BORES LOCATED NEAR BARRATTA CREEK AT NORTHCOTE 0.0000 0.1000 0.2000 0.3000 5/4/2012 6/4/2012 7/4/2012 8/4/2012 9/4/2012 10/4/2012 11/4/2012 12/4/2012 1/4/2013 2/4/2013 3/4/2013 4/4/2013 Milligrams/Litre Date Concentrations of nitrate+nitrite as N soluble present in bore RN11911173 0.0000 0.0050 0.0100 5/4/2012 6/4/2012 7/4/2012 8/4/2012 9/4/2012 10/4/2012 11/4/2012 12/4/2012 1/4/2013 2/4/2013 3/4/2013 4/4/2013 Milligrams/Litre Date Concentrations of nitrate+nitrite as N soluble present in bore RN11911174 0.0000 0.0500 0.1000 5/4/2012 6/4/2012 7/4/2012 8/4/2012 9/4/2012 10/4/2012 11/4/2012 12/4/2012 1/4/2013 2/4/2013 3/4/2013 4/4/2013 Milligrams/Litre Date Concentrations of nitrate+nitrite as N soluble present in bore RN11911175 0.0000 0.5000 1.0000 1.5000 6/7/2012 7/7/2012 8/7/2012 9/7/2012 10/7/2012 11/7/2012 12/7/2012 1/7/2013 2/7/2013 3/7/2013 4/7/2013 Milligrams/Litre Date Concentrations of nitrate+nitrite as N soluble present in 11910204
  • 15. CONCENTRATIONS OF TOTAL REACT P (ORTHO P) - SOLUBLE (FLDF) PRESENT IN ALL BORES LOCATED NEAR BARRATTA CREEK AT NORTHCOTE 0.0000 0.1000 0.2000 0.3000 5/4/2012 6/4/2012 7/4/2012 8/4/2012 9/4/2012 10/4/2012 11/4/2012 12/4/2012 1/4/2013 2/4/2013 3/4/2013 4/4/2013 Milligrams/Litre Date Concentrations of Total React P (Ortho P) - soluble (FldF) present in bore RN11911173 0.0000 0.0500 0.1000 0.1500 5/4/2012 6/4/2012 7/4/2012 8/4/2012 9/4/2012 10/4/2012 11/4/2012 12/4/2012 1/4/2013 2/4/2013 3/4/2013 4/4/2013 Milligrams/Litre Date Concentrations of Total React P (Ortho P) - soluble (FldF) present in bore RN11911174 0.0000 0.0500 0.1000 0.1500 5/4/2012 6/4/2012 7/4/2012 8/4/2012 9/4/2012 10/4/2012 11/4/2012 12/4/2012 1/4/2013 2/4/2013 3/4/2013 4/4/2013 Milligrams/Litre Date Concentrations of Total React P (Ortho P) - soluble (FldF) present in bore RN11911175 0.0000 0.0100 0.0200 0.0300 0.0400 6/7/2012 7/7/2012 8/7/2012 9/7/2012 10/7/2012 11/7/2012 12/7/2012 1/7/2013 2/7/2013 3/7/2013 4/7/2013 Milligrams/Litre Date Concentrations of Total React P (Ortho P) - soluble (FldF) present in bore RN11910204
  • 16. FINDINGS FROM GROUNDWATER INVESTIGATIONS – NITRATE+NITRITE AND PHOSPHATE CONCENTRATIONS  Data sampling no.2 • Increase in N and P concentrations throughout the years • Reason 1: Denitrification may be inexistent in groundwater near Barratta Creek • Reason 2: Quantity of nitrate used by farmers on crops have increased throughout the years
  • 17. INCREASING TREND IN THE CONCENTRATIONS OF NITRATE, TOTAL NITROGEN, ORGANIC NITROGEN AND NITRITE IN BARRATTA CREEK AT NORTHCOTE STATION 119101A 0 2 4 6 8 10 12 14 2/10/1977 2/10/1978 2/10/1979 2/10/1980 2/10/1981 2/10/1982 2/10/1983 2/10/1984 2/10/1985 2/10/1986 2/10/1987 2/10/1988 2/10/1989 2/10/1990 2/10/1991 2/10/1992 2/10/1993 2/10/1994 2/10/1995 2/10/1996 2/10/1997 2/10/1998 2/10/1999 2/10/2000 2/10/2001 2/10/2002 2/10/2003 2/10/2004 2/10/2005 2/10/2006 2/10/2007 2/10/2008 2/10/2009 2/10/2010 2/10/2011 2/10/2012 2/10/2013 2/10/2014 2/10/2015 Milligrams/Litre Date Nitrate as… Total Nitrogen… Organic… Nitrate+nitrite as…
  • 18. INCREASING TREND IN THE CONCENTRATIONS OF TOTAL PHOSPHORUS AND TOTAL REACT P (ORTHO P) - SOLUBLE (FLDF) BARRATTA CREEK AT NORTHCOTE STATION 119101A 0 0.05 0.1 0.15 0.2 Nilligrams/Litre Date Total Phosphorus as P (mg/L) Total React P (Ortho P) - soluble (FldF)
  • 19. COMPARISON OF N AND P CONCENTRATIONS AGAINST AUSTRALIAN AND NEW ZEALAND TRIGGER VALUES FOR TOXICANTS AND THE QUEENSLAND WATER QUALITY GUIDELINES (QWQGS)  Nitrogen concentrations • Median concentration  RN11919204 exceeds QWQGs • 95th percentile  RN11919204 exceeds ANZECC  Phosphorus concentrations •Median concentrations  RN 11911173 and RN 11911174 exceeds QWQGs  Gauge station 119191A N and P concentrations • Median concentrations exceeds QWQGs • 95th percentile  nitrogen concentrations exceeds ANZECC
  • 20. COMPARISON OF N AND P CONCENTRATIONS AGAINST AUSTRALIAN AND NEW ZEALAND TRIGGER VALUES FOR TOXICANTS AND THE QUEENSLAND WATER QUALITY GUIDELINES (QWQGS) May 2012 - April 2013 Gauge Station 119101A (1977-2015) May 2012 - April 2013 Gauge Station 119101A (1977-2015) Range 0.0010-1.2700 0.0010-0.0330 Median 1.1050 0.0140 95th percentile 1.2570 0.0310 Range 0.0010-0.0830 0.0120-0.1270 Median 0.0030 0.0420 95th percentile 0.0445 0.1270 Range 0.0030-0.0090 0.0880-0.1360 Median 0.0030 0.1170 95th percentile 0.0063 0.1320 Range 0.0030-0.2000 0.0010-0.1920 Median 0.0030 0.0010 95th percentile 0.0895 0.0680 Phosphate phosphorus as P (mg/L) 0.02 Range = 0.033-0.1722 Median = 0.083 95th Percentile = 0.14 RN 11911175 RN 11911174 RN 11911173 ANZECC and ARMCANZ (2000) 0.2** RN 11910204 Range = 0.003-2.7 Median= 0.1514 95th Perentile = 1.3 Nitrate+nitrite as N soluble (mg/L) QWQG 0.06
  • 21. FINDINGS FROM GROUNDWATER INVESTIGATIONS – AMMONIUM CONCENTRATIONS  Bores closest to the creek  reduction in N and P concentrations  increase in ammonium 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 11911173 11911174 11911175 11910204 Ammonia as N 0.811929 0.057909 0.082231 0.083571 Nitriate + Nitrite 0.0236 0.0038 0.0101 0.833 Phosphate as P 0.0146 0.1148 0.0513 0.0154 Meanconcentration(milligrams/litre) Bore Number Mean ammonium-N, nitrate+nitrite and phosphate-P concentrations in bore located near Barratta Creek at Northcote Ammonia as N Nitriate + Nitrite Phosphate as P
  • 22. 0 1 2 5/4/2012 6/4/2012 7/4/2012 8/4/2012 9/4/2012 10/4/20… 11/4/20… 12/4/20… 1/4/2013 2/4/2013 3/4/2013 4/4/2013 Milligrams/Litre Date Concentrations of Ammonia present in the water analysis for bore RN11911173 0 0.1 0.2 5/4/2012 6/4/2012 7/4/2012 8/4/2012 9/4/2012 10/4/20… 11/4/20… 12/4/20… 1/4/2013 2/4/2013 3/4/2013 4/4/2013 Milligrams/Litre Date Concentrations of Ammonia present in the water analysis for bore RN11911174 0 0.5 1 1.5 Milligrams/Litre Date Concentrations of Ammonia present in the water analysis for bore RN11910204 0 0.1 0.2 Milligrams/Litre Date Concentrations of Ammonia present in the water analysis for bore RN11911175 CONCENTRATIONS OF AMMONIA PRESENT IN ALL BORES LOCATED NEAR BARRATTA CREEK AT NORTHCOTE
  • 23. CONCENTRATIONS OF AMMONIA PRESENT IN BARRATTA CREEK AT NORTHCOTE STATION 119101A 0 0.05 0.1 0.15 0.2 0.25 Milligrams/Litre Date
  • 24. FINDINGS FROM GROUNDWATER INVESTIGATIONS – AMMONIUM CONCENTRATIONS  Elevated ammonium concentrations, Justification 1 • Result of dissimilatory nitrate reduction to ammonium (DNRA) • High carbon to nitrate+nitrite concentration  • transformation of nitrate-N to ammonium-N 11911173 11911174 11911175 11910204 Nitriate + Nitrite 0.0236 0.0038 0.0101 0.833 DOC 2.1300 0.8778 1.6889 0.5000 0 0.5 1 1.5 2 2.5 Meanconcentration(Milligrams/litre) Bore Number Mean nitrate+nitrite and DOC concentrations in bore located near Barratta Creek at Northcote
  • 25. FINDINGS FROM GROUNDWATER INVESTIGATIONS – AMMONIUM CONCENTRATIONS  Elevated ammonium concentrations, Justification 2 • Decomposition of organic material by removing nitrate nitrogen gas  ammonium
  • 26. FINDINGS FROM GROUNDWATER INVESTIGATIONS – DISSOLVED OXYGEN CARBON (DOC)  Riparian zone  dense stands of permanent + deep rooted vegetation  higher concentrations of DOC  Increase DOC  remove nitrate from groundwater  DOC concentrations above 2 mg/L  electrons for denitrification  Depletion of nitrate from groundwater  shallow aquifers that of 5 to 8 m of groundwater flow
  • 27. FINDINGS FROM GROUNDWATER INVESTIGATIONS – DISSOLVED OXYGEN CARBON (DOC)  Increase in DOC concentrations • RN11911173 • RN11911174 Rainfall event January/February 2013 • RN11911175  Low and steady concentrations • RN11910204 • average DOC 0.5 mg/L  DOC concentrations are lower that 2mg/L • DOC increase due to rainfall • Denitrification inexistent
  • 28. CONCENTRATIONS OF DISSOLVED ORGANIC CARBON PRESENT IN ALL FOUR BORES LOCATED NEAR BARRATTA CREEK AT NORTHCOTE 0.0000 2.0000 4.0000 6/7/2012 7/7/2012 8/7/2012 9/7/2012 10/7/2012 11/7/2012 12/7/2012 1/7/2013 2/7/2013 3/7/2013 4/7/2013 Milligrams/Litre Date Concentrations of Dissolved Organic Carbon present in bore RN11911173 0.0000 5.0000 10.0000 6/7/2012 7/7/2012 8/7/2012 9/7/2012 10/7/2012 11/7/2012 12/7/2012 1/7/2013 2/7/2013 3/7/2013 4/7/2013 Milligrams/Litre Date Concentrations of Dissolved Organic Carbon present bore RN11911175 0.0000 1.0000 2.0000 3.0000 6/7/2012 7/7/2012 8/7/2012 9/7/2012 10/7/2012 11/7/2012 12/7/2012 1/7/2013 2/7/2013 3/7/2013 4/7/2013 Milligrams/Litre Date Concentrations of Dissolved Organic Carbon present in bore RN11911174 0.0000 0.2000 0.4000 0.6000 6/7/2012 7/7/2012 8/7/2012 9/7/2012 10/7/2012 11/7/2012 12/7/2012 1/7/2013 2/7/2013 3/7/2013 4/7/2013 Milligrams/Litre Date Concentrations of Dissolved Organic Carbon present in bore RN11910204
  • 29. FINDINGS FROM GROUNDWATER INVESTIGATIONS – SPECIFIC CONDUCTIVITY  Highly variable conductivity levels  Assumption  each bore draws from different aquifers  RN 1191173  closest to the creek  significant specific conductivity (SC) variations  SC of samples had a reduction in variations during rainfall events Figure 39: Specific conductivity measured in bores at Barratta Creek (Vardy, et al., 2015)
  • 30. FINDINGS FROM GROUNDWATER INVESTIGATIONS – SPECIFIC CONDUCTIVITY Increasing conductivity measurements in the Barratta Creek at Northcote gauging station 119191A 0 100 200 300 400 500 600 700 4/29/1983 4/29/1984 4/29/1985 4/29/1986 4/29/1987 4/29/1988 4/29/1989 4/29/1990 4/29/1991 4/29/1992 4/29/1993 4/29/1994 4/29/1995 4/29/1996 4/29/1997 4/29/1998 4/29/1999 4/29/2000 4/29/2001 4/29/2002 4/29/2003 4/29/2004 4/29/2005 4/29/2006 4/29/2007 4/29/2008 4/29/2009 4/29/2010 4/29/2011 4/29/2012 4/29/2013 4/29/2014 4/29/2015 μS/cm Date Conductivity (at 25C FLD) measurements in Barratta Creek at Northcote Station 119101A
  • 31. UNCERTAINTIES AND LIMITATIONS – KNOWLEDGE GAPS
  • 32. UNCERTAINTIES AND LIMITATIONS – KNOWLEDGE GAPS
  • 33. UNCERTAINTIES AND LIMITATIONS – KNOWLEDGE GAPS

Editor's Notes

  1. Data sampling no.1 Increase in N levels  RN11911173, RN11911174 and RN1191117  intense rainfall events Low phosphate concentrations  RN11911173 Precipitation of phosphate onto soil Fe (II) is oxidised to Fe (III), as iron (III) Data sampling no.2 Increase in N and P concentrations throughout the years Denitrification may be inexistent in groundwater near Barratta Creek quantity of nitrate used by farmers on crops have increased throughout the years
  2. Rainfall