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[object Object],[object Object],[object Object],[object Object],Suez Canal University Faculty of Petroleum & Mining Engineering  Metallurgy & Materials Engineering Dept. Supervised by  Prof . Dr.  Mohamed abd El Fattah El Zeky See the details @   www.metallurgy.eg.vg
Cathodic Protection of Pipeline See the details @   www.metallurgy.eg.vg
Contents   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],See the details @   www.metallurgy.eg.vg
Ch.1 principles of corrosion ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],See the details @   www.metallurgy.eg.vg
[object Object],[object Object],[object Object],[object Object],[object Object],Figure (1-1), dry cell 1.2  corrosion principles See the details @   www.metallurgy.eg.vg
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],See the details @   www.metallurgy.eg.vg
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],See the details @   www.metallurgy.eg.vg
Ch:2  Forms of corrosion   ,[object Object],[object Object],Fig (2-1) , uniform corrosion  2.1.1 Mechanisms The anodic reaction in the corrosion process is always the oxidation reaction: M = M+ + e-   eq (2-1) In acidic environments, i.e., pH < 7,  the cathodic process is mainly the reduction of hydrogen ions: 2H+ + 2e = H2        eq (2-2) See the details @   www.metallurgy.eg.vg
[object Object],Fig (2-2) Real uniform corrosion   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],See the details @   www.metallurgy.eg.vg
[object Object],[object Object],[object Object],Fig (2-3)  Galvanic corrosion   2.2.1 Mechanism Different metals and alloys have different electrochemical potentials (or corrosion potentials) in the  same electrolyte . (i.e., the voltage) between two dissimilar metals is the driving force for the destructive attack on the active  metal (anode). Current flows through the electrolyte to the more noble metal (cathode) and the less noble (anode) metal will corrode.   Fig (2-4) Real example of Galvanic corrosion   See the details @   www.metallurgy.eg.vg
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],See the details @   www.metallurgy.eg.vg
Fig (2-5) Crevice corrosion   2.3.1 MECHANISM .  Autocatalytic process are three stage : 2.3.1.1   Stage one of a crevice formation  (  Induction   )   Fig (2-6) Stage one of a crevice formation   See the details @   www.metallurgy.eg.vg
[object Object],Fig (2-7) Stage two of a crevice formation (Restricted Convection)   2.3.1.3Stage three of a crevice formation(Obstruction  and  Electromigration)   Fig (2-8)   Stage three of a crevice formation(Obstruction and Electromigration)   See the details @   www.metallurgy.eg.vg
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],2.4 Pitting Pitting:  Pitting Corrosion is the localized corrosion of a metal surface confined to a point or small area, that takes the form of cavities. Pitting is one of the most damaging forms of corrosion   Fig(2-9) Morphology of pitting   See the details @   www.metallurgy.eg.vg
[object Object],[object Object],Fig (2-10) Real pitting corrosion   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],See the details @   www.metallurgy.eg.vg
[object Object],[object Object],[object Object],Fig(2-11) stress corrosion cracking   2.5.1 Mechanisms Stress corrosion cracking results from the conjoint action of three components:   (1) a susceptible material;  (2) a specific chemical species (environment) and (3) tensile stress. See the details @   www.metallurgy.eg.vg
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Fig (2-12)  intergranular corrosion   See the details @   www.metallurgy.eg.vg
[object Object],[object Object],Fig (2-13)  intergranular corrosion   ,[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],Fig (2-14) forms of  dezincification
[object Object],[object Object],Fig (2-15)  dezincification   ,[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],Fig(2-16) Erosion corrosion   2.8.1 Mechanism There are several mechanisms described by the conjoint action of flow and corrosion that result in flow-influenced corrosion:   * Mass transport-control:  Mass transport-controlled corrosion implies that the rate of corrosion is dependent on the convective mass transfer processes at the metal/fluid interface. Fig (2-17) Real of erosion corrosion
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Ch:3  Environment  Effects ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],Fig (3-4) corrosion by soil   ,[object Object],[object Object]
[object Object],3.  Capillary water . Most soils contain considerable amounts of water held in the  capillary spaces of the silt and clay particles. The actual amount present depends upon the soil type and weather conditions. Capillary moisture represents the important reservoir of water in soil which supplies the needs of plants and animals living in or on the soil. Only a portion of capillary water is available to plants. ‘Moisture-holding capacity’ of a soil is a term applied to the ability of a soil to hold water present in the form of capillary water. It is obvious that the moisture-holding capacity of a clay is much greater than that of a sandy type soil. Likewise, the degree of corrosion occurring in soil will be related to its moisture-holding capacity, although the complexities of the relationships do not allow any quantitative or predictive applications of the present state of knowledge
Ch 4 : corrosion protection ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Table (4-1)  Corrosion protection techniques
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],Fig (4-1) internal coat
[object Object],Fig (4-2) Fusion Bonded Epoxy (FBE) Powder Coating   ,[object Object],[object Object]
[object Object],Fig (4-3) Dual Fusion Bonded Epoxy (D-FBE ) coating   ,[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
•  risky if potential “slips” into the active/pitting region •  used often for very aggressive solutions when other methods fail, e.g. for  protection of tanks storing of strong acids (e.g. sulphuric, phosphoric, nitric)  Fig(4-11) Anodic protection
Ch :5  preparation of pipeline   ,[object Object],[object Object],[object Object],Fig(5-1) Stringing Process
[object Object],[object Object],Fig (5-2) Trenching Process
[object Object],[object Object],[object Object],Fig (5-3) pipe bending Process
[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],Fig (5-4) Coating Process   19682585
[object Object],[object Object],Fig (5-5) Lowering In Process
[object Object],[object Object],Fig (5-6) Backfilling Process
[object Object],[object Object],[object Object],[object Object],Fig (5-7) restoration Process
Ch :6  Corrosion of pipeline   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Fig (6-1). Concentration Cell Caused by Different Environments   6.1.2.1  Dissimilar Environment. Pipelines tend to pass through many different types of soils. The metal exhibits different electrical potentials in different soils  The electrical potential in those soils determines which areas become anodic and which areas become cathodic.
[object Object],[object Object],Fig (6-2) Concentration Cell Caused by Different Concentrations of Oxygen
[object Object],[object Object],Fig(6-3) Concentration Cell Caused by Different Concentrations of Water
[object Object],[object Object],Fig(6-4) Concentration Cell Caused by Non-Homogeneous Soil
[object Object],[object Object],Fig(6-5) Concentration Cell Caused by Concrete and Soil Electrolytes
[object Object],[object Object],[object Object]
[object Object],[object Object],Fig(6-6) Galvanic Corrosion Cell Caused by Different Metals
[object Object],[object Object],Fig(6-7) Galvanic Corrosion Cell Caused by Old and New Steel
[object Object],[object Object],Fig(6-8) Galvanic Corrosion Cell Caused by Marred and Scratched Surfaces
[object Object],[object Object],Fig(6-9) Combination of Many Different Corrosion Cells at Work
[object Object],[object Object],Fig (6-10) Stray Current Corrosion Cell Caused by External Anode and Cathode
[object Object],[object Object],Figure 2-13. Stray Current Corrosion Cell Caused by a DC Transit System
[object Object],[object Object],Fig(6-11) Stray Current Corrosion Cell Caused by an HVDC Transmission   System
Ch7  Cathodic protection of pipeline ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],Fig(7-1) Sacrificial Anode CP System in Seawater
[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],Fig(7-2) Impressed Current Cathodic Protection System   ,[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Table (7-1) Comparison of CP System Characteristic
7.4 CATHODIC PROTECTION - THEORY   ,[object Object],[object Object],[object Object],[object Object],These reactions can be shown schematically in a over voltage diagram (E - logi) according to Figure Fig(8-3) Over voltage diagram (E-log I) for steel in seawater
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],Fig(7-6) Anode Shape   a) Stand off, b) Flush mounted, c) Bracelet (Jotun Cathodic Protection – today Skarpenord Corrosion)
Ch.8  Case Study   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],Suez Canal University Faculty of Petroleum & Mining Engineering  Metallurgy & Materials Engineering Dept. Supervised by  Prof . Dr.  Mohamed abd El Fattah El Zeky

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Hitesh cathodic protection

  • 1.
  • 2. Cathodic Protection of Pipeline See the details @ www.metallurgy.eg.vg
  • 3.
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  • 7.
  • 8.
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  • 10.
  • 11.
  • 12. Fig (2-5) Crevice corrosion 2.3.1 MECHANISM . Autocatalytic process are three stage : 2.3.1.1 Stage one of a crevice formation ( Induction ) Fig (2-6) Stage one of a crevice formation See the details @ www.metallurgy.eg.vg
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  • 28. Table (4-1) Corrosion protection techniques
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  • 35.
  • 36. • risky if potential “slips” into the active/pitting region • used often for very aggressive solutions when other methods fail, e.g. for protection of tanks storing of strong acids (e.g. sulphuric, phosphoric, nitric) Fig(4-11) Anodic protection
  • 37.
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  • 44.
  • 45.
  • 46. Fig (6-1). Concentration Cell Caused by Different Environments 6.1.2.1 Dissimilar Environment. Pipelines tend to pass through many different types of soils. The metal exhibits different electrical potentials in different soils The electrical potential in those soils determines which areas become anodic and which areas become cathodic.
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  • 66. Table (7-1) Comparison of CP System Characteristic
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