This document provides an introduction to the concepts of exergy and energy quality. It begins by defining exergy as the maximum useful work possible during the conversion of a given form of energy to a reference state of equilibrium with the environment. Exergy is related to the quality or usefulness of different energy forms, with higher-quality forms capable of generating more work. The document uses a simple example of converting heat to work between reservoirs at different temperatures to illustrate how the second law of thermodynamics limits the amount of work possible. It establishes that heat has lower exergy (quality) than work, with the maximum conversion efficiency given by the Carnot cycle.
This document provides an introduction and overview of energy and exergy analyses of power cycles presented by Dr. Luis R. Rojas-Solórzano. It begins with definitions of key concepts in thermodynamics such as the zeroth, first, and second laws of thermodynamics. It then discusses properties of pure substances and ideal gases, including state equations and thermodynamic tables. The document concludes by defining work, heat, and the first law of thermodynamics.
The document discusses exergy analysis of thermal systems. Exergy analysis is based on the conservation of mass, conservation of energy, and the second law of thermodynamics. Exergy analysis can be used to design thermal systems, reduce inefficiencies in existing systems, and evaluate system economics. Exergy, unlike energy, is not conserved and can be destroyed by irreversibilities as a system approaches equilibrium with its environment. The document provides examples of calculating the specific exergy of systems.
Energy and exergy analysis of a 250 mw coal fired thermal power plant at diff...eSAT Journals
Abstract In this present investigation exergy and energy efficiencies of a coal fired 250 MW thermal power plant operating in eastern part of India are determined both for 100% and 90% load based on actual operating data. The efficiencies are evaluated for the overall plant as well as for different equipments like boiler, turbine, all feed water heaters and condenser. Similarly effectiveness of the feed water heaters is evaluated for both the loads. Exergy destruction % for each of the equipment are also given for clear understandingof the loss of available energy due to irreversibilities involved in the processes for each equipment and the whole plant. It is observed that a major irreversibility or, exergy destruction takes place at boiler though 1st law energy efficiency is quite high. This signifies that there might have further scope of improvement in this equipment. Similar analyses are carried out for other equipments. The results obtained in present analysis are compared with those of other investigators. Keywords: Energy, Exergy, Efficiency, Effectiveness, Exergy destruction, Power plant
The document discusses the concept of exergy, which is a measure of the available useful work in a system or flow of matter and energy. Exergy is defined as the maximum theoretical useful work obtained as the system is brought into equilibrium with its surroundings. The document covers definitions of heat, work and exergy, as well as exergy of closed and open systems. It also discusses exergy change, effectiveness and loss of exergy due to irreversibilities. Several example problems are provided to calculate exergy values and changes for various thermodynamic processes.
Energy and exergy analysis of reverse brayton refrigerator for gas turbine po...fsnexuss
This document discusses energy and exergy analysis of a proposed system to boost gas turbine power output using a reverse Brayton refrigerator. The system involves extracting a portion of compressed air from the gas turbine compressor and running it through a reverse Brayton refrigeration cycle to cool the air before it enters the compressor. The document provides background on gas turbine power degradation in hot climates and various air cooling methods. It then describes the proposed coupled gas turbine and reverse Brayton refrigeration cycle system and presents equations for the energy analysis of the cycles. The objective is to investigate the potential power boost through both energy and exergy (second law) analysis of the system.
Lecture 3-4: Exergy, Heating and Cooling, Solar Thermalcdtpv
The document discusses various topics related to energy and thermodynamics, including:
1) Different systems that can store 1 kW hr of energy and why we pay more for some forms.
2) The concept of exergy, which quantifies how useful energy is, and how it is lost as heat is converted to less useful forms.
3) Examples of heat engines and refrigerators/heat pumps, and calculations of their maximum possible efficiencies.
4) Ways of improving energy efficiency for heating, such as reducing heat loss, increasing heat pump coefficients of performance, and using combined heat and power systems.
Engineering thermodynemics-difference between heat and workKaushal Patel
Heat and work are both forms of energy transfer but they differ in key ways. Work is the energy transferred by a force acting through a distance and is dependent on the path, while heat is transferred between systems or a system and its surroundings due to a temperature difference and is dependent on the state. Specifically, work is defined as pressure-volume work in thermodynamics and is a function of the path, whereas heat is defined as the transfer of energy between bodies with different temperatures and is a function of the system's state. While both are transient quantities during state changes, work can be more efficiently converted to other forms of energy than heat.
This document provides an introduction and overview of energy and exergy analyses of power cycles presented by Dr. Luis R. Rojas-Solórzano. It begins with definitions of key concepts in thermodynamics such as the zeroth, first, and second laws of thermodynamics. It then discusses properties of pure substances and ideal gases, including state equations and thermodynamic tables. The document concludes by defining work, heat, and the first law of thermodynamics.
The document discusses exergy analysis of thermal systems. Exergy analysis is based on the conservation of mass, conservation of energy, and the second law of thermodynamics. Exergy analysis can be used to design thermal systems, reduce inefficiencies in existing systems, and evaluate system economics. Exergy, unlike energy, is not conserved and can be destroyed by irreversibilities as a system approaches equilibrium with its environment. The document provides examples of calculating the specific exergy of systems.
Energy and exergy analysis of a 250 mw coal fired thermal power plant at diff...eSAT Journals
Abstract In this present investigation exergy and energy efficiencies of a coal fired 250 MW thermal power plant operating in eastern part of India are determined both for 100% and 90% load based on actual operating data. The efficiencies are evaluated for the overall plant as well as for different equipments like boiler, turbine, all feed water heaters and condenser. Similarly effectiveness of the feed water heaters is evaluated for both the loads. Exergy destruction % for each of the equipment are also given for clear understandingof the loss of available energy due to irreversibilities involved in the processes for each equipment and the whole plant. It is observed that a major irreversibility or, exergy destruction takes place at boiler though 1st law energy efficiency is quite high. This signifies that there might have further scope of improvement in this equipment. Similar analyses are carried out for other equipments. The results obtained in present analysis are compared with those of other investigators. Keywords: Energy, Exergy, Efficiency, Effectiveness, Exergy destruction, Power plant
The document discusses the concept of exergy, which is a measure of the available useful work in a system or flow of matter and energy. Exergy is defined as the maximum theoretical useful work obtained as the system is brought into equilibrium with its surroundings. The document covers definitions of heat, work and exergy, as well as exergy of closed and open systems. It also discusses exergy change, effectiveness and loss of exergy due to irreversibilities. Several example problems are provided to calculate exergy values and changes for various thermodynamic processes.
Energy and exergy analysis of reverse brayton refrigerator for gas turbine po...fsnexuss
This document discusses energy and exergy analysis of a proposed system to boost gas turbine power output using a reverse Brayton refrigerator. The system involves extracting a portion of compressed air from the gas turbine compressor and running it through a reverse Brayton refrigeration cycle to cool the air before it enters the compressor. The document provides background on gas turbine power degradation in hot climates and various air cooling methods. It then describes the proposed coupled gas turbine and reverse Brayton refrigeration cycle system and presents equations for the energy analysis of the cycles. The objective is to investigate the potential power boost through both energy and exergy (second law) analysis of the system.
Lecture 3-4: Exergy, Heating and Cooling, Solar Thermalcdtpv
The document discusses various topics related to energy and thermodynamics, including:
1) Different systems that can store 1 kW hr of energy and why we pay more for some forms.
2) The concept of exergy, which quantifies how useful energy is, and how it is lost as heat is converted to less useful forms.
3) Examples of heat engines and refrigerators/heat pumps, and calculations of their maximum possible efficiencies.
4) Ways of improving energy efficiency for heating, such as reducing heat loss, increasing heat pump coefficients of performance, and using combined heat and power systems.
Engineering thermodynemics-difference between heat and workKaushal Patel
Heat and work are both forms of energy transfer but they differ in key ways. Work is the energy transferred by a force acting through a distance and is dependent on the path, while heat is transferred between systems or a system and its surroundings due to a temperature difference and is dependent on the state. Specifically, work is defined as pressure-volume work in thermodynamics and is a function of the path, whereas heat is defined as the transfer of energy between bodies with different temperatures and is a function of the system's state. While both are transient quantities during state changes, work can be more efficiently converted to other forms of energy than heat.
(1) Availability analyses determine the maximum work possible from a device given a fuel amount. (2) Available energy is the maximum portion convertible to useful work by ideal processes reducing the system to equilibrium. The remainder is unavailable energy. (3) The theoretical maximum work from a system at state p1, T1 operating with a reservoir at p0, T0 is called availability. (4) Availability accounts for both work against resisting forces and the environment.
The document summarizes the four laws of thermodynamics:
1) The first law states that energy cannot be created or destroyed, only changed in form.
2) The second law states that the entropy of an isolated system always increases.
3) The third law states that the entropy of a system approaches a minimum, zero, as the temperature approaches absolute zero.
4) There is no universally accepted fourth law, but some proposals include the Onsager reciprocal relations regarding heat and matter flow parameters.
This document discusses availability and irreversibility in transient and steady flow systems. It provides definitions for available energy, unavailable energy, dead state, and effectiveness. It examines availability in terms of the first and second laws of thermodynamics. Equations are given for calculating maximum work, availability, and irreversibility for various thermodynamic processes involving changes in temperature, pressure, and volume. Two sample problems are included and solved to demonstrate calculating work, availability change, and irreversibility for specified thermodynamic systems.
THERMODYNAMICS For Mechanical and Industrial EngineeringKum Visal
This document provides an introduction to key concepts in thermodynamics. It defines thermodynamics as the study of energy and properties of systems. A system is defined, along with properties, states, processes, cycles, extensive/intensive properties, phases, pure substances, and equilibrium. Examples are provided to illustrate these concepts. Common units used in thermodynamics like the Pascal, bar, and atmosphere are defined. Specific volume, density, molecular weight and their relationships are covered. Finally, different temperature scales (Celsius, Fahrenheit, Kelvin, Rankine) and their conversions are explained.
Thermodynamics is the branch of physics that studies heat, work, and energy. It is governed by four main laws:
1) The zeroth law establishes that thermal equilibrium is transitive.
2) The first law states that energy is conserved and the change in a system's internal energy equals heat added minus work done.
3) The second law specifies that entropy always increases for isolated systems undergoing spontaneous processes and heat cannot be fully converted to work.
4) The third law affirms that entropy reaches a minimum, zero for perfect crystals, as temperature approaches absolute zero.
This document discusses entropy in engineering thermodynamics. It defines entropy as a function that shows the possibility of converting heat into work. Entropy increases at a lower rate when heat is added at high temperatures compared to low temperatures. Maximum entropy corresponds to minimum availability to convert heat into work, and minimum entropy corresponds to maximum availability. Entropy can be considered a measure of microscopic disorder in a system. Irreversible processes are associated with a transition from ordered to more disordered states of energy. Mixing gases increases entropy by creating a more random arrangement. Characteristics of entropy include: it is a property of the system, changes depend on temperature for reversible processes, and it is an extensive property expressed in units of energy per degree of temperature.
Thermodynamics is the study of energy and its transformation. It deals with the relationship between heat, work, and the physical properties of substances. Thermodynamics can be studied through both a microscopic approach considering molecular behavior, and a macroscopic approach considering average properties without molecular details. A thermodynamic system is defined as a quantity of matter bounded by a surface, and can be classified as closed, open, or isolated depending on its interactions with the surroundings. Key thermodynamic properties describe the state of a system.
Thermodynamics is the science concerned with heat and its transformation into mechanical energy. The three laws of thermodynamics state that energy cannot be created or destroyed, heat cannot spontaneously flow from a cooler to a hotter body, and the entropy of a system approaches a constant value as the temperature approaches absolute zero. Thermodynamics describes the efficiency of converting heat into work using heat engines based on concepts such as internal energy, reversible and irreversible processes, and thermal equilibrium. The maximum theoretical efficiency is obtained by Carnot's ideal heat engine undergoing fully reversible processes.
This document discusses the First Law of Thermodynamics and the transfer of energy between chemical reaction systems and their surroundings. The First Law states that energy is conserved and can be transferred as either work or heat. It defines internal energy (ΔU) as the change in energy of a system, which can be altered by work (w), heat (q), or both. Work is a mechanical transfer of energy while heat is energy transferred between objects upon contact. The document provides examples of defining systems and surroundings, calculating work, and identifying exothermic and endothermic processes.
The document summarizes the first law of thermodynamics. It states that energy cannot be created or destroyed, only changed from one form to another. The total amount of energy in the universe remains constant. Energy exists in many forms, including mechanical, heat, light, chemical and electrical. Thermodynamics is the study of energy and how it is transferred or changed from one system to another or between systems and their surroundings.
This document discusses the four laws of thermodynamics:
1) The zeroth law defines temperature as a property of a system such that systems in thermal equilibrium have the same temperature.
2) The first law states that energy is conserved and can change forms but not be created or destroyed. It defines the relationship between changes in internal energy of a system and heat/work.
3) The second law states that the entropy of an isolated system never decreases, and perpetual motion machines of the second kind are impossible. It relates entropy to heat transfer.
4) The third law states that the entropy of a system approaches a constant minimum value as temperature approaches absolute zero.
This document discusses key concepts in kinetic theory, thermodynamics, and ideal gases. It defines an ideal gas as one mole of substance at a specific temperature, volume, and pressure. Kinetic theory describes gases as particles in random collision. The ideal gas law relates pressure, volume, and temperature. Thermodynamics' first law is the conservation of energy, while the second law is that heat flows from hot to cold objects. Heat engines convert thermal energy to mechanical work. Two examples calculate volume of gas at standard temperature and pressure and change in internal energy using the first law of thermodynamics.
the branch of physical science that deals with the relations between heat and other forms of energy (such as mechanical, electrical, or chemical energy), and, by extension, of the relationships between all forms of energy.
The Entropy is a thermodynamic property of a working substance and serves as a valuable tool in the second law analysis of engineering devices.
Entropy is a function of a quantity of heat which shows the possibility of conversion of that into work.
Entropy is a thermodynamic property; it can be viewed as a measure of disorder i.e. More disorganized a system the higher its entropy.
“ When a system undergoes a complete cyclic process, the integral of around the cycle is less than zero.”
Mathematically : ( ) ≤ 0
δQ is energy flow into the system due to heating and T being absolute temperature of the body when that energy is absorbed.
The following equation must be found true for any cyclical process that is possible, reversible or not.
This document provides an overview of thermodynamics basics. It discusses that thermodynamics is concerned with how energy is stored and transformed through heat and work. The first law of thermodynamics states that energy is conserved and cannot be created or destroyed. A thermodynamic system and its boundary with the surroundings are defined. Various thermodynamic processes like isothermal, adiabatic, and isobaric processes are also summarized. Key concepts like thermal energy, temperature, heat transfer methods, and the second law of thermodynamics are briefly explained.
Heat and thermodynamics - Preliminary / Dr. Mathivanan VelumaniMathivanan Velumani
The document discusses key concepts in thermodynamics including:
1. Thermodynamic states are characterized by macroscopic properties like temperature, pressure, and volume that determine a system's internal state and interaction with external bodies.
2. Thermal equilibrium exists when temperature is uniform throughout a system, as stated by the zeroth law of thermodynamics.
3. Internal energy (U) is the energy associated with the random, disordered motion of molecules within a system.
Thermodynamics is the branch of science concerned with heat, temperature, energy, and their relationships. It describes the behavior of these quantities through the four laws of thermodynamics. Heat engines convert thermal energy to mechanical work by transferring heat between a high and low temperature source. The efficiency of heat engines is limited by Carnot's theorem. Refrigerators and heat pumps move heat from low to high temperature areas using a working fluid and mechanical work, operating based on thermodynamic cycles.
The document summarizes the four laws of thermodynamics:
1) The zeroth law establishes thermal equilibrium and allows for temperature measurement.
2) The first law states that energy is conserved and heat and work are interchangeable.
3) The second law says that entropy always increases in spontaneous processes and disorder increases.
4) The third law establishes that entropy reaches zero at absolute zero temperature.
Here are the key steps to derive the expression for heat of reaction at constant pressure:
1) For a chemical reaction occurring at constant pressure, the enthalpy change (ΔH) is equal to the heat absorbed or released by the system (qP).
2) Enthalpy change (ΔH) is defined as the change in internal energy (ΔU) plus the product of pressure (P) and change in volume (ΔV).
ΔH = ΔU + PΔV
3) For a reaction at constant pressure, the volume change (ΔV) is small and pressure remains constant.
4) From the first law of thermodynamics, the change in internal energy (Δ
This document provides an overview of the course MCT-114: Fundamentals of Thermal Sciences. The objectives of the course are to provide a solid grounding in engineering thermodynamics and its fundamental concepts. Topics covered include the basic concepts, laws of energy, ideal gas model, entropy, and power/refrigeration cycles. The course also introduces heat transfer concepts. The document outlines the suggested textbooks, course learning objectives, and provides an introduction to thermal-fluid sciences, thermodynamics, heat transfer, and fluid mechanics.
This document provides information about P.T.Lee Chengalvaraya Naicker College of Engineering & Technology in Oovery, India. It specifically discusses the Department of Mechanical Engineering course ME3391 Engineering Thermodynamics, Unit I which covers basics, zeroth law, and first law of thermodynamics. The document then provides 15 multiple choice and short answer questions related to concepts covered in Unit I such as closed and open systems, intensive/extensive properties, steady flow processes, reversible processes, and applications of the first law of thermodynamics. It directs the reader to specific thermodynamics textbooks for reference in solving similar problems.
(1) Availability analyses determine the maximum work possible from a device given a fuel amount. (2) Available energy is the maximum portion convertible to useful work by ideal processes reducing the system to equilibrium. The remainder is unavailable energy. (3) The theoretical maximum work from a system at state p1, T1 operating with a reservoir at p0, T0 is called availability. (4) Availability accounts for both work against resisting forces and the environment.
The document summarizes the four laws of thermodynamics:
1) The first law states that energy cannot be created or destroyed, only changed in form.
2) The second law states that the entropy of an isolated system always increases.
3) The third law states that the entropy of a system approaches a minimum, zero, as the temperature approaches absolute zero.
4) There is no universally accepted fourth law, but some proposals include the Onsager reciprocal relations regarding heat and matter flow parameters.
This document discusses availability and irreversibility in transient and steady flow systems. It provides definitions for available energy, unavailable energy, dead state, and effectiveness. It examines availability in terms of the first and second laws of thermodynamics. Equations are given for calculating maximum work, availability, and irreversibility for various thermodynamic processes involving changes in temperature, pressure, and volume. Two sample problems are included and solved to demonstrate calculating work, availability change, and irreversibility for specified thermodynamic systems.
THERMODYNAMICS For Mechanical and Industrial EngineeringKum Visal
This document provides an introduction to key concepts in thermodynamics. It defines thermodynamics as the study of energy and properties of systems. A system is defined, along with properties, states, processes, cycles, extensive/intensive properties, phases, pure substances, and equilibrium. Examples are provided to illustrate these concepts. Common units used in thermodynamics like the Pascal, bar, and atmosphere are defined. Specific volume, density, molecular weight and their relationships are covered. Finally, different temperature scales (Celsius, Fahrenheit, Kelvin, Rankine) and their conversions are explained.
Thermodynamics is the branch of physics that studies heat, work, and energy. It is governed by four main laws:
1) The zeroth law establishes that thermal equilibrium is transitive.
2) The first law states that energy is conserved and the change in a system's internal energy equals heat added minus work done.
3) The second law specifies that entropy always increases for isolated systems undergoing spontaneous processes and heat cannot be fully converted to work.
4) The third law affirms that entropy reaches a minimum, zero for perfect crystals, as temperature approaches absolute zero.
This document discusses entropy in engineering thermodynamics. It defines entropy as a function that shows the possibility of converting heat into work. Entropy increases at a lower rate when heat is added at high temperatures compared to low temperatures. Maximum entropy corresponds to minimum availability to convert heat into work, and minimum entropy corresponds to maximum availability. Entropy can be considered a measure of microscopic disorder in a system. Irreversible processes are associated with a transition from ordered to more disordered states of energy. Mixing gases increases entropy by creating a more random arrangement. Characteristics of entropy include: it is a property of the system, changes depend on temperature for reversible processes, and it is an extensive property expressed in units of energy per degree of temperature.
Thermodynamics is the study of energy and its transformation. It deals with the relationship between heat, work, and the physical properties of substances. Thermodynamics can be studied through both a microscopic approach considering molecular behavior, and a macroscopic approach considering average properties without molecular details. A thermodynamic system is defined as a quantity of matter bounded by a surface, and can be classified as closed, open, or isolated depending on its interactions with the surroundings. Key thermodynamic properties describe the state of a system.
Thermodynamics is the science concerned with heat and its transformation into mechanical energy. The three laws of thermodynamics state that energy cannot be created or destroyed, heat cannot spontaneously flow from a cooler to a hotter body, and the entropy of a system approaches a constant value as the temperature approaches absolute zero. Thermodynamics describes the efficiency of converting heat into work using heat engines based on concepts such as internal energy, reversible and irreversible processes, and thermal equilibrium. The maximum theoretical efficiency is obtained by Carnot's ideal heat engine undergoing fully reversible processes.
This document discusses the First Law of Thermodynamics and the transfer of energy between chemical reaction systems and their surroundings. The First Law states that energy is conserved and can be transferred as either work or heat. It defines internal energy (ΔU) as the change in energy of a system, which can be altered by work (w), heat (q), or both. Work is a mechanical transfer of energy while heat is energy transferred between objects upon contact. The document provides examples of defining systems and surroundings, calculating work, and identifying exothermic and endothermic processes.
The document summarizes the first law of thermodynamics. It states that energy cannot be created or destroyed, only changed from one form to another. The total amount of energy in the universe remains constant. Energy exists in many forms, including mechanical, heat, light, chemical and electrical. Thermodynamics is the study of energy and how it is transferred or changed from one system to another or between systems and their surroundings.
This document discusses the four laws of thermodynamics:
1) The zeroth law defines temperature as a property of a system such that systems in thermal equilibrium have the same temperature.
2) The first law states that energy is conserved and can change forms but not be created or destroyed. It defines the relationship between changes in internal energy of a system and heat/work.
3) The second law states that the entropy of an isolated system never decreases, and perpetual motion machines of the second kind are impossible. It relates entropy to heat transfer.
4) The third law states that the entropy of a system approaches a constant minimum value as temperature approaches absolute zero.
This document discusses key concepts in kinetic theory, thermodynamics, and ideal gases. It defines an ideal gas as one mole of substance at a specific temperature, volume, and pressure. Kinetic theory describes gases as particles in random collision. The ideal gas law relates pressure, volume, and temperature. Thermodynamics' first law is the conservation of energy, while the second law is that heat flows from hot to cold objects. Heat engines convert thermal energy to mechanical work. Two examples calculate volume of gas at standard temperature and pressure and change in internal energy using the first law of thermodynamics.
the branch of physical science that deals with the relations between heat and other forms of energy (such as mechanical, electrical, or chemical energy), and, by extension, of the relationships between all forms of energy.
The Entropy is a thermodynamic property of a working substance and serves as a valuable tool in the second law analysis of engineering devices.
Entropy is a function of a quantity of heat which shows the possibility of conversion of that into work.
Entropy is a thermodynamic property; it can be viewed as a measure of disorder i.e. More disorganized a system the higher its entropy.
“ When a system undergoes a complete cyclic process, the integral of around the cycle is less than zero.”
Mathematically : ( ) ≤ 0
δQ is energy flow into the system due to heating and T being absolute temperature of the body when that energy is absorbed.
The following equation must be found true for any cyclical process that is possible, reversible or not.
This document provides an overview of thermodynamics basics. It discusses that thermodynamics is concerned with how energy is stored and transformed through heat and work. The first law of thermodynamics states that energy is conserved and cannot be created or destroyed. A thermodynamic system and its boundary with the surroundings are defined. Various thermodynamic processes like isothermal, adiabatic, and isobaric processes are also summarized. Key concepts like thermal energy, temperature, heat transfer methods, and the second law of thermodynamics are briefly explained.
Heat and thermodynamics - Preliminary / Dr. Mathivanan VelumaniMathivanan Velumani
The document discusses key concepts in thermodynamics including:
1. Thermodynamic states are characterized by macroscopic properties like temperature, pressure, and volume that determine a system's internal state and interaction with external bodies.
2. Thermal equilibrium exists when temperature is uniform throughout a system, as stated by the zeroth law of thermodynamics.
3. Internal energy (U) is the energy associated with the random, disordered motion of molecules within a system.
Thermodynamics is the branch of science concerned with heat, temperature, energy, and their relationships. It describes the behavior of these quantities through the four laws of thermodynamics. Heat engines convert thermal energy to mechanical work by transferring heat between a high and low temperature source. The efficiency of heat engines is limited by Carnot's theorem. Refrigerators and heat pumps move heat from low to high temperature areas using a working fluid and mechanical work, operating based on thermodynamic cycles.
The document summarizes the four laws of thermodynamics:
1) The zeroth law establishes thermal equilibrium and allows for temperature measurement.
2) The first law states that energy is conserved and heat and work are interchangeable.
3) The second law says that entropy always increases in spontaneous processes and disorder increases.
4) The third law establishes that entropy reaches zero at absolute zero temperature.
Here are the key steps to derive the expression for heat of reaction at constant pressure:
1) For a chemical reaction occurring at constant pressure, the enthalpy change (ΔH) is equal to the heat absorbed or released by the system (qP).
2) Enthalpy change (ΔH) is defined as the change in internal energy (ΔU) plus the product of pressure (P) and change in volume (ΔV).
ΔH = ΔU + PΔV
3) For a reaction at constant pressure, the volume change (ΔV) is small and pressure remains constant.
4) From the first law of thermodynamics, the change in internal energy (Δ
This document provides an overview of the course MCT-114: Fundamentals of Thermal Sciences. The objectives of the course are to provide a solid grounding in engineering thermodynamics and its fundamental concepts. Topics covered include the basic concepts, laws of energy, ideal gas model, entropy, and power/refrigeration cycles. The course also introduces heat transfer concepts. The document outlines the suggested textbooks, course learning objectives, and provides an introduction to thermal-fluid sciences, thermodynamics, heat transfer, and fluid mechanics.
This document provides information about P.T.Lee Chengalvaraya Naicker College of Engineering & Technology in Oovery, India. It specifically discusses the Department of Mechanical Engineering course ME3391 Engineering Thermodynamics, Unit I which covers basics, zeroth law, and first law of thermodynamics. The document then provides 15 multiple choice and short answer questions related to concepts covered in Unit I such as closed and open systems, intensive/extensive properties, steady flow processes, reversible processes, and applications of the first law of thermodynamics. It directs the reader to specific thermodynamics textbooks for reference in solving similar problems.
This document provides information about P.T.Lee Chengalvaraya Naicker College of Engineering & Technology in Oovery, India. It specifically discusses the Department of Mechanical Engineering course ME3391 Engineering Thermodynamics, Unit I which covers basics, zeroth law, and first law of thermodynamics. The document then provides 15 multiple choice and numerical problems related to thermodynamics concepts like systems, properties, processes, laws of thermodynamics, cycles and applications to devices like turbines, nozzles and compressors. It directs the reader to specific thermodynamics textbooks for reference in solving similar problems.
Análisis del balance energético en un dispositivo de oxidación catalítica de ...21012955
This document analyzes the energy balance of a catalytic preheating oxidation device. It discusses concepts related to energy balance like the first law of thermodynamics, energy transformations, and accounting for all energy flows in industrial processes. Energy balances are used in industries like chemicals, petroleum, and pulp and paper to track energy sources and usage.
Unit 1 thermodynamics by varun pratap singh (2020-21 Session)Varun Pratap Singh
Free Download Link (Copy URL):
https://sites.google.com/view/varunpratapsingh/teaching-engagements
Dear Students,
Please find the Basic Mechanical Engineering (TME-101, 2020-21 Session) Unit One notes in this section.
Topic cover in this section are:
UNIT-1: Fundamental Concepts and Definitions
Definition of thermodynamics, System, Surrounding and universe, Phase, Concept of continuum, Macroscopic & microscopic point of view. Density, Specific volume, Pressure, temperature. Thermodynamic equilibrium, Property, State, Path, Process, Cyclic and non-cyclic processes, Reversible and irreversible processes, Quasi-static process, Energy and its forms, Enthalpy.
Thermodynamics is the study of energy and its transformations between thermal and mechanical forms. Key concepts include systems, properties, state, process, and the laws of thermodynamics. A system is defined as a quantity of matter or space being studied. Properties can be intensive or extensive, and two intensive properties are required to define the state of a simple compressible system. A process is a change in a system from one equilibrium state to another. The first law concerns conservation of energy, and the second law concerns the direction of spontaneous processes and the irreversibility of real processes.
Thermodynamics is the study of energy and its transformations between thermal and mechanical forms. Key concepts include systems, properties, state, process, and the laws of thermodynamics. A system is defined as a quantity of matter or space being studied. Properties can be intensive or extensive, and two intensive properties are required to define the state of a simple compressible system. A process is a change in a system from one equilibrium state to another. The first law concerns conservation of energy, and the second law concerns the direction of spontaneous processes and the irreversibility of real processes.
The document presents a new approach to defining entropy in classical thermodynamics. It introduces the concept of internal heat energy (q) as a state function, representing the internal heat energy of the system. It then defines entropy (S) as the sum of two partial differentials - the internal heat energy (dq) divided by temperature (T), plus pressure-volume work (pdV) divided by temperature. This allows entropy to be expressed explicitly as the sum of state functions, satisfying the requirements for a state function definition without needing to restrict it to reversible processes.
The exergy of a system at a given state is the maximum work that can be extracted from it till it reaches the state of thermodynamic equilibrium with its surroundings.
Its concept is very important in all energy-producing, energy-consuming and energy-conveying systems.
Both 1st and 2nd law analyses, i.e., energy and exergy analyses require to be carried out for any energy conversion or energy conveying system, to make it more exergy efficient.
The document provides an overview of key thermodynamic concepts including:
1) Thermodynamics examines the transfer of heat and work to produce mechanical energy.
2) Precise definitions are needed for concepts like system, state, property, process, and reversible process.
3) Ideal gas behavior is an excellent approximation for many aerospace applications and the ideal gas law relates pressure, volume, temperature and moles of gas.
GETTING STARTED IN THERMODYNAMICS: INTRODUCTORY CONCEPTS AND DEFINITIONS Kum Visal
Thermodynamics is the study of energy and its transformations between thermal and mechanical forms. A system is defined as the subject of analysis, which has specified boundaries and properties that may change as it undergoes processes or reaches equilibrium states. Thermodynamic properties are either extensive, meaning their values depend on system size, or intensive, with values independent of system size. Temperature, pressure, and specific volume are important intensive properties. The SI system of units is commonly used, with the pascal and kelvin as units of pressure and temperature. A system reaches thermal equilibrium when its intensive properties become uniform throughout.
Thermodynamics deals with concepts of heat, temperature, and energy conversion. Thermal equilibrium occurs between substances when there is no further heat transfer between them. Internal energy is the total energy of all atoms and molecules in a substance due to their random motion. Thermodynamic systems are classified as open, closed, or isolated based on heat and matter transfer ability. The first law of thermodynamics relates heat and work through a mathematical equation. Entropy is a measure of disorder or randomness that increases for energy received by a system and decreases for energy given out. The second law of thermodynamics prohibits heat from spontaneously flowing from cold to hot without work.
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Exergy light version 4
1. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 1 of 26
AN INTRODUCTION TO
THE CONCEPT OF EXERGY
AND ENERGY QUALITY
by
Truls Gundersen
Department of Energy and Process Engineering
Norwegian University of Science and Technology
Trondheim, Norway
Version 4, March 2011
2. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 2 of 26
PREFACE
The main objective of this document is to serve as the reading text for the Exergy topic in
the course Engineering Thermodynamics 1 provided by the Department of Energy and
Process Engineering at the Norwegian University of Science and Technology, Trondheim,
Norway. As such, it will conform as much as possible to the currently used text book by
Moran and Shapiro 1 which covers the remaining topics of the course. This means that
the nomenclature will be the same (or at least as close as possible), and references will be
made to Sections of that text book. It will also in general be assumed that the reader of
this document is familiar with the material of the first 6 Chapters in Moran and Shapiro, in
particular the 1st
and the 2nd
Law of Thermodynamics and concepts or properties such as
Internal Energy, Enthalpy and Entropy.
The text book by Moran and Shapiro does provide material on Exergy, in fact there is an
entire Chapter 7 on that topic. It is felt, however, that this Chapter has too much focus on
developing various Exergy equations, such as steady-state and dynamic Exergy balances
for closed and open systems, flow exergy, etc. The development of these equations is
done in a way that may confuse the non-experienced reader.
In addition, when used in an introductory course on Thermodynamics, it is more important
to provide an understanding about how Exergy relates to Energy Quality, and how various
efficiencies can be developed for Exergy and Energy. This can be done without going into
detailed derivations of Exergy equations, thus there is a need for a simpler text on the
topic, focusing more on the applications of the concept, and this is the background and
main motivation behind this document.
This document is the 4th
version of the Introduction to Exergy and Energy Quality. The 1st
version was written under considerable time pressure in October/November 2008. Any
suggestions for improvements are most welcome; the same applies to information about
detected errors in the text as well as typographical errors.
1. INTRODUCTION
The term Exergy was used for the first time by Rant 2 in 1956, and refers to the Greek
words ex (external) and ergos (work). Another term describing the same is Available
Energy or simply Availability. The term Exergy also relates to Ideal Work as will be
explained later, and Exergy Losses relate to Lost Work.
One of the challenges in Thermodynamics compared to Mechanics is the introduction of
somewhat abstract entities (or properties) describing pVT systems, such as Internal Energy,
Entropy and Exergy. In addition, there are special energy functions such as Enthalpy,
Helmholtz energy and Gibbs (free) energy that are important in thermodynamic analysis
but can be difficult to fully comprehend. While Enthalpy is important for flow processes
(open systems) in Mechanical Engineering Thermodynamics, Helmholtz energy (to define
equations of state) and Gibbs free energy (for physical and chemical equilibrium) are
important in Chemical Engineering Thermodynamics.
3. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 3 of 26
Some text books introduce Internal Energy and Entropy as a way to be able to formulate
the 1st
and 2nd
Laws of Thermodynamics:
• “Assuming there is a property called Internal Energy (symbol U or u in specific form);
then the 1st
Law of Thermodynamics can be formulated for closed and open systems”.
The dynamic Energy balance for an open system in its most general form is then:
2 2
V V
2 2
pcv k
i e
cv cv i i i e e e
i e
dEdE dE dU
dt dt dt dt
Q W m h g z m h g z
(1)
• “Assuming there is a property called Entropy (symbol S or s in specific form); then
the 2nd
Law of Thermodynamics can be formulated for closed and open systems”.
The dynamic Entropy balance for an open system in its most general form is then:
jcv
i i e e cv
j i ej
QdS
m s m s
dt T
(2)
Fortunately, other text books, such as for example Moran and Shapiro 1, make an effort
trying to visualize what these properties really are. Common descriptions for Internal
Energy and Entropy are:
• Internal Energy (U) can be viewed as the Kinetic and Potential Energy at the micro
level of the system; i.e. for atoms and molecules. Kinetic Energy at this level can take
the form of translation, vibration and rotation of the molecules, while Potential Energy
can be related to vibrational and electrical energy of atoms within molecules (vapor or
liquid) or crystals (solids) as well as chemical bonds, electron orbits, etc.
• Entropy (S) can be viewed as a measure of the disorder (or “chaos”) in the system.
More scientifically, it can be said to be a measure of the randomness of molecules in a
system. In recent years, there has been a shift away from using the terms “order” and
“disorder”, to using energy dispersion and the systems inability to do work.
Exergy can also be described in a similar but somewhat more complicated way. Szargut
3 used the following statement to explain the term:
• “Exergy is the amount of work obtainable when some matter is brought to a state of
thermodynamic equilibrium with the common components of its surrounding nature
by means of reversible processes, involving interaction only with the above
mentioned components of nature”.
Since the term “reversible processes” is used in the definition, one could simply say that:
• “The Exergy of a system at a certain thermodynamic state is the maximum amount of
work that can be obtained when the system moves from that particular state to a state
of equilibrium with the surroundings”.
4. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 4 of 26
This is the background why Exergy is related to Ideal Work. It should also be emphasized
that there is a strong link between Exergy and Entropy since Entropy production (the term
cv in the Entropy balance, Equation 2) is equivalent to Exergy Loss (given by 0 cvT ),
which again is equivalent to Lost Work. Also notice that while Exergy is the ability to
produce work, Entropy was previously described as the systems inability to do work.
Finally in this introduction, and as indicated in the very title of this document, Exergy is an
indication of Energy Quality. Different energy forms have different quality (or different
amounts of Exergy) in the sense that they have different capabilities to generate work.
This is the main difference between the 1st
and the 2nd
Laws of Thermodynamics. The
former states that energy is conserved and makes no distinction between energy forms,
while the latter states that energy quality is destroyed, thus the different energy forms have
different energy quality. The energy transformation processes in a system can only
proceed from a higher quality form to a lower quality form unless there is some net input
of energy quality (such as for example work) from the surroundings.
2. THE ENERGY QUALITY OR EXERGY OF HEAT
Before deriving a general mathematical definition that relates Exergy to other state
variables and state functions (i.e. “properties”), the following simple example of
transforming heat to work is used to illustrate the concept of Exergy in its simplest form.
The Kelvin-Planck formulation of the 2nd
Law of Thermodynamics states that net work
cannot be produced from a cyclic thermodynamic process if there is interaction (i.e. heat
transfer) with only one thermal reservoir. The simplistic understanding of this is that heat
cannot be converted to work on a 1:1 basis (i.e. with 100% efficiency), see Figure 1.a. In
fact, the mathematical representation of Kelvin-Planck ( 0cycleW ) indicates that no work
can be produced, and equality ( 0cycleW ) only applies to the reversible case.
Figure 1.a Cyclic process interacting Figure 1.b Cyclic process interacting
with one thermal reservoir with two thermal reservoirs
If, on the other hand, the cyclic thermodynamic process interacts with two thermal
reservoirs (extracts heat QH from a reservoir with temperature TH and delivers heat QC to a
reservoir with temperature TC TH), see Figure 1.b, then some work can be delivered by
the system, ranging from zero to an upper bound given by the 2nd
Law of Thermodynamics
as shown below. For a cyclic process, the 1st
Law of Thermodynamics reduces to:
TH
QH
Wcycle = QH ?
TC
TH
QH
QC
Wcycle = QH QC
TC
5. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 5 of 26
0cycle cycle cycle
cycle cycle H C
U Q W
W Q Q Q
(3)
Notice that the sign convention of Mechanical Engineering Thermodynamics (heat is
positive if received by the system from the surroundings, and work is positive if developed
by the system and applied to the surroundings) is not used here; all entities are regarded to
be positive, and the arrows in Figures 1.a and 1.b indicate the direction of heat and work
between the system (undergoing a cyclic process) and the surroundings.
The work that can be developed from an arrangement as the one in Figure 1.b is then
constrained to be in the following range:
0 1 C
cycle H
H
T
W Q
T
(4)
In Equation 4, one recognizes the maximum thermal efficiency to be that of the Carnot
cycle, which is a reversible cyclic process with 2 adiabatic and 2 isothermal stages:
1 C
c
H
T
T
(5)
Rather than focusing on a cyclic process operating between two thermal reservoirs,
consider an amount of heat Q at a temperature T. The amount of Exergy that this heat
represents is stated by words in Section 1 to be the maximum amount of work (i.e. Ideal
Work) that can be developed if equilibrium is established with the surroundings and only
reversible processes are involved. A common definition of the surroundings is (despite of
variations in climate across the world) a large thermal reservoir with a fixed temperature
0T = 25ºC (or ≈ 298 K) and a fixed pressure 0p = 1 atm (or ≈ 1 bar).
Using Equation 4 and an analogy to the case in Figure 1.b, the surroundings act as the cold
reservoir, while heat Q at a temperature T is extracted from the hot reservoir. The Exergy
content of heat Q is then the maximum amount of work that can be extracted from this
arrangement:
0
1x max
T
E W Q
T
(6)
Equation 6 illustrates one important fact regarding the Energy Quality of heat. For a given
amount of heat Q, the amount of work that can be produced (and thus its Exergy or Energy
Quality) increases with temperature. Thus, temperature is a quality parameter for heat.
A common graphical illustration of the quality (or Exergy) of heat is shown in Figure 2.
The illustration is made in a Ts-diagram, since heat for internally reversible processes can
be found from the following integral:
Q m Tds (7)
Heat (as a form of energy) can be divided into one part that can produce work, referred to
as Exergy, and one part that cannot be used to produce work, which is commonly referred
6. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 6 of 26
to as Anergy. For heat Q at temperature T, the following decomposition can be made with
reference to the ambient temperature 0T :
Energy Exergy Anergy (8)
Unfortunately, Equation 8 only applies to heat, and this kind of Exergy will later be
referred to as temperature based Exergy. When also considering pressure and
composition, the simple relation in Equation 8 can no longer be used.
Figure 2 Decomposition of Energy (Heat) into Exergy and Anergy
3. EXPRESSIONS FOR THERMO-MECHANICAL EXERGY
In the more general case, the System is more than an amount of heat, and the calculation of
Exergy becomes a bit more complicated. Consider next a process stream with temperature
1T and pressure 1p with negligible kinetic and potential energies. The traditional control
volume used by Moran and Shapiro 1 to discuss mass, energy and entropy balances for
open systems (flow processes) is replaced by an idealized device used by Kotas 4 to
develop expressions for Exergy. This device is shown in Figure 3.
Figure 3 A reversible device (module) for determining thermo-mechanical Exergy
It should be emphasized that the heat transfer to/from the ideal reversible module in Figure
3 takes place at ambient temperature 0T , and that the work produced is the maximum
T (K)
s (kJ/kg·K)
T
T0
Exergy
Anergy
0
Reversible
physical
processes
Environment
cvQ
cvW
1 1,p T 0 0,p T
0 0( , )p T
Reversible
physical
processes
Reversible
physical
processes
Reversible
physical
processes
Environment
cvQ
cvW
1 1,p T 0 0,p T
0 0( , )p T
7. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 7 of 26
possible (since the processes in the device are reversible) when the process stream at a
state or condition 1 1,p T is brought to equilibrium with its natural surroundings, here
referred to as the environment, which is at the thermodynamic state of 0 0,p T .
An energy balance can be developed for our system from Equation 1, assuming steady
state and neglecting the changes in kinetic and potential energy for the process stream and
the ideal device. The corresponding Equation 9 includes the change of state for the stream
passing through the ideal device in Figure 3, as well as the exchange of heat and work.
1 00 ( )cv
cv cv
dE
Q W m h h
dt
(9)
Similarly, the entropy balance assuming no irreversibilities can be developed from
Equation 2:
1 0
0
0 ( )cv cvdS Q
m s s
dt T
(10)
Equation 10 can be solved to establish an expression for specific heat transfer:
0 0 1( )cvQ
T s s
m
(11)
Equation 9 can then be solved with respect to specific work (deliberately changing the sign
of the enthalpy terms):
0 0 1 0 1( ) ( )cvW
T s s h h
m
(12)
Exergy was introduced in Section 1 as the maximum amount of work that can be obtained
when the system moves from a particular thermodynamic state to a state of equilibrium
with the surroundings. This change in thermodynamic state is exactly what is happening
for the device in Figure 3. Since Exergy is related to the ability to produce work, it is
obvious that Exergy as a property of the system (in this case the stream at condition 1 1,p T )
will decrease when work is produced.
Using the sign convention applied in Mechanical Engineering Thermodynamics, work is
positive when following the direction of the arrow in Figure 3. The corresponding Exergy
change will have the opposite sign. In fact, the following general relation can be given:
x idealE W (13)
Equation (13) is more relevant when considering processes between two thermodynamic
states for a system. Exergy can also be viewed as an “absolute” property and measured by
the work obtained when the system moves from its current state to a state of equilibrium
with the surroundings. The specific Exergy of the process stream entering the ideal device
in Figure 3 can be derived from Equation 12 as follows:
,1 0 0 1 0 1 1 0 0 1 0( ) ( ) ( ) ( )xe T s s h h h h T s s (14)
8. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 8 of 26
The change in specific Exergy when a system undergoes a process from thermodynamic
state 1 to state 2 is then given by the following expression (notice that the Enthalpy and
Entropy functions at the surrounding conditions ( 0 0,h s ) cancel due to subtraction):
,2 ,1 2 1 0 2 1 0( ) ( ) ( )x x xe e e h h T s s h T s (15)
Kotas 4 introduced the term specific exergy function, and it can be established by a
simple rearrangement of Equation 15:
,2 ,1 2 0 2 1 0 1( ) ( )x xe e h T s h T s (16)
The specific exergy function and the corresponding total exergy function B are not
important for this document, but they are included to show similarity with another energy
function often used for physical and chemical equilibrium in Chemical Engineering
Thermodynamics called Gibbs free energy G. These three functions are shown in
Equation (17).
0
0
h T s
B H T S
G H T S
(17)
The situation illustrated by the device in Figure 3 only relates to pressure and temperature
changes; the issue of chemical composition is not included. Further, since changes in
kinetic and potential energy are ignored, the remaining exergy is only related to pressure
and temperature and is referred to as thermo-mechanical Exergy. The change in total
thermo-mechanical Exergy for a system is given by:
( )
0
tm
xE H T S (18)
4. CLASSIFICATION AND DECOMPOSITION OF EXERGY
The classification of Exergy can be done in a way that is similar to the classification of
energy, with some exceptions, see Figure 4. Emphasis in this document and in the course
Engineering Thermodynamics 1 is on Thermo-mechanical Exergy.
Figure 4 Classification of Exergy for pVT systems
Exergy
Physical Chemical
Mechanical
Thermo-
mechanical
Kinetic Potential
Temperature
based
Pressure
based
Mixing &
Separation
Chemical
Reaction
9. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 9 of 26
As indicated in Figure 4, Thermo-mechanical Exergy can be decomposed into a pressure
based part and a temperature based part. This decomposition has no real fundamental
significance, and is only done as a matter of convenience as will be described below. In
fact, the decomposition is not even unique, which underlines its lack of a deeper meaning.
Consider a system at thermodynamic state p, T that undergoes a set of reversible processes
to end up at a thermodynamic state in equilibrium with the surroundings 0 0,p T , where
equilibrium for pressure and temperature simply means equality.
The lack of uniqueness in the decomposition of thermo-mechanical Exergy is illustrated in
Figure 5, where two logical (“extreme”) paths (sets of processes) can be followed from the
actual state to equilibrium with the surroundings. These paths are (a+b) and (c+d). In
addition, both pressure and temperature could change simultaneously as indicated by path
(e). In the literature, there is some common agreement, that the temperature based part of
Exergy relates to first bringing the temperature of the system from T to 0T while keeping
the pressure constant at p. The pressure based part of Exergy then relates to the change in
pressure from p to 0p while keeping the temperature constant at 0T .
This decomposition is given by the path (a+b) in Figure 5. It should be emphasized that
other decompositions, such as path (c+d), would give different results for the temperature
based and the pressure based components. The total change in thermo-mechanical Exergy
is, of course, independent of the selected path, since Exergy is a property of the system.
Figure 5 Decomposition of Thermo-mechanical Exergy
The decomposition of thermo-mechanical Exergy can be illustrated for the simple case of
an ideal gas. Equation 14 shows that thermo-mechanical Exergy relates to Enthalpy and
Entropy as repeated in Equation (19):
( )
0 0 0( ) ( )tm
xe h h T s s (19)
By using the definition of temperature and pressure based Exergy given above in words,
the following general expressions can be used to describe these two components of
thermo-mechanical Exergy with reference to Figure 5:
( )
0 0 0( , ) ( , ) ( , ) ( , )T
xe h T p h T p T s T p s T p (20)
T (K)
p (bar)
T
T0
p0 p
d
c
a
b
e
10. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 10 of 26
( )
0 0 0 0 0 0 0( , ) ( , ) ( , ) ( , )p
xe h T p h T p T s T p s T p (21)
For ideal gas, Enthalpy is only a function of temperature, while Entropy is a simple
function of both pressure and temperature. Equations 22 and 23 show these ideal gas
relations for Enthalpy and Entropy respectively.
( )pdh c T dT (22)
( )p
dT dp
ds c T R
T p
(23)
A further simplification can be made by assuming constant specific heat capacity, cp.
Equations 22 and 23 can then be integrated from state (T0,p0) to state (T,p) with Enthalpy h
and Entropy s as follows:
0 0( )ph h c T T (24)
0
0 0
ln lnp
T p
s s c R
T p
(25)
By using the mathematical definitions for temperature based and pressure based Exergy
given by Equations 20 and 21, the following expressions can be derived for the case of an
ideal gas with constant specific heat capacities (and thus constant k=cp/cv):
( )
0
0
1 lnT
x p
T
e c T T
T
(26)
( )
0 0
0 0
1
ln lnp
x p
p k p
e T R c T
p k p
(27)
Notice that for ideal gas, the decomposition of thermo-mechanical Exergy is independent
of the chosen path from state (T,p) to state (T0,p0). This is clearly seen from the fact that
the temperature based component only depends on temperature and that the pressure based
component only depends on pressure.
Equations 26 and 27 show that temperature based and pressure based Exergy can be
manipulated individually by changing temperature and pressure respectively. Even more
interesting is the fact that within total thermo-mechanical Exergy, the two components can
be traded-off against each other. This is exploited in low temperature (subambient)
processes. A pressurized gas stream can be expanded to provide extra cooling and some
power. In this operation, pressure based Exergy is converted into temperature based
Exergy. Above ambient, the situation is completely different. A turbine (or expander)
above ambient will take both pressure and temperature closer to ambient conditions, and
as a result both pressure based and temperature based Exergy will be reduced. This is one
explanation why the produced work (or power) is much larger above ambient than below
ambient for the same pressure ratio. Another explanation, of course, is that expansion at
higher temperatures provides more work since the gas volumes are larger.
11. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 11 of 26
In Figure 6, this difference above and below ambient is illustrated by an expander and an
expression for the corresponding work developed in the two cases. Notice that no sign
convention is used in Figure 6 and the effect on produced work is handled by logic. The
change in pressure based Exergy (a reduction) is the background for work being developed
at all in both cases. Above ambient, there is also a reduction in temperature based Exergy
that adds to the work produced. Below ambient, however, the reduced temperature
(increased distance to ambient temperature) increases the temperature based Exergy, and
this results in a reduction of the work developed.
Figure 6 Turbine (expander) above and below ambient
In conclusion, above ambient the main objective for using an expander (not a valve) is to
produce work, while the main objective below ambient is to produce cooling with work as
a byproduct. For a gas based refrigeration cycle (referred to as an inverse Brayton cycle),
an expander is required to be able to reduce the temperature to a point where the working
fluid can absorb heat from the system to be cooled. Using a valve for a working fluid only
operating in vapor phase will only marginally reduce the temperature, since a valve
operates close to isenthalpic, and for an ideal gas, enthalpy only depends on temperature,
not pressure. Even for real gases, enthalpy changes are moderate with changing pressure.
Considering ideal gas and isentropic expansion/compression, Equation 28 can be derived
(see Moran and Shapiro 1) for the relationship between temperature and pressure:
1
2 2
1 1
k
k
T p
T p
(28)
Equation 28 can be used to calculate the outlet temperature from an expander or
compressor when the inlet temperature is known as well as the pressure ratio.
Example 1:
Consider air as an ideal gas being expanded from 5 bar to 1 bar assuming reversible and
adiabatic (i.e. isentropic) operation of the expander. Two cases will be analyzed, one case
above ambient, where the ideal gas has an inlet temperature of 250ºC (523 K), and one
case below ambient, where the ideal gas has an inlet temperature of -50ºC (223 K).
Assume ambient temperature to be 25ºC (298 K) and ambient pressure to be 1 bar. In the
calculations, air can be assumed to have the following properties:
ambient
Exp ( ) ( )
( )p T
W m e e
1 1,p T
2 2,p T
Exp ( ) ( )
( )p T
W m e e
1 1,p T
2 2,p T
ambientambient
Exp ( ) ( )
( )p T
W m e e
1 1,p T
2 2,p T
Exp ( ) ( )
( )p T
W m e e
1 1,p T
2 2,p T
Exp ( ) ( )
( )p T
W m e e
1 1,p T
2 2,p T
12. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 12 of 26
kJ 8.314 kJ
1.0 , 1.4 , 0.287
kg K 28.97 kg K
p
R
c k R
M
As indicated by Equation 13, the ideal work produced equals the change in Exergy with
opposite sign. Temperature and pressure based Exergy can be obtained from Equations 26
and 27. The two cases will be referred to as case a (above ambient) and case b (below
ambient). The corresponding states before (1) and after (2) expansion will be referred to
as states 1a, 2a and 1b, 2b. The temperature of the ideal gas exiting the expander is found
from Equation 28 for the two cases:
Above ambient: 2aT = 330.2 K , Below ambient: 2bT = 140.8 K
For the case above ambient, the following calculations can be made:
State 1a:
( )
,1
( )
,1
523
1.0 523 298 1 ln 57.38 kJ/kg
298
5
298 0.287 ln 137.65 kJ/kg
1
T
x a
p
x a
e
e
State 2a:
( )
,2
( )
,2
330.2
1.0 330.2 298 1 ln 1.62 kJ/kg
298
1
298 0.287 ln 0 kJ/kg
1
T
x a
p
x a
e
e
The maximum (ideal) work produced by the expander is then:
( ) ( )
(1.62 57.38) (0 137.65) 137.65 55.76 193.41 kJ/kgT pideal
x x
above
W
e e
m
For the case below ambient, the following calculations can be made:
State 1b:
( )
,1
( )
,1
223
1.0 223 298 1 ln 11.40 kJ/kg
298
5
298 0.287 ln 137.65 kJ/kg
1
T
x b
p
x b
e
e
State 2b:
( )
,2
( )
,2
140.8
1.0 140.8 298 1 ln 66.23 kJ/kg
298
1
298 0.287 ln 0 kJ/kg
1
T
x b
p
x b
e
e
The maximum (ideal) work produced by the expander is then:
( ) ( )
(66.23 11.40) (0 137.65) 137.65 54.83 82.82 kJ/kgT pideal
x x
below
W
e e
m
13. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 13 of 26
By expanding air as an ideal gas below ambient temperature, 137.65 kJ/kg of pressure
based Exergy is transformed into 54.83 kJ/kg of temperature based Exergy and 82.82
kJ/kg of work. Above ambient, 137.65 kJ/kg of pressure based Exergy adds to 55.76 kJ/kg
of temperature based Exergy to produce 193.41 kJ/kg of work, i.e. 133.5% more work (or
a factor of 2.3) for the same pressure ratio!
5. EFFICIENCY MEASURES FOR ENERGY
A large number of efficiencies have been proposed in Thermodynamics and elsewhere to
measure the quality of processes and their energy utilization. Great care should be taken
in choosing such efficiencies to make sure the answers given are relevant for the questions
asked. Another common requirement for efficiencies is that they are 0-1 normalized (i.e.
they should preferably have values between 0 and 100%), since relative numbers are easier
to interpret than absolute numbers. This section will review some of the most common
efficiencies used in energy conversion processes, trying to highlight their advantages and
disadvantages.
It is common in various process industries to measure the quality of individual processes
by the specific energy consumption given by the ratio between energy consumption (in
MJ, kWh, etc.) and materials production (in tons of product). This type of efficiency has
the advantage that one can easily compare different plants having the same main product;
however, there are a number of disadvantages as well. First, there is no indication what
the best possible performance is, and secondly, these numbers do not have a meaning
unless they also take into account the energy content of raw materials and products.
5.1 THERMODYNAMIC EFFICIENCIES
In Thermodynamics, the most obvious way to express efficiencies is to compare the real
behavior of a process (or equipment) with the ideal behavior. The term ideal process is
related to the absence of thermodynamic losses, referred to as irreversibilities. When
reversible behavior is combined with the absence of unintended heat transfer (adiabatic),
then the processes are referred to as isentropic.
Unfortunately, one cannot express these efficiencies by a single general equation. In
Mechanical Engineering Thermodynamics there is a need to distinguish between power
producing processes and power demanding processes. The corresponding efficiencies are
given by Equations 29 (power producing processes) and 30 (power demanding processes):
Actual useful energy produced
Ideal (max) useful energy produced
TD (29)
Ideal (min) useful energy required
Actual useful energy required
TD (30)
Isentropic efficiencies for turbines and compressors are examples of such thermodynamic
efficiencies. Consider the turbine and compressor in Figures 7 and 8 operating between an
initial state (1) and a final state (2). Ideal processes would have a final state (2s) where “s”
is an indication of isentropic behavior. This simply means that the entropy in the final
state equals the entropy of the initial state. For a compressor, more work is needed for a
14. Energy and Process Engineering Introduction to Exergy and Energy Quality
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real process than an ideal process. For a turbine, however, less work is produced in a real
process than in an ideal process. This obvious difference is the reason why there is a need
for two expressions for thermodynamic efficiency (Equations 29 and 30).
Figure 7 Isentropic Efficiency for a Turbine (Moran and Shapiro 1)
Figure 8 Isentropic Efficiency for a Compressor (Moran and Shapiro 1)
The mathematical expressions for thermodynamic efficiency, often referred to as
isentropic efficiency, for turbines and compressors are given by Equations 31 and 32:
real 1 2
1 2
ideal
/
/
t
t
st
W m h h
h hW m
(31)
ideal 2 1
2 1
real
/
/
c s
c
c
W m h h
h hW m
(32)
Typical isentropic efficiencies for turbines are in the range 70-90%, while similar numbers
for compressors are in the range 75-85%.
5.2 ENERGY EFFICIENCIES
The 1st
Law of Thermodynamics states that even though Energy can be transformed,
transferred and stored, it is always conserved. Nevertheless, different energy forms have
different quality, and it makes sense to distinguish between useful energy and energy
T
W
1 1,p T
2 2,p T
T
W
1 1,p T
2 2,p T
T
W
1 1,p T
2 2,p T
C
W
2 2,p T
1 1,p T
C
W
2 2,p T
1 1,p T
C
W
2 2,p T
1 1,p T
15. Energy and Process Engineering Introduction to Exergy and Energy Quality
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forms that can not be utilized. Friction, for example, causes energy “losses” in the sense
that the heat developed because of friction is scattered and has a fairly low temperature,
thus it cannot be easily utilized.
The corresponding typical energy efficiency can then be expressed as follows:
Useful Energy from the Process
Useful Energy to the Process
E (33)
This kind of efficiency is often used to measure the quality of steam turbines, gas turbines,
combined cycle power stations, heat pumps and refrigerators. The common term used in
Thermodynamics is thermal efficiency, even though focus is both on heat (thermal energy)
and power (mechanical energy). Figure 9 shows power producing and power demanding
cyclic thermodynamic processes operating between two thermal reservoirs.
Figure 9 Conversion Processes for Power, Heating and Refrigeration
For power producing processes (left part of Figure 9), the heat that is transferred to the
cold reservoir is normally not regarded as useful energy, since the cold reservoir quite
often is air or cooling water. For a steam turbine, the effluent heat could be used for
process heating, if QC is provided in the form of for example LP steam. The turbine will
then be referred to as a back pressure or extracting turbine. The effluent heat could also be
supplied to district heating systems or even fish farming.
The two situations with respect to what happens to the effluent heat in the left part of
Figure 9 can be illustrated by providing two different thermal efficiencies. First, consider
the case where the effluent heat is utilized:
cycle C
E
H
W Q
Q
(34)
If heat losses from the turbine can be neglected, then the thermal efficiency will approach
100%. This kind of efficiency then only deals with book-keeping, and it only detects
possible heat losses from the process (or equipment). A thermal efficiency defined in this
way fails to express the capability of the process to produce power, if that was the main
objective, and it does not indicate how well the process performs relative to ideal (and
reversible) processes. Secondly, consider the case where effluent heat has a temperature
that is too low for the heat to be utilized. The thermal efficiency can then be expressed by
QH
QC
WCycle
Hot Reservoir
TH
TC
Cold Reservoir
QC
WCycle
QH
Hot Reservoir
TH
TC
Cold Reservoir
16. Energy and Process Engineering Introduction to Exergy and Energy Quality
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Equation 35. In this case, the efficiency at least indicates to what extent the process is able
to convert heat into work (or power). The term heat engine (HE) is used to generalize and
cover any system producing power from heat.
cycle
HE
H
W
Q
(35)
The thermal efficiencies for heat engines defined by Equations 34 and 35 have the
advantage of being 0-1 normalized (i.e. values between 0 and 100%). Unfortunately,
when considering heat pumps and refrigeration cycles as indicated by the simple
illustration in the right part of Figure 9, the thermal efficiencies as defined by Equation 33
are no longer (0-1) normalized. The thermal efficiencies for heat pumps (HP) and
refrigeration cycles (RC) are given by Equations 36 and 37 respectively, where a
Coefficient of Performance (COP) is used rather than to indicate that the efficiency
measures are no longer (0-1) normalized.
H
HP HP
cycle
Q
COP
W
(36)
C
RC RC
cycle
Q
COP
W
(37)
For a heat pump, the heat from the cold reservoir is regarded to be “free” and is not
included in the thermal efficiency. Similarly, for the refrigeration cycle, the heat delivered
to the hot reservoir is not regarded as useful energy, and therefore not included in the
thermal efficiency.
The thermal efficiencies provided by Equations 36 and 37 not only could become larger
than one; in fact, they should be significantly larger than one to account for the lower
Energy Quality of heat compared to power as well as to give payback for the investment
cost for the heat pump or refrigeration cycle. As a “rule of thumb”, the COP for a heat
pump should be at least 3-4 to make its use economically feasible.
5.3 CARNOT EFFICIENCIES
A Carnot cycle is a thermodynamic process with 4 reversible stages, where 2 are adiabatic
(thus isentropic) and 2 are isothermal. The Carnot efficiency is then the maximum energy
efficiency of an ideal process converting heat to power or power to heating or cooling.
If the processes illustrated in Figure 9 are assumed to have negligible heat transfer to/from
the surroundings (i.e. there are no losses related to the 1st
Law of Thermodynamics), the
energy efficiencies in Equations 35-37 can be reformulated as follows:
, ,cycle H C C CH H
HE HP RC
H H cycle H C cycle H C
W Q Q Q QQ Q
COP COP
Q Q W Q Q W Q Q
(38)
Further, if the same processes are assumed to be reversible (i.e. there are no losses related
to the 2nd
Law of Thermodynamics), the following relation exists between heat duties and
temperatures (actually the definition of Kelvin as an absolute temperature scale):
17. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 17 of 26
int.
rev.
H H
C C
Q T
Q T
(39)
By combining Equations 38 and 39, the following expressions can be derived for the
Carnot efficiency for heat engines, heat pumps and refrigeration cycles:
, , ,1 , ,C CH
HE C HP C RC C
H H C H C
T TT
COP COP
T T T T T
(40)
If the energy efficiencies of Section 5.2 (that could be referred to as energy conversion
factors) are compared with the Carnot efficiencies as references, one can easily derive
thermodynamic efficiencies for heat engines, heat pumps and refrigeration cycles.
Energy (thermal) Efficiency
Carnot (maximum) Efficiency
E
TD
C
(41)
Since the efficiency defined by Equation 41 compares actual behavior with ideal
performance, it is by definition a thermodynamic efficiency as described in Section 5.1.
Example 2:
To illustrate the use of this “relative” efficiency, consider the refrigeration system in
Figure 10, where the temperature of a freezer is maintained at -5ºC (268 K).
Figure 10 Refrigeration Cycle for a Freezer (Moran and Shapiro 1)
The actual performance can be easily evaluated for the refrigeration cycle:
8000
2.5
3200
C
actual
cycle
Q
COP
W
18. Energy and Process Engineering Introduction to Exergy and Energy Quality
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The best performance (Carnot cycle) can be established based on the temperatures of the
freezer and the environment, while using the expression in Equation 40:
268
9.926
295 268
C
ideal
H C
T
COP
T T
The thermodynamic efficiency can be then found by using Equation 41:
2.5
0.252 25.2%
9.926
actual
TD
ideal
COP
COP
Example 3:
A thorough treatment of the various efficiencies can be found in Skogestad 5, where the
interesting example of an electrical heater is discussed. The example also illustrates the
important difference between energy efficiency and thermodynamic efficiency. As the
name indicates, an electric heater uses electricity (W) to provide heat (Q) to a room where
the temperature is maintained at 20ºC. Since electricity can be converted 100% into work,
it can be regarded as pure Exergy. Obviously, the electric heater also converts electricity
100% into heat. The energy efficiency for the electric heater is then:
Useful Energy out
1.0 100%
Useful Energy in
E
Q W
W W
The same amount of electricity could have been used to operate a heat pump between the
outdoor temperature TC = 5ºC (278 K) and the room temperature TH = 20ºC (293 K). The
maximum heat delivered from such a heat pump can be found by using Equation 40:
, max
293
19.533
293 278
H H
HP C
H C H C
T T
COP Q W W W
T T T T
The thermodynamic efficiency for the electric heater is then:
Useful energy out
0.051 5.1%
Ideal (max) useful energy out 19.533
TD
W
W
This very low thermodynamic efficiency is the background for the classical saying that
“using electricity for heating of buildings is similar to washing the floor with
Champagne”.
5.4 EXERGY EFFICIENCIES
Since this document has a focus on Exergy and Energy Quality, the obvious closure of this
section on various measures for Energy efficiency, is to derive Exergy efficiencies.
Similar to the case with energy (or thermal) efficiency, one can distinguish between total
Exergy and useful Exergy being delivered by the system and compare it with the inlet
Exergy. While counting total Energy does not make much sense (would give efficiencies
very close to 100% in most cases), counting total Exergy could make some sense.
19. Energy and Process Engineering Introduction to Exergy and Energy Quality
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A fundamental difference between Energy and Exergy is that while the former is
conserved, the latter is destroyed in all real processes due to irreversibilities. Figure 11
illustrates that Exergy is lost in two different ways. Internal losses (“destruction”) are
caused by irreversibilities in the process (heat transfer at 0T , chemical reaction,
mixing, unrestricted expansion, etc.); while external losses (“leakage”) are caused by
exergy content in effluent streams that are not utilized (exhaust gases, purge and bleed
streams, cooling water, etc.) An efficiency based on total Exergy would only account for
internal losses (irreversibilities) in the process.
Figure 11 Exergy Flows entering and exiting a Process or Unit Operation
Thus, it is more common to define Exergy efficiency by counting only useful Exergy
being produced (delivered) by the system:
Useful Exergy from the Process
Total Exergy to the Process
Ex (42)
When applying the Exergy efficiency defined by Equation 42 to the case of a heat engine
(for example steam turbine) illustrated in Figure 9 and combining it with Equation 6 that
provides an expression for the Exergy content of heat Q at temperature T, the following
result is obtained (remember that work is pure Exergy):
0 0
/
1 1
cycle cycle H
Ex
H
H H
W W Q
T T
Q
T T
(43)
The numerator in Equation 43 is the previously defined energy (or thermal) efficiency.
The denominator would have been equal to the Carnot efficiency provided that the cold
reservoir in Figure 9 had a temperature 0CT T . For that special case, the following
interesting result is obtained:
E
Ex TD
C
(44)
This equality between thermodynamic efficiency and Exergy efficiency requires that the
heat engine uses the surroundings as its cold reservoir. There are of course similarities
between thermodynamic efficiency and Exergy efficiency, since the former measures
actual performance relative to ideal performance, and Exergy is related to maximum work
Process or
Unit Operation
Exergy
in
Exergy out
Material
& Energy
Streams
Material
& Energy
Streams
20. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 20 of 26
produced with ideal (reversible) operation. When considering a heat pump, the opposite
exercise, i.e. starting with the thermodynamic efficiency, gives the following result:
1
/
C
H
H cycle HE
TD
HC cycle
H C
T
Q
Q W T
T W
T T
(45)
Again, if the heat pump uses the surroundings as its cold reservoir (i.e. 0CT T ), the
numerator becomes the Exergy delivered by the system. The denominator is of course the
Exergy input to the system. Thus, a similar result of equality between thermodynamic
efficiency and Exergy efficiency is obtained, identical to the case with the heat engine
(steam turbine):
Exergy out
Exergy in
TD Ex (46)
6. ENERGY QUALITY
It should be obvious from the previous discussions that different energy forms have
different qualities, meaning that they have different abilities to carry out certain tasks.
Exergy is the most common measure of Energy Quality and relates to the ability to
produce work (see the formal definition in Section 1).
6.1 REVISITING THE EXAMPLE WITH AN ELECTRIC HEATER
The reason why the electric heater in Example 3 had a thermodynamic efficiency of only
5.1% is the fact that high quality energy in the form of electricity (pure Exergy) is
converted into low quality heat at only 20ºC. The thermodynamic efficiency of 5.1% was
established by considering a heat pump operating between the outdoor temperature of 5ºC
and the indoor temperature of 20ºC.
The Exergy efficiency for the same process would be slightly different. Heat at 20ºC has
an Exergy content that can be calculated by Equation 6. Notice, however, that since the
room temperature of 20ºC is slightly below ambient temperature (25ºC), Equation 6 has to
be adjusted as follows:
0
1x
T
E Q
T
(47)
The derivation of Equation 47 is equivalent to the derivation of Equation 6 and uses the
same analogy to Figure 1.b. For subambient cases, however, the surroundings act as the
hot thermal reservoir, while the heat Q at temperature T acts as the cold reservoir. By
remembering that for the electric heater, Q=W, the Exergy efficiency can be calculated:
0
1
Exergy out 298
1 0.017 1.7%
Exergy in 293
Ex
T
W
T
W
21. Energy and Process Engineering Introduction to Exergy and Energy Quality
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Notice that the Exergy efficiency in this case is even lower than the thermodynamic
efficiency. The reason is that Exergy relates the room temperature (20ºC) to ambient
temperature (25ºC), while the thermodynamic efficiency was established by relating the
room temperature to the outdoor temperature (5ºC).
6.2 EXERGY OF VARIOUS ENERGY FORMS
The Energy Quality (or Exergy) of thermal energy (or heat) has been explained in large
detail. Figure 12 shows a graph of the Carnot efficiency (reflecting Exergy) of heat as a
function of temperature using Equation 6 above ambient and Equation 47 below ambient.
When examining Equation 47, the Carnot efficiency of heat actually becomes larger than
100% for temperatures below half of the ambient temperature (expressed in Kelvin):
0
02 0.5 149 K or 124 C
T
T T T T
T
This somewhat surprising result means that below -124ºC, heat (or cold thermal energy) is
more valuable than work. This fact is well known and actually utilized when designing
low temperature (subambient) processes such as LNG and Hydrogen liquefaction.
Figure 12 The Exergy of Heat (or Carnot factor) as a function of Temperature.
Since Energy Quality in the form of Exergy is counted as the ability to produce work, it is
obvious that electricity has the ability to completely be converted into work. In practice,
however, there are some minor losses when electricity is used for example to drive an
electric motor. Closely related is mechanical energy that can be produced by gas and
steam turbines. This energy form is also pure Exergy in the sense that these turbines can
be used to drive compressors and pumps directly (i.e. on the same shaft) without
converting to electricity by the use of a generator.
Even chemical energy is in principle pure Exergy, at least if it could be converted to
electricity without any temperature change (entropy production) in a fuel cell. In practice,
chemical energy (say in fossil fuels) is utilized in combustion to produce steam or run a
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
1.1
-125 -75 -25 25 75 125 175 225 275 325 375 425
C
T
22. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 22 of 26
gas turbine. There are large exergy losses related to combustion reactions, and in a steam
boiler, there are also considerable exergy losses related to heat transfer at large
temperature driving forces between the hot flue gas and the steam system.
6.3 EXERGY AND INDUSTRIAL ECOLOGY
Industrial Ecology is a systems oriented scientific discipline with a strong focus on
environmental impact of human activities. Within Industrial Ecology, Life Cycle
Assessment (LCA) is a well known analysis methodology trying to capture the entire life
span of a product from “cradle” to “grave”.
When dealing with materials, energy forms and sustainability, the Industrial Ecology
community 6 uses Exergy as a measure of quality to answer questions such as:
• Does the human production of one unit of an economic good by method A utilize
more of a resource's exergy than by method B?
• Does the human production of an economic good deplete the exergy of the Earth's
natural resources more quickly than those resources are able to receive exergy?
7. EXERGY ANALYSIS
Exergy Analysis has been extensively used in some areas, more moderately used in other
areas, to evaluate the energy efficiency of power stations, industrial plants and process
equipment. The methodology should be used with care, however, since there are a number
of pitfalls and limitations. First, Exergy Analysis is better suited for analyzing process
equipment (the unit operations level) than total processes (the systems level). Secondly,
the link between Exergy and cost is weak at best; in fact there is often a conflict between
reducing Exergy losses and reducing investment cost.
7.1 EXERGY ANALYSIS OF HEAT EXCHANGERS
Figure 13.a Heat transfer between streams Figure 13.b Heat transfer between streams
at constant temperature with gliding temperatures
T (K)
400
390
500 1500
T (K)
400
300
500 1500
340
380
(kW)Q (kW)Q
Q
Q
23. Energy and Process Engineering Introduction to Exergy and Energy Quality
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Two examples will be considered in this Section. In the first case (Figure 13.a) heat is
transferred from a condensing hot stream to a vaporizing cold stream. Assuming that both
streams contain only a single chemical component, phase change takes place at constant
temperature. In the second case (Figure 13.b); heat is transferred from a hot stream to a
cold stream, where both streams are subject to a change in sensible heat only, with no
phase changes. For the first case, Equation 6 can be used to calculate Exergy changes for
the two participating streams. For the second case, however, new relations have to be
derived for the case of non-constant temperatures.
In the case described by Figure 13.a, Equation 6 can be used to calculate the Exergy loss
of the hot stream at 400 K and the Exergy gain of the cold stream at 390 K when Q as
indicated in Figure 13.a is 1000 kW. Notice that the normal sign convention is not used
here, thus the heat transfer per time Q is regarded as a positive entity for both the hot and
the cold stream. The total (or net) change in Exergy (Exergy destruction due to heat
transfer at 0T ) is then the following:
0 0
, ,
0
1 + 1
1 1 1 1
1000 298 19.1 kW
400 390
x H x H C x C
H C
H C
T T
E m e m e Q Q
T T
Q T
T T
For the second case of heat transfer with changing temperatures (Figure 13.b), a new
formulation has to be established starting with a differential form of Equation 6. For an
infinitesimal amount of heat Q extracted from a hot stream at temperature TH, the
inherent change in Exergy is given by Equation 48. It should be obvious that a stream
giving away heat reduces its ability to produce work, thus its Exergy is reduced, which is
why there is a negative sign in Equation 48. Correspondingly, if heat is supplied to a cold
stream at temperature TC, the inherent change in Exergy is given by Equation 49. It should
be noted that the normal sign convention in thermodynamics is not used here, thus the
infinitesimal amount of heat Q is regarded as a positive entity for both hot streams
(Equation 48) and cold streams (Equation 49).
0
, 1x H
H
T
dE Q
T
(48)
0
, 1x C
C
T
dE Q
T
(49)
In Figure 13.b, the specific heat capacities of the two streams are assumed to be constant,
resulting in linear temperature-enthalpy relations. Integration of Equations 48 and 49 with
varying TH and TC then becomes a simple dT/T integration which results in logarithmic
expressions. The total (or net) change in Exergy (Exergy destruction due to heat transfer
at 0T ) is then:
, , 0
, ,
1 1
x H x H C x C
H LM C LM
E m e m e Q T
T T
(50)
24. Energy and Process Engineering Introduction to Exergy and Energy Quality
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Equation 50 shows that solving the differential equation for a heat exchanger with constant
parameters (cp,H and cp,C) results in an expression that includes the logarithmic mean
temperature for hot and cold streams. With reference to Figure 13.b, these logarithmic
mean temperatures can be calculated as follows:
, ,
,
,
,
400 380
389.92 K
400
lnln
380
H in H out
H LM
H in
H out
T T
T
T
T
, ,
,
,
,
340 300
319.58 K
340
lnln
300
C out C in
C LM
C out
C in
T T
T
T
T
Equation 50 can now be used to calculate the total (or net) change in Exergy for the case
when hot and cold temperatures are changing:
0
, ,
1 1 1 1
1000 298 168.2 kW
389.92 319.58
x
H LM C LM
E Q T
T T
NOMENCLATURE
Symbols
B Total exergy function (in kJ)
pc Specific heat capacity at constant pressure (in kJ/kgK)
vc Specific heat capacity at constant volume (in kJ/kgK)
COP Coefficient of Performance
d Differential operator
E Energy (in kJ or kWh)
xE Exergy (in kJ or kWh)
xE Exergy flow (in kJ/s or kW)
xe Specific exergy (in kJ/kg)
G Gibbs free energy (kJ or kWh)
g Gravitational acceleration (9.81 m/s2
)
H Total enthalpy (in kJ or kWh)
h Specific enthalpy (in kJ/kg)
k Ratio between specific heat capacities
ln Natural logarithm operator
M Molecular weight (or mass) (in kg/kmole)
m Mass (in kg)
m Mass flowrate (in kg/s)
p Pressure of a system (in bar)
Q Heat (in kJ or kWh)
Q Heat flow (in kJ/s or kW)
R Mass based (substance dependent) gas constant (in kJ/kgK)
R Universal (also referred to as ideal) gas constant (8.314 kJ/kmoleK)
25. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 25 of 26
S Total entropy (in kJ/K)
s Specific entropy (in kJ/kgK)
T Temperature of a system (in C or K)
t Time (in s)
U Internal energy (in kJ or kWh)
V Linear velocity (in m/s)
V Total volume of a system (in m3
)
W Work (in kJ or kWh)
W Power (or work per time) (in kW)
z Vertical position (altitude) (in m)
Greek Symbols
Specific exergy function (in kJ/kg)
Change in property
Small (infinitesimal) amount
Efficiency
Entropy production (in kJ/Ks or kW/K)
Subscripts
0 Thermodynamic state with ambient conditions
1 Thermodynamic state
2 Thermodynamic state
actual Actual or real behavior
above Above ambient
below Below ambient
C Cold stream/reservoir or Carnot
c Carnot or compressor
cv Control volume
cycle Cyclic thermodynamic process
E Energy
e Outlet (or exit) streams
Ex Exergy
H Hot stream or reservoir
HE Heat Engine
HP Heat Pump
i Inlet streams
ideal Ideal (reversible) process
in Inlet
. .int rev Internally reversible
j Heat flow identifier
k Kinetic energy
LM Logarithmic mean
max Maximum
out Outlet
p Potential energy or constant pressure
RC Refrigeration Cycle
s Isentropic
t Turbine
26. Energy and Process Engineering Introduction to Exergy and Energy Quality
Truls Gundersen Page 26 of 26
TD Thermodynamic
v Constant volume
x Exergy
Superscripts
p Pressure (part of thermo-mechanical exergy)
T Temperature (part of thermo-mechanical exergy)
tm Thermo-mechanical (exergy)
REFERENCES
1 Moran M.J. and Shapiro H.N., Fundamentals of Engineering Thermodynamics, John Wiley
& Sons, 6th
edition (SI Units), 2010.
2 Rant Z., Exergy, a new word for “technical available work”, Forschung auf dem Gebiete des
Ingenieurwesens (in German), vol. 22, pp. 36-37, 1956.
3 Szargut J., International progress in second law analysis, Energy, vol. 5, no. 8-9, pp. 709-
718, 1980.
4 Kotas T.J., The exergy method of thermal plant analysis, Krieger Publishing Company,
Malabar, Florida, 1995.
5 Skogestad S., Chemical and Energy Process Engineering, CRC Press, Boca Raton, Florida,
2009.
6 Wikipedia, http://en.wikipedia.org/wiki/Exergy , visited 5 March 2011.