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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 04 | Apr 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4278
Comparative Evaluation of Fuller’s Earth & China Clay for the Control of
leachate Generated From Municipal Solid Waste
Akansha Dinkar1, Mr. Anupam Mehrotra2, Dr. Arif Siddiquie3
1M. Tech Student, Department of Civil Engineering, Babu Banarsi Das University, Lucknow
2,3Associate Professor, Department of Civil Engineering, Babu Banarsi Das University, Lucknow
------------------------------------------------------------------------***-------------------------------------------------------------------------
ABSTRACT:- Leachate generation is a major problem for
municipal solid waste (MSW) landfills and causes
significant threat to surface water and groundwater.
Leachate is defined as a liquid, which passes through a
landfill and has extracted dissolved and suspended
matter from it. Leachate is the outcome from
precipitation entering the landfill from moisture that
exists in the waste when it is composed. A comparative
evaluation between the china clay and fullers earth is
performed to control the leachate, generated from the
solid waste.
Permeability and type of bonding are the major factors,
which are affecting the water movement from surface to
below the clay liners. In this study the effect of china clay
and fuller’s earth clay are compared to control the
leachate from MSW.
Keywords: Leachate, Fuller’s Earth, China Clay, MSW,
permeability
1. INTRODUCTION
Waste management is one of the major challenges faced by
municipality officials, public health engineers and
environmentalists in their quest to protect and preserveour
environment. The wastesthatgenerateincitiesdisposetheir
wastes in different ways. Historically waste is disposed of
unscientifically leading to the development of many waste
dumps around. These general natural anomalies in the
ground where trash is disposed of with very little or no
environmental regulations. One of the major pollution
problems caused by the municipal solid waste landfill
leachate can be defined as a liquid that is generated when
water or another liquid comes in contact with solid waste. It
contains numberofdissolvedandsuspended materials.After
municipal solid waste landfill site is closed, landfill will
continue to produce contaminated leachate process could
last for 30-50 years. Due to increase growth of population
and development of the industry, the landfill leachate
problem becomes increasingly serious. Leachate has
potential to contaminate ground and surface water and
threaten human health which migratingfromthelandfill and
contaminates surrounding lands and water. Once the
leachate enters the water bodies, it is very difficult and
expensive to clean up the contaminated water.
In this, the performance of a landfill clay liner is generally
evaluated; the design and maintenance of landfills for waste
disposal are the concerns over the last few decades due to
increasing awareness towards environment protection
issues, such as ground and ground water protection. Forlast
few decades, the landfill liner construction has developed
and advanced technology has emerged such as the addition
of engineered clays, synthetic lining material and designing
of more sophisticated leachate collection systems etc. The
main aim of these technology and methods are to improve
the landfill liner performancesasa hydraulic resistantandto
minimize or prevent the migration of landfill leachate into
surrounding environment. Clay minerals are available in
bulk, these are inexpensive, and are safe materials for
environmental applications. Because of their high porosity,
surface charge, large specific surface area, and surface
functional groups, clay minerals function as adsorbents,
filters, flocculates, and carbon stabilizers.
Fullers earth (palygorskite) and china (kaolin) clay is taken
for the clay liner. Fuller's earth is any clay material that has
the capability to decolorize oil or other liquids without
chemical treatment. Fuller's earth typically consists of
palygorskite or bentonite. Palygorskite is hydrated Mg-Al
silicate material. This mineral actually resembles the
amphiboles more than it doesclayminerals,buthasa special
property that smectite lacks - as a drilling fluid, it is stable in
salt-water environments. When drilling for offshore oil,
conventional drilling mud falls apart in the presence of salt
water. Fuller's earth (palygorskite) consists primarily
of hydrous aluminum silicates (clay minerals) of varying
composition. Common components are
montmorillonite, kaolinite and attapulgite.Small amountsof
other minerals may be present in fuller's earth deposits,
including calcite, dolomite, and quartz. In some localities
fuller's earth refers to calcium bentonite, which is altered
volcanic ash composed mostly of montmorillonite. Kaolinite
is this clay mineral is the weathering product of feldspars. It
has a white, powdery appearance. Kaolinite is named after a
locality in China called Kaolin, which invented porcelain
(known as china) using the local clay mineral. The ceramics
industry uses it extensively. Because kaolinite is electrically
balanced, its ability of adsorb ions is less than that of other
clay minerals.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 04 | Apr 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4279
2. METHODOLOGY AND EXPERIMENTAL SETUP
The sources of wastage form householdisaround40-45% in
Lucknow, which is the maximum as compared to others as
shown in the Fig 1
Source of waste percentage
Households 40-45
Restaurants 28-30
Market 9-10
Shops & Workshops 7-8
Street Sweeping 7-8
Offices 5-6
Hospitals 3-2
Hotels 1-1.5
Fig 1. Percentage of sources of waste
The movement of leachate, generated from the landfilled
solid wastes depends upon site circumstances and landfill
design features. It is especially importanttoplanforleachate
control during the development of the landfill rather than
after the landfill is constructed, since the control techniques
are usually employed beneath the waste. Interrelations
between topographical, hydrological, and geological factors
must be considered to select the site for maximum natural
containment of leachate.
If a landfill site does not have suitable sub-surfacehydrology
for natural attenuation, the bottom of the landfill is lined
with clay or silt, bentonite, kaolinite membrane liners, or
other rather impermeable materials. It prevents the
movement of leachate into the soil below the landfill. A
prime consideration when installing a liner is its
effectiveness in preventing leachate movement.
The bonding between the clay layers and permeability is
paramount important and major factors affectingtheflow of
leachate.
The experimental setup is shown in fig. 2. The left side of the
container is filled with soil, Middle container is filled with
china clay and right container is filledwithfuller’searthclay.
Three trays are kept below the containers to collect the
passing leachate.
Fig 2. Clay containers
Equal amount of water is poured into the containers and
kept for two days, then add more water and kept for two
more days. The water is absorbed by the soil and clays
Fig 3. Clay containers after five days
500 ml of leachate is added in each container and keep the
containers for 2 days and Observations are recorded.
3. RESULTS
It is observed that the leachate is passedthroughthesoil and
collected in the tray below the soil container shown in the
Fig. 4.
Fig 4. Clay containers after five days
A small amount of leachate is collected in the tray below the
fuller’s earth container. No leachate is passing through the
container, filled with china clay.
There are two major reasons for best performance of china
clay. One of them is the unit that is formed by stacking a
gibbsite sheet on a silica sheet. These basic units are stacked
on top of other to form a lattice structure. The units are
bound together by hydrogen bonding. This bond is strong
enough to prevent water to pass from the lattice. Thus,
kaolinite minerals are stable. The fuller’s earth clayunitsare
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 04 | Apr 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4280
bond together with van der waals forces. These forces are
weak and water easily enters into the lattice.
The second reason is the permeability of the china clay,
which is lower than the fuller’s earth. The typical average
permeability of china clay is 4.439E-13 m/s and that of
fuller’s earth is 2.845E-12 m/s. Because of low permeability
it is not easy to pass the water from the china clay.
4. CONCLUSION
Leachate means any liquid percolatedthroughthedeposited
waste and emitted from or contained within a landfill. The
leachate consists of many different organic and inorganic
compounds that may be either dissolvedorsuspended.They
will bring potential pollution issues for groundwater and
surface waters in nature. The landfill leachate is a secondary
contamination related to landfills. Clay liners are useful to
prevent passing of water from ground surface to the inner
surface of the earth. depending upon the physical and
mechanical properties of the clay liners. China clay is better
than the fuller’s earth clay in terms of water contents.
Mixture of both clays can be used with soil modification to
reduce the permeability.
REFERENCES
[1]Bhalla B, Saini M. S. and Jha M. K., ‘Characterization of
Leachate from Municipal Solid Waste (MSW) Landfilling
Sites of Ludhiana, India: A Comparative Study’,International
Journal of Engineering Research and Applications (IJERA),
Vol. 2, Issue 6, November- December 2012, pp.732-74
[2]Ayub S. and Khan A. H., ‘Landfill practice in India: A
review’, Journal of Chemical and Pharmaceutical Research,
2011, 3(4):270-279
[3] Jayasekera S. and Mohajerani A. ‘A STUDY OF THE
EFFECTS OF MUNICIPAL LANDFILL LEACHATE ON A
BASALTIC CLAY SOIL’, Australian Geomechanics Journal,
36(9):63-73 · September 2001.
[4]Francis R. C., Singh L. P. and Prakash E. V., ‘Solid Waste
Management and Characteristics in Lucknow,UttarPradesh,
India’, International Journal of Scientific & Engineering
Research, Volume 4, Issue 11, November-2013.
[5] Lesteri D. I., Rustamji R. N., Priadi E., Aprianto and
Purwoko B., ‘SOIL MODIFICATION WITHMIXEDKAOLINITE
AND BENTONITE ON REDUCING COEFFICIENT OF
PERMEABILITY (k)’ , Tanjungpura University.
[6] Raghub, S. N., Meguid A. M. A. E. and Hegazi H. A.’
Treatment of leachate from municipal solid waste landfill’,
Housing and Building National Research Center, February-
2013.
BIOGRAPHIES
Ms. Akansha Dinkar is pursing M.Tech in
Enviromental Engineering from Babu
Banarsi Das University ,Lucknow. He
also holds a B.tech degree in Civil
Engineering.
Mr. Anupam Mehrotra is currently working as an Associate
Professor in Department of Civil Engineering at Babu
Banarasi Das University (BBDU), Lucknow.
Dr. Arif Siddiquie is currently workingasan
Associate Professor in Department of Civil
Engineering at BBDNITM, Lucknow. He has
been awarded PhD in Environmental
Impact Assessment (EIA) in the year 2009
from Baba Saheb Bhimrao Ambedkar (A
Central) University Lucknow and also holding a M.Tech.
degree in Environmental engineering from Department of
Civil Engineering Integral University, Lucknow. Besides
teaching and research assignments he has also worked as a
consultant to the Indian Minister of State Maneka Gandhi in
the Ministry of culture and Ministry of Statistics & Program
Implementation Govt. of India, Shastri Bhawan, New Delhi,
India where he developed a state-of-the art on foreign
funding sources for non-profit sectors in India. He has also
published various research papers in various reputed
national and International journals.

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  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 04 | Apr 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4278 Comparative Evaluation of Fuller’s Earth & China Clay for the Control of leachate Generated From Municipal Solid Waste Akansha Dinkar1, Mr. Anupam Mehrotra2, Dr. Arif Siddiquie3 1M. Tech Student, Department of Civil Engineering, Babu Banarsi Das University, Lucknow 2,3Associate Professor, Department of Civil Engineering, Babu Banarsi Das University, Lucknow ------------------------------------------------------------------------***------------------------------------------------------------------------- ABSTRACT:- Leachate generation is a major problem for municipal solid waste (MSW) landfills and causes significant threat to surface water and groundwater. Leachate is defined as a liquid, which passes through a landfill and has extracted dissolved and suspended matter from it. Leachate is the outcome from precipitation entering the landfill from moisture that exists in the waste when it is composed. A comparative evaluation between the china clay and fullers earth is performed to control the leachate, generated from the solid waste. Permeability and type of bonding are the major factors, which are affecting the water movement from surface to below the clay liners. In this study the effect of china clay and fuller’s earth clay are compared to control the leachate from MSW. Keywords: Leachate, Fuller’s Earth, China Clay, MSW, permeability 1. INTRODUCTION Waste management is one of the major challenges faced by municipality officials, public health engineers and environmentalists in their quest to protect and preserveour environment. The wastesthatgenerateincitiesdisposetheir wastes in different ways. Historically waste is disposed of unscientifically leading to the development of many waste dumps around. These general natural anomalies in the ground where trash is disposed of with very little or no environmental regulations. One of the major pollution problems caused by the municipal solid waste landfill leachate can be defined as a liquid that is generated when water or another liquid comes in contact with solid waste. It contains numberofdissolvedandsuspended materials.After municipal solid waste landfill site is closed, landfill will continue to produce contaminated leachate process could last for 30-50 years. Due to increase growth of population and development of the industry, the landfill leachate problem becomes increasingly serious. Leachate has potential to contaminate ground and surface water and threaten human health which migratingfromthelandfill and contaminates surrounding lands and water. Once the leachate enters the water bodies, it is very difficult and expensive to clean up the contaminated water. In this, the performance of a landfill clay liner is generally evaluated; the design and maintenance of landfills for waste disposal are the concerns over the last few decades due to increasing awareness towards environment protection issues, such as ground and ground water protection. Forlast few decades, the landfill liner construction has developed and advanced technology has emerged such as the addition of engineered clays, synthetic lining material and designing of more sophisticated leachate collection systems etc. The main aim of these technology and methods are to improve the landfill liner performancesasa hydraulic resistantandto minimize or prevent the migration of landfill leachate into surrounding environment. Clay minerals are available in bulk, these are inexpensive, and are safe materials for environmental applications. Because of their high porosity, surface charge, large specific surface area, and surface functional groups, clay minerals function as adsorbents, filters, flocculates, and carbon stabilizers. Fullers earth (palygorskite) and china (kaolin) clay is taken for the clay liner. Fuller's earth is any clay material that has the capability to decolorize oil or other liquids without chemical treatment. Fuller's earth typically consists of palygorskite or bentonite. Palygorskite is hydrated Mg-Al silicate material. This mineral actually resembles the amphiboles more than it doesclayminerals,buthasa special property that smectite lacks - as a drilling fluid, it is stable in salt-water environments. When drilling for offshore oil, conventional drilling mud falls apart in the presence of salt water. Fuller's earth (palygorskite) consists primarily of hydrous aluminum silicates (clay minerals) of varying composition. Common components are montmorillonite, kaolinite and attapulgite.Small amountsof other minerals may be present in fuller's earth deposits, including calcite, dolomite, and quartz. In some localities fuller's earth refers to calcium bentonite, which is altered volcanic ash composed mostly of montmorillonite. Kaolinite is this clay mineral is the weathering product of feldspars. It has a white, powdery appearance. Kaolinite is named after a locality in China called Kaolin, which invented porcelain (known as china) using the local clay mineral. The ceramics industry uses it extensively. Because kaolinite is electrically balanced, its ability of adsorb ions is less than that of other clay minerals.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 04 | Apr 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4279 2. METHODOLOGY AND EXPERIMENTAL SETUP The sources of wastage form householdisaround40-45% in Lucknow, which is the maximum as compared to others as shown in the Fig 1 Source of waste percentage Households 40-45 Restaurants 28-30 Market 9-10 Shops & Workshops 7-8 Street Sweeping 7-8 Offices 5-6 Hospitals 3-2 Hotels 1-1.5 Fig 1. Percentage of sources of waste The movement of leachate, generated from the landfilled solid wastes depends upon site circumstances and landfill design features. It is especially importanttoplanforleachate control during the development of the landfill rather than after the landfill is constructed, since the control techniques are usually employed beneath the waste. Interrelations between topographical, hydrological, and geological factors must be considered to select the site for maximum natural containment of leachate. If a landfill site does not have suitable sub-surfacehydrology for natural attenuation, the bottom of the landfill is lined with clay or silt, bentonite, kaolinite membrane liners, or other rather impermeable materials. It prevents the movement of leachate into the soil below the landfill. A prime consideration when installing a liner is its effectiveness in preventing leachate movement. The bonding between the clay layers and permeability is paramount important and major factors affectingtheflow of leachate. The experimental setup is shown in fig. 2. The left side of the container is filled with soil, Middle container is filled with china clay and right container is filledwithfuller’searthclay. Three trays are kept below the containers to collect the passing leachate. Fig 2. Clay containers Equal amount of water is poured into the containers and kept for two days, then add more water and kept for two more days. The water is absorbed by the soil and clays Fig 3. Clay containers after five days 500 ml of leachate is added in each container and keep the containers for 2 days and Observations are recorded. 3. RESULTS It is observed that the leachate is passedthroughthesoil and collected in the tray below the soil container shown in the Fig. 4. Fig 4. Clay containers after five days A small amount of leachate is collected in the tray below the fuller’s earth container. No leachate is passing through the container, filled with china clay. There are two major reasons for best performance of china clay. One of them is the unit that is formed by stacking a gibbsite sheet on a silica sheet. These basic units are stacked on top of other to form a lattice structure. The units are bound together by hydrogen bonding. This bond is strong enough to prevent water to pass from the lattice. Thus, kaolinite minerals are stable. The fuller’s earth clayunitsare
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 04 | Apr 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 4280 bond together with van der waals forces. These forces are weak and water easily enters into the lattice. The second reason is the permeability of the china clay, which is lower than the fuller’s earth. The typical average permeability of china clay is 4.439E-13 m/s and that of fuller’s earth is 2.845E-12 m/s. Because of low permeability it is not easy to pass the water from the china clay. 4. CONCLUSION Leachate means any liquid percolatedthroughthedeposited waste and emitted from or contained within a landfill. The leachate consists of many different organic and inorganic compounds that may be either dissolvedorsuspended.They will bring potential pollution issues for groundwater and surface waters in nature. The landfill leachate is a secondary contamination related to landfills. Clay liners are useful to prevent passing of water from ground surface to the inner surface of the earth. depending upon the physical and mechanical properties of the clay liners. China clay is better than the fuller’s earth clay in terms of water contents. Mixture of both clays can be used with soil modification to reduce the permeability. REFERENCES [1]Bhalla B, Saini M. S. and Jha M. K., ‘Characterization of Leachate from Municipal Solid Waste (MSW) Landfilling Sites of Ludhiana, India: A Comparative Study’,International Journal of Engineering Research and Applications (IJERA), Vol. 2, Issue 6, November- December 2012, pp.732-74 [2]Ayub S. and Khan A. H., ‘Landfill practice in India: A review’, Journal of Chemical and Pharmaceutical Research, 2011, 3(4):270-279 [3] Jayasekera S. and Mohajerani A. ‘A STUDY OF THE EFFECTS OF MUNICIPAL LANDFILL LEACHATE ON A BASALTIC CLAY SOIL’, Australian Geomechanics Journal, 36(9):63-73 · September 2001. [4]Francis R. C., Singh L. P. and Prakash E. V., ‘Solid Waste Management and Characteristics in Lucknow,UttarPradesh, India’, International Journal of Scientific & Engineering Research, Volume 4, Issue 11, November-2013. [5] Lesteri D. I., Rustamji R. N., Priadi E., Aprianto and Purwoko B., ‘SOIL MODIFICATION WITHMIXEDKAOLINITE AND BENTONITE ON REDUCING COEFFICIENT OF PERMEABILITY (k)’ , Tanjungpura University. [6] Raghub, S. N., Meguid A. M. A. E. and Hegazi H. A.’ Treatment of leachate from municipal solid waste landfill’, Housing and Building National Research Center, February- 2013. BIOGRAPHIES Ms. Akansha Dinkar is pursing M.Tech in Enviromental Engineering from Babu Banarsi Das University ,Lucknow. He also holds a B.tech degree in Civil Engineering. Mr. Anupam Mehrotra is currently working as an Associate Professor in Department of Civil Engineering at Babu Banarasi Das University (BBDU), Lucknow. Dr. Arif Siddiquie is currently workingasan Associate Professor in Department of Civil Engineering at BBDNITM, Lucknow. He has been awarded PhD in Environmental Impact Assessment (EIA) in the year 2009 from Baba Saheb Bhimrao Ambedkar (A Central) University Lucknow and also holding a M.Tech. degree in Environmental engineering from Department of Civil Engineering Integral University, Lucknow. Besides teaching and research assignments he has also worked as a consultant to the Indian Minister of State Maneka Gandhi in the Ministry of culture and Ministry of Statistics & Program Implementation Govt. of India, Shastri Bhawan, New Delhi, India where he developed a state-of-the art on foreign funding sources for non-profit sectors in India. He has also published various research papers in various reputed national and International journals.