Continuous Emission Monitoring system to measure various gaseous polutants which are emiting from the stack.

1. Environnement S.A
1
Solutions for
Continuous Emission Monitoring
Environnement S.A
1
WELL COME
TO
GRASIM INDUSTRIES LIMITED,
CHEMICAL DIVISION ,GANJAM

2. Environnement S.A
2

3. Environnement S.A
3

4. Environnement S.A
4
The Company in few words…
 Founded in 1978 by its current Chairman
 A European leader in the instrumentation sector, with its
headquarter based in Poissy, France (Paris Region)
 More than 600 employees worldwide, including 220 in 3
facilities in France
 A 2016 turnover of 76,6M€, with 78% in Export Market
 An average growth of 10 to 15% per year
 A public company listed on the Alternext stock exchange
market since January 2006
ESA General Presentation

5. Environnement S.A
5
A state of the art Range of Product and Services
ESA General Presentation

6. Environnement S.A
6
Innovation by constant R&D investments
 8 to 10% of annual revenue invested in R&D
 3D conception tools and internal Labs
 Scientific & Technical partnerships
 Member of International working groups
ESA General Presentation
Internal R&D Center

7. Environnement S.A
7
A very large workshop
 10.000 m2 of surface for manufacturing, integration & QC
 Production capacity > 2000 analyzers per year
 4 Quality Control platforms
 1 Dedicated area for integration
ESA General Presentation

8. Environnement S.A
8
Environnement S.A Group in France
ESA General Presentation
ENVIRONNEMENT S.A
Global supplier of
Environmental
instrumentation
(78300 Poissy - France)
Iséo
Environmental Data
Management
Systems
(64210 Bidart - France)
OTI Industry
Industrial instrumentation
specialist
(63800 Cournon d'Auvergne -
France)
Cairpol
Micro
Air Quality Monitoring
Systems
(30340 Alès - France)

9. Environnement S.A
9
ENVIRONNEMENT S.A France
POISSY – Head Quarter
Biarritz, Clermont -Ferrand
Environnement
Italia Spa.
Italy (Milano)
ALTECH
Environment Inc.
USA (Chicago)
Environnement
S.A India Pvt Ltd.
India (Mumbai)
Environnement
China Ltd
China (HK / Beijing)
ESA Deutschland
Germany (Frankfurt)
ESA Worldwide
Distribution Network
> 65 countries
PCME Ltd
UK (Cambridge)
America
Asia
Europe
TDL Sensors.
UK (Manchester)
SWR Engineering
Germany (Schliengen )
NEW
Members
ESA General Presentation
Environnement S.A Group worldwide

10. Environnement S.A
10
An R&D platform of ESA
Dedicated in laser absorption
(TDL) technology
Main Applications : Industrial
processes
Parameters :
NH3, H2O, HCl, HF, CO, O2
Products :
In situ cross duct TDL analyzers
In situ O2 probe
Extractive TDL analyzers
Few in Ambient air monitoring of
special parameters (HCl, HF)
Focus on new acquisition : TDL Sensors Ltd (UK)

11. Environnement S.A
11
Environnement SA India Pvt. Ltd.
– Indian Subsidiary
The Company

12. Environnement S.A
12
Director – CSD
DGM
N.A. SARDESAI
Director – Sales
P. KRISHNA MURTHY
SANJAY K. TRIPATHY
SARADA
SUBRAT SANJEET ANAND
TAPASA R. SAHOO
Engineer-Sales
ASHIK
PRIYA
MAITREYA SIBANANDA
Prabhat(Joda)
Rajesh
Ch. Victor Paul
Durga Prasad
M. Nagaraju
Shilpa Khuntia
Ajit Mohanty
Debasis Sahoo
S. Megha mallhar
Sandip Sethi
Ratiranjan behera
Ramesh Meragu
Engineer CSD

13. Environnement S.A
13
• A 100% Subsidiary of Environnement SA, France
• Combined 10000 Sq. ft. & 50,000 sq. feet Head Office & Factory at Turbhe, Navi
Mumbai for Sales, Administration, Customer Support Service, Projects,
Manufacturing, Integration, Testing, Assembly & Inspections
• State of the Art Training Centre at Factory to meet training requirements of
Customers in India & Asia Pacific and Distributers of ESA, France
• 4 Branch office –Kolkata, Delhi , Bhubaneswar & Chennai
• Resident Engineers in Baroda, Bangalore, Bongaigaon, Haldia, Vizag & Lucknow,
Angul, Rourkela, Sambalpur, Ranchi, Gawhati,
• Average experience of 15 years in the field of Environment Monitoring
The Company

14. Environnement S.A
14
CEMS – Main applications

15. Environnement S.A
15
 A complete range of approved CEMS
 Our CEMS solutions for Gas
 Cold/Dry Extractive NDIR => SEC box + MIR 9000
 In Situ (Short extractive) NDIR => MIR-IS
 Hot extractive NDIR => HOFI box + MIR 9000-H
 Hot extractive FTIR => HOFI box + MIR FT
 Hot extractive FID => Graphite 52M
 Hot extractive CLD => Topaze 32M
 In Situ TDL => LAS300 XD
 Dioxin & Hg samplers => AMESA D & M
 Dust analyzers & Flow monitors
 Fully certified solutions
(MCERT and / or TÜV)
ESA CEMS products range

16. Environnement S.A
16
DRY EXTRACTIVE CEMS

17. Environnement S.A
17
DRY EXTRACTIVE CEMS
ESA – Focus on our CEMS – Dry Extractive

18. Environnement S.A
18
ESA – Focus on our CEMS – Dry Extractive
 SEC sampling box + MIR 9000 analyzer – QAL1
 More than 2000 references all over the world
 More than 20 years return of experience
 Up to 12 simultaneous gas measurement
 Compatible with a lot of applications
 Robust & Proven solution

19. Environnement S.A
19
ESA – Focus on our CEMS – Dry Extractive
 Minimum Certified ranges – MCERTS

20. Environnement S.A
20
ESA – Focus on our AMS – Sampling Probes
 Sampling Probes
 Probe design and material to match with flue gas conditions
 PTFE for Wet process : T° max 140°C
 Hastelloy for acid process: T° max 250°C
 SS for High T° process : T° max 600°C
 Embedded Velocity/Pressure/Temperature measurement (pitot tube)
WARNING not a QAL1 certified solution => For QAL1 certified
solution you need to use PCME SF200/400)
 Flexible heated line Option => to ease integration

21. Environnement S.A
21
ESA – Focus on our AMS – Dry Extractive
 SEC sampling box:
 Sample treatment by permeation dryer + dust filtration
 H2O is removed at the sampling point (residual dew point < 20°C)
 No loss of soluble gases such as HCl, NO2, SO2…
 Sampling transfer by unheated sampling line (up to 100 meters)
 Cost effective solution Vs Heated line
 Measurement on dry gas (H2O correction not required)

22. Environnement S.A
22
ESA – Focus on our AMS – Dry Extractive
 SEC sampling box with NH3 in the flue gas:
 NH3 presence in sample gas affects efficiency of permeation dryer
 Sampling system needs a NH3 Scrubber
 NH3 Scrubber = an Oven to be placed Between Probe & SEC box
 Need a special Bracket to hold the SEC Box

23. Environnement S.A
23
ESA – Focus on our AMS – Dry Extractive
 MIR9000 Multi-gas analyzer
 NDIR + GFC (Gas Filter Correlation) principle
 Up to 12 available measuring parameters:
 HCl/HF/SO2/NO/NO2/CO/CO2/CH4/TOC/N2O
 O2 by integrated paramagnetic analyzer
 Communication : Serial RS422/232 & TCPIP – Analogue (Option)
 CLD Option for low NOx level measurement

24. Environnement S.A
24
ESA – Focus on our AMS – Dry Extractive

25. Environnement S.A
25
ESA – Focus on our AMS – Dry Extractive
 Alternative for SEC box : MIR 9000 “BB”
Heated sampling + gas cooler + MIR 9000 analyzer
 Sampling probe with heated filter
 Heated line 180°C
 Gas cooler (reducing dew point below 4°C)
 IR-GFC MIR9000 analyzer (SO2/CO/NO)
 NOx measurement using external converter
 Mid to High range : 0-200-1500 mg/m3
 No residual H2O measurement

26. Environnement S.A
26
ESA – Focus on our AMS – Dry Extractive
 Upcoming alternative : MIR 9000-L using UV absorption
Heated sampling + gas cooler + MIR 9000-L analyzer
 Hot Sampling with dust filter and gas cooler
 UV absorption MIR9000-L analyzer (based on UV-LED technology)
 Based on new ambient e-Series = Touchscreen color display
 Available for SO2 or NO2 with range 0-200-1000 mg/m3
 Very good sensitivity for low and high ranges
 NOx measurement using converter (GPT principle)
 Soon available for dual SO2/NOx measurement (dual LED monitor)

27. Environnement S.A
27
ESA – Focus on our AMS – Dry Extractive
 Upcoming alternative : MIR 9000-L using UV absorption
Principle of measurement :

28. Environnement S.A
28
ESA – Focus on our AMS – Dry Extractive
 MIR9000 Multi gas analyzer with CLD Option
 Up to 12 available measuring parameters :
 HCl/HF/SO2/CO/CO2/CH4/TOC/N2O (NDIR+GFC)
 NOx (NO+NO2) by CLD
 O2 by paramagnetic analyzer
+ =

29. Environnement S.A
29
ESA – Focus on our AMS – Dry Extractive
 MIR9000 Multi gas analyzer with CLD Option

30. Environnement S.A
30
ESA – Focus on our AMS – Dry Extractive
 Minimum Certified ranges – MCERTS

31. Environnement S.A
31
3U – 19’ Rack version (CLD only)
 A MIR9000-CLD in Rack version for NOx
 Typical application : Ultra low NOx measurement
(< 0-20 mg/m3) in Gas Turbine Power Plants
 The options :
Built-in Optional O2 paramagnetic analyser (0–25%)
Built-in Optional CO2 NDIR analyser (0–20 %)
ESA – Focus on our AMS – Dry Extractive

32. Environnement S.A
32
ESA – Focus on our AMS – Dry Extractive
 Application : Transportable Analyzer for stack testing labs
 NDIR + CLD + Paramagnetic as Reference measuring principles
= 3 Reference Methods in 1 box (Stack Testing Companies)
- CO/CO2 by IR
- NO/NO2/NOx by CLD
- O2 by Paramagnetic
 Transportable version available (analyzer + SEC sampling)

33. Environnement S.A
33
 Multiplexing solution with Cold MVS (2, 3 or 4 stacks)
 Fully automatic (DAHS control) or manual
 Minimum switching sequence = 7,5 min
Cold MVS4
ESA – Focus on our AMS – Dry Extractive

34. Environnement S.A
34
ESA – Focus on our AMS – Dry Extractive
 Our “In Situ” (short extractive) Solution :
MIR-IS Multi gas analyzer
 Integrated solution = SEC sampling box + MIR 9000 analyzer
 NDIR + GFC (Gas Filter Correlation) principle as MIR 9000
 Up to 12 available parameters (same as MIR 9000)
 An industrial IP65 Stainless Steel enclosure
 T° range for installation -10°C to +50°C
 Communication : RS422/232, TCPIP, USB
 A cost effective solution
 Require an easy access to sample point
+ =

35. Environnement S.A
35
ESA – Focus on our AMS – Dry Extractive
 Minimum Certified ranges – MCERTS

36. Environnement S.A
36
ESA – Focus on our AMS – Dry Extractive
 Our “In Situ” Solution for measurement:
MIR-IS Multi gas analyzer – 3 possible installations
 Stack mounting (directly hanged on flange with arm support)
 Stack platform installation (Frame integration with short sample line)
 Ground installation (With LCPD box and heated line up to 40m)

37. Environnement S.A
37
HOT EXTRACTIVE CEMS

38. Environnement S.A
38
Hot extractive CEMS Architecture
MIR 9000 H

39. Environnement S.A
39
 Our heated sampling solution :
HOFI sampling box
 180°C Sampling + dust filtration
 Sampling transfer by 180°C heated line
 Measurement on wet gas
 No loss of soluble gases
 Compatible with NH3/H2O measurements
Standard HOFI box
LCPD box
ESA – Focus on our AMS – Hot Extractive

40. Environnement S.A
40
 Our Solution for measurement:
MIR-FT heated FTIR Multi-gas analyzer
 Fourier Transform Infra Red measuring principle
 Standard list of available measuring parameters :
 HCl/HF/SO2/NO/NO2/CO/CO2/TOC/N2O/NH3/H2O
 O2 by heated zirconium analyzer
 Heated Multiplexer for 2 to 4 channels :
 For Stand by system used
ESA – Focus on our AMS – Hot Extractive

41. Environnement S.A
41
 Minimum Certified ranges – MCERTS
ESA – Focus on our AMS – Hot Extractive

42. Environnement S.A
42
ESA – Focus on our AMS – Hot Extractive
 Our Solution for measurement:
MIR9000-H heated NDIR Multi gas analyzer
 NDIR + GFC (Gas Filter Correlation) principle
 Measurement up to 8 parameters to be selected:
 NH3/H2O
 SO2/NO/NO2/CO/CO2/N2O/HCl/HF
 O2 by heated zirconium analyzer
 Flow-T°-Pressure measurements available
 Communication : RS232/422, TCPIP, USB, Analog
 Applications : Fertilizers, Chemical, Combustion
 Heated Multiplexer for 2 to 4 channels :
 Stand by system can be used

43. Environnement S.A
43
ESA – Focus on our AMS – Hot Extractive
 MIR9000-H : typical integrations

44. Environnement S.A
44
ESA – Focus on our AMS – Hot Extractive
 Minimum certified ranges – TÜV Germany

45. Environnement S.A
45
ESA – Focus on our AMS – Hot Extractive
 Multiplexing system – MVS H (Hot version) :
 2 / 3 or 4 channels version (MVSH2 / MVSH3 or MVSH4)

46. Environnement S.A
46
ESA – Focus on our AMS – Hot Extractive
 Our Solution for specific TOC measurement:
GRAPHITE52M FID analyzer
 Hot FID measuring principle
 Alternative to TOC measurement by NDIR-GFC or FTIR
 H2/He (40%/60%) as fuel gas required
 Communication : RS422/232, TCPIP, Analog
 Transportable version :
 Stack Testing Company
 Standard Reference method use
 2 available versions in Fixed or Transportable type :
 TOC (S type)
 TOC / nmHC / CH4 (D type)

47. Environnement S.A
47
 Certified ranges – MCERTS
ESA – Focus on our AMS – Hot Extractive

48. Environnement S.A
48
CEMS Dilution using Ambient air monitors
Dilution mainly used in specific applications like
petrochemical, refineries (explosion proof area, very
high concentrations, …)
 Long distance between Sampling and Analyzer (>200m),
 Can also be associated with MIR9000 analyzer for very
high measurement range of SO2/CO/NO (%)

49. Environnement S.A
49
Dust Analyzers & Flow monitors
ESA – Focus on our Particulates Analyzers

50. Environnement S.A
50
ESA – Focus on our Particulates Analyzers
 Dust analyser :
 Optical method for dry & wet processes – QAL181 & 181WS
 Electrodynamic method for dry processes – QAL991

51. Environnement S.A
51
 Flow Measurement :
 Multi points Average Pitot tube principle - STACKFLØW 200
 Unique features
 Single stack-mounted probe able to integrate ESA gas probe
 Manual Zero & Span check : Compliant for QAL3
QAL1 Certification
ESA – Focus on Flow measurement

52. Environnement S.A
52
 SF 200
 Technical data
Range for Velocity : 2 - 50 m/s
Approvals : QAL1 TÜV approved according EN16911 & EN15267-3
Resolution : 0,1 m/s
Measurement Units :
– m/s or ft/s (Velocity)
– Nm3/min, kNm3/min, Nm3/h, kNm3/h, CFM*,
kCFM, CFH**, or kCFH (Flow)
Detectable minimum : 2 m/s
Response time : 15 seconds
Linearity deviation :
< 0,3 m/s from 0 to 30 m/s ; < 0,5 m/s from 30 to 50
m/s
Zero drift : < 0,1 m/s over 30 days
Span drift : < 0,1 m/s over 30 days
Probe technology : Average Pitot tube
Available probe length : 0,6 m, 1 m, 1,5 m
Static pressure sensor : 600 hPa - 1100 hPa (+ 1%)
Power supply of the probe: 24 V DC 135 mA (nominal)
Compressed Air supply :
– Dry & clean air,
– Pressure from 2.103 hPa to 6.103 hPa
– Flow for backflush : 20 l/min (i.e. 1,2 m3/h).
T° sensor technology : Pt 100 
Max fumes T°: 500 °C
Operating T° : - 20°C to + 50 °C
Display & Operation : By external Control Unit or remote PC
Analog output : 1 x 4-20 mA isolated for Velocity or Flow
Logic output : 2 x programmable relays
Logic input : 1 remote contact for backflush of the probe
ESA – Focus on Flow measurement

53. Environnement S.A
53
ESA – Focus on our Project Management
 Rack cabinet / shelter / engineering

54. Environnement S.A
54
FOR EACH APPLICATION : PLEASE FILL THE QUESTIONNAIRE
Plant type : MWI HWI , Glassworks ,Power plant , GT ,Cement plant other:
Gas treatment : yes /no , wet process , dry process , DENOx type :
SAMPLING CONDITIONS :
Mounting : Weather protected Outside Platform Elevation/floor : m
Stack Duct Internal diameter : m External diameter: m Thermal insulation thickness: mm
Process temperature: Mini : °C Average : °C Maxi : °C
GAZ STREAM COMPOSITION AND CHARACTERISTICS
ALKALINE : Yes / No ACID : Yes / No
Gaz stream
composition
Components
to measure
Min. Average Max.
Full scale
required
Unit (ppm, mg/m3
,%)
H2O %
Opacity %
Particulate mg/m3
Pressure bar, hPa, mm Hg
Temperature °C
Gaz flow m3
/h
Gas velocity m/s
IMPORTANT : The eventual presence and concentration of following components has to be confirmed :
Components HBr NH3 HF Hg SO3 N2O Alcohol Ketone
Concentration

55. Environnement S.A
55
Application case : Cement Plant
Gases
Kiln Stack
Particulates

56. Environnement S.A
56 5
Main (Kiln) Stack CEMS Technologies
Gases
 In-situ
 TDL
 Extractive (hot & cold)
 FTIR
 NDIR + GFC
 Sorbet trap (Hg &
dioxins)
Particulates
 In-situ
 Scatter (forward &
back)
 Cross-stack
(opacity)
 ElectroDynamic
 Extractive
 Scatter (forward)
Flow
 In-situ
 Ultrasonic
 Averaging Pitot
CEMs Shelter
 Analysers
 DAHS
Extracted gases
& Data to CEMs
Shelter A fully-integrated
CEMs system
Data outputs
from DAHS to
Plant:
 Examples
 4-20mA
 Modbus
 Ethernet
 Etc.

57. Environnement S.A
57
Application case : the 17th cat of Industries
Categories of
Industries
Aluminium Cement Distillery
Chlor
Alkali
Fertilizers
Iron
&
Steel
Oil
refinery
Petrochemical
Power
Plants
Zinc Copper
Emission
Parameters as
per CPCB
requirements
PM, HF
PM, NOx,
SO2
PM
Cl2,
HCl
PM, HF,
NH3
PM,
SO2
PM, CO,
NOx, SO2
PM, CO, NOx,
SO2
PM, NOx,
SO2
PM,
SO2
PM, SO2
Hot/Dry
Extractive
MIR9000 (with
gas cooler)
BRT OPT BRT OPT OPT
Dry Extractive
MIR9000 (with
permeation
dryer)
BRT BRT
In-Situ MIR IS
(with permeation
dryer)
OPT OPT OPT OPT
Hot extractive
MIR9000-H
BRT
Dilution sampling
+ ambient
monitors
OPT BRT BRT BRT OPT BRT BRT
BRT = Best Recommended Technique
OPT : Optional Possible Technique

58. Environnement S.A
58
Environnement S.A… invest for the future
The future is Measured Today!